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RESEARCH PAPER · Inorganic Chemistry · 2011

Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties

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Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical PropertiesOriginalChemInform Abstract: Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties.0Polymorphism of BaTeMo 2 O 9 : A New Polar Polymorph and the Phase Transformation186Growth, thermal and optical properties of a novel nonlinear optical material K 3 B 6 O 10 Cl57Alkaline-Alkaline Earth Fluoride Carbonate Crystals ABCO3F (A = K, Rb, Cs; B = Ca, Sr, Ba) as Nonlinear Optical Materials525A new congruent-melting oxyborate, Pb 4 O(BO 3 ) 2 with optimally aligned BO 3 triangles adopting layered-type arrangement112A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O1222A novel deep UV nonlinear optical crystal Ba3B6O11F2, with a new fundamental building block, B6O14 group180Cadmium-rare earth oxyborates Cd4ReO(BO3)3 (Re = Y, Gd, Lu): congruently melting compounds with large SHG responses65Li5Rb2B7O14: a new congruently melting compound with two kinds of B–O one-dimensional chains and short UV absorption edge25Synthesis, crystal structure and optical properties of a new orthorhombic phase, Na3ZnB5O1014Synthesis, crystal structure and properties of a new lead calcium diborate7Synthesis, structure and characterization of layered Ca[B(C6H6O7)2](H2O)4⋅HCl3Synthesis, crystal structure and characterization of a new compound, Li3NaBaB6O1226Synthesis, growth, crystal structure and optical properties of BaBiBO49Na3Cd3B(PO4)4: A New Noncentrosymmetric Borophosphate with Zero-Dimensional Anion Units81Synthesis, Crystal Structure, and Properties of a New Lead Aluminum Fluoride Borate, Pb6AlB2O7F710M2Cd3B16O28 (M = Rb, Cs): Two Isostructural Alkali Cadmium Borates with a New Type of Borate Layer29Na2Cd7B8O20: a new noncentrosymmetric compound with special [B3O7] units20Synthesis, structure, and characterization of a new promising nonlinear optical crystal: Cd5(BO3)3F42Cs2B4SiO9: A Deep‐Ultraviolet Nonlinear Optical Crystal278Cs2B4SiO9: A Deep‐Ultraviolet Nonlinear Optical Crystal224Synthesis and relative optical properties of Eu3+/Tb3+-activated Li3InB2O615Synthesis, crystal structure and optical properties of a new lithium dilead pentaborate, LiPb2B5O105New Salt-Inclusion Borate, Li3Ca9(BO3)7·2[LiF]: A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles56Synthesis and crystal structure of a novel ludwigite borate: Mg2InBO518Na 11 B 21 O 36 X 2 (X=Cl, Br): Halogen Sodium Borates with a New Graphene‐Like Borate Double Layer38Thermodynamic properties of two mixed alkali metal borates with NLO behaviour: Li6Rb5B11O22 and Li4Cs3B7O144Synthesis and characterization of powder four borate Sr 3 Sm 2 (BO 3 ) 44Synthesis, crystal structure, optical properties and theoretical calculations of a new potassium lead pentaborate, KPbB5O92Three New Mixed-Alkali- and Alkaline-Earth-Metal Borates: From 1D Chain to 2D Layer to 3D Framework57Synthesis, structures, optical properties and electronic structures of two mixed metal borates MBaB5O9 (M=Na, K)32Two new organic borates with the large [B14O20(OH)6]4− oxoboron clusters8Ba3M2[B3O6(OH)]2[B4O7(OH)2] (M=Al, Ga): Two Novel UV Nonlinear Optical Metal Borates Containing Two Types of Oxoboron Clusters123Pb3B6O11F2: the first non-centrosymmetric lead borate fluoride with a large second harmonic generation response61Ba 2 B 10 O 17 : a new centrosymmetric alkaline-earth metal borate with a deep-UV cut-off edge50K 7 B 2 P 5 O 19 : a novel alkali metal borophosphate with zero dimensional [B 2 P 5 O 19 ] 7− anionic units23p–(p,π*) interaction mechanism revealing and accordingly designed new member in deep-ultraviolet NLO borates Li n M n−1 B 2n−1 O 4n−2 (M = Cs/Rb, n = 3, 4, 6)52Structural, electronic and optical properties of novel carbonate fluorides ABCO3F (A=K, Rb, Cs; B=Ca, Sr)25Noncentrosymmetric versus Centrosymmetric: Influence of the Na+ Substitution on Structural Transition and Second-Harmonic Generation Property50The Effect of the Ratio of [M/(B+P)] on the Configuration of Anionic Groups: Synthesis of the Borate–Phosphate LiPb4(BO3)(PO4)215Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework36An Acentric Calcium Borate Ca2[B5O9]·(OH)·H2O: Synthesis, Structure, and Nonliner Optical Property94Q 18 Mg 6 (B 5 O 10 ) 3 (B 7 O 14 ) 2 F (Q=Rb and Cs): New Borates Containing Two Large Isolated Polyborate Anions with Similar Topological Structures39Synthesis and structural characterization of a new rubidium borosulfate, Rb5BS4O1616Na 3 B 4 O 7 X (X = Cl, Br): two new borate halides with a 1D Na-X (X = Cl, Br) chain formed by the face-sharing XNa 6 octahedra13Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS2 and Centric Ba8Hg4S5Se752Ba2B6O11, a Member of the BaO‐B2O3 Family, Featuring a Layer Framework19Two New Crystals in LimCsnBm+nO2(m+n) (m + n = 5, 7; m > n) Series: Noncentrosymmetric Li5Cs2B7O14 and Centrosymmetric Li4CsB5O1016Efficient photodechlorination of chlorophenols on polarized MZnB5O10 (M = Na and K) nonlinear optical materials20Versatile Coordination Mode of LiNaB8O13 and α- and β-LiKB8O13 via the Flexible Assembly of Four-Connected B5O10 and B3O7 Groups19Alkali metal–alkaline earth metal borate crystal LiBa 3 (OH)(B 9 O 16 )[B(OH) 4 ] as a new deep-UV nonlinear optical material34IR Spectra of Minerals and Related Compounds, and Reference Samples’ Data21Rb2Na(NO3)3: A Congruently Melting UV-NLO Crystal with a Very Strong Second-Harmonic Generation Response71Synthesis, structure and properties of nonlinear optical crystal Li(H 2 O) 4 B(OH) 4 ·2H 2 O5Crystal Growth and Associated Properties of a Nonlinear Optical Crystal—Ba2Zn(BO3)226Deep Ultraviolet Nonlinear Optical Materials644Li 6 Zn 3 (BO 3 ) 4 : a new zincoborate featuring vertex-, edge- and face-sharing LiO 4 tetrahedra and exhibiting reversible phase transitions18PbLnB 7 O 13 (Ln = Tb or Eu): a new type of layered polyborate with multi-colour light emission properties39Solvent-controlled syntheses of mixed-alkali-metal borates exhibiting UV nonlinear optical properties23The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges16Li3VO4: A Promising Mid-Infrared Nonlinear Optical Material with Large Laser Damage Threshold51Insight on the growth and property studies of inorganic hydrated borate (Na6 [B4O5 (OH)4]3. 8H2O) single crystal – An effective third order nonlinear optical (NLO) material for optical limiting application20Synthesis, structure and characterization of a new nonlinear optical calcium borate [Ca2B5O9]·[H(OH)2]6Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals258Three Alumino/Galloborate Frameworks Templated by Organic Amines: Syntheses, Structures, and Nonlinear Optical Properties23The Rubidium Barium Borate Resulting from B7O15 Fundamental Building Block Exhibits DUV Cutoff Edge17The structure and classification of complex borates43Li2CsB7O10(OH)4: A Deep-Ultraviolet Nonlinear-Optical Mixed-Alkaline Borate Constructed by Unusual Heptaborate Anions98Four new deep ultraviolet borates with isolated B12O24 groups: Synthesis, structure, and optical properties9Nitrate nonlinear optical crystals: A survey on structure-performance relationships146IR Spectra of Minerals and Related Compounds, and Reference Samples Data3Structure-property relationship in nonlinear optical materials with π-conjugated CO3 triangles146Borates: A Rich Source for Optical Materials1090Sn3B8O15: A Ternary Tin(II) Borate with Flexible [B8O18]12– Fundamental Building Block Formed by [B7O16]11– and [BO3]3– Groups10Computationally assisted multistage design and prediction driving the discovery of deep-ultraviolet nonlinear optical materials41An Overview on Recent Trends in Deep‐Ultraviolet (DUV) and Ultraviolet (UV) Nonlinear Optical Crystals25Cd 4 REO(BO 3 ) 3 (RE = Sm, Eu, Tb): three new cadmium–rare earth oxyborates with both good NLO and luminescence properties6Rearrangement of [B2O5] Dimers within [B7O14] Clusters Enables Enhanced Optical Anisotropy in Li3Cs6Al2B14O28F4LiCs 3 AlB 7 O 14 : achieving enhanced optical anisotropy via [AlO 4 ] tetrahedron introduction to rearrange the anionic framework5Ba3.75MgB7O14F2.5: A Mixed Alkaline-Earth Metal Borate Fluoride with Short Ultraviolet Cutoff Edge and Large Birefringence9Exploration of silver borates with diverse low-dimensional anion frameworks by introducing monovalent heteroanions6K, Rb-hydroxyborates series with deep-ultraviolet KRbB 5 O 8 (OH) possessing moderate second harmonic generation response0Two Alkaline Metal Borates: from Layer to Layer-Pillared Framework8Promising UV/DUV nonlinear optical materials with X-membered (X = multiples of 6) rings in anhydrous inorganic borates20

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  1. ChemInform Abstract: Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties.

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  2. Polymorphism of BaTeMo 2 O 9 : A New Polar Polymorph and the Phase Transformation

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  3. Growth, thermal and optical properties of a novel nonlinear optical material K 3 B 6 O 10 Cl

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  4. Alkaline-Alkaline Earth Fluoride Carbonate Crystals ABCO3F (A = K, Rb, Cs; B = Ca, Sr, Ba) as Nonlinear Optical Materials

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  5. A new congruent-melting oxyborate, Pb 4 O(BO 3 ) 2 with optimally aligned BO 3 triangles adopting layered-type arrangement

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  6. A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O12

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  7. A novel deep UV nonlinear optical crystal Ba3B6O11F2, with a new fundamental building block, B6O14 group

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  8. Cadmium-rare earth oxyborates Cd4ReO(BO3)3 (Re = Y, Gd, Lu): congruently melting compounds with large SHG responses

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  9. Li5Rb2B7O14: a new congruently melting compound with two kinds of B–O one-dimensional chains and short UV absorption edge

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  10. Synthesis, crystal structure and optical properties of a new orthorhombic phase, Na3ZnB5O10

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  11. Synthesis, crystal structure and properties of a new lead calcium diborate

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  12. Synthesis, structure and characterization of layered Ca[B(C6H6O7)2](H2O)4⋅HCl

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  13. Synthesis, crystal structure and characterization of a new compound, Li3NaBaB6O12

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  14. Synthesis, growth, crystal structure and optical properties of BaBiBO4

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  15. Na3Cd3B(PO4)4: A New Noncentrosymmetric Borophosphate with Zero-Dimensional Anion Units

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  16. Synthesis, Crystal Structure, and Properties of a New Lead Aluminum Fluoride Borate, Pb6AlB2O7F7

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  17. M2Cd3B16O28 (M = Rb, Cs): Two Isostructural Alkali Cadmium Borates with a New Type of Borate Layer

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  18. Na2Cd7B8O20: a new noncentrosymmetric compound with special [B3O7] units

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  19. Synthesis, structure, and characterization of a new promising nonlinear optical crystal: Cd5(BO3)3F

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  20. Cs2B4SiO9: A Deep‐Ultraviolet Nonlinear Optical Crystal

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  21. Cs2B4SiO9: A Deep‐Ultraviolet Nonlinear Optical Crystal

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  22. Synthesis and relative optical properties of Eu3+/Tb3+-activated Li3InB2O6

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  23. Synthesis, crystal structure and optical properties of a new lithium dilead pentaborate, LiPb2B5O10

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  24. New Salt-Inclusion Borate, Li3Ca9(BO3)7·2[LiF]: A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles

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  25. Synthesis and crystal structure of a novel ludwigite borate: Mg2InBO5

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  28. Synthesis and characterization of powder four borate Sr 3 Sm 2 (BO 3 ) 4

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  29. Synthesis, crystal structure, optical properties and theoretical calculations of a new potassium lead pentaborate, KPbB5O9

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  31. Synthesis, structures, optical properties and electronic structures of two mixed metal borates MBaB5O9 (M=Na, K)

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  32. Two new organic borates with the large [B14O20(OH)6]4− oxoboron clusters

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  33. Ba3M2[B3O6(OH)]2[B4O7(OH)2] (M=Al, Ga): Two Novel UV Nonlinear Optical Metal Borates Containing Two Types of Oxoboron Clusters

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  34. Pb3B6O11F2: the first non-centrosymmetric lead borate fluoride with a large second harmonic generation response

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  35. Ba 2 B 10 O 17 : a new centrosymmetric alkaline-earth metal borate with a deep-UV cut-off edge

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  36. K 7 B 2 P 5 O 19 : a novel alkali metal borophosphate with zero dimensional [B 2 P 5 O 19 ] 7− anionic units

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  37. p–(p,π*) interaction mechanism revealing and accordingly designed new member in deep-ultraviolet NLO borates Li n M n−1 B 2n−1 O 4n−2 (M = Cs/Rb, n = 3, 4, 6)

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  39. Noncentrosymmetric versus Centrosymmetric: Influence of the Na+ Substitution on Structural Transition and Second-Harmonic Generation Property

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  40. The Effect of the Ratio of [M/(B+P)] on the Configuration of Anionic Groups: Synthesis of the Borate–Phosphate LiPb4(BO3)(PO4)2

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  41. Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework

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  42. An Acentric Calcium Borate Ca2[B5O9]·(OH)·H2O: Synthesis, Structure, and Nonliner Optical Property

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  43. Q 18 Mg 6 (B 5 O 10 ) 3 (B 7 O 14 ) 2 F (Q=Rb and Cs): New Borates Containing Two Large Isolated Polyborate Anions with Similar Topological Structures

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  44. Synthesis and structural characterization of a new rubidium borosulfate, Rb5BS4O16

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  49. Efficient photodechlorination of chlorophenols on polarized MZnB5O10 (M = Na and K) nonlinear optical materials

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  50. Versatile Coordination Mode of LiNaB8O13 and α- and β-LiKB8O13 via the Flexible Assembly of Four-Connected B5O10 and B3O7 Groups

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