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RESEARCH PAPER · Journal of the American Chemical Society · 1999

Time-Resolved In-Situ Energy and Angular Dispersive X-ray Diffraction Studies of the Formation of the Microporous Gallophosphate ULM-5 under Hydrothermal Conditions

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Time-Resolved In-Situ Energy and Angular Dispersive X-ray Diffraction Studies of the Formation of the Microporous Gallophosphate ULM-5 under Hydrothermal ConditionsOriginalTime-Resolved in Situ X-ray Powder Diffraction Study of the Formation of Mesoporous Silicates66An in Situ Energy-Dispersive X-ray Diffraction Study of the Hydrothermal Crystallizations of Open-Framework Gallium Oxyfluorophosphates with the ULM-3 and ULM-4 Structures61Aminphosphate als Intermediate bei der Bildung von offenen Gerüststrukturen8Determination of the kinetics of crystallisation of gibbsite using time resolved in situ energy dispersive powder X-ray diffraction32Dynamic neutron and synchrotron X-ray powder diffraction methods in the study of chemical processes19On the advantages of the use of the three-element detector system for measuring EDXRD patterns to follow the crystallisation of open-framework structures49Oxyfluorinated Open Frameworks8The room-temperature crystallisation of a one-dimensional gallium fluorophosphate, Ga(HPO4)2F·H3N(CH2)3NH3·2H2O, a precursor to three-dimensional microporous gallium fluorophosphates60Watching solids crystallise using in situ powder diffraction124Open-framework fluorinated gallium and aluminium phosphates: an in situ study of the hydrothermal synthesis by X-ray diffraction using synchrotron radiation8Exploration of a Simple Universal Route to the Myriad of Open-Framework Metal Phosphates206Building Units Design and Scale Chemistry396Synthesis and characterization of a novel layered zinc phosphate9Spectroscopy of the Formation of Microporous Transition Metal Ion Containing Aluminophosphates under Hydrothermal Conditions39Spectroscopy of the Formation of Microporous Transition Metal Ion Containing Aluminophosphates under Hydrothermal Conditions43Aufbau Principle of Complex Open-Framework Structures of Metal Phosphates with Different Dimensionalities357An in Situ Energy-Dispersive X-ray Diffraction Study of the Hydrothermal Crystallization of Zeolite A. 1. Influence of Reaction Conditions and Transformation into Sodalite130Crystallization of a Large-Pore Three-Dimensional Gallium Fluorophosphate under Mild Conditions37Crystallization of a Large-Pore Three-Dimensional Gallium Fluorophosphate under Mild Conditions7Solvothermal Synthesis and Characterization of a New Titanium Phosphate with a One-Dimensional Chiral Chain48Ambient temperature crystallisation of a lamellar gallium fluorophosphate from the synthesis solution of microporous ULM-518Direct in situ observation of increasing structural dimensionality during the hydrothermal formation of open-framework zinc phosphates53Synthons and design in metal phosphates and oxalates with open architectures44In Situ X-ray Diffraction Studies of the Crystallization of Layered Manganese Thioantimonates(III) under Hydrothermal Conditions75Hydrothermal Synthesis and Characterization of Two New Zinc Phosphates Assembled about a Chiral Metal Complex: [CoII(en)3]2[Zn6P8O32H8] and [CoIII(en)3][Zn8P6O24Cl]·2H2O104Basic building units, self-assembly and crystallization in the formation of complex inorganic open architectures13Piperazine templated 3D fluorogallophosphate: synthesis and characterization of Ga5(PO4)5F4·2[N2C4H12]13Real Time Observation of the Hydrothermal Crystallization of Barium Titanate Using in Situ Neutron Powder Diffraction152Synthesis and structure of a novel open-framework zincophosphate with intersecting three-dimensional helical channels28Utilization of Cyclopentylamine as Structure-Directing Agent for the Formation of Fluorinated Gallium Phosphates Exhibiting Extra-Large-Pore Open Frameworks with 16-ring (ULM-16) and 18-ring Channels (MIL-46)63Two chain gallium fluorodiphosphates: synthesis, structure solution, and their transient presence during the hydrothermal crystallisation of a microporous gallium fluorophosphateElectronic supplementary information (ESI) available: crystal data, atomic coordinates and metrical data for 1 and 2. See http://www.rsc.org/suppdata/cc/b2/b201178f/31Synthesis and Structure of Low-Dimensional Gallium Fluorodiphosphates Seen during the Crystallization of the Three-Dimensional Microporous Gallium Fluorophosphate ULM-334Synthesis and characterization of a new layered gallium phosphate [Co(en)3][Ga3(H2PO4)6(HPO4)3] templated by cobalt complex42In‐situ Energy‐Dispersive X‐ray Diffraction Studies of Crystal Growth and Compound Conversion Under Solvothermal Conditions47Role of Chains in the Formation of Extended Framework Tin(II) Phosphates and Related Materials30Comparison of one-, two-, and three-dimensional iron phosphates containing ethylenediamine20Zur Kinetik der Bildung von Na2PdC28Synthesis of a Single Four-Ring (S4R) Molecular Zinc Phosphate and Its Assembly to an Extended Polymeric Structure: A Single-Crystal and in-Situ MAS NMR Investigation53Chirality Transfer from Guest Chiral Metal Complexes to Inorganic Framework: The Role of Hydrogen Bonding105Synthesis, Crystal Structures, and Properties of Novel Lamellar Gallium Methylenediphosphonates18Studies of Inorganic Layer and Framework Structures Using Time-, Temperature- and Pressure-Resolved Powder Diffraction Techniques0Time-Resolved, In Situ X-ray Diffraction Studies of Staging during Phosphonic Acid Intercalation into [LiAl2(OH)6]Cl·H2O65Kinetic and Mechanistic Investigations of Hydrothermal Transformations in Zinc Phosphates64Two layered gallophosphates assembled about the chiral metal complexes: Co(en)3·Ga3P4O16·5H2O and trans−Co(dien)2·Ga3P4O16·3H2O9[Co(en)3][In3(H2PO4)6(HPO4)3]·H2O: A new layered indium phosphate templated by cobalt complex23In‐situ Energy Dispersive X‐ray Diffraction Studies of the Crystallization of (1, 2‐DAPH2)2Ge9(OH)4O18 · 2 H2O under Solvothermal Conditions32High pressurein situx-ray absorption spectroscopy cell for studying simultaneously the liquid phase and the solid/liquid interface68The Role of Amine Sulfates in Hydrothermal Uranium Chemistry63Studying the Solvothermal Formation of MoO3 Fibers by Complementary In Situ EXAFS/EDXRD Techniques105Untersuchung der solvothermalen Bildung von MoO3‐Fasern mithilfe komplementärer In‐situ‐EXAFS/EDXRD‐Techniken24Hydrothermal synthesis and structures of two zero-dimensional zinc phosphate polymorphs4Polymorphism of [Zn(2,2′‐bipy)(H2PO4)2]26Capturing an Aluminophosphite Intermediate in the New Route of Synthesizing Zeolite-like Aluminophosphates27In-situ XRD as a tool to understanding zeolite crystallization105Growth Kinetics and Cracking of Liquid-Phase-Deposited Anatase Films37Hybrid Porous Solids34Metal-organic frameworks: the young child of the porous solids family62Monitoring of crystallization processes during synthesis of zeolite A by in situ 27Al NMR spectroscopy29Synthesis, Structure, and Photoluminescence Property of a New Layered Zirconium Phosphate |Co(dien)2|[Zr4H8P5O26]·3H2O14Wüstite nanocrystals: Synthesis, structure and superlattice formation29Hybrid porous solids: past, present, future5822Syntheses and structures of two chiral zincophosphite compounds: [Zn(C8H8N2)(HPO3)] and (C6H13N2)[Zn3(C6H12N2)(HPO3)3(H2PO3)]17Structural Effects of Solvents on the Breathing of Metal–Organic Frameworks: An In Situ Diffraction Study210Structural Effects of Solvents on the Breathing of Metal–Organic Frameworks: An In Situ Diffraction Study47In-situ synchrotron diffraction study of the hydrothermal transformation of goethite to hematite in sodium aluminate solutions52Metal Complexes of Organophosphate Esters and Open-Framework Metal Phosphates: Synthesis, Structure, Transformations, and Applications370Kinetic analysis of experimental intensity curves obtained during zeolite a synthesis using in situ 27Al NMR spectroscopy4The Long Story and the Brilliant Future of Crystallized Porous Solids5Phase Transformation of Biphasic Cu2S−CuInS2 to Monophasic CuInS2 Nanorods264Characterization of the gel phases formed in the synthesis of microporous gallophosphate, cloverite3In situ X-ray diffraction study of the hydrothermal crystallization of hierarchical Bi2WO6 nanostructures42The role of synchrotron radiation in examining the self-assembly of crystalline nanoporous framework materials: from zeolites and aluminophosphates to metal organic hybrids47Weathering trajectory of bauxite residue mud as predicted by high-temperature treatment0Observation and Isolation of Layered and Framework Ytterbium Hydroxide Phases Using In Situ Energy-Dispersive X-ray Diffraction56A thermosyphon-driven hydrothermal flow-through cell forin situand time-resolved neutron diffraction studies14An investigation of goethite-seeded Al(OH)3precipitation usingin situX-ray diffraction and Rietveld-based quantitative phase analysis16Strategies for Solid-State NMR Studies of Materials: From Diamagnetic to Paramagnetic Porous Solids77A large volume cell for in situ neutron diffraction studies of hydrothermal crystallizations10Anion Exchange Kinetics of Nanodimensional Layered Metal Hydroxides: Use of Isoconversional Analysis14The application of statistical methodology to the analysis of time-resolved X-ray diffraction data12In‐Situ Monitoring of the Formation of Crystalline Solids251In‐situ‐Verfolgung der Bildung kristalliner Feststoffe69Simple and Mixed Metal Oxides and Hydroxides: Solids with Extended Structures of Different Dimensionalities and Porosities2Uptake of Liquid Alcohols by the Flexible Fe III Metal–Organic Framework MIL‐53 Observed by Time‐Resolved In Situ X‐ray Diffraction47An investigation of the mechanisms of goethite, hematite and magnetite-seeded Al(OH)3 precipitation from synthetic Bayer liquor20In Situ Hydrothermal Synthesis of LiFePO4 Studied by Synchrotron X-ray Diffraction67Recrystallization of metamict allanite11An in situ synchrotron X-ray diffraction investigation of lepidocrocite and ferrihydrite-seeded Al(OH)3 crystallisation from supersaturated sodium aluminate liquor8Single-pass flow-through reaction cell for high-temperature and high-pressurein situneutron diffraction studies of hydrothermal crystallization processes7In situstudies into the formation kinetics of potassium jarosite20Annealing induced recrystallization of radiation damaged titanite and allanite1Controlling Nucleation and Crystal Growth of a Distinct Polyoxovanadate Cluster: An In Situ Energy Dispersive X‐ray Diffraction Study under Solvothermal Conditions30Formation and characterisation of Mn-MIL-100129Influence of preparation method on the catalytic performances of Re2O7/SiO2-Al2O3 catalysts in the metathesis of ethylene and 2-pentene18Hydrothermal–galvanic couple synthesis of directionally oriented BaTiO3 thin films on TiN-coated substrates15Controlled Release Kinetics in Hydroxy Double Salts: Effect of Host Anion Structure6In Situ Studies of Solvothermal Synthesis of Energy Materials159Powder Diffraction3Controlling Allotropism in Ruthenium Nanoparticles: A Pulsed-Flow Supercritical Synthesis and in Situ Synchrotron X-ray Diffraction Study41In situ 27Al NMR kinetic investigation of zeolite A crystallization24Pulsed-Flow Near-Critical and Supercritical Synthesis of Carbon-Supported Platinum Nanoparticles and In Situ X-ray Diffraction Study of Their Formation and Growth9Is Single-4-Ring the Most Basic but Elusive Secondary Building Unit That Transforms to Larger Structures in Zinc Phosphate Chemistry?24Experimental Simulation of Long Term Weathering in Alkaline Bauxite Residue Tailings16An in situ study of resin-assisted solvothermal metal-organic framework synthesis8Exchange of Coordinated Solvent During Crystallization of a Metal–Organic Framework Observed by In Situ High‐Energy X‐ray Diffraction53Exchange of Coordinated Solvent During Crystallization of a Metal–Organic Framework Observed by In Situ High‐Energy X‐ray Diffraction14In SituStudies of the Crystallization of Metal-Organic Frameworks10In Situ Studies on Phase Transitions of Tris(acetylacetonato)-Aluminum(III) Al(acac)321A gel aging effect in the synthesis of open-framework gallium phosphates: structure solution and solid-state NMR of a large-pore, open-framework material7Combined in- and ex situ studies of pyrazine adsorption into the aliphatic MOF Al-CAU-13: structures, dynamics and correlations23Systematic study of the crystallization process of CrAPO-5 using in situ high resolution X-ray diffraction7Mechanistic Aspects in the Formation, Growth and Surface Functionalization of Metal Oxide Nanoparticles in Organic Solvents125Panoramic Synthesis as an Effective Materials Discovery Tool: The System Cs/Sn/P/Se as a Test Case45A multi-purpose reaction cell for the investigation of reactions under solvothermal conditions33Green synthesis of a new layered aluminium citraconate: crystal structures, intercalation behaviour towards H 2 O and in situ PXRD studies of its crystallisation12Green Synthesis of a New Al‐MOF Based on the Aliphatic Linker Mesaconic Acid: Structure, Properties and In Situ Crystallisation Studies of Al‐MIL‐68‐Mes41Formation of a new type of uranium( iv ) poly-oxo cluster {U 38 } based on a controlled release of water via esterification reaction44Lepidocrocite-Type Titanate Formation from Isostructural Prestructures under Hydrothermal Reactions: Observation by Synchrotron X-ray Total Scattering Analyses51Investigation of the Kinetic Stabilization of a Ce4+‐based MOF by in‐situ Powder X‐ray Diffraction26In situ Monitoring of the Formation of [Bis(acetylacetonato)manganese(II)] Complexes10Naturally derived pyroxene nanomaterials: an ore for wide applications1Quantitative Precipitation of Uranyl or Plutonyl Nitrate with N-(1-Adamantyl)acetamide in Nitric Acid Aqueous Solution9Copper Surfaces with Bimodal Nanoporosity by Microstructural Length Scale Controlled Dealloying of a Hypereutectic Al-Cu Alloy3WITHDRAWN: Supercritical solvothermal synthesis and growth mechanism of nano lithium iron phosphate3Near room-temperature formation of Cu3Sn: In-situ synchrotron X-ray diffraction characterization and thermodynamic assessments of its nucleation6In situ scattering studies of material formation during wet-chemical syntheses1Solvothermal and hydrothermal methods for preparative solid-state chemistry5Application of ultrafast x-ray lasers in studying the material structure under shock compression1

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