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RESEARCH PAPER · Chemistry - A European Journal · 2003

Chirality Transfer from Guest Chiral Metal Complexes to Inorganic Framework: The Role of Hydrogen Bonding

Yu Wang, Jihong Yu, Yi Li, Zhan Shi, Ruren Xu

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Chirality Transfer from Guest Chiral Metal Complexes to Inorganic Framework: The Role of Hydrogen BondingOriginalToward the rational design and synthesis of inorganic microporous and related materials10Hydrogen‐Bonded Helices in the Layered Aluminophosphate (C2H8N)2[Al2(HPO4)(PO4)2]73Hydrogen‐Bonded Helices in the Layered Aluminophosphate (C2H8N)2[Al2(HPO4)(PO4)2]4(C6H17N3)[Zn4(PO4)2(HPO3)2]: a new layered zinc phosphate–phosphite templated by 1-(2-Aminoethyl) piperazine10Two layered gallophosphates assembled about the chiral metal complexes: Co(en)3·Ga3P4O16·5H2O and trans−Co(dien)2·Ga3P4O16·3H2O9[Co(en)3][In3(H2PO4)6(HPO4)3]·H2O: A new layered indium phosphate templated by cobalt complex23The chiral structure induced by lone-pair electrons: syntheses and characterization of two novel chiral rare-earth selenites containing homochiral helical chains11Synthesis and Characterization of a Molecular Zinc Phosphate Ni(2, 2'‐bipy)3·[ZnCl(H2PO4)3]4Co-templated synthesis and characterization of two new 1D zincophosphates, [Co III (dien) 2 ][Zn(PO 4 )(HPO 4 )]·H 3 BO 3 and [Co III (dien) 2 ][Zn 2 (PO 4 )(HPO 4 ) 2 ]·C 2 H 6 O 24Hydrothermal synthesis and structure determination of UH-6 and UH-8: Two novel zincophosphates containing cobalt complexes1New Zinc Phosphates Decorated by Imidazole-Containing Ligands95The synthesis and structure of a chiral 1D aluminophosphate chain compound: d-Co(en)3[AlP2O8]·6.5H2O20Assembly of Helical Hydrogen Bonds in a New Layered Aluminophosphate [C6N3H17][Al2(HPO4)(PO4)2]20Template synthesis and characterization of a novel three-dimensional open-framework indium phosphate (C6N4H22)1/2[In3(HPO4)6]·H3O18A Germanate Framework Containing 24‐Ring Channels, NiGe Bonds, and Chiral [Ni@Ge14O24(OH)3] Cluster Motifs Transferred from Chiral Metal Complexes120A Germanate Framework Containing 24‐Ring Channels, NiGe Bonds, and Chiral [Ni@Ge14O24(OH)3] Cluster Motifs Transferred from Chiral Metal Complexes28Hybrid Inorganic–Organic 1D and 2D Frameworks with [As6V15O42]6– Polyoxoanions as Building Blocks57Syntheses, Structures, and Magnetic Properties of Inorganic−Organic Hybrid Cobalt(II) Phosphites Containing Bifunctional Ligands137Hydrothermal synthesis and crystal structure of a novel three-dimensional supramolecular network containing cyclic water hexamers: [Co(en)3]4[P2Mo5O23]2·9H2O(en=ethylenediamine)21Synthesis and Characterization of a New Three‐dimensional Organically Templated Nickel‐Zinc Phosphate2Highly Stable Chiral Cadmium 1,2,4-Benzenetricarboxylate: Synthesis, Structure, and NLO and Fluorescence Properties210Hydrothermal synthesis of a new open-framework zinc phosphate containing 20-ring channels5[Ni(C6N2H14)2][Zn4(H2O)(HPO3)5]: A new open-framework zinc phosphite with intersecting 8-, 12- and 16-ring channels15Novel open-framework fluorinated indium phosphate with 14-ring intersecting channels: Assembled from 6∗1 and racemic pillared secondary building units20Pd(II) polymeric compounds directed by intermolecular C–H⋯X–C interactions (X=F, Cl): Suzuki–Miyaura cross-coupling catalytic activity by a novel N4-type saturated Pd complex8Characterization of Two Zincophosphates (UH‐6 and UH‐10) Synthesized using the Cobalt(III) Sarcophagine Complex as Structure‐directing Agent10Synthesis of Zeolites87Syntheses and Structures of Three Unprecedented Metal−Ciprofloxacin Complexes with Helical Character128Synthesis, Structure, and Photoluminescence Property of a New Layered Zirconium Phosphate |Co(dien)2|[Zr4H8P5O26]·3H2O14Syntheses and Characterizations of Three Low-Dimensional Chloride-Rich Zincophosphates Assembled about [ d -Co(en) 3 ] 3+ and [ dl -Co(en) 3 ] 3+ Complex Cations17Germanates of 1D Chains, 2D Layers, and 3D Frameworks Built from Ge–O Clusters by Using Metal‐Complex Templates: Host–Guest Symmetry and Chirality Transfer35The effect of mixed amines on the competitive formation of two open-framework zinc phosphates with 16-ring large channels4Construction of ZnII Compounds with a Chelating 2,2′‐Dipyridylamine (Hdpa) Ligand: Anion Effect and Catalytic Activities48Structural characterization of two lanthanide complexes attached to [H2W12O40]6−5[Ni(1,2-PDA)3]2(HOCH2CH2CH2NH3)3(H3O)2 [Ge7O14X3]3 (X = F, OH): A New 1D Germanate with 12-Ring Hexagonal Tubular Channels55Chiral zeolitic materials: structural insights and synthetic challenges130Supramolecular Helix‐to‐Helix Induction: A 3D Anionic Framework Containing Double‐Helical Strands Templated by Cationic Triple‐Stranded Cluster Helicates98Supramolecular Helix‐to‐Helix Induction: A 3D Anionic Framework Containing Double‐Helical Strands Templated by Cationic Triple‐Stranded Cluster Helicates15Zinc(II) polymeric compounds with a chelating ligand bis(2-pyridylmethyl)amine (bispicam) directed by intermolecular C/N/O–H⋯X (X=Cl, Br, I) interactions: Catalytic activities25A zeolite family with chiral and achiral structures built from the same building layer223A novel 4 · 82 CdII network constructed from helical motif: Incorporating alternate left- and right-hand helical water chains19Solvothermal synthesis and structure of a novel 3D zincophosphite |Co(en)3|[Zn4(HPO3)5(H2PO3)] containing helical chains9Synthesis, structure and NMR characterization of a new monomeric aluminophosphate [dl-Co(en)3]2[Al(HPO4)2(H1.5PO4)2(H2PO4)2](H3PO4)4 containing four different types of monophosphates10A new layered aluminoborate [Zn(dien)2][{Al(OH)}{B5O9F}] templated by transition metal complexes56Spontaneous Assembly of 63 Topological Metal−Organic Nanotubes with Distinct Asymmetric Subunits for the Construction of Hydrophilic Intertube Channels Encapsulating Rare Helical Water-Chains36Construction of Cd(II) compounds with a chelating ligand 2,2′-dipyridiylamine (Hdpa): Anion effect, catalytic activities and luminescence30[Zn(HPO3)(C11N2O2H12)] and [Zn3(H2O)(PO4)(HPO4)(C6H9N3O2)2 (C6H8N3O2)]: homochiral zinc phosphite/phosphate networks with biofunctional amino acids38Helical chain observed under transmission electron microscope: Synthesis and structure refinement of lutetium disilicate Lu2Si2O711Synthesis, crystal structure and characterization of a new layered gallium phosphite Ga(HPO3)F3·(trans-C6N2H16) with left- and right-handed helical chains12Template-directed synthesis of three new open-framework metal(ii) oxalates using Co(iii) complex as template65A Series of Open‐Framework Aluminoborates Templated by Transition‐Metal Complexes107|Co(en)3|1/3[In(ox)2]·3.5H2O: A zeolitic metal-organic framework templated by Co(en)3Cl344Understanding the Mechanism of Chirality Transfer in the Formation of a Chiral MCM-41 Mesoporous Silica37Construction, photoluminescence, and catalytic reactivity study of Cd(II) complexes containing amide ligand with hydrogen-bond capable backbone: 1-Dimensional looped chain11[Cu(en)2]0.5[Al3P3O12(OH)]-aluminophosphate with zeotype AWO: Synthesis, crystal structure and phase transformation2Steric effect on construction of extended architectures of Ni(II) complexes directed by intermolecular C-H...F and C-H...O interactions2Structural and Selective Gas Adsorption Studies of Polyoxometalate and Tris(ethylenediamine) Cobalt(III) Based Ionic Crystals33Anion effects on construction of ZnII compounds with a chelating ligand bis(2-pyridylmethyl)amine and their catalytic activities13Solvent-mediated crystal-to-crystal transformation within the CoBr2(1,4-dioxane)m(H2O)n family (m = 2, 3; n = 0, 2, 4) from 2D to 1D, and 0D12A Gallogermanate Zeolite Constructed Exclusively by Three‐Ring Building Units60A Gallogermanate Zeolite Constructed Exclusively by Three‐Ring Building Units11Tris(ethylenediamine)cobalt(III) diformatodioxalatoindate(III) dihydrate3Anion effects on the crystal structures of ZnII complexes containing 2,2′-bipyridine: Their photoluminescence and catalytic activities51Bis(diethylenetriamine)cobalt(III) hexachloridoindate(III)2Study of the structure directing effect of the chiral cation (1S,2S)-2-hydroxymethyl-1-benzyl-1-methylpyrrolidinium in aluminosilicate preparations in the presence of co-structure directing agents5Different Effects of a Cotemplate and [(Transition-Metal)(1,10-Phenanthroline)m]2+ (m = 1–3) Complex Cations on the Self-assembly of a Series of Hybrid Selenidostannates Showing Combined Optical Properties of Organic and Inorganic Components50Tris(2,2′-bi-1H-imidazole-κ2N3,N3′)cobalt(II) hydrogen phosphate1Construction of HgII complexes containing chelating 2,2′-dipyridylamine ligands: Anion effect, photoluminescence and catalytic activities11具有AWO分子筛结构的磷酸铝[Cu(en)_2]_(0.5)[Al_3P_3O_(12)(OH)]:合成、结构与相转变1Tris(ethylenediamine-κ2N,N′)cobalt(III) aquatris(oxalato-κ2O1,O2)indate(III)0A series of chiral coordination polymers containing helicals assembled from a new chiral (R)-2-(4′-(4′′-carboxybenzyloxy)phenoxy)propanoic acid: syntheses, structures and photoluminescent properties47Anion effects on construction of cadmium(II) compounds with a chelating ligand bis(2-pyridylmethyl)amine: Their photoluminescence and catalytic activities26Anion Effects on Crystal Structures of CdIIComplexes Containing 2,2'-Bipyridine: Photoluminescence and Catalytic Reactivity12A Germanate Compound Constructed from Dissymmetric Ge7 Chains and Metal Complexes4[Ni(dien)2]3[Ge3Sb8S21]·0.5H2O: A new 2-D layered thiogermanate–thioantimonate with metal complexes as template ions16A 3-D chiral organic–inorganic hybrid zinc vanadate assembled from helical units20A novel 3-D chiral polyoxovanadate architecture based on breaking high symmetry of spherical [V15O36Cl]8− cluster22A polyoxometalate-based ionic crystal assembly from a heterometallic cluster and polyoxoanions with visible-light catalytic activity33Achiral diamondoid or chiral quartz net: the effect of substituents in the topology and catenation of coordination polymers based on tetrahedral Cd(COO)4 building units14Catalytic transesterification reactions of one-dimensional coordination polymers containing paddle-wheel-type units connected by various bridging ligands9[Co(NH3)6]2[Cd8(C2O4)11(H2O)4]·8H2O: A 5-connected sqp topological metal–organic framework co-templated by Co(NH3)63+ cation and (H2O)4 cluster4Homochiral Zinc(II) Coordination Compounds Based on In-Situ-Generated Chiral Amino Acid–Tetrazole Ligands: Circular Dichroism, Excitation Light-Induced Tunable Photoluminescence, and Energetic Performance75A family of germanates constructed from Ge 7 clusters co-templated by metal complexes and organic/inorganic species5Series of crystalline beryllium phosphates including new templates generated by in situ N-methylation transformation22Assembly of an unprecedented metal-pipemidic acid complex modifying octamolybdates containing like DNA spiral chain5Towards chiral distributions of dopants in microporous frameworks: helicoidal supramolecular arrangement of (1R,2S)-ephedrine and transfer of chirality17Hydrothermal Synthesis of New Organically Templated Beryllium Phosphite and Phosphate with 3,4‐connected Networks3Symmetrically Related Construction and Optical Properties of Two Noncentrosymmetric 3D Iodides of d10 Cation (Cu+, Ag+) Based on the N-Benzylpyridinium and Its Supramolecular Interactions73A Series of Aluminoborates Templated or Supported by Zinc–Amine Complexes51Supramolecular Chemistry Controlled by Conformational Space during Structure Direction of Nanoporous Materials: Self-Assembly of Ephedrine and Pseudoephedrine23Synthesis, structure, photo-physical properties and catalytic activities of Zn(II), Cd(II) and Hg(II) complexes of an azinopyridyl ligand17Syntheses and Characterizations of Three Organically Templated Zinc Phosphites with 12-Ring Channels0Supramolecular chemistry controlled by packing interactions during structure-direction of nanoporous materials: Effect of the addition of methyl groups on ephedrine derivatives8Two New Octaborates Constructed of Two Different Sub-clusters and Supported by Metal Complexes11Chiral Organic Structure-Directing Agents9Introduction to the Zeolite Structure-Directing Phenomenon by Organic Species: General Aspects35Supramolecular chirality of amphiphilic block copolymer films made through two steps: self-assembling first, and then solution coating1Comparison of the structure-directing effect of ephedrine and pseudoephedrine during crystallization of nanoporous aluminophosphates13Self-assembly of chiral (1 R ,2 S )-ephedrine and (1 S ,2 S )-pseudoephedrine into low-dimensional aluminophosphate materials driven by their amphiphilic nature3Synthesis and characterization of new silver(I) naphthalenedisulfonate complexes with heterocyclic N-donor ligands: Packing analyses and antibacterial studies5Helicity of perfluoroalkyl chains controlled by the self‐assembly of the Ala‐Ala dipeptides9Two Chiral Metal Complex Templated Aluminoborates Constructed from Three Types of Oxoboron Clusters17Chiral templated synthesis of homochiral metal-organic frameworks54Advances and challenges in designing active site environments in zeolites for Brønsted acid catalysis18Recent progress in chiral zeolites: Structure, synthesis, characterization and applications12

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  1. Toward the rational design and synthesis of inorganic microporous and related materials

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  2. Hydrogen‐Bonded Helices in the Layered Aluminophosphate (C2H8N)2[Al2(HPO4)(PO4)2]

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  3. Hydrogen‐Bonded Helices in the Layered Aluminophosphate (C2H8N)2[Al2(HPO4)(PO4)2]

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  4. (C6H17N3)[Zn4(PO4)2(HPO3)2]: a new layered zinc phosphate–phosphite templated by 1-(2-Aminoethyl) piperazine

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  5. Two layered gallophosphates assembled about the chiral metal complexes: Co(en)3·Ga3P4O16·5H2O and trans−Co(dien)2·Ga3P4O16·3H2O

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  6. [Co(en)3][In3(H2PO4)6(HPO4)3]·H2O: A new layered indium phosphate templated by cobalt complex

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  7. The chiral structure induced by lone-pair electrons: syntheses and characterization of two novel chiral rare-earth selenites containing homochiral helical chains

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  8. Synthesis and Characterization of a Molecular Zinc Phosphate Ni(2, 2'‐bipy)3·[ZnCl(H2PO4)3]

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  9. Co-templated synthesis and characterization of two new 1D zincophosphates, [Co III (dien) 2 ][Zn(PO 4 )(HPO 4 )]·H 3 BO 3 and [Co III (dien) 2 ][Zn 2 (PO 4 )(HPO 4 ) 2 ]·C 2 H 6 O 2

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  10. Hydrothermal synthesis and structure determination of UH-6 and UH-8: Two novel zincophosphates containing cobalt complexes

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  11. New Zinc Phosphates Decorated by Imidazole-Containing Ligands

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  12. The synthesis and structure of a chiral 1D aluminophosphate chain compound: d-Co(en)3[AlP2O8]·6.5H2O

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  13. Assembly of Helical Hydrogen Bonds in a New Layered Aluminophosphate [C6N3H17][Al2(HPO4)(PO4)2]

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  14. Template synthesis and characterization of a novel three-dimensional open-framework indium phosphate (C6N4H22)1/2[In3(HPO4)6]·H3O

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  15. A Germanate Framework Containing 24‐Ring Channels, NiGe Bonds, and Chiral [Ni@Ge14O24(OH)3] Cluster Motifs Transferred from Chiral Metal Complexes

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  16. A Germanate Framework Containing 24‐Ring Channels, NiGe Bonds, and Chiral [Ni@Ge14O24(OH)3] Cluster Motifs Transferred from Chiral Metal Complexes

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  17. Hybrid Inorganic–Organic 1D and 2D Frameworks with [As6V15O42]6– Polyoxoanions as Building Blocks

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  18. Syntheses, Structures, and Magnetic Properties of Inorganic−Organic Hybrid Cobalt(II) Phosphites Containing Bifunctional Ligands

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  19. Hydrothermal synthesis and crystal structure of a novel three-dimensional supramolecular network containing cyclic water hexamers: [Co(en)3]4[P2Mo5O23]2·9H2O(en=ethylenediamine)

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  20. Synthesis and Characterization of a New Three‐dimensional Organically Templated Nickel‐Zinc Phosphate

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  22. Hydrothermal synthesis of a new open-framework zinc phosphate containing 20-ring channels

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  23. [Ni(C6N2H14)2][Zn4(H2O)(HPO3)5]: A new open-framework zinc phosphite with intersecting 8-, 12- and 16-ring channels

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  24. Novel open-framework fluorinated indium phosphate with 14-ring intersecting channels: Assembled from 6∗1 and racemic pillared secondary building units

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  25. Pd(II) polymeric compounds directed by intermolecular C–H⋯X–C interactions (X=F, Cl): Suzuki–Miyaura cross-coupling catalytic activity by a novel N4-type saturated Pd complex

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  26. Characterization of Two Zincophosphates (UH‐6 and UH‐10) Synthesized using the Cobalt(III) Sarcophagine Complex as Structure‐directing Agent

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  27. Synthesis of Zeolites

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  28. Syntheses and Structures of Three Unprecedented Metal−Ciprofloxacin Complexes with Helical Character

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  29. Synthesis, Structure, and Photoluminescence Property of a New Layered Zirconium Phosphate |Co(dien)2|[Zr4H8P5O26]·3H2O

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  30. Syntheses and Characterizations of Three Low-Dimensional Chloride-Rich Zincophosphates Assembled about [ d -Co(en) 3 ] 3+ and [ dl -Co(en) 3 ] 3+ Complex Cations

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  31. Germanates of 1D Chains, 2D Layers, and 3D Frameworks Built from Ge–O Clusters by Using Metal‐Complex Templates: Host–Guest Symmetry and Chirality Transfer

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  32. The effect of mixed amines on the competitive formation of two open-framework zinc phosphates with 16-ring large channels

    Microporous and Mesoporous Materials · 2007-10-02

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  33. Construction of ZnII Compounds with a Chelating 2,2′‐Dipyridylamine (Hdpa) Ligand: Anion Effect and Catalytic Activities

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  34. Structural characterization of two lanthanide complexes attached to [H2W12O40]6−

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  35. [Ni(1,2-PDA)3]2(HOCH2CH2CH2NH3)3(H3O)2 [Ge7O14X3]3 (X = F, OH): A New 1D Germanate with 12-Ring Hexagonal Tubular Channels

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    Qinhe Pan, Jiyang Li, Xiaoyan Ren, Zhuopeng Wang, Guanghua Li, Jihong Yu, Ruren Xu

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  36. Chiral zeolitic materials: structural insights and synthetic challenges

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  37. Supramolecular Helix‐to‐Helix Induction: A 3D Anionic Framework Containing Double‐Helical Strands Templated by Cationic Triple‐Stranded Cluster Helicates

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  38. Supramolecular Helix‐to‐Helix Induction: A 3D Anionic Framework Containing Double‐Helical Strands Templated by Cationic Triple‐Stranded Cluster Helicates

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  39. Zinc(II) polymeric compounds with a chelating ligand bis(2-pyridylmethyl)amine (bispicam) directed by intermolecular C/N/O–H⋯X (X=Cl, Br, I) interactions: Catalytic activities

    Journal of Molecular Structure · 2008-04-12

    Byeong Kwon Park, Sun Hwa Lee, Eun Yong Lee, Han Kwak, Young Min Lee, Yu Jin Lee, Je Yeol Jun, Cheal Kim, Sung‐Jin Kim, Youngmee Kim

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  40. A zeolite family with chiral and achiral structures built from the same building layer

    Nature Materials · 2008-04-13

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  41. A novel 4 · 82 CdII network constructed from helical motif: Incorporating alternate left- and right-hand helical water chains

    Inorganic Chemistry Communications · 2008-05-09

    Mei‐Li Zhang, Dong‐Sheng Li, Feng Fu, Xiao‐Gang Yang, Ya‐Pan Wu, Enbo Wang

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  42. Solvothermal synthesis and structure of a novel 3D zincophosphite |Co(en)3|[Zn4(HPO3)5(H2PO3)] containing helical chains

    Journal of Solid State Chemistry · 2008-07-27

    Jian Qiao, Lirong Zhang, Li Liu, Yang Yu, Minghui Bi, Qisheng Huo, Yunling Liu

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  43. Synthesis, structure and NMR characterization of a new monomeric aluminophosphate [dl-Co(en)3]2[Al(HPO4)2(H1.5PO4)2(H2PO4)2](H3PO4)4 containing four different types of monophosphates

    Solid State Sciences · 2008-12-09

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  45. Spontaneous Assembly of 63 Topological Metal−Organic Nanotubes with Distinct Asymmetric Subunits for the Construction of Hydrophilic Intertube Channels Encapsulating Rare Helical Water-Chains

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  46. Construction of Cd(II) compounds with a chelating ligand 2,2′-dipyridiylamine (Hdpa): Anion effect, catalytic activities and luminescence

    Polyhedron · 2009-10-30

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  47. [Zn(HPO3)(C11N2O2H12)] and [Zn3(H2O)(PO4)(HPO4)(C6H9N3O2)2 (C6H8N3O2)]: homochiral zinc phosphite/phosphate networks with biofunctional amino acids

    Dalton Transactions · 2010-01-01

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  48. Helical chain observed under transmission electron microscope: Synthesis and structure refinement of lutetium disilicate Lu2Si2O7

    CrystEngComm · 2010-01-01

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  49. Synthesis, crystal structure and characterization of a new layered gallium phosphite Ga(HPO3)F3·(trans-C6N2H16) with left- and right-handed helical chains

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  50. Template-directed synthesis of three new open-framework metal(ii) oxalates using Co(iii) complex as template

    CrystEngComm · 2010-01-01

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