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RESEARCH PAPER · Journal of Materials Chemistry · 2012

A novel deep UV nonlinear optical crystal Ba3B6O11F2, with a new fundamental building block, B6O14 group

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A novel deep UV nonlinear optical crystal Ba3B6O11F2, with a new fundamental building block, B6O14 groupOriginalNoncentrosymmetric salt inclusion oxides: Role of salt lattices and counter ions in bulk polarity52Exploratory Investigation of New SHG Materials Based on Galloborates46An unusual seven-connected lead borate constructed by different cluster building units of {B 6 } and {Pb 6 }19Pb2B5O9Cl: a chloride borate with second harmonic generation effect40BaClBF4: a new noncentrosymmetric pseudo-Aurivillius type material with transparency range from deep UV to middle IR and a high laser damage threshold42Crystal growth and efficient second-harmonic-generation of the monoclinic LaCa4O(BO3)3 crystal23From discrete borate cluster to three-dimensional open framework32Growth, optical and electrical properties of a nonlinear optical crystal NaBa4Al2B8O18Cl315Na2Cd7B8O20: a new noncentrosymmetric compound with special [B3O7] units20Synthesis, structure, and characterization of a new promising nonlinear optical crystal: Cd5(BO3)3F42New Molybdenum(VI) Phosphates: Synthesis, Characterization, and Calculations of Centrosymmetric RbMoO2PO4and Noncentrosymmetric Rb4Mo5P2O2239Cs2B4SiO9: A Deep‐Ultraviolet Nonlinear Optical Crystal278Cs2B4SiO9: A Deep‐Ultraviolet Nonlinear Optical Crystal224Designing a Deep-Ultraviolet Nonlinear Optical Material with a Large Second Harmonic Generation Response597Synthesis, Structure Characterization, and Optical Properties of the Aluminosilicate Li2Na3AlSi2O87Synthesis, crystal structure and optical properties of a new lithium dilead pentaborate, LiPb2B5O105New Salt-Inclusion Borate, Li3Ca9(BO3)7·2[LiF]: A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles56Sr3BeB6O13: A New Borate in the SrO/BeO/B2O3 System with Novel Tri-Six-Membered Ring (BeB6O15)10– Building Block22Cs2GeB4O9: a New Second-Order Nonlinear-Optical Crystal139Exploration of a new compound in the M–B–O–X (M: alkali metals; X: halogen) system: Preparation, crystal and electronic structures, and optical properties of Na3B6O10Br19Synthesis and Structure of KPbBP 2 O 8 – A Congruent Melting Borophosphate with Nonlinear Optical Properties35Sr3B6O11F2: a promising polar fluoroborate with short UV absorption edge and moderate second harmonic generation response30Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)2F2Cl and Noncentrosymmetric NaBa4(AlB4O9)2Br350Synthesis, crystal structure, optical properties and theoretical calculations of a new potassium lead pentaborate, KPbB5O92Na8Lu2(CO3)6F2 and Na3Lu(CO3)2F2: Rare Earth Fluoride Carbonates as Deep-UV Nonlinear Optical Materials139Three New Mixed-Alkali- and Alkaline-Earth-Metal Borates: From 1D Chain to 2D Layer to 3D Framework57Noncentrosymmetric Cubic CsCdBO3 with Bichromophore23Sr 4 B 10 O 18 (OH) 2 ·2H 2 O: a new UV nonlinear optical material with a [B 10 O 23 ] 16− building block53A novel aluminoborate open-framework [In(dien) 2 ][Al 2 B 7 O 16 H 2 ] with large chiral cavities templated by chiral main group metal complexes51Prospects for Fluoride Carbonate Nonlinear Optical Crystals in the UV and Deep-UV Regions116Pb3B6O11F2: the first non-centrosymmetric lead borate fluoride with a large second harmonic generation response61A new alkaline beryllium borate KBe 4 B 3 O 9 with ribbon alveolate [Be 2 BO 5 ] ∞ layers and the structural evolution of ABe 4 B 3 O 9 (A = K, Rb and Cs)12Ba18F18In8S21 and Ba9F10In4S10: new kind of mixed anion compounds with the novel low-dimensional structure9Ba4(BO3)3(SiO4)·Ba3X (X = Cl, Br): new salt-inclusion borosilicate halides as potential deep UV nonlinear optical materials58BaPbSi 2 O 6 ·BaSO 4 : the first mixed anionic compound synthesized via BaSO 4 salt-inclusion8Ca 3 Be 6 B 5 O 16 F: the first alkaline-earth beryllium borate with fluorine anions11Exploring the influence of cationic skeletons on the arrangement of isolated BO 3 groups based on RbMgBO 3 , CsZn 4 (BO 3 ) 3 and Cs 4 Mg 4 (BO 3 ) 422Two Cu-complex directed aluminoborates: from 2D layers to 3D frameworks16β-BaGa[B 4 O 8 (OH)](H 2 O) and Ba 4 Ga[B 10 O 18 (OH) 5 ](H 2 O): new barium galloborates featuring unusual [B 4 O 8 (OH)] 5− and [B 10 O 18 (OH) 5 ] 11− clusters26Noncentrosymmetric YVSe2O8 and Centrosymmetric YVTe2O8: Macroscopic Centricities Influenced by the Size of Lone Pair Cation Linkers63Cs 3 Zn 6 B 9 O 21 : A Chemically Benign Member of the KBBF Family Exhibiting the Largest Second Harmonic Generation Response361SrBeB2O5: Growth, crystal structure and optical properties13Three New Alkaline Beryllium Borates LiBeBO3, Li6Be3B4O12, and Li8Be5B6O18 in the Ternary Phase Diagrams Li2O–BeO–B2O314Noncentrosymmetric versus Centrosymmetric: Influence of the Na+ Substitution on Structural Transition and Second-Harmonic Generation Property50Series of Lead Oxide Hydroxide Nitrates Obtained by Adjusting the pH Values of the Reaction Systems32Reinvestigation and Characterization of the Magnesium Borate Fluoride Mg5(BO3)F12Synthesis, crystal structure, and optical properties of a new lead barium borate, PbBa 2 (B 3 O 6 ) 217NaB3O5·0.5H2O and NH4NaB6O10: Two Cluster Open Frameworks with Chiral Quartz and Achiral Primitive Cubic Nets Constructed from Oxo Boron Cluster Building Units41Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework36Zn 4 B 3 O 9 C 2 H 8 N 2 : an organic–inorganic hybrid borate with a novel graphene-like layer8An Acentric Calcium Borate Ca2[B5O9]·(OH)·H2O: Synthesis, Structure, and Nonliner Optical Property94Lanthanum Lead Oxide Hydroxide Nitrates with a Nonlinear Optical Effect30Borate Fluoride and Fluoroborate in Alkali-Metal Borate Prepared by an Open High-Temperature Solution Method50Synthesis, crystal structure and properties of a new barium calcium borate, Ba2Ca2(B2O5)25Effect of cation substitution on structural transition: synthesis, characterization and theoretical studies of NaCa 4 B 3 O 9 , NaCaBO 3 , NaSrBO 3 and Li 4 CaB 2 O 618Effect of the cation size on the framework structures of magnesium tungstate, A 4 Mg(WO 4 ) 3 (A = Na, K), R 2 Mg 2 (WO 4 ) 3 (R = Rb, Cs)31Second-harmonic generation (SHG) and photoluminescence properties of noncentrosymmetric (NCS) layered perovskite solid solutions, CsBi 1−x Eu x Nb 2 O 7 (x = 0, 0.1, and 0.2)30Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS2 and Centric Ba8Hg4S5Se752Synthesis, Crystal Structure, and Properties of the Sodium Molybdate Fluoride Na3MoO4F5The lone-pairs enhanced birefringence and SHG response: A DFT investigation on M2B5O9Cl (M=Sr, Ba, and Pb)48Polar Polymorphism: α-, β-, and γ-Pb2Ba4Zn4B14O31–Synthesis, Characterization, and Nonlinear Optical Properties79Pb2Ba3(BO3)3Cl: A Material with Large SHG Enhancement Activated by Pb-Chelated BO3 Groups279Linear optical and thermo-physical properties of polar K3B6O10Cl crystal21Series of SHG Materials Based on Lanthanide Borate–Acetate Mixed Anion Compounds39Growth, structure and optical properties of nonlinear optical crystal BaZnBO3F31Bidenticity-Enhanced Second Harmonic Generation from Pb Chelation in Pb3Mg3TeP2O14169Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials340Frequency-Doubling Oxide Fluorides, Borate Fluorides, and Fluorooxoborates9Li 3 Cs 2 M 2 B 3 P 6 O 24 (M = Pb, Sr): borophosphates with double six-membered ring of [BP 2 O 8 ] 3−22Synthesis and Characterization of Three New Layered Vanadium Tellurites, MVTe2O8 (M = Al, Ga, and Mn): Three-Dimensional (3-D) Antiferromagnetic Behavior of MnVTe2O8 with a Zigzag S = 2 Spin Chain19Synthesis, structure and optical properties of two isotypic crystals, Na3MO4Cl (M=W, Mo)11Nonlinear optical (NLO) properties and temperature-dependent photoluminescence in activator-doped noncentrosymmetric (NCS) bismuth tellurite solid solutions, Bi2−Ln TeO5 (Ln = Ce and Eu)8Synthesis and structure of a new halophosphate Sr 3 P 3 O 10 Cl with the flexible [P 3 O 10 ] 5− anions9Electronic, Crystal Chemistry, and Nonlinear Optical Property Relationships in the Dugganite A3B3CD2O14 Family148Crystal growth and optical characteristics of beryllium-free polyphosphate, KLa(PO3)4, a possible deep-ultraviolet nonlinear optical crystal101Fluoride Borates with [(BO3)F]4– ↔ [F4]4– Anionic Isomorphism and X-ray Sensitivity13Deep Ultraviolet Nonlinear Optical Materials644DFT Based Theoretical Study about the Contributions of Fluorine to Nonlinear Optical Properties in Borate Fluoride Crystals27Hydrothermal synthesis of a new lead(II) borate (Pb4O)Pb2B6O14-II5Na2B6O9F2: A Fluoroborate with Short Cutoff Edge and Deep-Ultraviolet Birefringent Property Prepared by an Open High-Temperature Solution Method106KB(PO 4 )F: a novel acentric deep-ultraviolet material43Structural diversities induced by cation sizes in a series of fluorogermanophosphates: A 2 [GeF 2 (HPO 4 ) 2 ] (A = Na, K, Rb, NH 4 , and Cs)4Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect238Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect71M4Mg4(P2O7)3 (M = K, Rb): Structural Engineering of Pyrophosphates for Nonlinear Optical Applications238Birefringence of the new fluoride borates Ba2Na3[B3O6]2F and Ba7(BO3)4−F2+3 in the Na, Ba, B//O, F quaternary reciprocal system4Borate-Based Ultraviolet and Deep-Ultraviolet Nonlinear Optical Crystals58Two Zeolitic Open-Framework Aluminoborates Directed by Similar Zn-Complexes23Pb@Pb8 Basket-like-Cluster-Based Lead Tellurate–Nitrate Kleinman-Forbidden Nonlinear-Optical Crystal: Pb9Te2O13(OH)(NO3)326Crystal Growth and Linear and Nonlinear Optical Properties of KIO 3 ·Te(OH) 615Synthesis, Structure, and Properties of Nonlinear Optical Crystal Na2SiF622A cation size effect on the framework structures in ABi 2 SeO 3 F 5 (A = K and Rb): first examples of alkali metal bismuth selenite fluorides14Ba 3 B 10 O 17 Br 2 : a new barium borate halide with B–O layered structure4BaLiZn 3 (BO 3 ) 3 : a new member of the KBe 2 BO 3 F 2 family possessing dense BO 3 triangles and the smallest interlayer distance16First principle study of nonlinear optical crystals15K 2 TeP 2 O 8 : a new telluro-phosphate with a pentagonal Te–P–O layer structure26Structural insights into T 2 -cluster-containing chalcogenides with vertex-, edge- and face-sharing connection modes of NaQ 6 ligands: Na 3 ZnM III Q 4 (M III = In, Ga; Q = S, Se)13Surface microstructure engenders unusual hydrophobicity in phyllosilicates21From AgGaS2 to Li2ZnSiS4: Realizing Impressive High Laser Damage Threshold Together with Large Second-Harmonic Generation Response134Pb8M(BO3)6 (M = Mg, Ca): Two new borates with large birefringence activated by the ∞[Pb8B6O18]2- double layers6Pb2BO3I: A Borate Iodide with the Largest Second‐Harmonic Generation (SHG) Response in the KBe2BO3F2 (KBBF) Family of Nonlinear Optical (NLO) Materials238Pb2BO3I: A Borate Iodide with the Largest Second‐Harmonic Generation (SHG) Response in the KBe2BO3F2 (KBBF) Family of Nonlinear Optical (NLO) Materials24Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals258Deep-ultraviolet nonlinear optical materials: Development trend and innovative exploration16Crystal structures and theoretical studies of polyphosphate LiZnP3O9 for nonlinear optical applications18Li3.366Mg0.317B2O5: The first pyroborate in the Li2O-MgO-B2O3 system1From LiB3O5 to NaRbB6O9F2: Fluorine‐Directed Evolution of Structural Chemistry33High-Temperature, High-Pressure Hydrothermal Synthesis and Characterization of an Acentric Borate Fluoride: Ba2B5O9F·0.5H2O5Non-centrosymmetric BaNaP3O9 with a short deep-ultraviolet cutoff edge14Assisting the Effective Design of Polar Iodates with Early Transition-Metal Oxide Fluoride Anions206Fluorooxoborates: Ushering in a New Era of Deep Ultraviolet Nonlinear Optical Materials102Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)2(IO3)4O, Ba3[(MoO2)2(IO3)4O(OH)4]·2H2O, and Sr[(MoO2)6(IO4)2O4]·H2O24Second-order nonlinear optical crystals with mixed anions250Synthesis and Characterization of the First Tin Fluoride Borate Sn3[B3O7]F with Second Harmonic Generation Response28Removal of A-Site Alkali and Alkaline Earth Metal Cations in KBe2BO3F2-Type Layered Structures To Enhance the Deep-Ultraviolet Nonlinear Optical Capability47Two new mixed metal borates with the large birefringence in borates system confirmed by a disordered crystal optical calculation method6NaCa4V5O17 with isolated V2O7 dimer and V3O10 trimer exhibiting a large birefringence18Structure–Property Relationship and Systematic Study of a Series of Terpyridine Based Nonlinear Optical Compounds: DFT Computation of Interactive Design14Na 3 B 7 O 11 F 2 : a new sodium-rich fluorooxoborate with a unique [B 14 O 24 F 4 ] ring and a short ultraviolet absorption edge27The linear and nonlinear optical response of CsGeX3 (X=Cl, Br, and I): The finite field and first-principles investigation26The structure and classification of complex borates43Two Lanthanide Borate Chlorides LnB4O6(OH)2Cl (Ln = La, Ce) with Wide Ultraviolet Transmission Windows and Large Second-Harmonic Generation Responses25Noncentrosymmetric cubic RbBSi2O6 polymorph with deep ultraviolet cut-off edge4Synthesis, growth and third order nonlinear optical studies of a rhombohedral crystal: Sodium tetraborate pentahydrate7A UV Transmittable NLO crystal Hydrofluoric Acid Mixed Sulphamic acid (FASA) : Synthesis, Growth and Characterization0Fluoroborophosphates: a family of potential deep ultraviolet NLO materials43Investigation on two new antimony-based quaternary chalcogenides: Na 6 CdSb 4 S 10 and Na 3 CdSbSe 41Multifunctional property exploration: Bi 4 O 5 I 2 with high visible light photocatalytic performance and a large nonlinear optical effect32Pb 10 O 4 (BO 3 ) 3 I 3 : a new noncentrosymmetric oxyborate iodide synthesized by the straightforward hydrothermal method6BaV2O6·H2O: A nonlinear optical crystal with a large bandgap7Ba4M(CO3)2(BO3)2 (M=Ba, Sr): two borate-carbonates synthesized by open high temperature solution method29Targeting the Next Generation of Deep-Ultraviolet Nonlinear Optical Materials: Expanding from Borates to Borate Fluorides to Fluorooxoborates450NaCa5BO3(SiO4)2 with Interesting Isolated [BO3] and [SiO4] Units in Alkali- and Alkaline-Earth-Metal Borosilicates14Heteroanionic Materials by Design: Progress Toward Targeted Properties237RbB 11 O 16 (OH) 2 : First Hydroxyl Rubidium Borate with the B‐O 2D Layer Featuring Large Birefringence in the Rb‐B‐O‐H System5BaB 2 O 3 F 2 : A Barium Fluorooxoborate with a Unique [B 2 O 3 F] − Layer and Short Cutoff Edge38Synthesis and Characterization of the Tin Iodide Borate Sn3[B3O7]I14Crystal structure and second harmonic generation in Bi2TeO5: An X-N study from synchrotron and neutron diffraction data8Synthesis, characterization and theoretical calculation of a noncentrosymmetric compound, Cs0.92B0.92Si5.08O122Agar and egg shell derived calcium carbonate and calcium hydroxide nanoparticles: Synthesis, characterization and applications61Average Structure, Local Structure, Photoluminescence, and NLO Properties of Scheelite Type NaCe(WO4)215Synthesis of Co3O4 Nano Aggregates by Co-precipitation Method and its Catalytic and Fuel Additive Applications79Synthesis and structure of calcium-tin hybrid microparticles from egg shell and investigation of their thermal behavior and catalytic application13Effect of anion dimensionality on optical properties: the ∞ [B 7 O 10 (OH) 2 ] layer in CsB 7 O 10 (OH) 2 vs. the ∞ [B 7 O 12 ] framework in CsBaB 7 O 1219K 2.64 Cs 0.36 SiF 7 : a new fluorosilicate with a trans -perovskite structure3Li 2 CdSiS 4 , a promising IR NLO material with a balanced E g and SHG response originating from the effect of Cd with d 10 configuration36Li 3 CaB 2 O 5 F: a unique sandwich-like structure with diverse and wide Li ion diffusion pathways5Synthesis, characterization and crystal structure of a new mixed alkali and alkaline-earth metal borate Rb 9 Ba 24 (BO 3 ) 196Controllable synthesis and spontaneous phase transition of photonic coordination polymer to produce a strong second-harmonic generation response25Syntheses, characterization and calculations of LimAnM6O15 (A=Rb, Cs; M=Si, Ge; m+n=6)18

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  4. Pb2B5O9Cl: a chloride borate with second harmonic generation effect

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  5. BaClBF4: a new noncentrosymmetric pseudo-Aurivillius type material with transparency range from deep UV to middle IR and a high laser damage threshold

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  31. Pb3B6O11F2: the first non-centrosymmetric lead borate fluoride with a large second harmonic generation response

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  33. Ba18F18In8S21 and Ba9F10In4S10: new kind of mixed anion compounds with the novel low-dimensional structure

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  34. Ba4(BO3)3(SiO4)·Ba3X (X = Cl, Br): new salt-inclusion borosilicate halides as potential deep UV nonlinear optical materials

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  35. BaPbSi 2 O 6 ·BaSO 4 : the first mixed anionic compound synthesized via BaSO 4 salt-inclusion

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  37. Exploring the influence of cationic skeletons on the arrangement of isolated BO 3 groups based on RbMgBO 3 , CsZn 4 (BO 3 ) 3 and Cs 4 Mg 4 (BO 3 ) 4

    New Journal of Chemistry · 2014-01-01

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  38. Two Cu-complex directed aluminoborates: from 2D layers to 3D frameworks

    Dalton Transactions · 2014-01-01

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  39. β-BaGa[B 4 O 8 (OH)](H 2 O) and Ba 4 Ga[B 10 O 18 (OH) 5 ](H 2 O): new barium galloborates featuring unusual [B 4 O 8 (OH)] 5− and [B 10 O 18 (OH) 5 ] 11− clusters

    RSC Advances · 2014-01-01

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  40. Noncentrosymmetric YVSe2O8 and Centrosymmetric YVTe2O8: Macroscopic Centricities Influenced by the Size of Lone Pair Cation Linkers

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  41. Cs 3 Zn 6 B 9 O 21 : A Chemically Benign Member of the KBBF Family Exhibiting the Largest Second Harmonic Generation Response

    Journal of the American Chemical Society · 2014-01-06

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  42. SrBeB2O5: Growth, crystal structure and optical properties

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  43. Three New Alkaline Beryllium Borates LiBeBO3, Li6Be3B4O12, and Li8Be5B6O18 in the Ternary Phase Diagrams Li2O–BeO–B2O3

    Inorganic Chemistry · 2014-02-17

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  44. Noncentrosymmetric versus Centrosymmetric: Influence of the Na+ Substitution on Structural Transition and Second-Harmonic Generation Property

    Crystal Growth & Design · 2014-03-13

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  45. Series of Lead Oxide Hydroxide Nitrates Obtained by Adjusting the pH Values of the Reaction Systems

    Inorganic Chemistry · 2014-05-05

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  46. Reinvestigation and Characterization of the Magnesium Borate Fluoride Mg5(BO3)F

    Zeitschrift für anorganische und allgemeine Chemie · 2014-07-03

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  47. Synthesis, crystal structure, and optical properties of a new lead barium borate, PbBa 2 (B 3 O 6 ) 2

    Journal of Alloys and Compounds · 2014-07-05

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  48. NaB3O5·0.5H2O and NH4NaB6O10: Two Cluster Open Frameworks with Chiral Quartz and Achiral Primitive Cubic Nets Constructed from Oxo Boron Cluster Building Units

    European Journal of Inorganic Chemistry · 2014-08-05

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  49. Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework

    Inorganic Chemistry · 2014-09-26

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  50. Zn 4 B 3 O 9 C 2 H 8 N 2 : an organic–inorganic hybrid borate with a novel graphene-like layer

    New Journal of Chemistry · 2014-09-30

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