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RESEARCH PAPER · Crystal Growth & Design · 2005

Directed Synthesis of Noncentrosymmetric Molybdates

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Directed Synthesis of Noncentrosymmetric MolybdatesOriginalDirected Synthesis of Noncentrosymmetric Molybdates Using Composition Space Analysis72Organically Directed Iron Sulfate Chains: Structural Diversity Based on Hydrogen Bonding Interactions31(S)-2-Methylpiperazinediium dichloride 0.42-hydrate2Synthetic Approaches for Noncentrosymmetric Molybdates59Strong Second Harmonic Generation from the Tantalum Thioarsenates A3Ta2AsS11 (A = K and Rb)265Charge density matching in templated molybdates26Synthesis, structural characterisation and thermal decomposition of a new organic–inorganic hybrid material (C5H14N2)[Cu(SO4)2(H2O)4]·H2O16Second-Order Nonlinear Optical Properties of Polyoxometalate Salts of a Chiral Stilbazolium Derivative67A Novel Nonlinear Optical Crystal Bi2ZnOB2O6107A Series of New Infrared NLO Semiconductors, ZnY6Si2S14, AlxDy3(SiyAl1−y)S7, and Al0.33Sm3SiS7134Synthesis, Structure, and Properties of the Noncentrosymmetric Hydrated Borate Na2B5O8(OH)·2H2O81Noncentrosymmetry in New Templated Gallium Fluorophosphates34Crystal structure, phase transition and thermal decomposition of a copper (II) sulfate dihydrate containing a chiral organic ammonium cation23NaVO2(IO3)2(H2O): A Unique Layered Material Produces A Very Strong SHG Response143Soluble Semiconductors AAsSe2 (A = Li, Na) with a Direct-Band-Gap and Strong Second Harmonic Generation: A Combined Experimental and Theoretical Study241Noncentrosymmetric Inorganic Oxide Materials: Synthetic Strategies and Characterisation Techniques8Syntheses, structures and properties of three nonmetal borates with salicylic acid and organic amines9Hybrid Organic−Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications1755A Slow Leak Synthetic Route to Organically Templated Gallium Sulfates8A congruently melting and deep UV nonlinear optical material: Li3Cs2B5O10104Synthesis, characterization and magnetic properties of four new organically templated metal sulfates [C5H14N2][MII(H2O)6](SO4)2, (MII = Mn, Fe, Co, Ni)35Synthesis, structure, and properties of the non-centrosymmetric borate Rb 2 CaB 8 O 26 H 240Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties84In-Phase Alignments of Asymmetric Building Units in Ln 4 GaSbS 9 (Ln = Pr, Nd, Sm, Gd−Ho) and Their Strong Nonlinear Optical Responses in Middle IR212Top-Seeded Solution Growth, Morphology, and Properties of a Polar Crystal Cs2TeMo3O1277[R-C7H16N2][V2Te2O10] and [S-C7H16N2][V2Te2O10]; new polar templated vanadium tellurite enantiomers34K3B6O10Cl: A New Structure Analogous to Perovskite with a Large Second Harmonic Generation Response and Deep UV Absorption Edge670Synthesis, structure, and properties of the non-centrosymmetric borate Rb2CaB8O26H2412A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks72Growth, thermal and optical properties of a novel nonlinear optical material K 3 B 6 O 10 Cl57Synthesis, crystal structures and thermal behaviour of organic–inorganic hybrids incorporating a chiral diamine19New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)50A new congruent-melting oxyborate, Pb 4 O(BO 3 ) 2 with optimally aligned BO 3 triangles adopting layered-type arrangement112A novel deep UV nonlinear optical crystal Ba3B6O11F2, with a new fundamental building block, B6O14 group180Li5Rb2B7O14: a new congruently melting compound with two kinds of B–O one-dimensional chains and short UV absorption edge25Noncentrosymmetric Inorganic Open-Framework Chalcohalides with Strong Middle IR SHG and Red Emission: Ba3AGa5Se10Cl2 (A = Cs, Rb, K)257Two New Noncentrosymmetric (NCS) Polar Oxides: Syntheses, Characterization, and Structure–Property Relationships in BaMTe2O7 (M = Mg2+ or Zn2+)50Inducing polarity in [VO3]nn− chain compounds using asymmetric hydrogen-bonding networks17Small non-polar complexes exhibiting significant piezoelectric properties: Solvothermal synthesis and crystal structures of MO5V(tren)·H2O (M=Mo and W; tren=tris(2-aminoethyl)amine)7Crystal structures of two enantiomorphous 2-ethylpiperazinediium hexaaquacopper sulfates [(R or S)-C5H14N2][Cu(H2O)6](SO4)26Noncentrosymmetry in new 2-methylpiperazinediium hexaaquazinc(II) bis(sulfate)4Sulfides with Strong Nonlinear Optical Activity and Thermochromism: ACd4Ga5S12 (A = K, Rb, Cs)1722-Dihydromethylpiperazinediium-M II (M II = Cu II , Fe II , Co II , Zn II ) double sulfates and their catalytic activity in diastereoselective nitroaldol (Henry) reaction49Role of Hydrogen-Bonding in the Formation of Polar Achiral and Nonpolar Chiral Vanadium Selenite Frameworks26Electronic structure and optical properties of the nonlinear optical crystal Pb4O(BO3)2 by first-principles calculations10Preservation of Chirality and Polarity between Chiral and Polar Building Units in the Solid State21Chiral polyoxometalate-based materials: From design syntheses to functional applications235From Racemic Units to Polar Materials23A first-principles investigation of the electronic, elastic, piezoelectric and acoustic properties of K3B6O10Cl11Crystal Structure, Thermal Behaviour and Vibrational Spectra of Tetraethylammonium Dihydrogenmonophosphate Bis Phosphoric Acid5New Molybdenum(VI) Phosphates: Synthesis, Characterization, and Calculations of Centrosymmetric RbMoO2PO4and Noncentrosymmetric Rb4Mo5P2O2239New Fluoride Carbonates: Centrosymmetric KPb2(CO3)2F and Noncentrosymmetric K2.70Pb5.15(CO3)5F367Steric-Induced Layer Flection in Templated Vanadium Tellurites11The structural transformation of monoclinic [(R)-C5H14N2][Cu(SO4)2(H2O)4]·2H2O into orthorhombic [(R)-C5H14N2]2[Cu(H2O)6](SO4)3: crystal structures and thermal behavior3Crystal structure and spectroscopic study of bis-tetrapropylammonium hexachlorodicuprate(II), [N(C3H7)4]2Cu2Cl66Formation Principles for Templated Vanadium Selenite Oxalates22Crystal growth and calculation of the electronic band structure and density of states of Li3Cs2B5O1013Ba4(BO3)3(SiO4)·Ba3X (X = Cl, Br): new salt-inclusion borosilicate halides as potential deep UV nonlinear optical materials58Two novel organic–inorganic hybrid molybdenum( v ) cobalt/nickel phosphate compounds based on isolated nanosized Mo/Co(Ni)/P cluster wheels40Specific Chemistry of the Anions: [TaOF5]2–, [TaF6]−, and [TaF7]2–20A one-dimensional ladder-like six-coordinate cadmium polymer: catena-poly[bis[(S)-2-methylpiperazine-1,4-diium] [bis[trichloridocadmium(II)]-di-μ3-chlorido]]2Formation Principles for Vanadium Selenites: The Role of pH on Product Composition12Role of Noncovalent Interactions in Vanadium Tellurite Chain Connectivities14The role of inorganic acidity on templated vanadate composition and dimensionality4Spontaneous Resolution of Evans–Showell-Type Polyoxometalates in Constructing Chiral Inorganic–Organic Hybrid Architectures33Chiral polyoxomolybdate-based hybrid compounds obtained by spontaneous resolution: syntheses, structures and non-linear optical properties10Design, synthesis and excellent third-order NLO properties of two new polyoxometalates constructed from Keggin polyanions bonded by a solvent molecule11Reactions of metal salts with bronsted acidic ionic liquid: Formations of imidazole template metal sulfates or imidazole-metal complexes6Two excellent phase-matchable infrared nonlinear optical materials based on 3D diamond-like frameworks: RbGaSn 2 Se 6 and RbInSn 2 Se 639Understanding structural adaptability: a reactant informatics approach to experiment design12Syntheses, Structures, and Properties of Non-Centrosymmetric Quaternary Tellurates BiMTeO6 (M = Al, Ga)21Templated vanadium tellurites: Identifying the effects of low density attractions on inorganic layer topology4Synthesis, crystal structure and properties of a new noncentrosymmetric tetraoxidomolybdate(VI)3Machine-Learning-Assisted Synthesis of Polar Racemates32Rare example of chiral and achiral polymorphs of a metal-oxide/organic hybrid compound2Symmetry-Dependent Intermolecular π–π Stacking Directed by Hydrogen Bonding in Racemic Copper-Phenanthroline Compounds12Chiral Template‐Driven Macroscopic Chirality Control: Structure‐Second‐Harmonic Generation Properties Relationship24New Solids in As-O-Mo, As(P)-O-Mo(W) and As(P)-O-Nb(W) Systems That Exhibit Nonlinear Optical Properties0Crystalline Porous Materials for Nonlinear Optics91Prediction of Large Second Harmonic Generation in the Metal-Oxide/Organic Hybrid Compound CuMoO3(p2c)2Machine learning and experiments: A synergy for the development of functional materials19Exploration of new chiral hybrid semiconducting palladium halide complexes: [(R)/(S)-2-Methylpiperazinediium]PdCl49Investigation of the Ferroelectric, Magnetic and Magnetoelectric Properties in Honeycomb-Layered YCrTeO62

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  1. Directed Synthesis of Noncentrosymmetric Molybdates Using Composition Space Analysis

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    Thomas R. Veltman, Adam K. Stover, Amy Narducci Sarjeant, Kang Min Ok, P. Shiv Halasyamani, Alexander J. Norquist

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  2. Organically Directed Iron Sulfate Chains: Structural Diversity Based on Hydrogen Bonding Interactions

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    Yunlong Fu, Zhiwei Xu, Jia-Lin Ren, Hai‐Shun Wu, Rong Yuan

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  3. (S)-2-Methylpiperazinediium dichloride 0.42-hydrate

    Acta Crystallographica Section E Structure Reports Online · 2008-04-23

    William T. A. Harrison

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  4. Synthetic Approaches for Noncentrosymmetric Molybdates

    Inorganic Chemistry · 2008-09-29

    Desmond J. Hubbard, Alexander R. Johnston, Hernan Sanchez Casalongue, Amy Narducci Sarjeant, Alexander J. Norquist

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  5. Strong Second Harmonic Generation from the Tantalum Thioarsenates A3Ta2AsS11 (A = K and Rb)

    Journal of the American Chemical Society · 2008-12-17

    Tarun Kumar Bera, Joon Ik Jang, John B. Ketterson, Mercouri G. Kanatzidis

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  6. Charge density matching in templated molybdates

    Journal of Solid State Chemistry · 2009-03-07

    Hernan Sanchez Casalongue, Sarah J. Choyke, Amy Narducci Sarjeant, Joshua Schrier, Alexander J. Norquist

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  7. Synthesis, structural characterisation and thermal decomposition of a new organic–inorganic hybrid material (C5H14N2)[Cu(SO4)2(H2O)4]·H2O

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    Fadhel Hajlaoui, S. Yahyaoui, Houcine Naı̈li, Tahar Mhiri, Thierry Bataille

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  8. Second-Order Nonlinear Optical Properties of Polyoxometalate Salts of a Chiral Stilbazolium Derivative

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  9. A Novel Nonlinear Optical Crystal Bi2ZnOB2O6

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  10. A Series of New Infrared NLO Semiconductors, ZnY6Si2S14, AlxDy3(SiyAl1−y)S7, and Al0.33Sm3SiS7

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  11. Synthesis, Structure, and Properties of the Noncentrosymmetric Hydrated Borate Na2B5O8(OH)·2H2O

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  12. Noncentrosymmetry in New Templated Gallium Fluorophosphates

    Inorganic Chemistry · 2009-10-28

    Sarah J. Choyke, Samuel M. Blau, A.A. Larner, Amy Narducci Sarjeant, Jeongho Yeon, P. Shiv Halasyamani, Alexander J. Norquist

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  13. Crystal structure, phase transition and thermal decomposition of a copper (II) sulfate dihydrate containing a chiral organic ammonium cation

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  14. NaVO2(IO3)2(H2O): A Unique Layered Material Produces A Very Strong SHG Response

    Chemistry of Materials · 2010-01-12

    Bing‐Ping Yang, Chun‐Li Hu, Xiang Xu, Chuan‐Fu Sun, Jian‐Han Zhang, Jiang‐Gao Mao

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  15. Soluble Semiconductors AAsSe2 (A = Li, Na) with a Direct-Band-Gap and Strong Second Harmonic Generation: A Combined Experimental and Theoretical Study

    Journal of the American Chemical Society · 2010-02-19

    Tarun K. Bera, Joon Ik Jang, Jung‐Hwan Song, Christos D. Malliakas, Arthur J Freeman, John B. Ketterson, Mercouri G. Kanatzidis

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  16. Noncentrosymmetric Inorganic Oxide Materials: Synthetic Strategies and Characterisation Techniques

    Unknown journal · 2010-06-11

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  17. Syntheses, structures and properties of three nonmetal borates with salicylic acid and organic amines

    Inorganica Chimica Acta · 2010-06-17

    Yun Mo Yang, Shilie Pan, Xueling Hou, Jing Guo, Feng Li, Jian Wei Han, Jixi Guo, Dianzeng Jia

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  18. Hybrid Organic−Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications

    Chemical Reviews · 2010-07-28

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  19. A Slow Leak Synthetic Route to Organically Templated Gallium Sulfates

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  20. A congruently melting and deep UV nonlinear optical material: Li3Cs2B5O10

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  21. Synthesis, characterization and magnetic properties of four new organically templated metal sulfates [C5H14N2][MII(H2O)6](SO4)2, (MII = Mn, Fe, Co, Ni)

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  22. Synthesis, structure, and properties of the non-centrosymmetric borate Rb 2 CaB 8 O 26 H 24

    Unknown journal · 2011-01-01

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  23. Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties

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  24. In-Phase Alignments of Asymmetric Building Units in Ln 4 GaSbS 9 (Ln = Pr, Nd, Sm, Gd−Ho) and Their Strong Nonlinear Optical Responses in Middle IR

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  25. Top-Seeded Solution Growth, Morphology, and Properties of a Polar Crystal Cs2TeMo3O12

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  26. [R-C7H16N2][V2Te2O10] and [S-C7H16N2][V2Te2O10]; new polar templated vanadium tellurite enantiomers

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  27. K3B6O10Cl: A New Structure Analogous to Perovskite with a Large Second Harmonic Generation Response and Deep UV Absorption Edge

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  28. Synthesis, structure, and properties of the non-centrosymmetric borate Rb2CaB8O26H24

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  29. A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks

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  30. Growth, thermal and optical properties of a novel nonlinear optical material K 3 B 6 O 10 Cl

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  31. Synthesis, crystal structures and thermal behaviour of organic–inorganic hybrids incorporating a chiral diamine

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  32. New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)

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  33. A new congruent-melting oxyborate, Pb 4 O(BO 3 ) 2 with optimally aligned BO 3 triangles adopting layered-type arrangement

    Journal of Materials Chemistry · 2011-12-13

    Hongwei Yu, Shilie Pan, Hongping Wu, Wenwu Zhao, Fangfang Zhang, Hongyi Li, Zhihua Yang

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  34. A novel deep UV nonlinear optical crystal Ba3B6O11F2, with a new fundamental building block, B6O14 group

    Journal of Materials Chemistry · 2012-01-01

    Hongwei Yu, Hongping Wu, Shilie Pan, Zhihua Yang, Xin Su, Fangfang Zhang

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  35. Li5Rb2B7O14: a new congruently melting compound with two kinds of B–O one-dimensional chains and short UV absorption edge

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  36. Noncentrosymmetric Inorganic Open-Framework Chalcohalides with Strong Middle IR SHG and Red Emission: Ba3AGa5Se10Cl2 (A = Cs, Rb, K)

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  37. Two New Noncentrosymmetric (NCS) Polar Oxides: Syntheses, Characterization, and Structure–Property Relationships in BaMTe2O7 (M = Mg2+ or Zn2+)

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  38. Inducing polarity in [VO3]nn− chain compounds using asymmetric hydrogen-bonding networks

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  39. Small non-polar complexes exhibiting significant piezoelectric properties: Solvothermal synthesis and crystal structures of MO5V(tren)·H2O (M=Mo and W; tren=tris(2-aminoethyl)amine)

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  40. Crystal structures of two enantiomorphous 2-ethylpiperazinediium hexaaquacopper sulfates [(R or S)-C5H14N2][Cu(H2O)6](SO4)2

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  41. Noncentrosymmetry in new 2-methylpiperazinediium hexaaquazinc(II) bis(sulfate)

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  42. Sulfides with Strong Nonlinear Optical Activity and Thermochromism: ACd4Ga5S12 (A = K, Rb, Cs)

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  43. 2-Dihydromethylpiperazinediium-M II (M II = Cu II , Fe II , Co II , Zn II ) double sulfates and their catalytic activity in diastereoselective nitroaldol (Henry) reaction

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  44. Role of Hydrogen-Bonding in the Formation of Polar Achiral and Nonpolar Chiral Vanadium Selenite Frameworks

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  45. Electronic structure and optical properties of the nonlinear optical crystal Pb4O(BO3)2 by first-principles calculations

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  46. Preservation of Chirality and Polarity between Chiral and Polar Building Units in the Solid State

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  47. Chiral polyoxometalate-based materials: From design syntheses to functional applications

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  48. From Racemic Units to Polar Materials

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  49. A first-principles investigation of the electronic, elastic, piezoelectric and acoustic properties of K3B6O10Cl

    Computational Materials Science · 2012-12-23

    Han Han, Gen Yin, Darshana Wickramaratne

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  50. Crystal Structure, Thermal Behaviour and Vibrational Spectra of Tetraethylammonium Dihydrogenmonophosphate Bis Phosphoric Acid

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