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RESEARCH PAPER · Journal of the American Chemical Society · 2001

Real Time Observation of the Hydrothermal Crystallization of Barium Titanate Using in Situ Neutron Powder Diffraction

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Real Time Observation of the Hydrothermal Crystallization of Barium Titanate Using in Situ Neutron Powder DiffractionOriginalSubcritical solvothermal synthesis of condensed inorganic materials409Recent results from the in situ study of hydrothermal crystallisations using time-resolved X-ray and neutron diffraction methods33Mechanism of nanocrystalline BaTiO3 particle formation by hydrothermal refluxing synthesis25Investigation of Hydrothermal Routes to Mixed-Metal Cerium Titanium Oxides and Metal Oxidation State Assignment Using XANES17Short-range dissolution–precipitation crystallization of hydrothermal barium titanate45A General Soft‐Chemistry Route to Perovskites and Related Materials: Synthesis of BaTiO3, BaZrO3, and LiNbO3 Nanoparticles305A General Soft‐Chemistry Route to Perovskites and Related Materials: Synthesis of BaTiO3, BaZrO3, and LiNbO3 Nanoparticles64Solvothermal Morphology Studies: Alkali and Alkaline Earth Molybdates20Nonaqueous and Halide-Free Route to Crystalline BaTiO3, SrTiO3, and (Ba,Sr)TiO3 Nanoparticles via a Mechanism Involving C−C Bond Formation284Synthesis of nanosized NaTaO3 in low temperature and its photocatalytic performance95Mass production of Ba1−xSrxTi1−yZryO3 (0≤x≤1, 0≤y≤0.5) nanoparticles6Synthesis of nanotabular barium titanate via a hydrothermal route14Hydrothermal synthesis of the perovskite manganites Pr0.5Sr0.5MnO3 and Nd0.5Sr0.5MnO3 and alkali-earth manganese oxides CaMn2O4, 4H-SrMnO3, and 2H-BaMnO350High pressurein situx-ray absorption spectroscopy cell for studying simultaneously the liquid phase and the solid/liquid interface68Studying the Solvothermal Formation of MoO3 Fibers by Complementary In Situ EXAFS/EDXRD Techniques105Untersuchung der solvothermalen Bildung von MoO3‐Fasern mithilfe komplementärer In‐situ‐EXAFS/EDXRD‐Techniken24BaTiO3 nanocrystals: Hydrothermal synthesis and structural characterization60Solvothermal Synthesis and Crystal Structures of Alkali Molybdates15Kinetic Modeling of Aqueous and Hydrothermal Synthesis of Barium Titanate (BaTiO3)85Template‐Free Hydrothermal Synthesis of Single‐Crystalline Barium Titanate and Strontium Titanate Nanowires130Time-resolved Neutron Diffraction Studies with Emphasis on Water Ices and Gas Hydrates28Preparation of Ultrafine BaTiO3 and SrTiO3 Powders from Na2-xHxTi3O7 Nanowires via Hydrothermal Processing2Synthesis and Characterization of Novel Fluorinated Poly(oxomolybdates)25Room-Temperature Biosynthesis of Ferroelectric Barium Titanate Nanoparticles310Hydrothermal synthesis of ultrafine ZnO powders as investigated by calvet calorimetry4Low Temperature One Step Synthesis of Barium Titanate: Particle Formation Mechanism and Large-scale Synthesis10Phase Transition in Perovskite Oxide La0.75Sr0.25Cr0.5Mn0.5O3-δ Observed by in Situ High-Temperature Neutron Powder Diffraction85Hydrothermal Synthesis of Molybdenum Oxide Based Materials: Strategy and Structural Chemistry62New nonhydrolytic route to synthesize crystalline BaTiO3 nanocrystals with surface capping ligands14Hydrothermal Synthesis and Crystal Structure of Novel Alkali Trimolybdates7Growth Kinetics and Cracking of Liquid-Phase-Deposited Anatase Films37Rapid formation of nanocrystalline HfO2 powders from amorphous hafnium hydroxide under ultrasonically assisted hydrothermal treatment47Effects of Composition on the Reaction Kinetics of Hydrothermally Derived Barium Strontium Titanate9Formation process of BaTiO3 particles by reaction between barium hydroxide aqueous solution and titania obtained by hydrolysis of titanium alkoxide5Synthesis of BaTiO3 Nanowires at Low Temperature32Continuous hydrothermal synthesis of nanometric BaZrO3 in supercritical water39Hydrothermal synthesis of nanocrystalline BaTiO3 particles and structural characterization by high-resolution transmission electron microscopy46Atomic‐Scale Characterization of Barium Titanate Powders Formed by the Hydrothermal Process45Hydrothermal synthesis of BaTiO3: Crystal phase and the Ba2+ ions leaching behavior in aqueous medium44Generalized Nonaqueous Sol–Gel Synthesis of Different Transition‐Metal Niobate Nanocrystals and Analysis of the Growth Mechanism42Composition and shape control of single-crystalline Ba1−xSrxTiO3 (x=0–1) nanocrystals via a solvothermal route48Synthesis and characterization of BaTi1-xSnxO3 powders and multilayered ceramic materials0Surfactant‐Free Nonaqueous Synthesis of Metal Oxide Nanostructures478Tensidfreie nichtwässrige Synthese von Metalloxid‐Nanostrukturen36In-situ synchrotron diffraction study of the hydrothermal transformation of goethite to hematite in sodium aluminate solutions52Morphology and atomic-scale surface structure of barium titanate nanocrystals formed at hydrothermal conditions42Kinetics and Mechanisms of the Hydrothermal Crystallization of Calcium Titanate Species47Low-temperature hydrothermal–galvanic couple synthesis of BaTiO3 thin films on Ti-coated silicon substrates13One-step synthesis of fine SrTiO3 particles using SrSO4 ore under alkaline hydrothermal conditions34Complex inorganic/organic core-shell architectures via an inverse emulsion process14Time‐Resolved In Situ Diffraction Study of the Solvothermal Crystallization of Some Prototypical Metal–Organic Frameworks220Time‐Resolved In Situ Diffraction Study of the Solvothermal Crystallization of Some Prototypical Metal–Organic Frameworks51In situ X-ray diffraction study of the hydrothermal crystallization of hierarchical Bi2WO6 nanostructures42Low Temperature Hydrothermal Synthesis and the Growth Kinetics of BaTiO[sub 3] Films on TiN/Si, Ti/Si, and Bulk-Ti Substrates14Modification of bone-like apatite nanoparticle size and growth kinetics by alizarin red S29Solution based approaches for the morphology control of BaTiO3 particulates0Solvothermal synthesis of perovskites and pyrochlores: crystallisation of functional oxides under mild conditions353A thermosyphon-driven hydrothermal flow-through cell forin situand time-resolved neutron diffraction studies14Genesis of bismuth molybdenum oxide catalyst followed by in-situ techniques and its use in catalytic dense membrane reactor0Polymer-directed synthesis and magnetic property of nanoparticles-assembled BiFeO3 microrods39In Situ X-ray Diffraction and Absorption Studies of the Growth and Phase Transformation of Yttrium Hydroxide Nanotubes to Their Oxide Counterparts16A time-resolved diffraction study of a window of stability in the synthesis of a copper carboxylate metal–organic framework154Anisotropic Crystal Growth Kinetics of Anatase TiO2 Nanoparticles Synthesized in a Nonaqueous Medium80Systematic and In Situ Energy Dispersive X-ray Diffraction Investigations on the Formation of Lanthanide Phosphonatobutanesulfonates: Ln(O3P-C4H8-SO3)(H2O) (Ln = La−Gd)53Synthesis and Characterization of Nano-Barium Titanate Prepared by Hydrothermal Process21New large volume hydrothermal reaction cell for studying chemical processes under supercritical hydrothermal conditions using time-resolved in situ neutron diffraction14Direct Hydrothermal Synthesis and Physical Properties of Rare-Earth and Yttrium Orthochromite Perovskites181In‐Situ Monitoring of the Formation of Crystalline Solids251In‐situ‐Verfolgung der Bildung kristalliner Feststoffe69In‐situ Synchrotron X‐ray Diffraction Study of the Formation of Cubic Li 2 TiO 3 Under Hydrothermal Conditions35Kinetic Study of the Static Hydrothermal Synthesis of BaTiO3 Using Titanate Nanotubes Precursors43Preparation of Double-Shelled BaTiO3 Composite Hollow Microspheres by Template Method1Multiple Nucleation and Crystal Growth of Barium Titanate76Hydrothermal synthesis map of bismuth titanates31Synthesis, Structure, and Crystallization Study of a Layered Lithium Thiophene-Dicarboxylate39Probing Liquid/Solid Interfaces at the Molecular Level458Synthesis and dielectric behavior of nano-scale barium titanate24In situstudies into the formation kinetics of potassium jarosite20Preparation of Selected Ceramic Compounds by Controlled Crystallization Under Hydrothermal Conditions7Time-Resolved in Situ Neutron Diffraction under Supercritical Hydrothermal Conditions: A Study of the Synthesis of KTiOPO428Characterisation of organic solid forms and real-time in situ monitoring of their transformations using solid-state fluorescence32Crystallisation of solvothermally synthesised ZIF-8 investigated at the bulk, single crystal and surface level60Hydrothermal synthesis of ferroelectric PbTiO3 nanoparticles with dominant {001} facets by titanate nanostructure14Multi Variant Surface Mounted Metal–Organic Frameworks69Hydrothermal–galvanic couple synthesis of directionally oriented BaTiO3 thin films on TiN-coated substrates15From an Open Framework to a Layered and a Hexagonal Tungsten Oxide Structure: Controlled Transformation Reactions of an Extended Solid-State Material, Cs3Ga7(SeO3)12 to Ga(OH)(SeO3) and KGa3(SeO4)2(OH)613Virus-Directed Design of a Flexible BaTiO3 Nanogenerator231High temperature in situ neutron powder diffraction of oxides23Solvothermal Synthesis of Shape-Controlled Perovskite MTiO3 (M = Ba, Sr, and Ca) Particles in H2O/Polyols Mixed Solutions22Hydrothermal synthesis of size- and shape-controlled CaTiO 3 fine particles and their photocatalytic activity72Rapid synthesis of barium titanate microcubes using composite-hydroxides-mediated avenue5Coupling in situ synchrotron radiation with ex situ spectroscopy characterizations to study the formation of Ba1−Sr TiO3 nanoparticles in supercritical fluids54Influence of Sr+2 concentrations on growth of SrTiO3 thin films synthesized by hydrothermal–galvanic couple method12Supercritical fluid technology: A reliable process for high quality BaTiO3 based nanomaterials92In Situ Studies of Solvothermal Synthesis of Energy Materials159Structural Characterization and Optical Properties of Perovskite ZnZrO 3 Nanoparticles33Single-step synthesis of SrMoO4 particles from SrSO4 and their anti-corrosive activity9Diversity in size of barium titanate nanocubes synthesized by a hydrothermal method using an aqueous Ti compound24Chemical Reactions followed byin situNeutron Powder Diffraction57Hydrothermal synthesis and formation mechanism of photocatalytically active SrTiO 3 nanocrystals using anatase TiO 2 with different facets as a precursor19Impact of the Nature of the Organic Spacer on the Crystallization Kinetics of UiO‐66(Zr)‐Type MOFs49Self-Template Synthesis of Porous Perovskite Titanate Solid and Hollow Submicrospheres for Photocatalytic Oxygen Evolution and Mesoscopic Solar Cells74Pursuing the Crystallization of Mono- and Polymetallic Nanosized Crystalline Inorganic Compounds by Low-Temperature Wet-Chemistry and Colloidal Routes80Hydrothermal Synthesis of SrTiO3: Role of Interfaces55Perovskite Oxide Nanocrystals — Synthesis, Characterization, Functionalization, and Novel Applications8Hydrothermal synthesis and formation mechanism of tetragonal barium titanate in a highly concentrated alkaline solution58Insights into BaTi1–yZryO3 (0 ≤ y ≤ 1) Synthesis under Supercritical Fluid Conditions30Continuous Hydrothermal Synthesis of Pr-Doped CaTiO3 Nanoparticles from a TiO2 Sol14Reactive Hydrothermal Liquid‐Phase Densification ( rHLPD ) of Ceramics – A Study of the BaTiO 3 [TiO 2 ] Composite System41Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures601Hydrothermal synthesis of strontium titanate: thermodynamic considerations, morphology control and crystallisation mechanisms92Nucleation and Growth Mechanism of Barium Titanate Nanoblocks in Hydrothermal Process Using Aqueous Titanium Compound12In Situ Neutron Diffraction Studies of the Ion Exchange Synthesis Mechanism of Li2Mg2P3O9N: Evidence for a Hidden Phase Transition31Time-Resolved Powder X-ray Diffraction of the Solvothermal Crystallization of Cobalt Gallate Spinel Photocatalyst Reveals Transient Layered Double Hydroxides20Characterization of fouling processes in ceramic membranes used for the recovery and recycle of oil sands produced water22Facile Synthesis of Perovskite-Structured Powders Using Barite–Celestite Ore under Hydrothermal Alkaline Conditions21Temperature-induced structural transition of ceria by bulk reduction under hydrogen atmosphere14Very fast crystallisation of MFe2O4 spinel ferrites (M = Co, Mn, Ni, Zn) under low temperature hydrothermal conditions: a time-resolved structural investigation34Facile Low Temperature Hydrothermal Synthesis of BaTiO3 Nanoparticles Studied by In Situ X-ray Diffraction21Following the Kinetics of Barium Titanate Nanocrystal Formation in Benzyl Alcohol Under Near‐Ambient Conditions1Effect of Reagents on the Properties of Barium Titanate Synthesized in Subcritical Water8Naturally derived pyroxene nanomaterials: an ore for wide applications1Probing Liquid/Solid Interfaces at the Molecular Level1Recrystallization of fine-crystalline barium titanate in low-density water medium15A Fast, Low‐Temperature Synthesis Method for Hexagonal YMnO3: Kinetics, Purity, Size and Shape as Studied by In Situ X‐ray Diffraction6Synthesis of nanocrystalline barium titanate: Effect of microwave power on phase evolution11EFFECT OF REAGENTS ON THE PROPERTIES OF BARIUM TITANATE SYNTHESIZED IN SUBCRITICAL WATER0Hydrothermal synthesis of barium titanate nano/microrods and particle agglomerates using a sodium titanate precursor52Review of Advances in Engineering Nanomaterial Adsorbents for Metal Removal and Recovery from Water: Synthesis and Microstructure Impacts104Colloidal Oxide Perovskite Nanocrystals: From Synthesis to Application6SrTiO3 Nanokubus: Sintesis, Kontrol Morfologi dan Sifat Termoelektrik (Tinjauan)2In situ scattering studies of material formation during wet-chemical syntheses1Nucleation and Coalescence of BaTiO3 Using a Continuous Flow Reactor with Water–Ethanol Mixed Solvents10Panoramic (in beam) studies of materials synthesis1In Situ and In Operando Neutron Diffraction of Transition Metal Oxides for Electrochemical Storage1Solution‐Based Synthesis Routes for the Preparation of Noncentrosymmetric 0‐D Oxide Nanocrystals with Perovskite and Nonperovskite Structures29Synthesis of crystalline BaZrO3 thin films over preferred-oriented ZrN by a hydrothermal-galvanic couple method for photoelectrochemical evaluations3In situ characterisation for studying nucleation and growth of nanostructured materials and thin films during liquid-based synthesis7Solvothermal and hydrothermal methods for preparative solid-state chemistry5Multi-scale Crystallization Materials: Advances in in-situ Characterization Techniques and Computational Simulations2Microwave‐Assisted Synthesis of SrTiO3 Nanocuboids without TiCl46Mechanism and kinetics study on waste acid leaching from copper smelting dust7Methods for the synthesis of barium titanate as a component of functional dielectric ceramics3Exploring lead-free materials for screen-printed piezoelectric wearable devices13Solid-State Synthesis for High-Tetragonality, Small-Particle Barium Titanate10Surface reconstruction via dissolution-reprecipitation of commercial alumina support to improve propane dehydrogenation performance1Recent advances in layered double hydroxides for pharmaceutical wastewater treatment: A critical review89The latest progress of nanostructured barium titanate crystal materials: Industrial synthesis, modification and application11Stepwise Reduction of Ruthenium and Growth of Magnetic Structure During Hydrothermal Crystallisation of SrRu 2 O 6 from KRuO 40Stepwise Reduction of Ruthenium and Growth of Magnetic Structure During Hydrothermal Crystallisation of SrRu 2 O 6 from KRuO 40

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