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RESEARCH PAPER · Journal of the American Chemical Society · 2000

Exploration of a Simple Universal Route to the Myriad of Open-Framework Metal Phosphates

C. N. R. Rao, Srinivasan Natarajan, S. Neeraj

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Exploration of a Simple Universal Route to the Myriad of Open-Framework Metal PhosphatesOriginalOrganic–inorganic hybrid solids: control of perhalometallate solid state structures †113Simple linear-chain cobalt phosphates27Solution-mediated synthesis of a three-dimensional zinc phosphate in the presence of a monoamine16Building Open-Framework Metal Phosphates from Amine Phosphates and a Monomeric Four-Membered Ring Phosphate63Synthesis and Structure of a One-Dimensional Cobalt Phosphate: (R, S)-(C5H14N2)Co(HPO4)217Three-Dimensional Zinc Phosphates with Open Architectures45Formation of One-, Two-, and Three-Dimensional Open-Framework Zinc Phosphates in the Presence of a Tetramine119Synthesis and Structure of (H3NC2H4NH3)2Co7(PO4)6: A Novel Open Framework Cobalt Phosphate23A Three-Dimensional Iron(III) Phosphate, [C2N2H10]2[Fe5F4(PO4)(HPO4)6]25Layered Cobalt Phosphates by the Amine Phosphate Route33Aufbau Principle of Complex Open-Framework Structures of Metal Phosphates with Different Dimensionalities357Cooperative Guest Inclusion by a Zeolite Analogue Coordination Polymer. Sorption Behavior with Gases and Amine and Group 1 Metal Salts252A layered chlorophosphate, Na3[Cd4Cl3(HPO4)2(H2PO4)4], containing Na+ ions in the interlamellar space4A zinc phosphate oxalate with phosphate layers pillared by the oxalate units24Direct in situ observation of increasing structural dimensionality during the hydrothermal formation of open-framework zinc phosphates53Linear-Chain AlPOs Obtained by the Reaction of Amine Phosphates with Al3+ Ions15Synthesis and Characterization of A New Open-Framework Cobalt Phosphate: Cs2Co3(HPO4)(PO4)2·H2O14Synthesis of a hierarchy of zinc oxalate structures from amine oxalates81Transformations of low-dimensional zinc phosphates to complex open-framework structures. Part 1: zero-dimensional to one-, two- and three-dimensional structures111Transformations of the low-dimensional zinc phosphates to complex open-framework structures. Part 2: one-dimensional ladder to two- and three-dimensional structures103A Layered Zinc Phosphate, [C6N4H22][Zn6(PO4)4(HPO4)2], Formed by One-Dimensional Tubes21Hydrothermal synthesis and structure determination of Ag3(VVO2){O3PCH2PO3} or MIL-42: a new vanadium(V) methylendiphosphonate inserting silver cations17Synthons and design in metal phosphates and oxalates with open architectures44Understanding the Movement, Encapsulation, and Energy Barrier of Water Molecule Diffusion into and in Silicalites Using Ab Initio Calculations17Highly stable open frameworks of Ln–Cu (Ln=La, Ce) 3D coordination polymers containing spacious hexagon channels and unusual μ2-H2O bridges35Hydrothermal synthesis of a new layered inorganic–organic hybrid cobalt(II) phosphite: (C2H10N2)[Co3(HPO3)4]84A three-dimensional zeolitic zinc phosphate, [C8N5H28][Zn5(PO4)5]H2O, with thomsonite structure22One-dimensional zinc phosphates with linear chain structure25Structural influences of 1,10-phenanthroline on one- and two-dimensional organic–inorganic hybrid materials of the copper–oxovanadium–phosphate family28Basic building units, self-assembly and crystallization in the formation of complex inorganic open architectures13Synthesis and characterization of Mu-19, a new zincophosphate with a three-dimensional 12-membered ring channel system22Hydrothermal synthesis of the first organically templated open-framework uranium phosphate66Synthesis and Characterization of a New Layered Zinc Phosphate: (C3H4N2)3Zn4(HPO4)(PO4)2 with Imidazole Coordinating to Zn Atoms5The First Open-Framework Cadmium Phosphate, K4[Cd3(HPO4)4(H2PO4)2], with a Layered Structure16A new route for the synthesis of open-framework metal phosphates using organophosphates20An approach to the synthesis of organically templated open-framework metal sulfates by the amine–sulfate route94Hydrothermal synthesis and characterization of a new inorganic–organic hybrid layered zinc phosphate–phosphite (C 6 H 15 N 2 ) 2 Zn 4 (PO 4 ) 2 (HPO 3 ) 254Synthesis and characterization of the one-dimensional zincophosphate Mu-22: [Zn(HPO4)2]8[C5H13N2]8• 8 H2O14[C6N4H24]CoBe6P6O24·3H2O: a novel 3-dimensional beryllophosphate zeolite-like structure encapsulating CoII ions20Solvothermal Synthesis and Characterization of an One-Dimensional Zinc Phosphate4Hydrothermal synthesis and structural characterization of organically templated zinc vanadium phosphates: [Zn(2,2′-bipyridine)(VO2)(PO4)], [Zn(2,2′:6′,2″-terpyridine)(VO2)(PO4)], and [Zn(1,10-phenanthroline)(ZnVO)(PO4)2]31Perovskites by Design: A Toolbox of Solid-State Reactions736Sulfates of organic diamines: hydrogen-bonded structures and properties46An open-framework zincoborate formed by Zn6B12O24 clusters64Transformations of two-dimensional layered zinc phosphates to three-dimensional and one-dimensional structures43Synthesis of a layered zinc phosphate, [NH3(CH2)2NH2(CH2)3NH3][Zn2(PO4)(HPO4)2]·H2O, and its transformation to a extra-large pore three-dimensional zinc phosphate, [NH3(CH2)2NH2(CH2)3NH3][Zn3(PO4)(HPO4)3]26A layered zinc oxalate possessing a 12-membered honeycomb aperture, stabilized by an amine and an alkali cation10Synthesis and Structure of an Open-Framework Zincophosphate [C6N4H22][ZnPO4]412A Reactive Intermediate in the Synthesis of Iron Arsenates: Synthesis of the First One-Dimensional Iron Arsenate Oxalate and Its Transformation into Two- and Three-Dimensional Iron Arsenates50A Reactive Intermediate in the Synthesis of Iron Arsenates: Synthesis of the First One-Dimensional Iron Arsenate Oxalate and Its Transformation into Two- and Three-Dimensional Iron Arsenates6Synthesis and structure of a layered zinc phosphate–acetate, [C5H10NH2]2[Zn(ZnO2CCH3)(PO4)(HPO4)]8Direct synthesis of bis(n-alkylammonium) monohydrogen phosphates by solid–vapour reaction2Hydrothermal Synthesis and Structure of a Neutral Open-Framework Zincophosphate6Novel Inorganic Coordination Polymers Based on Cadmium Oxalates22On the diffusion of water in silicalite-1: MD simulations using ab initio fitted potential and PFG NMR measurements45Synthesis and Structure of a New Layered Zincophosphate Zn6(PO4)5(HPO4)·C8N5H28·5H2O, Intercalated with Quintuply Protonated Tetraethylenepentamine12Two polymorphs of a piperazinium zincophosphate with different interrupted SOD-type frameworks11Combinatorial approach for the hydrothermal syntheses of open-framework zinc phosphates49Synthesis of open-framework zinc phosphates from organophosphorus amides19Synthesis and structure of an open-framework cobalt zincophosphate17Recent results from the in situ study of hydrothermal crystallisations using time-resolved X-ray and neutron diffraction methods33Open-Framework Cobalt (II) Phosphates with Sodalite-Related Architectures17Hydro/Solvothermal Synthesis and Structures of New Zinc Phosphates of Varying Dimensionality36Synthesis and structure of a zinc oxalate with honeycomb layers and zinc phosphates with one- and three-dimensional structures31Hydrothermal Synthesis and Structures of Three-Dimensional Zinc Phosphates Built-Up from Two-Dimensional Layers and One-Dimensional Chains and Ladders17Synthesis of AlPO4s and Other Crystalline Materials11C4N3OH7·Zn(H2O)HPO4, a Neutral Zincophosphate Cluster26Isolation of a monomeric hybrid zinc phosphate and its one-dimensional relative24Synthesis and characterization of a new layered gallium phosphate [Co(en)3][Ga3(H2PO4)6(HPO4)3] templated by cobalt complex42Zinc10Synthesis and characterisation of the layered zinc phosphate KZn2(PO4)(HPO4)10(C6H16N2)Zn3(HPO3)4H2O: a new layered zinc phosphite templated by diprotonated trans-1,4-diaminocyclohexane35New Framework Connectivity Patterns in Templated Networks: The Creatinine Zinc Phosphites C 4 N 3 OH 7 ·ZnHPO 3 , C 4 N 3 OH 7 ·Zn(H 2 O)HPO 3 , and (C 4 N 3 OH 7 ) 2 ·ZnHPO 3 ·H 2 O47An Open-framework Zincophosphate with Intersecting Channels3Synthesis and structure of a new layered zinc phosphite (C5H6N2)Zn(HPO3) containing helical chains107Role of Chains in the Formation of Extended Framework Tin(II) Phosphates and Related Materials30Order−Disorder in the Super-Sodalite Zn3Al6(PO4)12, 4tren, 17H2O (MIL-74): A Combined XRD−NMR Assessment84Synthesis of a Single Four-Ring (S4R) Molecular Zinc Phosphate and Its Assembly to an Extended Polymeric Structure: A Single-Crystal and in-Situ MAS NMR Investigation53Synthesis and characterization of a new zinc phosphate with 16-ring channels: Zn3PO4(HPO4)3·C6N3H1815Hydrothermal synthesis and structural characterization of novel organically templated zincophosphites: [C6H4(CH2NH3)2]·[Zn3(HPO3)4] and [CH3CH2CH2NH3]2·[Zn3(HPO3)4]22Synthesis and Structure of the First Three‐legged Low‐dimensional Iron Phosphate, [H3N(CH2)3NH2(CH2)2NH2(CH2)3NH3][Fe3F6(HPO4)2(PO4)]·3H2O3Theoretical prediction of low-frequency vibrations of extra-framework cations in mordenite zeolites8Synthesis and characterization of a new layered vanadium selenite: β-(H3NCH2CH2NH3)[(VO)(SeO3)2]10Hydrothermal synthesis and characterization of new hybrid open-framework indium phosphate-oxalates10Open-framework zinc and cobalt phosphates synthesized by the tributylphosphate route25Amino Acid Templating of Inorganic Networks: Synthesis and Structure of l -Asparagine Zinc Phosphite, C4N2O3H8·ZnHPO388Modeling the Effect of Hydration in Zeolite Na+−Mordenite65Hydrothermal synthesis and structural characterization of organically-templated copper vanadium phosphates: the two-dimensional [{Cu2(bisterpy)}V3O5(HPO4)2(PO4)] (1) and the three-dimensional [{Cu2(bisterpy)}V2O5(HPO4)2] (2) (bisterpy=2,2′:4′,4″:2″,2‴-quarterpyridyl, 6′,6″-dipyridine)27Formation of One-Dimensional Water Inside an Organic Solid: Supramolecular Architectures Derived by the Interaction of Aminobenzoic Acids with Nitrogen Bases and H2SO449Two zincophosphite frameworks templated by 1,4-diaminobenzene: syntheses and structures of C6N2H10·Zn(HPO3)2 and (C6N2H8)0.5·ZnHPO325Solvothermal synthesis of an open-framework zinc chlorophosphate, [C8N4H26][Zn3Cl(HPO4)3(PO4)], with a layer structure11A novel self-complementary three-dimensional inorganic network organized by H-bond dimers of inorganic chains Synthesis and crystal structure of (C6H16N2)[Zn(HPO4)2]5Kinetic and Mechanistic Investigations of Hydrothermal Transformations in Zinc Phosphates64Nanoporous Metal‐Containing Nickel Phosphates: A Class of Shape‐Selective Catalyst49Nanoporous Metal‐Containing Nickel Phosphates: A Class of Shape‐Selective Catalyst2(C6H17N3)[Zn4(PO4)2(HPO3)2]: a new layered zinc phosphate–phosphite templated by 1-(2-Aminoethyl) piperazine10Building three-dimensional metal phosphites from the corner-shared four-membered rings chain26[Co(en)3][In3(H2PO4)6(HPO4)3]·H2O: A new layered indium phosphate templated by cobalt complex23A New 3‐D Open‐Framework Zinc Phosphate [C6H16N2]·[Zn2(HPO4)3] Synthesized by a Solvothermal Combinatorial Approach8Chiral Bisphosphinite Metalloligands Derived from a P-Chiral Secondary Phosphine Oxide40Hydrothermal synthesis and structural characterization of novel organically templated zincophosphites: [H2mpipe] · [Zn3(HPO3)4] and [H2en]1.5· [Zn4.5(HPO3)6] (mpipe = 1-methylpiperazine and en = ethylenediamine)8A Templated Bimetallic Phosphate Open-structure with 16-MR Channels6A New Organic‐Inorganic Hybrid Gallophosphate Prepared in the Presence of Glycine18Hydrothermal synthesis and crystal structure of a hybrid material based on [Cu4(bpy)4(H2O)2(PO4)2]2+ and an α-Keggin polyoxoanion22Isomorphous Substitution of Transition-Metal Ions in the Nanoporous Nickel Phosphate VSB-549The pH-controlled hydrothermal synthesis and crystal structures of two zinc N,N′-piperazinebis(methylenephosphonate) frameworks26Two new cobalt–zinc orthophosphate monohydrates: hydrothermal synthesis, crystal structures and thermal investigation6New Amine-Templated Zinc Phosphates with a Temperature-Induced Increase of Structural Dimensionality20New Zinc Phosphates Decorated by Imidazole-Containing Ligands95Toward the Rational Design of Open-Framework Materials21Five New Zinc Phosphite Structures: Tertiary Building Blocks in the Construction of Hybrid Materials75[Zn(H2PO4)4]2− clusters and ∞[Zn2(HPO4)3(H2PO4)2]4− layers in two new zinc phosphates templated by [H2(4-amino-2.2.6.6-tetramethylpiperidine)]2+ cations7The Role of Amine Sulfates in Hydrothermal Uranium Chemistry63Synthesis, structure and magnetic characterization of a vanadium(IV) phosphite, [C2N2H10]·[(VO)3(H2O)(HPO3)4]·H2O16Cobalt substitution in a nano-porous zinc phosphate: Hydrothermal synthesis and crystal structure11Hydrothermal synthesis and structural characterization of organically templated zincophosphites: [C6H22N4]0.5⋅[Zn2(HPO3)3] and [C3N2H5]⋅[Zn1.5(HPO3)2]13An Organo-templated Iron Zincophosphate with Zeolite DFT Topology11Novel Zinc Phosphate Topologies Defined by Organic Ligands95{Zn3(Et2O)2[(EtO)PO2(C6H5NH)]6·2THF}: A Trinuclear Zinc Amidophosphate with an Hourglass Structure6Synthesis and X‐ray Structure of n‐Propylimidodiphosphonic Anhydride, a New Precursor for the Hydrothermal or Solvothermal Synthesis of Zinc Phosphates2MnII/CoII‐Terephthalate Frameworks Containing Dipyridine Coligands: Syntheses, Crystal Structures, Magnetic Behaviors, and Thermal Studies74A tetranuclear zinc cluster, (bipy)4Zn4(HPO3)4, that stabilizes a hydrogen bonded chain of water molecules: Transformation of a zinc phosphite 4-ring to a cluster16Hydrothermal synthesis and structural characterization of organically templated zincophosphites: [Zn(C4N3H13)][Zn4(HPO3)6]⋅(C4N3H15) and [Zn5(H2O)4(HPO3)6]⋅(C7NH10)2(H2O)11Syntheses, Structures, and Magnetic Properties of Inorganic−Organic Hybrid Cobalt(II) Phosphites Containing Bifunctional Ligands137Organically-templated metal sulfates, selenites and selenates194Two new high-nuclearity copper(II) chloride oligomers with herringbone stacking patterns synthesized by in situ templation7A novel hydrogen-bonded cyclic dibromide in an organic diammonium salt7Solvothermal synthesis and removal capacity for hydrogen chloride gas of Zn(OH)(NO3) with a rare (10,3)-d net8Synthesis of open-framework zinc phosphite structures of varying dimensionality17[Zn2(HPO3)2(H2PO3)][C3H5N2] and [Zn2(HPO3)3][C4H7N2]2·2H2O: Two new layered zinc phosphites with double 12-membered rings templated by imidazole and 2-methylimidazole14Hydrothermal synthesis and characterization of a novel 3D open framework structure of mixed valence ethylenediamine–vanadium phosphate: [C2H10N2][(HVIVO3)(HVVO2) (PO4)]9A new three-dimensional cobalt phosphate: Co5(OH2)4(HPO4)2(PO4)211Hydrothermal Synthesis and Characterization of Two Cobalt Phosphates Based on Double-Four-Ring Units with Fluorine-Occlusion and Phosphite-Substitution Modifications15Transformations of a layer and a chain aluminophosphates to the zeotype ∣Al–P–M–O∣–GIS (M = Co2+, Mn2+, Mg2+)7Inorganic–Organic Calcium Carbonate Composite of Synthetic Polymer Ligands with an Intramolecular NH···O Hydrogen Bond9Two Organically Templated Niobium and Zinconiobium Fluorophosphates: Low Temperature Hydrothermal Syntheses of NbOF(PO4)2(C2H10N2)2 and Zn3(NbOF)(PO4)4(C2H10N2)217Old materials with new tricks: multifunctional open-framework materials1073Piperazinium dihydrogen phosphate, C4H12N2(H2PO4)2: Synthesis, 31P CP/MAS NMR, structural and thermal investigations15Synthesis of Tin(II) Phosphate Open Frameworks Using Isomers of 1,2‐Diaminocyclohexane as Template3Na[H2TETA]0.5[ZnPO4]2·0.5H2O or TJPU-1: A New Zincophosphate Open-structure Co-templated by Sodium and Organoamine7Hydrothermal synthesis and structure of an open framework Co0.7Zn1.3(PO4)2(NH3–CH2CH2NH3) and Co6.2(OH)4(PO4)4Zn1.80, a new adamite type phase2Solvent effects on the reactions of copper chlorides with OP(NH-t-Bu)3 — Formation of the novel [Cu5Cl10]5– anion via in situ templation9Cobalt(II) Complexes with N‐Thioacylamidophosphates and 2,2′‐Bipyridyl and 1,10‐Phenathroline. Crystal Structures, Solution 1H NMR Spectral and Magnetic Properties20Syntheses and Characterizations of Three Low-Dimensional Chloride-Rich Zincophosphates Assembled about [ d -Co(en) 3 ] 3+ and [ dl -Co(en) 3 ] 3+ Complex Cations17A 3D supramolecular network of cobalt(II)(bis(4-pyridyl)ethylene) with terephthalate dianions5The effect of mixed amines on the competitive formation of two open-framework zinc phosphates with 16-ring large channels4A Zeolite‐Like Zinc Phosphonocarboxylate Framework and Its Transformation into Two‐ and Three‐Dimensional Structures46Tuning Orbital Energetics in Arylene Diimide Semiconductors. Materials Design for Ambient Stability of n-Type Charge Transport1056Syntheses and Crystal Structures of Two New Open‐Framework Tin(II) Phosphates: Sn5O2(PO4)2 and Sn4O(PO4)27Hierarchical Structures in Tin(II) Oxalates19

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  1. Organic–inorganic hybrid solids: control of perhalometallate solid state structures †

    Journal of the Chemical Society Dalton Transactions · 2000-01-01

    Amy L. Gillon, G.R. Lewis, A. Guy. Orpen, Sarah Rotter, Jonathan Starbuck, Ximeng Wang, Yolanda Rodríguez-Martín, Catalina Ruíz-Pérez

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  2. Simple linear-chain cobalt phosphates

    Journal of the Chemical Society Dalton Transactions · 2000-01-01

    Amitava Choudhury, Srinivasan Natarajan, C.N.R. Rao

    Read original paper ↗ ·

  3. Solution-mediated synthesis of a three-dimensional zinc phosphate in the presence of a monoamine

    Journal of Materials Chemistry · 2000-01-01

    Ayi A. Ayi, Amitava Choudhury, Srinivasan Natarajan, C. N. R. Rao

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  4. Building Open-Framework Metal Phosphates from Amine Phosphates and a Monomeric Four-Membered Ring Phosphate

    Journal of Solid State Chemistry · 2000-06-01

    C. N. R. Rao, Srinivasan Natarajan, S. Neeraj

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  5. Synthesis and Structure of a One-Dimensional Cobalt Phosphate: (R, S)-(C5H14N2)Co(HPO4)2

    Journal of Solid State Chemistry · 2000-08-01

    Ray‐Kuang Chiang

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  6. Three-Dimensional Zinc Phosphates with Open Architectures

    Chemistry of Materials · 2000-08-22

    S. Neeraj, Srinivasan Natarajan

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  7. Formation of One-, Two-, and Three-Dimensional Open-Framework Zinc Phosphates in the Presence of a Tetramine

    Inorganic Chemistry · 2000-08-23

    Amitava Choudhury, Srinivasan Natarajan, C.N.R. Rao

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  8. Synthesis and Structure of (H3NC2H4NH3)2Co7(PO4)6: A Novel Open Framework Cobalt Phosphate

    Inorganic Chemistry · 2000-09-23

    Ray‐Kuang Chiang

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  9. A Three-Dimensional Iron(III) Phosphate, [C2N2H10]2[Fe5F4(PO4)(HPO4)6]

    Journal of Solid State Chemistry · 2000-11-01

    Amitava Choudhury, Srinivasan Natarajan

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  10. Layered Cobalt Phosphates by the Amine Phosphate Route

    Journal of Solid State Chemistry · 2000-11-01

    Amitava Choudhury, Srinivasan Natarajan, C.N.R. Rao

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  11. Aufbau Principle of Complex Open-Framework Structures of Metal Phosphates with Different Dimensionalities

    Accounts of Chemical Research · 2000-11-15

    C. N. R. Rao, Srinivasan Natarajan, Amitava Choudhury, S. Neeraj, Ayi A. Ayi

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  12. Cooperative Guest Inclusion by a Zeolite Analogue Coordination Polymer. Sorption Behavior with Gases and Amine and Group 1 Metal Salts

    Journal of the American Chemical Society · 2000-12-29

    Leandro C. Tabares, Jorge A. R. Navarro, Juan Manuel Salas

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  13. A layered chlorophosphate, Na3[Cd4Cl3(HPO4)2(H2PO4)4], containing Na+ ions in the interlamellar space

    New Journal of Chemistry · 2001-01-01

    Jayaraman Krishnamoorthy, Amitava Choudhury, Ramanathan Vaidhyanathan, C. N. R. Rao

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  14. A zinc phosphate oxalate with phosphate layers pillared by the oxalate units

    Journal of the Chemical Society Dalton Transactions · 2001-01-01

    S. Neeraj, Srinivasan Natarajan, C. N. R. Rao

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  15. Direct in situ observation of increasing structural dimensionality during the hydrothermal formation of open-framework zinc phosphates

    Chemical Communications · 2001-01-01

    Richard I. Walton, Alexander J. Norquist, Dermot M. O'Hare, S. Neeraj, Srinivasan Natarajan, C.N.R. Rao

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  16. Linear-Chain AlPOs Obtained by the Reaction of Amine Phosphates with Al3+ Ions

    Journal of Solid State Chemistry · 2001-01-01

    Ayi A. Ayi, Amitava Choudhury, Srinivasan Natarajan

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  17. Synthesis and Characterization of A New Open-Framework Cobalt Phosphate: Cs2Co3(HPO4)(PO4)2·H2O

    Journal of Solid State Chemistry · 2001-01-01

    Ray‐Kuang Chiang, Chi‐Chun Huang, Chun-Rong Lin, Ching‐Shuei Wur

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  18. Synthesis of a hierarchy of zinc oxalate structures from amine oxalates

    Journal of the Chemical Society Dalton Transactions · 2001-01-01

    Ramanathan Vaidhyanathan, Srinivasan Natarajan, C. N. R. Rao

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  19. Transformations of low-dimensional zinc phosphates to complex open-framework structures. Part 1: zero-dimensional to one-, two- and three-dimensional structures

    Journal of Materials Chemistry · 2001-01-01

    Ayi A. Ayi, Amitava Choudhury, Srinivasan Natarajan, S. Neeraj, C. N. R. Rao

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  20. Transformations of the low-dimensional zinc phosphates to complex open-framework structures. Part 2: one-dimensional ladder to two- and three-dimensional structures

    Journal of Materials Chemistry · 2001-01-01

    Amitava Choudhury, S. Neeraj, Srinivasan Natarajan, C. N. R. Rao

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  21. A Layered Zinc Phosphate, [C6N4H22][Zn6(PO4)4(HPO4)2], Formed by One-Dimensional Tubes

    Journal of Solid State Chemistry · 2001-02-01

    Amitava Choudhury, Srinivasan Natarajan, C.N.R. Rao

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  22. Hydrothermal synthesis and structure determination of Ag3(VVO2){O3PCH2PO3} or MIL-42: a new vanadium(V) methylendiphosphonate inserting silver cations

    Solid State Sciences · 2001-02-01

    Karin Barthelet, Didier Riou, Gérard Férey

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  23. Synthons and design in metal phosphates and oxalates with open architectures

    Acta Crystallographica Section B Structural Science · 2001-02-01

    C. N. R. Rao, Srinivasan Natarajan, Amitava Choudhury, S. Neeraj, Ramanathan Vaidhyanathan

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  24. Understanding the Movement, Encapsulation, and Energy Barrier of Water Molecule Diffusion into and in Silicalites Using Ab Initio Calculations

    The Journal of Physical Chemistry B · 2001-04-04

    Chuenchit Bussai, Supot V. Hannongbua, Reinhold Haberlandt

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  25. Highly stable open frameworks of Ln–Cu (Ln=La, Ce) 3D coordination polymers containing spacious hexagon channels and unusual μ2-H2O bridges

    Inorganic Chemistry Communications · 2001-06-01

    Qin‐De Liu, Jun-Ran Li, Song Wei Gao, Bao‐Qing Ma, Fuhui Liao, Qingzhong Zhou, Kai‐Bei Yu

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  26. Hydrothermal synthesis of a new layered inorganic–organic hybrid cobalt(II) phosphite: (C2H10N2)[Co3(HPO3)4]

    International Journal of Inorganic Materials · 2001-07-01

    Sergio Fernández, José Luis Pizarro, Jose Luis Mesa, Luis M. Lezama, María Isabel Arriortua, Teófilo Rojo

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  27. A three-dimensional zeolitic zinc phosphate, [C8N5H28][Zn5(PO4)5]H2O, with thomsonite structure

    Journal of Physics and Chemistry of Solids · 2001-08-01

    S. Neeraj, Srinivasan Natarajan

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  28. One-dimensional zinc phosphates with linear chain structure

    Journal of Physics and Chemistry of Solids · 2001-08-01

    Ayi A. Ayi, S Neeraj, Amitava Choudhury, Srinivasan Natarajan, C. N. R. Rao

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  29. Structural influences of 1,10-phenanthroline on one- and two-dimensional organic–inorganic hybrid materials of the copper–oxovanadium–phosphate family

    Journal of Physics and Chemistry of Solids · 2001-08-01

    Robert C. Finn, Jon A. Zubieta

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  30. Basic building units, self-assembly and crystallization in the formation of complex inorganic open architectures

    Journal of Chemical Sciences · 2001-10-01

    C. N. R. Rao

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  31. Synthesis and characterization of Mu-19, a new zincophosphate with a three-dimensional 12-membered ring channel system

    Microporous and Mesoporous Materials · 2001-10-01

    Angélique Simon‐Masseron, Ludovic Josien, V. Gramlich, Joël Patarin

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  32. Hydrothermal synthesis of the first organically templated open-framework uranium phosphate

    Chemical Communications · 2001-10-31

    Janet A. Danis, Wolfgang H. Runde, Brian L. Scott, James C. Fettinger, Bryan W. Eichhorn

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  33. Synthesis and Characterization of a New Layered Zinc Phosphate: (C3H4N2)3Zn4(HPO4)(PO4)2 with Imidazole Coordinating to Zn Atoms

    Chemistry Letters · 2001-11-01

    Ai‐Li Cui, Youwei Yao

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  34. The First Open-Framework Cadmium Phosphate, K4[Cd3(HPO4)4(H2PO4)2], with a Layered Structure

    Journal of Solid State Chemistry · 2001-12-01

    K. S. Jayaraman, Ramanathan Vaidhyanathan, Srinivasan Natarajan, C. N. R. Rao

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  35. A new route for the synthesis of open-framework metal phosphates using organophosphates

    Chemical Communications · 2001-12-06

    S. Neeraj, Paul M. Forster, C. N. R. Rao, Anthony Kevin Cheetham

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  36. An approach to the synthesis of organically templated open-framework metal sulfates by the amine–sulfate route

    Chemical Communications · 2001-12-10

    Amitava Choudhury, Jayaraman Krishnamoorthy, C. N. R. Rao

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  37. Hydrothermal synthesis and characterization of a new inorganic–organic hybrid layered zinc phosphate–phosphite (C 6 H 15 N 2 ) 2 Zn 4 (PO 4 ) 2 (HPO 3 ) 2

    Journal of the Chemical Society Dalton Transactions · 2002-01-01

    Yu Wang, Jihong Yu, Yu Du, Zhan Shi, Yongcun Zou, Ruren Xu

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  38. Synthesis and characterization of the one-dimensional zincophosphate Mu-22: [Zn(HPO4)2]8[C5H13N2]8• 8 H2O

    Solid State Sciences · 2002-01-01

    Sandrine Fleith, Ludovic Josien, Angélique Simon‐Masseron, V. Gramlich, Joël Patarin

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  39. [C6N4H24]CoBe6P6O24·3H2O: a novel 3-dimensional beryllophosphate zeolite-like structure encapsulating CoII ions

    Journal of Materials Chemistry · 2002-01-28

    Haoyu Zhang, Linhong Weng, Yaming Zhou, Zhenxia Chen, Jinyu Sun, Dongyuan Zhao

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  40. Solvothermal Synthesis and Characterization of an One-Dimensional Zinc Phosphate

    Crystal Research and Technology · 2002-02-01

    Yanxiong Ke, L. Jianmin, Z. Yugen, H. Gaofei, Jin Zheng, L. Zhibin

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  41. Hydrothermal synthesis and structural characterization of organically templated zinc vanadium phosphates: [Zn(2,2′-bipyridine)(VO2)(PO4)], [Zn(2,2′:6′,2″-terpyridine)(VO2)(PO4)], and [Zn(1,10-phenanthroline)(ZnVO)(PO4)2]

    Journal of the Chemical Society Dalton Transactions · 2002-02-08

    Robert C. Finn, Jon A. Zubieta

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  42. Perovskites by Design: A Toolbox of Solid-State Reactions

    Chemistry of Materials · 2002-02-09

    Raymond E. Schaak, Thomas E. Mallouk

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  43. Sulfates of organic diamines: hydrogen-bonded structures and properties

    Solid State Sciences · 2002-03-01

    K. Jayaraman, Amitava Choudhury, C. N. R. Rao

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  44. An open-framework zincoborate formed by Zn6B12O24 clusters

    Journal of the Chemical Society Dalton Transactions · 2002-03-05

    Amitava Choudhury, S. Neeraj, Srinivasan Natarajan, C. N. R. Rao

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  45. Transformations of two-dimensional layered zinc phosphates to three-dimensional and one-dimensional structures

    Journal of Materials Chemistry · 2002-03-05

    Amitava Choudhury, S. Neeraj, Srinivasan Natarajan, C.N.R. Rao

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  46. Synthesis of a layered zinc phosphate, [NH3(CH2)2NH2(CH2)3NH3][Zn2(PO4)(HPO4)2]·H2O, and its transformation to a extra-large pore three-dimensional zinc phosphate, [NH3(CH2)2NH2(CH2)3NH3][Zn3(PO4)(HPO4)3]

    Chemical Communications · 2002-03-12

    Srinivasan Natarajan

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  47. A layered zinc oxalate possessing a 12-membered honeycomb aperture, stabilized by an amine and an alkali cation

    Solid State Sciences · 2002-04-01

    Ramanathan Vaidhyanathan, Srinivasan Natarajan, C. N. R. Rao

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  48. Synthesis and Structure of an Open-Framework Zincophosphate [C6N4H22][ZnPO4]4

    Journal of Solid State Chemistry · 2002-04-01

    Yongnan Zhao, Jing Ju, Xiangming Chen, Xiuhong Li, Ru‐Ji Wang, Zhenhong Mai

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  49. A Reactive Intermediate in the Synthesis of Iron Arsenates: Synthesis of the First One-Dimensional Iron Arsenate Oxalate and Its Transformation into Two- and Three-Dimensional Iron Arsenates

    Angewandte Chemie International Edition · 2002-04-02

    Sandip Chakrabarti, Srinivasan Natarajan

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  50. A Reactive Intermediate in the Synthesis of Iron Arsenates: Synthesis of the First One-Dimensional Iron Arsenate Oxalate and Its Transformation into Two- and Three-Dimensional Iron Arsenates

    Angewandte Chemie · 2002-04-02

    Sandip Chakrabarti, Srinivasan Natarajan

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