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RESEARCH PAPER · Inorganic Chemistry · 2012

Two New Noncentrosymmetric (NCS) Polar Oxides: Syntheses, Characterization, and Structure–Property Relationships in BaMTe2O7 (M = Mg2+ or Zn2+)

Jeongho Yeon, Sang‐Hwan Kim, Sau Doan Nguyen, Hana Lee, P. Shiv Halasyamani

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Two New Noncentrosymmetric (NCS) Polar Oxides: Syntheses, Characterization, and Structure–Property Relationships in BaMTe2O7 (M = Mg2+ or Zn2+)OriginalChemInform Abstract: Two New Noncentrosymmetric (NCS) Polar Oxides: Syntheses, Characterization, and Structure—Property Relationships in BaMTe2O7 (M: Mg2+ or Zn2+).0A New Mixed Halide, Cs2HgI2Cl2: Molecular Engineering for a New Nonlinear Optical Material in the Infrared Region145A combination of multiple chromophores enhances second-harmonic generation in a nonpolar noncentrosymmetric oxide: CdTeMoO681ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units53New Fluoride Carbonates: Centrosymmetric KPb2(CO3)2F and Noncentrosymmetric K2.70Pb5.15(CO3)5F367Crystal Growth, Structure, Polarization, and Magnetic Properties of Cesium Vanadate, Cs2V3O8: A Structure–Property Study40U3F12(H2O), a Noncentrosymmetric Uranium(IV) Fluoride Prepared via a Convenient In Situ Route That Creates U4+ under Mild Hydrothermal Conditions38Formation Principles for Templated Vanadium Selenite Oxalates22High temperature redox reactions with uranium: Synthesis and characterization of Cs(UO2)Cl(SeO3), Rb2(UO2)3O2(SeO3)2, and RbNa5U2(SO4)77Synthesis and characterization of ASnF3 (A=Na+, K+, Rb+, Cs+)29Helical ∞1[Pb2O] Chains in Polymorphs of Pb2O(C6H5COO)211Role of Acentric Displacements on the Crystal Structure and Second-Harmonic Generating Properties of RbPbCO3F and CsPbCO3F90Borate Fluoride and Fluoroborate in Alkali-Metal Borate Prepared by an Open High-Temperature Solution Method50Bi 2 Te(IO 3 )O 5 Cl: a novel polar iodate oxychloride exhibiting a second-order nonlinear optical response29BaBi(SeO 3 ) 2 Cl: a new polar material showing high second-harmonic generation efficiency enhanced by constructive alignment of chloride ions36K 3 LaTe 2 O 9 : a new alkali-rare earth tellurate with face-sharing TeO 6 octahedra17Na2RE2TeO4(BO3)2 (RE = Y, Dy–Lu): Luminescent and Structural Studies on a Series of Mixed Metal Borotellurates51Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS2 and Centric Ba8Hg4S5Se752Crystal Growth of Four Oxovanadium(IV) Tartrates Prepared via a Mild Two-Step Hydrothermal Method: Observation of Spin-Dimer Behavior and Second Harmonic Generation28Second order nonlinear optical properties of Cs_2TeW_3O_12 single crystal21Electronic, Crystal Chemistry, and Nonlinear Optical Property Relationships in the Dugganite A3B3CD2O14 Family148A review of the structural architecture of tellurium oxycompounds170Syntheses, characterization and theoretical studies of three apatite-type phosphates MPb4(PO4)3 (M = K, Rb, Cs)17Characterization and optimization of the growth conditions of a novel Cs 2 TeW 3 O 12 piezoelectric crystal5Crystal Growth and Structure Analysis of Ce 18 W 10 O 57 : A Complex Oxide Containing Tungsten in an Unusual Trigonal Prismatic Coordination Environment14125Te NMR Probes of Tellurium Oxide Crystals: Shielding-Structure Correlations18Verres, vitrocéramique et céramique à base de TeO2 pour l'optique0Structural insights into three phosphates with distinct polyanionic configurations20Three new phosphates, Cs8Pb4(P2O7)4, CsLi7(P2O7)2 and LiCa(PO3)3: structural comparison, characterization and theoretical calculation23Molten Alkali Halide Flux Growth of an Extensive Family of Noncentrosymmetric Rare Earth Sulfides: Structure and Magnetic and Optical (SHG) Properties47NaYTe2O7: A new compound with mixed valence of tellurium and large birefringence6Crystal Structure and Properties of a UV‐Transparent High‐Pressure Polymorph of Mg3TeO6 with Second Harmonic Generation Response18MII2M3IIIF3(Te6F2O16) (MII = Pb, Ba; MIII = Al, Ga): New mixed anionic tellurites with isolated Te6 coplanar rings23Polymorphism and Molten Nitrate Salt-Assisted Single Crystal to Single Crystal Ion Exchange in the Cesium Ferrogermanate Zeotype: CsFeGeO412Na1.7Li0.3BaZn7(TeO6)3: The first mixed alkali metal and alkaline earth metal zinc tellurate0Structure and magnetic properties of the S = 3/2 zigzag spin chain antiferromagnet BaCoTe2O724Band gap modulation and nonlinear optical properties of quaternary tellurates Li 2 GeTeO 613HgSO4: An excellent mid-infrared sulfate nonlinear optical crystal with wide band gap and strong second harmonic generation response19Flux crystal growth of rubidium–iron silicates and germanates and their ion-exchange using alkali nitrate salts1Speciation of Tellurium(VI) in Aqueous Solutions: Identification of Trinuclear Tellurates by 17O, 123Te, and 125Te NMR Spectroscopy1Structural phase stability and thermodynamical properties of transition metal complex hydrides Na2MgTMH7 (TM=Sc−Cu) for hydrogen storage applications16The calcium oxidotellurates Ca2(TeIVTeVIO7), Ca2(TeIVO3)Cl2 and Ca5(TeIVO3)4Cl2 obtained from salt melts0Understanding of the structural chemistry in the uranium oxo-tellurium system under HT/HP conditions5Magnetic properties of the quasi-one-dimensional S=1 spin chain antiferromagnet BaNiTe2O77Ag 2 [TeO 2 (OH) 4 ]: a nonlinear optical tellurate with balanced comprehensive performance2Synthesis, crystal structure and investigation of ion-exchange possibility for sodium tellurate NaTeO 3 (OH)3Block Mott insulating state induced by next-nearest-neighbor hopping in the S=32 zigzag chain BaCoTe2O72Polymorphism of BaTeO 3 under High Pressure: Single-Crystal Structure Analysis and Characterization of HP-BaTeO 32Multistep transitions in noncollinear spin zigzag chain in BaCoT e 2 O 70Coordination-Driven Color Tuning in Non-Centrosymmetric Ba M Te2O7 Solid Solutions for High Near-Infrared Reflective Inorganic Pigments0

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  1. ChemInform Abstract: Two New Noncentrosymmetric (NCS) Polar Oxides: Syntheses, Characterization, and Structure—Property Relationships in BaMTe2O7 (M: Mg2+ or Zn2+).

    ChemInform · 2012-04-05

    Jeongho Yeon, Sang‐Hwan Kim, Sau Doan Nguyen, Hana Lee, P. Shiv Halasyamani

    Read original paper ↗ ·

  2. A New Mixed Halide, Cs2HgI2Cl2: Molecular Engineering for a New Nonlinear Optical Material in the Infrared Region

    Journal of the American Chemical Society · 2012-08-15

    Gang Zhang, Yanjun Li, Kui Jiang, Hui‐Yi Zeng, Tao Liu, Xingguo Chen, Jingui Qin, Zheshuai Lin, Peizhen Fu, Yicheng Wu, Chuangtian Chen

    Read original paper ↗ ·

  3. A combination of multiple chromophores enhances second-harmonic generation in a nonpolar noncentrosymmetric oxide: CdTeMoO6

    Journal of Materials Chemistry C · 2013-01-01

    Sangen Zhao, Xingxing Jiang, Ran He, Shuquan Zhang, Zhihua Sun, Junhua Luo, Zheshuai Lin, Maochun Hong

    Read original paper ↗ ·

  4. ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units

    RSC Advances · 2013-01-01

    Sangen Zhao, Junhua Luo, Pan Zhou, Shuquan Zhang, Zhihua Sun, Maochun Hong

    Read original paper ↗ ·

  5. New Fluoride Carbonates: Centrosymmetric KPb2(CO3)2F and Noncentrosymmetric K2.70Pb5.15(CO3)5F3

    Inorganic Chemistry · 2013-02-08

    T. Thao Tran, P. Shiv Halasyamani

    Read original paper ↗ ·

  6. Crystal Growth, Structure, Polarization, and Magnetic Properties of Cesium Vanadate, Cs2V3O8: A Structure–Property Study

    Inorganic Chemistry · 2013-05-09

    Jeongho Yeon, Athena S. Sefat, T. Thao Tran, P. Shiv Halasyamani, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  7. U3F12(H2O), a Noncentrosymmetric Uranium(IV) Fluoride Prepared via a Convenient In Situ Route That Creates U4+ under Mild Hydrothermal Conditions

    Inorganic Chemistry · 2013-07-08

    Jeongho Yeon, Mark D. Smith, Athena S. Sefat, T. Thao Tran, P. Shiv Halasyamani, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  8. Formation Principles for Templated Vanadium Selenite Oxalates

    Crystal Growth & Design · 2013-08-08

    Jacob H. Koffer, Jacob H. Olshansky, Matthew D. Smith, Kristen J. Hernandez, Mat­thias Zeller, Gregory M. Ferrence, Joshua Schrier, Alexander J. Norquist

    Read original paper ↗ ·

  9. High temperature redox reactions with uranium: Synthesis and characterization of Cs(UO2)Cl(SeO3), Rb2(UO2)3O2(SeO3)2, and RbNa5U2(SO4)7

    Journal of Solid State Chemistry · 2013-08-13

    Jean‐Marie Babo, Thomas E. Albrecht‐Schmitt

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  10. Synthesis and characterization of ASnF3 (A=Na+, K+, Rb+, Cs+)

    Journal of Solid State Chemistry · 2013-11-25

    T. Thao Tran, P. Shiv Halasyamani

    Read original paper ↗ ·

  11. Helical ∞1[Pb2O] Chains in Polymorphs of Pb2O(C6H5COO)2

    Crystal Growth & Design · 2014-03-06

    Clay C. Easterday, Liv R. Dedon, Mat­thias Zeller, Catherine M. Oertel

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  12. Role of Acentric Displacements on the Crystal Structure and Second-Harmonic Generating Properties of RbPbCO3F and CsPbCO3F

    Inorganic Chemistry · 2014-05-27

    T. Thao Tran, P. Shiv Halasyamani, James M. Rondinelli

    Read original paper ↗ ·

  13. Borate Fluoride and Fluoroborate in Alkali-Metal Borate Prepared by an Open High-Temperature Solution Method

    Inorganic Chemistry · 2014-12-01

    Hongping Wu, Hongwei Yu, Qiang Bian, Zhihua Yang, Shujuan Han, Shilie Pan

    Read original paper ↗ ·

  14. Bi 2 Te(IO 3 )O 5 Cl: a novel polar iodate oxychloride exhibiting a second-order nonlinear optical response

    Dalton Transactions · 2014-12-11

    Lei Geng, Chang‐Yu Meng, Hong‐Yan Lu, Zhong‐Zhen Luo, Chensheng Lin, Wendan Cheng

    Read original paper ↗ ·

  15. BaBi(SeO 3 ) 2 Cl: a new polar material showing high second-harmonic generation efficiency enhanced by constructive alignment of chloride ions

    Journal of Materials Chemistry C · 2015-01-01

    Lei Geng, Qiang Li, Chang‐Yu Meng, Kai Dai, Hong‐Yan Lu, Chensheng Lin, Wen‐Dan Cheng

    Read original paper ↗ ·

  16. K 3 LaTe 2 O 9 : a new alkali-rare earth tellurate with face-sharing TeO 6 octahedra

    Dalton Transactions · 2015-01-01

    Xinyuan Zhang, Jiyong Yao, Xingxing Jiang, Ying Fu, Zheshuai Lin, Guochun Zhang, Yicheng Wu

    Read original paper ↗ ·

  17. Na2RE2TeO4(BO3)2 (RE = Y, Dy–Lu): Luminescent and Structural Studies on a Series of Mixed Metal Borotellurates

    Inorganic Chemistry · 2015-02-18

    Jiang-He Feng, Chun‐Li Hu, Xiang Xu, Fang Kong, Jiang‐Gao Mao

    Read original paper ↗ ·

  18. Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS2 and Centric Ba8Hg4S5Se7

    Inorganic Chemistry · 2015-03-05

    Kui Wu, Xin Su, Shilie Pan, Zhihua Yang

    Read original paper ↗ ·

  19. Crystal Growth of Four Oxovanadium(IV) Tartrates Prepared via a Mild Two-Step Hydrothermal Method: Observation of Spin-Dimer Behavior and Second Harmonic Generation

    Inorganic Chemistry · 2015-03-31

    Anthony J. Cortese, Branford O. Wilkins, Mark D. Smith, Jeongho Yeon, Gregory W. Morrison, T. Thao Tran, P. Shiv Halasyamani, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  20. Second order nonlinear optical properties of Cs_2TeW_3O_12 single crystal

    Optical Materials Express · 2016-01-14

    Peng Zhao, Qian Wu, Chunlong Li, Shao-Jun Zhang, Youxuan Sun, Chengqian Zhang, Sheng‐Qing Xia, Zeliang Gao, Xutang Tao

    Read original paper ↗ ·

  21. Electronic, Crystal Chemistry, and Nonlinear Optical Property Relationships in the Dugganite A3B3CD2O14 Family

    Journal of the American Chemical Society · 2016-03-25

    Hongwei Yu, Joshua Young, Hongping Wu, Weiguo Zhang, James M. Rondinelli, P. Shiv Halasyamani

    Read original paper ↗ ·

  22. A review of the structural architecture of tellurium oxycompounds

    Mineralogical Magazine · 2016-05-01

    Andrew G. Christy, Stuart J. Mills, Anthony R. Kampf

    Read original paper ↗ ·

  23. Syntheses, characterization and theoretical studies of three apatite-type phosphates MPb4(PO4)3 (M = K, Rb, Cs)

    Journal of Alloys and Compounds · 2016-08-20

    Maierhaba Abudoureheman, Shujuan Han, Xiaoyu Dong, Bing‐Hua Lei, Ying Wang, Zhihua Yang, Xifa Long, Shilie Pan

    Read original paper ↗ ·

  24. Characterization and optimization of the growth conditions of a novel Cs 2 TeW 3 O 12 piezoelectric crystal

    RSC Advances · 2017-01-01

    Peng Zhao, Qian Wu, Zeliang Gao, Xiangxin Tian, Conggang Li, Youxuan Sun, Chengqian Zhang, Sheng‐Qing Xia, Xutang Tao

    Read original paper ↗ ·

  25. Crystal Growth and Structure Analysis of Ce 18 W 10 O 57 : A Complex Oxide Containing Tungsten in an Unusual Trigonal Prismatic Coordination Environment

    Inorganic Chemistry · 2017-02-15

    Dileka Abeysinghe, Mark D. Smith, Jeongho Yeon, T. Thao Tran, Robert Paria Sena, Joke Hadermann, P. Shiv Halasyamani, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  26. 125Te NMR Probes of Tellurium Oxide Crystals: Shielding-Structure Correlations

    Inorganic Chemistry · 2017-12-29

    Mounesha N. Garaga, Ulrike Werner‐Zwanziger, Josef W. Zwanziger

    Read original paper ↗ ·

  27. Verres, vitrocéramique et céramique à base de TeO2 pour l'optique

    Unknown journal · 2018-12-07

    Morgane Dolhen

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  28. Structural insights into three phosphates with distinct polyanionic configurations

    Dalton Transactions · 2019-01-01

    Jun Sun, Hongping Wu, Miriding Mutailipu, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  29. Three new phosphates, Cs8Pb4(P2O7)4, CsLi7(P2O7)2 and LiCa(PO3)3: structural comparison, characterization and theoretical calculation

    Dalton Transactions · 2019-01-01

    Shujuan Han, Hao Li, Zhihua Yang, Hao Yu, Shilie Pan

    Read original paper ↗ ·

  30. Molten Alkali Halide Flux Growth of an Extensive Family of Noncentrosymmetric Rare Earth Sulfides: Structure and Magnetic and Optical (SHG) Properties

    Inorganic Chemistry · 2019-06-19

    Mohammad Usman, Mark D. Smith, Gregory W. Morrison, Vladislav V. Klepov, Weiguo Zhang, P. Shiv Halasyamani, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  31. NaYTe2O7: A new compound with mixed valence of tellurium and large birefringence

    Journal of Alloys and Compounds · 2019-10-02

    Houping Xia, Jinni Shen, Zhi-An Zhu, Yang‐Yang Lv, Qian Ma, Haiqing Wang

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  32. Crystal Structure and Properties of a UV‐Transparent High‐Pressure Polymorph of Mg3TeO6 with Second Harmonic Generation Response

    European Journal of Inorganic Chemistry · 2019-10-24

    Elisabeth Selb, Lisa Declara, Lkhamsuren Bayarjargal, Maren Podewitz, Martina Tribus, Günter Heymann

    Read original paper ↗ ·

  33. MII2M3IIIF3(Te6F2O16) (MII = Pb, Ba; MIII = Al, Ga): New mixed anionic tellurites with isolated Te6 coplanar rings

    Journal of Solid State Chemistry · 2020-02-29

    Pengfei Li, Fang Kong, Jiang‐Gao Mao

    Read original paper ↗ ·

  34. Polymorphism and Molten Nitrate Salt-Assisted Single Crystal to Single Crystal Ion Exchange in the Cesium Ferrogermanate Zeotype: CsFeGeO4

    Inorganic Chemistry · 2020-07-02

    Mohammad Usman, Vancho Kocevski, Mark D. Smith, Gregory W. Morrison, Weiguo Zhang, Theodore M. Besmann, P. Shiv Halasyamani, Hans‐Conrad zur Loye

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  35. Na1.7Li0.3BaZn7(TeO6)3: The first mixed alkali metal and alkaline earth metal zinc tellurate

    Inorganic Chemistry Communications · 2020-12-01

    Ting Zhang, Jingjing Zheng, Shichao Cheng, Junwei Feng, Chunyan Bai

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  36. Structure and magnetic properties of the S = 3/2 zigzag spin chain antiferromagnet BaCoTe2O7

    Science China Physics Mechanics and Astronomy · 2021-07-01

    Lisi Li, Xunwu Hu, Zengjia Liu, Jia Yu, Benyuan Cheng, Sihao Deng, Lunhua He, Kun Cao, Dao-Xin Yao, Meng Wang

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  37. Band gap modulation and nonlinear optical properties of quaternary tellurates Li 2 GeTeO 6

    Dalton Transactions · 2022-01-01

    Dan Wang, Yunxi Zhang, Qian Liu, Bingbing Zhang, Daqing Yang, Ying Wang

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  38. HgSO4: An excellent mid-infrared sulfate nonlinear optical crystal with wide band gap and strong second harmonic generation response

    Journal of Alloys and Compounds · 2022-01-11

    Yinglei Han, Xin Lei Zhao, Feng Xu, Bingxuan Li, Ning Ye, Min Luo

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  39. Flux crystal growth of rubidium–iron silicates and germanates and their ion-exchange using alkali nitrate salts

    Solid State Sciences · 2022-08-27

    Mohammad Usman, Matthew S. Christian, Gregory W. Morrison, Mark D. Smith, Weiguo Zhang, Theodore M. Besmann, P. Shiv Halasyamani, Hans‐Conrad zur Loye

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  40. Speciation of Tellurium(VI) in Aqueous Solutions: Identification of Trinuclear Tellurates by 17O, 123Te, and 125Te NMR Spectroscopy

    Molecules · 2022-12-07

    Alexander G. Medvedev, Oleg Yu. Saveliev, Д.П. Крутько, Alexey A. Mikhaylov, Ovadia E. Lev, Petr V. Prikhodchenko

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  41. Structural phase stability and thermodynamical properties of transition metal complex hydrides Na2MgTMH7 (TM=Sc−Cu) for hydrogen storage applications

    Journal of Solid State Chemistry · 2023-02-10

    S. Kiruthika, P. Sundar, Ponniah Ravindran

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  42. The calcium oxidotellurates Ca2(TeIVTeVIO7), Ca2(TeIVO3)Cl2 and Ca5(TeIVO3)4Cl2 obtained from salt melts

    Zeitschrift für Naturforschung B · 2023-03-01

    Tobias Wolflehner, Berthold Stöger, Matthias Weil

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  43. Understanding of the structural chemistry in the uranium oxo-tellurium system under HT/HP conditions

    Frontiers in Chemistry · 2023-03-10

    Yucheng Hao, Eike M. Langer, Bin Xiao, Philip Kegler, Xin Cao, Kunhong Hu, Rüdiger‐A. Eichel, Shuao Wang, Evgeny V. Alekseev

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  44. Magnetic properties of the quasi-one-dimensional S=1 spin chain antiferromagnet BaNiTe2O7

    Physical Review Materials · 2023-09-19

    Xiyu Chen, Yiming Gao, Meifeng Liu, Tao Zou, Vasile Ovidiu Garlea, Clarina dela Cruz, Zhen Liu, Wenjing Niu, Leili Tan, G. Z. Zhou, Fei Liu, Shuhan Zheng, Zhen Ma, Xiuzhang Wang, Hong Li, Shuai Dong, Jun‐Ming Liu

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  45. Ag 2 [TeO 2 (OH) 4 ]: a nonlinear optical tellurate with balanced comprehensive performance

    Journal of Materials Chemistry C · 2024-01-01

    Wenjing Tan, Xuefan Wang, Ruqing Wei, Hongbo Huang, Daqing Yang, Ying Wang, Bingbing Zhang

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  46. Synthesis, crystal structure and investigation of ion-exchange possibility for sodium tellurate NaTeO 3 (OH)

    Dalton Transactions · 2024-01-01

    T. Ishii, Yue Jin Shan, Kotaro Fujii, Tetsuhiro Katsumata, Hideo Imoto, Ariunaa Baterdene, Keitaro Tezuka, Masatomo Yashima

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  47. Block Mott insulating state induced by next-nearest-neighbor hopping in the S=32 zigzag chain BaCoTe2O7

    Physical review. B./Physical review. B · 2024-04-26

    Ling-Fang Lin, Yang Zhang, Gonzalo Álvarez, Adriana Moreo, Elbio R. Dagotto

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  48. Polymorphism of BaTeO 3 under High Pressure: Single-Crystal Structure Analysis and Characterization of HP-BaTeO 3

    Crystal Growth & Design · 2026-01-22

    Benjamin J. Pullicino, Stefan Schwarzmüller, Günter Heymann

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  49. Multistep transitions in noncollinear spin zigzag chain in BaCoT e 2 O 7

    Physical review. B./Physical review. B · 2026-02-26

    Dequan Jiang, Zhengcai Xia, Huakun Zuo, Zhuo Zeng, Hao Huang, Youyuan Liang, Shanshan Pan, T.Y. Li, Meng Wang, Zhongwen Ouyang, Zhengcai Xia

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  50. Coordination-Driven Color Tuning in Non-Centrosymmetric Ba M Te2O7 Solid Solutions for High Near-Infrared Reflective Inorganic Pigments

    Inorganic Chemistry · 2026-09-11

    Chung-Yi Hsu, Gopika Meenakumari Gopakumar, Jun Li, Arthur P. Ramirez, Mas A. Subramanian

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