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RESEARCH PAPER · Inorganic Chemistry · 2011

New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)

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New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)OriginalChemInform Abstract: New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3 (H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4 (Se2O5) (A: Sr2+ or Pb2+).1Pb2TiOF(SeO3)2Cl and Pb2NbO2(SeO3)2Cl: small changes in structure induced a very large SHG enhancement117New Fluoride Carbonates: Centrosymmetric KPb2(CO3)2F and Noncentrosymmetric K2.70Pb5.15(CO3)5F367Large scale synthesis, second-harmonic generation, and piezoelectric properties of a noncentrosymmetric vanadium phosphate, Li2VPO69Crystal Growth, Structure, Polarization, and Magnetic Properties of Cesium Vanadate, Cs2V3O8: A Structure–Property Study40Formation Principles for Templated Vanadium Selenite Oxalates22α-ScVSe2O8, β-ScVSe2O8, and ScVTe2O8: New Quaternary Mixed Metal Oxides Composed of Only Second-Order Jahn–Teller Distortive Cations34Synthesis and characterization of ASnF3 (A=Na+, K+, Rb+, Cs+)29Cobalt selenium oxohalides: catalysts for water oxidation15Role of Acentric Displacements on the Crystal Structure and Second-Harmonic Generating Properties of RbPbCO3F and CsPbCO3F90Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons67A Barium Vanadium(v) Selenite Hydrate, Ba(VO2)2(SeO3)2·H2O: A Novel 3D Polymer of Cross-Linked Sheets with Embedded ···V–O–V··· 21 Helices*3A series of novel mercury( i ) selenites and tellurites containing SOJT Mo 6+ cations18Structural and magnetic studies on three new mixed metal copper( ii ) selenites and tellurites16pH Controlled Pathway and Systematic Hydrothermal Phase Diagram for Elaboration of Synthetic Lead Nickel Selenites18Cs(TaO 2 ) 3 (SeO 3 ) 2 and Cs(TiOF) 3 (SeO 3 ) 2 : Structural and Second Harmonic Generation Changes Induced by the Different d 0 -TM Coordination Octahedra67Explorations of New SHG Materials in the Alkali-Metal–Nb5+–Selenite System33New niobium selenites, ANbO(SeO3)2 (A = Na, K, Rb, and Cs): Effect of alkali metal cation size on the dimensionality and intraoctahedral distortion10Pathways for synthesis of new selenium-containing oxo-compounds: Chemical vapor transport reactions, hydrothermal techniques and evaporation method19Exploration of Vanadate Selenites Solid Phase Space, Crystal Structures, and Polymorphism16Syntheses and structural characterization of vanado-tellurites and vanadyl-selenites: SrVTeO 5 (OH), Cd 2 V 2 Te 2 O 11 , Ca 3 VSe 4 O 13 ·H 2 O and Ba 2 VSe 3 O 108Li3VO4: A Promising Mid-Infrared Nonlinear Optical Material with Large Laser Damage Threshold51Li13Mn(SeO3)8: Lithium-Rich Transition Metal Selenite Containing Jahn–Teller Distortive Cations5New quaternary alkali metal cadmium selenites, A 2 Cd(SeO 3 ) 2 (A = K, Rb, and Cs) and Li 2 Cd 3 (SeO 3 ) 43A(VO 2 F)(SeO 3 ) (A = Sr, Ba) and Ba(MOF 2 )(TeO 4 ) (M = Mo, W): first examples of alkali-earth selenites/tellurites with a fluorinated d 0 -TM octahedron33Li6M(SeO3)4 (M = Co, Ni, and Cd) and Li2Zn(SeO3)2: Selenites with Late Transition-Metal Cations32Crystal structures and characterizations of two new selenite chlorides: 1D Ba2Zn(SeO3)2Cl2 and 2D BaZn2(SeO3)2Cl26Second-order nonlinear optical crystals with mixed anions250Interrelationship «Composition - Structure - Property» for Acentric Selenite Crystals0Changes of optical transition models caused by crystal structural changes in CaSe2O50Pb 2 Cd(SeO 3 ) 2 X 2 (X = Cl and Br): two halogenated selenites with phase matchable second harmonic generation27BaV2O6·H2O: A nonlinear optical crystal with a large bandgap7New cadmium-selenium-oxyhalides: Noncentrosymmetric Cd5(SeO3)4Cl2(H2O) and centrosymmetric Cd2(SeO3)F2, Cd2(SeO3)(OH)Br17New Members of SHG Active Dugganite Family, A3BC3D2O14 (A = Ba, Pb; B = Te, Sb; C = Al, Ga, Fe, Zn; D = Si, Ge, P, V): Synthesis, Structure, and Materials Properties30Recent progress in selenite and tellurite based SHG materials32Mixed-valent selenium compounds: Noncentrosymmetric Cd3(SeO3)2(SeO4) and Hg3(SeO3)2(SeO4) and centrosymmetric Pb2(SeO3) (SeO4)22BiGa(SeO3)3: A Phase Matchable SHG Material Achieved by Cation Substitution19Role of fluorine on the structure and second-harmonic-generation property of inorganic selenites and tellurites23Hg 2 (SeO 3 )(SO 4 ): the first sulfate selenite with large birefringence explored from d 10 transition metal compounds36Flux synthesis, crystal structure, and characterization of a gamma-vanadate selenite polymorph1Synthesis, structures and properties of two new selenite optical materials: K 2 Zn 3 Se 4 O 12 and K 4 Zn 3 V 4 Se 2 O 192Gladstone–Dale compatibility, electronic polarizability and vibrational spectroscopy of minerals and inorganic compounds with V 4+ O and V 4+ O 2 vanadyl groups1Syntheses, Crystal Structure, and Second Harmonic Generation Response of Four Novel Noncentrosymmetric Tellurites of Quaternary A/M/Te/O (A = Ba, Sr, Ca; M = V, Nb, Ta) System: BaTa4Te3O17, BaNb4Te3O17, SrTa4Te3O17, and CaV2TeO84Polymorphism of Niobium Phosphate Bronze Na4Nb8P4O32Deduced by the Packings of Structural Units: A Centrosymmetric Phase7Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites56RE(HSeO3)(SeO3)(H2O)·(H2O) (RE = Y, Gd): Two Rare-Earth Selenite Nonlinear Optical Crystals with Wide Band Gaps6Hg3(TeO3)2(NO3)2 and Hg3(Te2O5)2(NO3)2: The First Two Hg‐Based Tellurite Nitrate Unit‐Mixed Crystals with Large Optical Anisotropy16Nonlinear Optical Series A(VO2)3(SeO3)2 (A = NH4+, K+, and H3O+) with Large Birefringence Derived from High-Anisotropic VO6 Octahedra and SeO3 Pyramids8Cd/V Ratio-Driven Centrosymmetric Transition of Crystal Structures in Cesium Cadmium Vanadate Oxychlorides Cs 3 CdV 4 O 12 Cl and CsCdV 2 O 6 Cl0

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  1. ChemInform Abstract: New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3 (H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4 (Se2O5) (A: Sr2+ or Pb2+).

    ChemInform · 2012-02-09

    Jeongho Yeon, Sang‐Hwan Kim, Sau Doan Nguyen, Hana Lee, P. Shiv Halasyamani

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  2. Pb2TiOF(SeO3)2Cl and Pb2NbO2(SeO3)2Cl: small changes in structure induced a very large SHG enhancement

    Chemical Communications · 2013-01-01

    Xue‐Li Cao, Chun‐Li Hu, Xiang Xu, Fang Kong, Jiang‐Gao Mao

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  3. New Fluoride Carbonates: Centrosymmetric KPb2(CO3)2F and Noncentrosymmetric K2.70Pb5.15(CO3)5F3

    Inorganic Chemistry · 2013-02-08

    T. Thao Tran, P. Shiv Halasyamani

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  4. Large scale synthesis, second-harmonic generation, and piezoelectric properties of a noncentrosymmetric vanadium phosphate, Li2VPO6

    Journal of Solid State Chemistry · 2013-03-19

    Eun Pyo Lee, Dong Woo Lee, Yoon‐Ho Cho, T. Thao Tran, P. Shiv Halasyamani, Kang Min Ok

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  5. Crystal Growth, Structure, Polarization, and Magnetic Properties of Cesium Vanadate, Cs2V3O8: A Structure–Property Study

    Inorganic Chemistry · 2013-05-09

    Jeongho Yeon, Athena S. Sefat, T. Thao Tran, P. Shiv Halasyamani, Hans‐Conrad zur Loye

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  6. Formation Principles for Templated Vanadium Selenite Oxalates

    Crystal Growth & Design · 2013-08-08

    Jacob H. Koffer, Jacob H. Olshansky, Matthew D. Smith, Kristen J. Hernandez, Mat­thias Zeller, Gregory M. Ferrence, Joshua Schrier, Alexander J. Norquist

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  7. α-ScVSe2O8, β-ScVSe2O8, and ScVTe2O8: New Quaternary Mixed Metal Oxides Composed of Only Second-Order Jahn–Teller Distortive Cations

    Inorganic Chemistry · 2013-09-11

    Yeong Hun Kim, Dong Woo Lee, Kang Min Ok

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  8. Synthesis and characterization of ASnF3 (A=Na+, K+, Rb+, Cs+)

    Journal of Solid State Chemistry · 2013-11-25

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  9. Cobalt selenium oxohalides: catalysts for water oxidation

    Dalton Transactions · 2014-01-01

    Faiz Rabbani, Henrik Svengren, Iwan Zimmermann, Shichao Hu, Tanja M. Laine, Wenming Hao, Björn Åkermark, Torbjörn Åkermark, Mats Johnsson

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  10. Role of Acentric Displacements on the Crystal Structure and Second-Harmonic Generating Properties of RbPbCO3F and CsPbCO3F

    Inorganic Chemistry · 2014-05-27

    T. Thao Tran, P. Shiv Halasyamani, James M. Rondinelli

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  11. Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons

    Inorganic Chemistry · 2014-08-07

    Xue‐Li Cao, Fang Kong, Chun‐Li Hu, Xiang Xu, Jiang‐Gao Mao

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  12. A Barium Vanadium(v) Selenite Hydrate, Ba(VO2)2(SeO3)2·H2O: A Novel 3D Polymer of Cross-Linked Sheets with Embedded ···V–O–V··· 21 Helices*

    Australian Journal of Chemistry · 2014-09-17

    Kieryn L. Kilminster, Francis Lincoln, Brian W. Skelton, ALLAN HENRY WHITE

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  13. A series of novel mercury( i ) selenites and tellurites containing SOJT Mo 6+ cations

    Inorganic Chemistry Frontiers · 2014-10-15

    Xue‐Li Cao, Fang Kong, Chun‐Li Hu, Jiang‐Gao Mao

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  14. Structural and magnetic studies on three new mixed metal copper( ii ) selenites and tellurites

    Dalton Transactions · 2015-01-01

    Xue‐Li Cao, Fang Kong, Zhangzhen He, Jiang‐Gao Mao

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  15. pH Controlled Pathway and Systematic Hydrothermal Phase Diagram for Elaboration of Synthetic Lead Nickel Selenites

    Inorganic Chemistry · 2015-02-17

    Vadim M. Kovrugin, Marie Colmont, Christine Terryn, S. Colis, Oleg I. Siidra, Sergey V. Krivovichev, Olivier Mentré

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  16. Cs(TaO 2 ) 3 (SeO 3 ) 2 and Cs(TiOF) 3 (SeO 3 ) 2 : Structural and Second Harmonic Generation Changes Induced by the Different d 0 -TM Coordination Octahedra

    Inorganic Chemistry · 2015-04-02

    Xue‐Li Cao, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  17. Explorations of New SHG Materials in the Alkali-Metal–Nb5+–Selenite System

    Inorganic Chemistry · 2015-10-29

    Xue‐Li Cao, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  18. New niobium selenites, ANbO(SeO3)2 (A = Na, K, Rb, and Cs): Effect of alkali metal cation size on the dimensionality and intraoctahedral distortion

    Journal of Alloys and Compounds · 2015-12-17

    Youngkwon Kim, Bongsu Kim, Kang Min Ok

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  19. Pathways for synthesis of new selenium-containing oxo-compounds: Chemical vapor transport reactions, hydrothermal techniques and evaporation method

    Journal of Crystal Growth · 2016-01-15

    Vadim M. Kovrugin, Marie Colmont, Oleg I. Siidra, Vladislav V. Gurzhiy, Sergey V. Krivovichev, Olivier Mentré

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  20. Exploration of Vanadate Selenites Solid Phase Space, Crystal Structures, and Polymorphism

    Crystal Growth & Design · 2016-03-15

    Vadim M. Kovrugin, Marie Colmont, Oleg I. Siidra, Sergey V. Krivovichev, Olivier Mentré

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  21. Syntheses and structural characterization of vanado-tellurites and vanadyl-selenites: SrVTeO 5 (OH), Cd 2 V 2 Te 2 O 11 , Ca 3 VSe 4 O 13 ·H 2 O and Ba 2 VSe 3 O 10

    Journal of Solid State Chemistry · 2017-02-21

    Satish Konatham, Kanamaluru Vidyasagar

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  22. Li3VO4: A Promising Mid-Infrared Nonlinear Optical Material with Large Laser Damage Threshold

    Crystal Growth & Design · 2017-03-30

    Zhaohui Chen, Zhizhong Zhang, Xiaoyu Dong, Yunjing Shi, Yaqin Liu, Qun Jing

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  23. Li13Mn(SeO3)8: Lithium-Rich Transition Metal Selenite Containing Jahn–Teller Distortive Cations

    Inorganic Chemistry · 2017-07-25

    Hongil Jo, Seung Yoon Song, Eunjeong Cho, Jongho So, Suheon Lee, Kwang‐Yong Choi, Kang Min Ok

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  24. New quaternary alkali metal cadmium selenites, A 2 Cd(SeO 3 ) 2 (A = K, Rb, and Cs) and Li 2 Cd 3 (SeO 3 ) 4

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  25. A(VO 2 F)(SeO 3 ) (A = Sr, Ba) and Ba(MOF 2 )(TeO 4 ) (M = Mo, W): first examples of alkali-earth selenites/tellurites with a fluorinated d 0 -TM octahedron

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  26. Li6M(SeO3)4 (M = Co, Ni, and Cd) and Li2Zn(SeO3)2: Selenites with Late Transition-Metal Cations

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  27. Crystal structures and characterizations of two new selenite chlorides: 1D Ba2Zn(SeO3)2Cl2 and 2D BaZn2(SeO3)2Cl2

    Journal of Solid State Chemistry · 2018-05-26

    Qiang Li, Lei Geng, Hong‐Yan Lu, Kai Dai, Wen‐Dan Cheng

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  28. Second-order nonlinear optical crystals with mixed anions

    Coordination Chemistry Reviews · 2018-08-06

    Yu Pan, Sheng‐Ping Guo, Bin‐Wen Liu, Huaiguo Xue, Guo‐Cong Guo

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  29. Interrelationship «Composition - Structure - Property» for Acentric Selenite Crystals

    International Scientific-Technical Conference on Actual Problems of Electronic Instrument Engineering (APEIE) · 2018-10-01

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  30. Changes of optical transition models caused by crystal structural changes in CaSe2O5

    Journal of Solid State Chemistry · 2018-12-29

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  31. Pb 2 Cd(SeO 3 ) 2 X 2 (X = Cl and Br): two halogenated selenites with phase matchable second harmonic generation

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  32. BaV2O6·H2O: A nonlinear optical crystal with a large bandgap

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  33. New cadmium-selenium-oxyhalides: Noncentrosymmetric Cd5(SeO3)4Cl2(H2O) and centrosymmetric Cd2(SeO3)F2, Cd2(SeO3)(OH)Br

    Journal of Solid State Chemistry · 2019-02-27

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  34. New Members of SHG Active Dugganite Family, A3BC3D2O14 (A = Ba, Pb; B = Te, Sb; C = Al, Ga, Fe, Zn; D = Si, Ge, P, V): Synthesis, Structure, and Materials Properties

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  35. Recent progress in selenite and tellurite based SHG materials

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  36. Mixed-valent selenium compounds: Noncentrosymmetric Cd3(SeO3)2(SeO4) and Hg3(SeO3)2(SeO4) and centrosymmetric Pb2(SeO3) (SeO4)

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  37. BiGa(SeO3)3: A Phase Matchable SHG Material Achieved by Cation Substitution

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  38. Role of fluorine on the structure and second-harmonic-generation property of inorganic selenites and tellurites

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  39. Hg 2 (SeO 3 )(SO 4 ): the first sulfate selenite with large birefringence explored from d 10 transition metal compounds

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  40. Flux synthesis, crystal structure, and characterization of a gamma-vanadate selenite polymorph

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  41. Synthesis, structures and properties of two new selenite optical materials: K 2 Zn 3 Se 4 O 12 and K 4 Zn 3 V 4 Se 2 O 19

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  42. Gladstone–Dale compatibility, electronic polarizability and vibrational spectroscopy of minerals and inorganic compounds with V 4+ O and V 4+ O 2 vanadyl groups

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  43. Syntheses, Crystal Structure, and Second Harmonic Generation Response of Four Novel Noncentrosymmetric Tellurites of Quaternary A/M/Te/O (A = Ba, Sr, Ca; M = V, Nb, Ta) System: BaTa4Te3O17, BaNb4Te3O17, SrTa4Te3O17, and CaV2TeO8

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  44. Polymorphism of Niobium Phosphate Bronze Na4Nb8P4O32Deduced by the Packings of Structural Units: A Centrosymmetric Phase

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  45. Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites

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  46. RE(HSeO3)(SeO3)(H2O)·(H2O) (RE = Y, Gd): Two Rare-Earth Selenite Nonlinear Optical Crystals with Wide Band Gaps

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  47. Hg3(TeO3)2(NO3)2 and Hg3(Te2O5)2(NO3)2: The First Two Hg‐Based Tellurite Nitrate Unit‐Mixed Crystals with Large Optical Anisotropy

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