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RESEARCH PAPER · Chemistry of Materials · 2002

Utilization of Cyclopentylamine as Structure-Directing Agent for the Formation of Fluorinated Gallium Phosphates Exhibiting Extra-Large-Pore Open Frameworks with 16-ring (ULM-16) and 18-ring Channels (MIL-46)

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Utilization of Cyclopentylamine as Structure-Directing Agent for the Formation of Fluorinated Gallium Phosphates Exhibiting Extra-Large-Pore Open Frameworks with 16-ring (ULM-16) and 18-ring Channels (MIL-46)Original22 New compounds and structures in the solid state2Hydrothermal synthesis and characterization of a new inorganic–organic hybrid layered zinc phosphate–phosphite (C 6 H 15 N 2 ) 2 Zn 4 (PO 4 ) 2 (HPO 3 ) 254Templated inorganic networks: recent developments36Partial substitution of the amine template by alkali metals (Rb, Cs) in the open-framework gallium phosphates ULM-3 and TREN-GaPO1021 New compounds and structures in the solid state1Rational design of porous titanophosphates69MIL-50, an Open-Framework GaPO with a Periodic Pattern of Small Water Ponds and Dry Rubidium Atoms: a Combined XRD, NMR, and Computational Study61Refinement of the crystal structure of gallium oxide hydroxide, GaO(OH)13A Novel Open‐Framework Gallium Phosphate Containing Two Different Building Units7Synthesis and Crystal Structure of a New Fluorogallophosphate Named Mu-124Order−Disorder in the Super-Sodalite Zn3Al6(PO4)12, 4tren, 17H2O (MIL-74): A Combined XRD−NMR Assessment84Ga(2,2‘-bipy)(HPO4)(H2PO4): First Layered Inorganic−Organic Hybrid Gallium Phosphate with a Neutral Framework41A novel gallium arsenate organically templated by propane-1,3-diyldiammonium with a ULM-3-type open framework: [Ga3(AsO4)3(OH)F](C3H12N2)·H2O3Hydrothermal synthesis and structure of the new three-dimensional fluorogallophosphate JGP-4 with a Ga/P ratio of 7/810SSZ-51A New Aluminophosphate Zeotype: Synthesis, Crystal Structure, NMR, and Dehydration Properties107Hydrothermal synthesis and characterization of two new three-dimensional fluoroindium phosphates In4(PO4)4(H2O)4F2·C6H14N2 and In8(PO4)8(H2O)8F4·(C5H14N2)212Structural Analysis of F/OH Distribution in a Hybrid Open-Framework Fluorinated Gallium Oxalate−Phosphate Templated by 1,3-Diaminopropane (MIL-90)28Thermal Transformation of (NH4)[Fe(AsO4)F] Into the New Textural Porous Orthorhombic Fe(AsO4) Phase. Crystal Structures, Thermal Behavior, and Spectroscopic and Magnetic Properties28Hydrothermal synthesis and characterization of two new three-dimensional open-framework gallophosphates JGP-n (, 9) constructed from inorganic layers and HPO4 tetrahedra10Crystallized Frameworks with Giant Pores: Are There Limits to the Possible?1327Hydrothermal synthesis and structure of organically templated chain, layered and framework scandium phosphates31Ga3(HPO3)4F4(H3DETA) (DETA=diethylenetriamine): A new open-framework fluorinated gallium phosphite with pentameric building unit19[(C4H12N)2][Zn3(HPO3)4]: An Open‐Framework Zinc Phosphite Containing Extra‐Large 24‐Ring Channels145[(C4H12N)2][Zn3(HPO3)4]: An Open‐Framework Zinc Phosphite Containing Extra‐Large 24‐Ring Channels164[Ni(C6N2H14)2][Zn4(H2O)(HPO3)5]: A new open-framework zinc phosphite with intersecting 8-, 12- and 16-ring channels15Crystalline oxyfluorinated open-framework compounds: Silicates, metal phosphates, metal fluorides and metal-organic frameworks (MOF)81Novel open-framework fluorinated indium phosphate with 14-ring intersecting channels: Assembled from 6∗1 and racemic pillared secondary building units20Hydrothermal synthesis and crystal structures of two open-framework fluorinated aluminum phosphates templated by 1,3-diaminopropane (ULM-4 & MIL-64)202,2′-Bipyridine,1,10-phenanthroline and 2,2′:6′,2″-terpyridine in gallium(III) chemistry: Complexes containing the core34Computational simulation study towards the synthesis of extra-large microporous materials26The effect of the nature of included metal cations on the structure and the adsorption and acidic characteristics of VFI aluminophosphates32H3O·[Co8(HPO3)9(CH3OH)3]·2H2O: An Open-Framework Cobalt Phosphite Containing Extra-Large 18-Ring Channels56Retracted article: Recognition of 1,3-cyclohexane bis(methylamine) isomers via template synthesis of open-framework bimetallic phosphites0Doping-Induced Structure Variation of 1,3-Cyclohexane− Bis(methylamine)-Templated Zinc−Phosphorus Open Structures46Hydrothermal synthesis, characterization and fluorescence property of a novel layered fluorinated gallium phosphite with heptameric building unit20Template-Designed Syntheses of Open-Framework Zinc Phosphites with Extra-Large 24-Ring Channels64Two Neutral Open-framework Metal Phosphites with Ten-ring Channels Constructed by Three-, Four-, and Five-connected Centers3Metal Complexes of Organophosphate Esters and Open-Framework Metal Phosphates: Synthesis, Structure, Transformations, and Applications370Template Syntheses of Two Open‐framework Zinc Phosphites1Separation of 1,3‐Cyclohexanebis(methylamine) Isomers by Template Synthesis of Open‐Framework Bimetallic Phosphites2The Long Story and the Brilliant Future of Crystallized Porous Solids5Mild hydrothermal synthesis, crystal structure, thermal behavior, spectroscopic and magnetic properties of the (NH4)[Fe(AsO4)1−x(PO4)xF] (x=0.3, 0.6, 0.8) series. Thermal transformation of (NH4)[Fe(AsO4)0.7(PO4)0.3F] into the textural porous orthorhombic Fe(AsO4)0.7(PO4)0.34[Cu4OCl6(DABCO)2]·0.5DABCO·4CH3OH (“MFU-5”): Modular synthesis of a zeolite-like metal-organic framework constructed from tetrahedral {Cu4OCl6} secondary building units and linear organic linkers22Characterization of the gel phases formed in the synthesis of microporous gallophosphate, cloverite3Extra‐Large‐Pore Zeolites: Bridging the Gap between Micro and Mesoporous Structures514Zeolithe mit sehr großen Poren als Bindeglied zwischen mikro‐ und mesoporösen Strukturen84Oxidation Tools in the Synthesis of Catalysts and Related Functional Materials1A new open-framework indium phosphate–phosphite containing intersecting extra-large 16-ring channels13Mild hydrothermal synthesis, crystal structure, thermal behaviour, spectroscopic and magnetic properties of (NH4)0.80Li0.20[Fe(AsO4)F]1Assembly of a new circle connecting circle chain through exerting the template role of a Keggin polyoxometalate7Syntheses and structures of two open-framework zinc phosphites with extra-large 24-ring channels19Single-crystal XRD and solid-state NMR structural resolution of a layered fluorinated gallium phosphate: RbGa 3 (PO 4 ) 2 (HPO 4 )F 4 ·C 5 N 2 H 16 ·2H 2 O (MIL-145)20In situ template generation via N-alkylation in the syntheses of open-framework zinc phosphites and phosphate29Synthesis of an extra-large molecular sieve using proton sponges as organic structure-directing agents118Solvothermal synthesis of new open-framework metal phosphites with structure-directing agents generated in situ6The role of small organic amine molecules and their aggregates in the crystallization of microporous materials3Fluorinated mixed valence Fe( ii )–Fe( iii ) phosphites with channels templated by linear tetramine chains. Structural and magnetic implications of partial replacement of Fe( ii ) by Co( ii )3Synthesis and characterization of a novel inorganic–organic hybrid open-framework zinc phosphate with 16-ring channels10Concise template syntheses of gallium phosphates driven by in situ direct alkylation of aliphatic and aromatic precursors by methanol10Synthesis, structure and characterization of two new organic template-directed gallium phosphate/phosphite-oxalates18Syntheses and Crystal Structures of Three Organically Templated Gallium Phosphates2Silver-Rich Hybrid Framework Iodide Based on [Ag8I6]2+ Clusters Displays Low-Temperature Dual Emission and Luminescence Thermochromism4A supramolecular non centrosymmetric 2,6-diaminopyridinium perchlorate salt: Crystal structure and optoelectronic DFT study9

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  1. 22 New compounds and structures in the solid state

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  2. Hydrothermal synthesis and characterization of a new inorganic–organic hybrid layered zinc phosphate–phosphite (C 6 H 15 N 2 ) 2 Zn 4 (PO 4 ) 2 (HPO 3 ) 2

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  3. Templated inorganic networks: recent developments

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  4. Partial substitution of the amine template by alkali metals (Rb, Cs) in the open-framework gallium phosphates ULM-3 and TREN-GaPO

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  5. 21 New compounds and structures in the solid state

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  6. Rational design of porous titanophosphates

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  7. MIL-50, an Open-Framework GaPO with a Periodic Pattern of Small Water Ponds and Dry Rubidium Atoms: a Combined XRD, NMR, and Computational Study

    Journal of the American Chemical Society · 2003-01-24

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  8. Refinement of the crystal structure of gallium oxide hydroxide, GaO(OH)

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  9. A Novel Open‐Framework Gallium Phosphate Containing Two Different Building Units

    European Journal of Inorganic Chemistry · 2003-03-20

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  10. Synthesis and Crystal Structure of a New Fluorogallophosphate Named Mu-12

    Chemistry of Materials · 2003-06-05

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  11. Order−Disorder in the Super-Sodalite Zn3Al6(PO4)12, 4tren, 17H2O (MIL-74): A Combined XRD−NMR Assessment

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    L. Beitone, Clarisse Huguenard, Axel Gansmüller, Marc Henry, Françis Taulelle, Thierry Loiseau, Gérard Férey

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  12. Ga(2,2‘-bipy)(HPO4)(H2PO4): First Layered Inorganic−Organic Hybrid Gallium Phosphate with a Neutral Framework

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    Zhien Lin, Jie Zhang, Yan‐Qiong Sun, Guo‐Yu Yang

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  13. A novel gallium arsenate organically templated by propane-1,3-diyldiammonium with a ULM-3-type open framework: [Ga3(AsO4)3(OH)F](C3H12N2)·H2O

    Acta Crystallographica Section C Crystal Structure Communications · 2004-02-10

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  14. Hydrothermal synthesis and structure of the new three-dimensional fluorogallophosphate JGP-4 with a Ga/P ratio of 7/8

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  15. SSZ-51A New Aluminophosphate Zeotype: Synthesis, Crystal Structure, NMR, and Dehydration Properties

    Chemistry of Materials · 2004-06-26

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  16. Hydrothermal synthesis and characterization of two new three-dimensional fluoroindium phosphates In4(PO4)4(H2O)4F2·C6H14N2 and In8(PO4)8(H2O)8F4·(C5H14N2)2

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  17. Structural Analysis of F/OH Distribution in a Hybrid Open-Framework Fluorinated Gallium Oxalate−Phosphate Templated by 1,3-Diaminopropane (MIL-90)

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  18. Thermal Transformation of (NH4)[Fe(AsO4)F] Into the New Textural Porous Orthorhombic Fe(AsO4) Phase. Crystal Structures, Thermal Behavior, and Spectroscopic and Magnetic Properties

    Chemistry of Materials · 2004-11-13

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  19. Hydrothermal synthesis and characterization of two new three-dimensional open-framework gallophosphates JGP-n (, 9) constructed from inorganic layers and HPO4 tetrahedra

    Solid State Sciences · 2004-12-24

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  20. Crystallized Frameworks with Giant Pores: Are There Limits to the Possible?

    Accounts of Chemical Research · 2005-01-19

    Gérard Férey, Caroline Mellot‐Draznieks, Christian Serre, Franck Millange

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  21. Hydrothermal synthesis and structure of organically templated chain, layered and framework scandium phosphates

    Journal of Solid State Chemistry · 2005-04-26

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  22. Ga3(HPO3)4F4(H3DETA) (DETA=diethylenetriamine): A new open-framework fluorinated gallium phosphite with pentameric building unit

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    Li Wang, Tianyou Song, Yong Fan, Ying Wang, Jianing Xu, Suhua Shi, Tao Zhu

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  23. [(C4H12N)2][Zn3(HPO3)4]: An Open‐Framework Zinc Phosphite Containing Extra‐Large 24‐Ring Channels

    Angewandte Chemie · 2006-03-17

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  24. [(C4H12N)2][Zn3(HPO3)4]: An Open‐Framework Zinc Phosphite Containing Extra‐Large 24‐Ring Channels

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  25. [Ni(C6N2H14)2][Zn4(H2O)(HPO3)5]: A new open-framework zinc phosphite with intersecting 8-, 12- and 16-ring channels

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  26. Crystalline oxyfluorinated open-framework compounds: Silicates, metal phosphates, metal fluorides and metal-organic frameworks (MOF)

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  27. Novel open-framework fluorinated indium phosphate with 14-ring intersecting channels: Assembled from 6∗1 and racemic pillared secondary building units

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  28. Hydrothermal synthesis and crystal structures of two open-framework fluorinated aluminum phosphates templated by 1,3-diaminopropane (ULM-4 & MIL-64)

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  29. 2,2′-Bipyridine,1,10-phenanthroline and 2,2′:6′,2″-terpyridine in gallium(III) chemistry: Complexes containing the core

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  30. Computational simulation study towards the synthesis of extra-large microporous materials

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  31. The effect of the nature of included metal cations on the structure and the adsorption and acidic characteristics of VFI aluminophosphates

    Theoretical and Experimental Chemistry · 2007-09-01

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  32. 2H3O·[Co8(HPO3)9(CH3OH)3]·2H2O: An Open-Framework Cobalt Phosphite Containing Extra-Large 18-Ring Channels

    Chemistry of Materials · 2007-12-08

    Lang Zhao, Jiyang Li, Peng Chen, Guanghua Li, Jihong Yu, Ruren Xu

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  33. Retracted article: Recognition of 1,3-cyclohexane bis(methylamine) isomers via template synthesis of open-framework bimetallic phosphites

    Chemical Communications · 2007-12-20

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  34. Doping-Induced Structure Variation of 1,3-Cyclohexane− Bis(methylamine)-Templated Zinc−Phosphorus Open Structures

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  35. Hydrothermal synthesis, characterization and fluorescence property of a novel layered fluorinated gallium phosphite with heptameric building unit

    Journal of Solid State Chemistry · 2008-02-12

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  36. Template-Designed Syntheses of Open-Framework Zinc Phosphites with Extra-Large 24-Ring Channels

    Crystal Growth & Design · 2008-05-24

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  37. Two Neutral Open-framework Metal Phosphites with Ten-ring Channels Constructed by Three-, Four-, and Five-connected Centers

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  38. Metal Complexes of Organophosphate Esters and Open-Framework Metal Phosphates: Synthesis, Structure, Transformations, and Applications

    Chemical Reviews · 2008-06-28

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  39. Template Syntheses of Two Open‐framework Zinc Phosphites

    Zeitschrift für anorganische und allgemeine Chemie · 2008-07-28

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  40. Separation of 1,3‐Cyclohexanebis(methylamine) Isomers by Template Synthesis of Open‐Framework Bimetallic Phosphites

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  41. The Long Story and the Brilliant Future of Crystallized Porous Solids

    Structure and bonding · 2009-01-01

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  42. Mild hydrothermal synthesis, crystal structure, thermal behavior, spectroscopic and magnetic properties of the (NH4)[Fe(AsO4)1−x(PO4)xF] (x=0.3, 0.6, 0.8) series. Thermal transformation of (NH4)[Fe(AsO4)0.7(PO4)0.3F] into the textural porous orthorhombic Fe(AsO4)0.7(PO4)0.3

    Journal of Solid State Chemistry · 2009-02-02

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  43. [Cu4OCl6(DABCO)2]·0.5DABCO·4CH3OH (“MFU-5”): Modular synthesis of a zeolite-like metal-organic framework constructed from tetrahedral {Cu4OCl6} secondary building units and linear organic linkers

    Journal of Solid State Chemistry · 2009-11-01

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  44. Characterization of the gel phases formed in the synthesis of microporous gallophosphate, cloverite

    Journal of Materials Chemistry · 2010-01-01

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  45. Extra‐Large‐Pore Zeolites: Bridging the Gap between Micro and Mesoporous Structures

    Angewandte Chemie International Edition · 2010-04-07

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  46. Zeolithe mit sehr großen Poren als Bindeglied zwischen mikro‐ und mesoporösen Strukturen

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  47. Oxidation Tools in the Synthesis of Catalysts and Related Functional Materials

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  48. A new open-framework indium phosphate–phosphite containing intersecting extra-large 16-ring channels

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  49. Mild hydrothermal synthesis, crystal structure, thermal behaviour, spectroscopic and magnetic properties of (NH4)0.80Li0.20[Fe(AsO4)F]

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  50. Assembly of a new circle connecting circle chain through exerting the template role of a Keggin polyoxometalate

    Journal of Coordination Chemistry · 2011-12-21

    Jun Ying, Min-Hou, Xiaojing Liu, Aixiang Tian, Xiuli Wang

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