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RESEARCH PAPER · Inorganic Chemistry · 2012

Preservation of Chirality and Polarity between Chiral and Polar Building Units in the Solid State

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Preservation of Chirality and Polarity between Chiral and Polar Building Units in the Solid StateOriginalFrom Racemic Units to Polar Materials23Stereochemistry of fluoride and mixed-ligand fluoride complexes of zirconium and hafnium22Alignment of Acentric Units in Infinite Chains: A “Lock and Key” Model16Chiral and achiral imidazole-linked tetrahedral zinc phosphonate frameworks with photoluminescent properties34Influence of the cation size on the second harmonic generation response of chiral A(VO 2 ) 2 (PO 4 )·3H 2 O (A = K + , NH 4 + and Rb + )3Specific Chemistry of the Anions: [TaOF5]2–, [TaF6]−, and [TaF7]2–20Helical ∞1[Pb2O] Chains in Polymorphs of Pb2O(C6H5COO)211On the Origin of the Differences in Structure Directing Properties of Polar Metal Oxyfluoride [MOxF6–x]2– (x = 1, 2) Building Units55Electronic Structures of “Low‐Valent” Neutral Complexes [NiL2]0 (S = 0; L = bpy, phen, tpy) – An Experimental and DFT Computational Study51Design of noncentrosymmetric perovskites from centric and acentric basic building units39Optical activity from racemates50Packing of Helices: Is Chirality the Highest Crystallographic Symmetry?8Cd3(MoO4)(TeO3)2: A Polar 3D Compound Containing d10–d0 SCALP-Effect Cations85Variable Asymmetric Chains in Transition Metal Oxyfluorides: Structure–Second-Harmonic-Generation Property Relationships16Syntheses, Structures, and Properties of Non-Centrosymmetric Quaternary Tellurates BiMTeO6 (M = Al, Ga)21Synthesis and Characterization of Heterometallic Iron–Uranium Complexes with a Bidentate N-Donor Ligand (2,2′-Bipyridine or 1,10-Phenanthroline)16Cyclohexylammonium sulfanilate: A simple representative of the chiral materials containing only achiral building units8Symmetry-Dependent Intermolecular π–π Stacking Directed by Hydrogen Bonding in Racemic Copper-Phenanthroline Compounds12Guanidinium sulfates as directors of noncentrosymmetric structures9Phase transitions and potential ferroelectricity in noncentrosymmetric KNaNbOF52Strong Optical Nonlinearity in Polar Hypophosphites via Chiral Cation Assembly1

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  1. From Racemic Units to Polar Materials

    Crystal Growth & Design · 2012-11-06

    Romain Gautier, Alexander J. Norquist, Kenneth Reinhard Poeppelmeier

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  2. Stereochemistry of fluoride and mixed-ligand fluoride complexes of zirconium and hafnium

    Coordination Chemistry Reviews · 2013-07-07

    R.L. Davidovich, Dmitry V. Marinin, Vitalie Stavila, Kenton H. Whitmire

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  3. Alignment of Acentric Units in Infinite Chains: A “Lock and Key” Model

    Crystal Growth & Design · 2013-07-31

    Romain Gautier, Kenneth Reinhard Poeppelmeier

    Read original paper ↗ ·
  4. Chiral and achiral imidazole-linked tetrahedral zinc phosphonate frameworks with photoluminescent properties

    Dalton Transactions · 2013-09-17

    Xiuling Zhang, Kai Fan Cheng, Fei Wang, Jian Zhang

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  5. Influence of the cation size on the second harmonic generation response of chiral A(VO 2 ) 2 (PO 4 )·3H 2 O (A = K + , NH 4 + and Rb + )

    CrystEngComm · 2014-01-01

    Romain Gautier, Sandy Auguste, Simon Clevers, Valérie Dupray, Gérard Coquerel, Éric Le Fur

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  6. Specific Chemistry of the Anions: [TaOF5]2–, [TaF6]−, and [TaF7]2–

    Crystal Growth & Design · 2014-01-06

    Hongcheng Lu, Romain Gautier, Martin D. Donakowski, Lindsay Fuoco, Zheng‐Tang Liu, Kenneth Reinhard Poeppelmeier

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  7. Helical ∞1[Pb2O] Chains in Polymorphs of Pb2O(C6H5COO)2

    Crystal Growth & Design · 2014-03-06

    Clay C. Easterday, Liv R. Dedon, Mat­thias Zeller, Catherine M. Oertel

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  8. On the Origin of the Differences in Structure Directing Properties of Polar Metal Oxyfluoride [MOxF6–x]2– (x = 1, 2) Building Units

    Inorganic Chemistry · 2015-01-22

    Romain Gautier, Régis Gautier, Kelvin B. Chang, Kenneth Reinhard Poeppelmeier

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  9. Electronic Structures of “Low‐Valent” Neutral Complexes [NiL2]0 (S = 0; L = bpy, phen, tpy) – An Experimental and DFT Computational Study

    European Journal of Inorganic Chemistry · 2015-02-16

    Mei Wang, Jason England, Thomas Weyhermüller, Karl E. Wieghardt

    Read original paper ↗ ·
  10. Design of noncentrosymmetric perovskites from centric and acentric basic building units

    Journal of Materials Chemistry C · 2016-01-01

    Joshua Young, Parth Lalkiya, James M. Rondinelli

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  11. Optical activity from racemates

    Nature Materials · 2016-04-18

    Romain Gautier, Jordan M. Klingsporn, Richard P. Van Duyne, Kenneth Reinhard Poeppelmeier

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  12. Packing of Helices: Is Chirality the Highest Crystallographic Symmetry?

    Crystals · 2016-08-30

    Romain Gautier, Kenneth Reinhard Poeppelmeier

    Read original paper ↗ ·
  13. Cd3(MoO4)(TeO3)2: A Polar 3D Compound Containing d10–d0 SCALP-Effect Cations

    Inorganic Chemistry · 2016-11-09

    Yuquan Feng, Hui‐Tao Fan, Zhiguo Zhong, Hongwei Wang, Dongfang Qiu

    Read original paper ↗ ·
  14. Variable Asymmetric Chains in Transition Metal Oxyfluorides: Structure–Second-Harmonic-Generation Property Relationships

    Inorganic Chemistry · 2018-05-15

    Belal Ahmed, Hongil Jo, Seung‐Jin Oh, Kang Min Ok

    Read original paper ↗ ·
  15. Syntheses, Structures, and Properties of Non-Centrosymmetric Quaternary Tellurates BiMTeO6 (M = Al, Ga)

    Inorganic Chemistry · 2018-06-15

    Fenghua Ding, Matthew Lander Nisbet, Hongwei Yu, Weiguo Zhang, Liyuan Chai, P. Shiv Halasyamani, Kenneth Reinhard Poeppelmeier

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  16. Synthesis and Characterization of Heterometallic Iron–Uranium Complexes with a Bidentate N-Donor Ligand (2,2′-Bipyridine or 1,10-Phenanthroline)

    Inorganic Chemistry · 2018-10-10

    Sebastian Schöne, Thomas Radoske, Juliane März, Thorsten Stumpf, Atsushi Ikeda‐Ohno

    Read original paper ↗ ·
  17. Cyclohexylammonium sulfanilate: A simple representative of the chiral materials containing only achiral building units

    Materials Letters · 2019-01-11

    Antoine Blaise Kama, Romain Génois, Florian Massuyeau, Mamadou Sidibé, Cheikh Diop, Romain Gautier

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  18. Symmetry-Dependent Intermolecular π–π Stacking Directed by Hydrogen Bonding in Racemic Copper-Phenanthroline Compounds

    Crystal Growth & Design · 2020-12-01

    Matthew Lander Nisbet, Yiran Wang, Kenneth Reinhard Poeppelmeier

    Read original paper ↗ ·
  19. Guanidinium sulfates as directors of noncentrosymmetric structures

    CrystEngComm · 2021-01-01

    Beau R. Brummel, Kinsey G. Lee, Joseph W. Kolis, Daniel C. Whitehead, Colin D. McMillen

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  20. Phase transitions and potential ferroelectricity in noncentrosymmetric KNaNbOF5

    Physical Review Materials · 2021-12-01

    Jaye K. Harada, Po‐Hsiu Chien, Haoyu Liu, Sawankumar V. Patel, Ching-Hwa A. Chen, Nenian Charles, Yan‐Yan Hu, Kenneth Reinhard Poeppelmeier, James M. Rondinelli

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  21. Strong Optical Nonlinearity in Polar Hypophosphites via Chiral Cation Assembly

    Chemistry of Materials · 2026-04-21

    Yiran Zhang, Qiao Xia, Xiaotian Zhang, Zhipeng Huang, Mark Graeme Humphrey, Liming Cheng, Kasper Moth‐Poulsen, C L Zhang, Chao Wu

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