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RESEARCH PAPER · Chemistry of Materials · 2012

Sulfides with Strong Nonlinear Optical Activity and Thermochromism: ACd4Ga5S12 (A = K, Rb, Cs)

Hua Lin, Liujiang Zhou, Ling Chen

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Sulfides with Strong Nonlinear Optical Activity and Thermochromism: ACd4Ga5S12 (A = K, Rb, Cs)OriginalChemInform Abstract: Sulfides with Strong Nonlinear Optical Activity and Thermochromism: ACd4Ga5S12 (A: K, Rb, Cs).0Synthesis, structure, optical property, and electronic structure of Ba7AgGa5Se159Functionalization Based on the Substitutional Flexibility: Strong Middle IR Nonlinear Optical Selenides AXII4XIII5Se12219Synthesis, Structure and Bonding, Optical Properties of Ba4MTrQ6 (M=Cu, Ag; Tr=Ga, In; Q=S, Se)18Syntheses and characterization of one-dimensional alkali metal antimony(III) thiostannates(IV), A2Sb2Sn3S10 (A=K, Rb, Cs)21Synthesis, structures, optical properties and electronic structures of PbGa2Q4 (Q=S, Se) crystals13[Mn 2 Ga 4 Sn 4 S 20 ] 8− T3 supertetrahedral nanocluster directed by a series of transition metal complexes42An investigation of new infrared nonlinear optical material: BaCdSnSe 4 , and three new related centrosymmetric compounds: Ba 2 SnSe 4 , Mg 2 GeSe 4 , and Ba 2 Ge 2 S 696Second Harmonic Generation Response Optimized at Various Optical Wavelength Ranges through a Series of Cubic Chalcogenides Ba6Ag2.67+4δSn4.33−δS16–xSex41Strongest Second Harmonic Generation in the Polar R3MTQ7 Family: Atomic Distribution Induced Nonlinear Optical Cooperation86Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS2 and Centric Ba8Hg4S5Se752Strong IR NLO Material Ba4MGa4Se10Cl2: Highly Improved Laser Damage Threshold via Dual Ion Substitution Synergy97Syntheses, crystal structures, and NLO properties of the quaternary sulfides RE3Sb0.33SiS7 (RE=La, Pr)24Syntheses, Characterization, and Optical Properties of Centrosymmetric Ba3(BS3)1.5(MS3)0.5 and Noncentrosymmetric Ba3(BQ3)(SbQ3)47Syntheses, crystal structures and physical properties of three new chalcogenides: NaGaGe 3 Se 8 , K 3 Ga 3 Ge 7 S 20 , and K 3 Ga 3 Ge 7 Se 2018AXII4XIII5Te 12 (A = Rb, Cs; X II = Mn, Zn, Cd; X III = Ga, In): quaternary semiconducting tellurides with very low thermal conductivities25BaCdSnS 4 and Ba 3 CdSn 2 S 8 : syntheses, structures, and non-linear optical and photoluminescence properties97Pb 5 Ga 6 ZnS 15 : a noncentrosymmetric framework with chains of T2-supertetrahedra41Structure, optical spectroscopy properties and thermochromism of Sm 3 Fe 5 O 12 garnets44Syntheses, structures, physical and electronic properties of quaternary semiconductors: Cs[RE 9 Cd 4 Se 18 ] (RE = Tb–Tm)14The effect of indium substitution on the structure and NLO properties of Ba 6 Cs 2 Ga 10 Se 20 Cl 446(Cs6Cl)6Cs3[Ga53Se96]: A Unique Long Period-Stacking Structure of Layers Made from Ga2Se6 Dimers via Cis or Trans Intralayer Linking12Syntheses and structural characterization of non-centrosymmetric Na2M2M'S6 (M, M′=Ga, In, Si, Ge, Sn, Zn, Cd) sulfides36Syntheses, structural variants and characterization of AInM′S4 (A=alkali metals, Tl; M′ = Ge, Sn) compounds; facile ion-exchange reactions of layered NaInSnS4 and KInSnS4 compounds40SrMnO3 Thermochromic Behavior Governed by Size-Dependent Structural Distortions15Na 2 Hg 3 M 2 S 8 (M = Si, Ge, and Sn): New Infrared Nonlinear Optical Materials with Strong Second Harmonic Generation Effects and High Laser-Damage Thresholds186Strong Infrared NLO Tellurides with Multifunction: CsXII4In5Te12 (XII = Mn, Zn, Cd)58Na 2 BaMQ 4 (M=Ge, Sn; Q=S, Se): Infrared Nonlinear Optical Materials with Excellent Performances and that Undergo Structural Transformations202Na2BaMQ4 (M=Ge, Sn; Q=S, Se): Infrared Nonlinear Optical Materials with Excellent Performances and that Undergo Structural Transformations44Na 2 ZnGe 2 S 6 : A New Infrared Nonlinear Optical Material with Good Balance between Large Second-Harmonic Generation Response and High Laser Damage Threshold302A High Laser Damage Threshold and a Good Second-Harmonic Generation Response in a New Infrared NLO Material: LiSm3SiS725Quaternary non-centrosymmetric sulfide Y 4 GaSbS 9 : Syntheses, structures, optical properties and theoretical studies16Syntheses, structures, and properties of sulfides constructed by SbS 4 teeter-totter polyhedra: Ba 3 La 4 Ga 2 Sb 2 S 15 and BaLa 3 GaSb 2 S 1013Analysis and prediction of mid-IR nonlinear optical metal sulfides with diamond-like structures336Non‐centrosymmetric Selenides AZn4In5Se12 (A=Rb, Cs): Synthesis, Characterization and Nonlinear Optical Properties47Infrared SHG Materials CsM3Se6 (M = Ga/Sn, In/Sn): Phase Matchability Controlled by Dipole Moment of the Asymmetric Building Unit102Recent achievements on middle and far-infrared second-order nonlinear optical materials433Alkali earth MO x ( x = 6, 7, 9, 12) polyhedra tuned cadmium selenites with different dimensions and diverse SeO 3 2− coordinations1BaCu 2 M IV Q 4 (M IV = Si, Ge, and Sn; Q = S, Se): synthesis, crystal structures, optical performances and theoretical calculations54Centrosymmetric to noncentrosymmetric structural transformation of new quaternary selenides induced by isolated dimeric [Sn 2 Se 4 ] units: from Ba 8 Ga 2 Sn 7 Se 18 to Ba 10 Ga 2 Sn 9 Se 2210Na 2 CdGe 2 Q 6 (Q = S, Se): two metal-mixed chalcogenides with phase-matching abilities and large second-harmonic generation responses78Syntheses and characterization of three new sulfides with large band gaps: acentric Ba 4 Ga 4 SnS 12 , centric Ba 12 Sn 4 S 23 and Ba 7 Sn 3 S 1327Tailored synthesis of nonlinear optical quaternary chalcohalides: Ba 4 Ge 3 S 9 Cl 2 , Ba 4 Si 3 Se 9 Cl 2 and Ba 4 Ge 3 Se 9 Cl 252The first quaternary diamond-like semiconductor with 10-membered LiS 4 rings exhibiting excellent nonlinear optical performances104Two excellent phase-matchable infrared nonlinear optical materials based on 3D diamond-like frameworks: RbGaSn 2 Se 6 and RbInSn 2 Se 639Superpolyhedron-Built Second Harmonic Generation Materials Exhibit Large Mid-Infrared Conversion Efficiencies and High Laser-Induced Damage Thresholds101Mid-Infrared Nonlinear Optical Materials Based on Metal Chalcogenides: Structure–Property Relationship338Li2HgMS4 (M = Si, Ge, Sn): New Quaternary Diamond-Like Semiconductors for Infrared Laser Frequency Conversion64Na2ZnSn2S6: A mixed-metal thiostannate with large second-harmonic generation response activated by penta-tetrahedral [ZnSn4S14]10− clusters10Ba 6 Zn 7 Ga 2 S 16 : A Wide Band Gap Sulfide with Phase-Matchable Infrared NLO Properties111Coexistence of Strong Second Harmonic Generation Response and Wide Band Gap in AZn4Ga5S12 (A=K, Rb, Cs) with 3D Diamond‐like Frameworks65Hg-Based Infrared Nonlinear Optical Material KHg4Ga5Se12 Exhibits Good Phase-Matchability and Exceptional Second Harmonic Generation Response101Experimental and theoretical studies on the NLO properties of two quaternary non-centrosymmetric chalcogenides: BaAg 2 GeS 4 and BaAg 2 SnS 468PbGa2GeS6: An Infrared Nonlinear Optical Material Synthesized by an Intermediate-Temperature Self-Fluxing Method42Four new quaternary chalcogenides A 2 Ba 7 Sn 4 Q 16 (A = Li, Na; Q = S, Se): syntheses, crystal structures determination, nonlinear optical performances investigation26New strategy for designing promising mid-infrared nonlinear optical materials: narrowing the band gap for large nonlinear optical efficiencies and reducing the thermal effect for a high laser-induced damage threshold142Remarkable multimember-ring configurations in a new family of Na 7 M II Sb 5 S 12 (M II = Zn, Cd, Hg) exhibiting various three-dimensional tunnel structures25Structural insights into T 2 -cluster-containing chalcogenides with vertex-, edge- and face-sharing connection modes of NaQ 6 ligands: Na 3 ZnM III Q 4 (M III = In, Ga; Q = S, Se)13Effect of Element Substitution on Structural Transformation and Optical Performances in I2BaMIVQ4 (I = Li, Na, Cu, and Ag; MIV = Si, Ge, and Sn; Q = S and Se)63Six New Members of the A2MIIMIV3Q8 Family and Their Structural Relationship26BaM2As2S6 (M = Cd, Hg): Synthesis, crystal structure, optical and electronic properties16Nonbonding Electrons Driven Strong SHG Effect in Hg2GeSe4: Experimental and Theoretical Investigations61Quaternary sulfide Ba5Cd2Ga2S10 containing chains of edge- and corner-sharing tetrahedra16TlInGe2S6, A Prospective Nonlinear Optical Material: First-Principles DFT Calculations of the Electronic Structure and Optical Properties14Ternary Mixed-Metal Cd4GeS6: Remarkable Nonlinear-Optical Properties Based on a Tetrahedral-Stacking Framework41A review on structure-performance relationship toward the optimal design of infrared nonlinear optical materials with balanced performances253Solid-State Preparation, Structural Characterization, Physical Properties, and Theoretical Studies of a Series of Novel Rare-Earth Metal Chalcogenides with Unprecedented Closed-Cavities15Ba10Zn7M6Q26: Two New Mid-infrared Nonlinear Optical Crystals with T2 Supertetrahedron 3D Framework11Electronic band structure and basic optical constants of TlGaSn2Se6, a promising NLO semiconductor: First-principles calculations under DFT framework12Centric-to-acentric structure transformation induced by a stereochemically active lone pair: a new insight for design of IR nonlinear optical materials90Impressive second harmonic generation response in a novel phase-matchable NLO-active MOF derived from achiral precursors38Investigation on two new antimony-based quaternary chalcogenides: Na 6 CdSb 4 S 10 and Na 3 CdSbSe 41Mn-Based tin sulfide Sr 3 MnSn 2 S 8 with a wide band gap and strong nonlinear optical response30Pb 7 F 12 Cl 2 : a promising infrared nonlinear optical material with high laser damage threshold19Quaternary semiconductor Ba 8 Zn 4 Ga 2 S 15 featuring unique one-dimensional chains and exhibiting desirable yellow emission24Rational design of a new chalcogenide with good infrared nonlinear optical performance: SrZnSnS 452Synthesis and nonlinear optical properties of new gallium thiophosphate Rb 2 Ga 2 P 2 S 913Synthesis, crystal structures and nonlinear optical properties of β-RbCdI 3 ·H 2 O and CsCdI 3 ·H 2 O8Broadening Frontiers of Infrared Nonlinear Optical Materials with π-Conjugated Trigonal-Planar Groups67MnSiP2: A New Mid-IR Ternary Phosphide with Strong SHG Effect and Ultrabroad Transparency Range66Dislocations that Decrease Size Mismatch within the Lattice Leading to Ultrawide Band Gap, Large Second‐Order Susceptibility, and High Nonlinear Optical Performance of AgGaS229Dislocations that Decrease Size Mismatch within the Lattice Leading to Ultrawide Band Gap, Large Second‐Order Susceptibility, and High Nonlinear Optical Performance of AgGaS2186Density Functional Theory Investigations of the Optoelectronic Properties of Li2MnGeS4 and Li2CoSnS41Mixed-Anion Inorganic Compounds: A Favorable Candidate for Infrared Nonlinear Optical Materials140Sn 2 Ga 2 S 5 : A Polar Semiconductor with Exceptional Infrared Nonlinear Optical Properties Originating from the Combined Effect of Mixed Asymmetric Building Motifs81LiBa2MIIIQ4 (MIII = Al, Ga, In; Q = S, Se): A Series of Metal Chalcogenides with a Structural Transition12Rb10Zn4Sn4S17: A Chalcogenide with Large Laser Damage Threshold Improved from the Mn-Based Analogue28Solvothermal Syntheses and Characterizations of Four Quaternary Copper Sulfides BaCu3MS4 (M = In, Ga) and BaCu2MS4 (M = Sn, Ge)27A new family of quaternary thiosilicates SrA 2 SiS 4 (A = Li, Na, Cu) as promising infrared nonlinear optical crystals48Rational design of infrared nonlinear optical chalcogenides by chemical substitution287A new type of novel salt-inclusion chalcogenide with ultralow thermal conductivity14Li 2 CdSiS 4 , a promising IR NLO material with a balanced E g and SHG response originating from the effect of Cd with d 10 configuration36Mixed-metal thiophosphate CuCd 3 PS 6 : an infrared nonlinear optical material activated by its three-in-one tetrahedra-stacking architecture33Reversible thermochromic property of Cr, Mn, Fe, Co-doped Ca 14 Zn 6 Ga 10 O 3520Sr 4 Pb 1.5 Sb 5 O 5 Se 8 : a new mid-infrared nonlinear optical material with a moderate SHG response22Infrared Nonlinear Optical Polymorphs α- and β-SrCu 2 SnS 4 Exhibiting Large Second Harmonic Generation Responses with Requisite Phase-Matching Behavior44One-Dimensional Chains in Pentanary Chalcogenides A2Ba3Cu2Sb2S10 (A = K, Rb, Cs) Displaying a Photocurrent Response44One-Dimensional Double Chains in Sodium-Based Quaternary Chalcogenides Displaying Intriguing Red Emission and Large Optical Anisotropy17Molecular Construction from AgGaS 2 to CuZnPS 4 : Defect-Induced Second Harmonic Generation Enhancement and Cosubstitution-Driven Band Gap Enlargement97Optimized Metal Chalcogenides for Boosting Water Splitting292HgCuPS4: An Exceptional Infrared Nonlinear Optical Material with Defect Diamond-like Structure146Crystal chemistry, second-order nonlinear optical, and magnetic properties of Eu8Sn4Se2014Functional Chalcogenide Na2HgSn2Se6 and K2MnGe2Se6 Exhibiting Flexible Chain Structure and Intriguing Birefringence Tunability16Inherent laws between tetrahedral arrangement pattern and optical performance in tetrahedron-based mid-infrared nonlinear optical materials131Salt-Inclusion Chalcogenide [Ba4Cl2][ZnGa4S10]: Rational Design of an IR Nonlinear Optical Material with Superior Comprehensive Performance Derived from AgGaS2134Ultralow thermal conductivity in the quaternary semiconducting chalcogenide Cs 4 [Ho 26 Cd 7 Se 48 ] with an unprecedented closed cavity architecture7Intriguing Dimensional Transition Inducing Variable Birefringence in K2Na2Sn3S8 and Rb3NaSn3Se828A 3 Mn 2 Sb 3 S 8 (A = K and Rb): a new type of multifunctional infrared nonlinear optical material based on unique three-dimensional open frameworks53Aliovalent-cation-substitution-induced structure transformation: a new path toward high-performance IR nonlinear optical materials47New nonlinear optical-active AAgGa 6 S 10 (A = K, Rb, Cs) featuring {[AgGa 6 S 10 ] − } ∞ framework and high laser damage threshold42Na 6 MQ 4 (M=Zn, Cd; Q=S, Se): Promising New Ternary Infrared Nonlinear Optical Materials24Second-order nonlinear optical and photoelectric properties of Zn4B6O12S20Inorganic Chalcogenides: From Zero‐Dimensional Clusters to Three‐Dimensional Frameworks5AZn4Ga5Se12 (A = K, Rb, or Cs): Infrared Nonlinear Optical Materials with Simultaneous Large Second Harmonic Generation Responses and High Laser-Induced Damage Thresholds34Solvothermal synthesis and properties of three antimony chalcogenides containing transition metal zinc13Stepwise Li Substitution Induced Structure Evolution and Improved Nonlinear Optical Performance for Diamond-like Sulfides28Highly Distorted [HgS 4 ] Motif-Driven Structural Symmetry Degradation and Strengthened Second-Harmonic Generation Response in the Defect Diamond-Like Chalcogenide Hg 3 P 2 S 847Triclinic Layered A2ZnSi3S8 (A = Rb and Cs) with Large Optical Anisotropy and Systematic Research on the Inherent Structure–Performance Relationship in the A2MIIBMIV3Q8 Family11Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials184CsCu 3 SbS 4 : rational design of a two-dimensional layered material with giant birefringence derived from Cu 3 SbS 442Cs 3 CuAs 4 Q 8 (Q = S, Se): unique two-dimensional layered inorganic thioarsenates with the lowest Cu-to-As ratio and remarkable photocurrent responses17Phase Matchability Transformation in the Infrared Nonlinear Optical Materials with Diamond‐Like Frameworks63Infrared nonlinear optical sulfide CsCd 4 In 5 S 12 exhibiting large second harmonic generation response16Interesting dimensional transition through changing cations as the trigger in multinary thioarsenates displaying variable photocurrent response and optical anisotropy22KAg3Ga8S14: An Mid- and Far-infrared Nonlinear Optical Material Exhibiting High Laser-induced Damage Threshold※3Wide band gap thiophosphates ASrPS 4 (A = Li, Na, K, Rb, Cs): cation size effect induced successive structural transformation13Quaternary Noncentrosymmetric Rare-Earth Sulfides Ba4RE2Cd3S10 (RE = Sm, Gd, or Tb): A Joint Experimental and Theoretical Investigation17Optimizing the Nonlinear Optical Performance of an A-N-M-Q (A: Alkali Metal; N: d10 Metal; M: Main Group Metal; Q: Chalcogen) System44From Cc to P 6 3 mc : Structural Variation in La 3 S 2 Cl 2 [SbS 3 ] and La 3 OSCl 2 [SbS 3 ] Induced by the Isovalent Anion Substitution22A deep ultraviolet transparent birefringent monofluorophosphate: Cd2.5(NH4)2(PO3F)3Cl ⋅ 2H2O4New quaternary sulfide LiGaSiS4: Synthesis, structure and optical properties0A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications115Ba 3 HgGa 2 S 7 : A Zero-Dimensional Quaternary Sulfide Featuring a Unique [Hg 2 Ga 4 S 14 ] 12– String and Exhibiting a High Photocurrent Response27Solvothermal syntheses, crystal structures, and photocurrent responses of quaternary sulfides RbAgZnS2 and Cs2Ag2Zn2S45d6versus d10, Which Is Better for Second Harmonic Generation Susceptibility? A Case Study of K2TGe3Ch8 (T = Fe, Cd; Ch = S, Se)18A novel bifunctional thioarsenate based on unprecedented molecular [Cd 4 As 8 Se 16 (Se 2 ) 2 ] 8− cluster anions11Ba4cd2ge2te9: A Promising Infrared Functional Crystal with Large Birefringent And Photoluminescent Properties0Heteroanion-introduction-driven birefringence enhancement in oxychalcogenide Ba 3 M II Ge 3 O 2 S 8 (M II = Mn, Cd)19Open honeycomb frameworks of sulphides AHg 4 Ga 5 S 12 (A = Rb, Cs) exhibiting infrared nonlinear optical properties12Stereochemically active lone-pair-driven giant enhancement of birefringence from three-dimensional CsZn 4 Ga 5 Se 12 to two-dimensional CsZnAsSe 319Isomeric Cd(NH4)2(PO3F)2·2H2O: Solution concentration-driven elimination of antiparallel dipole-dipole interaction generating an SHG β phase12Salt-inclusion chalcogenides: Double functional moieties design strategy toward excellent nonlinear optical materials12Recent progress in the design of IR nonlinear optical materials by partial chemical substitution: Structural evolution and performance optimization133HgB2S4: A d10 Metal Thioborate with Giant Birefringence and Wide Band Gap31[Ba4(S2)][ZnGa4S10]: Design of an Unprecedented Infrared Nonlinear Salt‐Inclusion Chalcogenide with Disulfide‐Bonds36KHg4Ga3S9: A Hg-Based Sulfide with Nonlinear-Optical Activity in the A–MII–MIII–Q (A = Alkali Metal; MII = d10 Metal; MIII = Ga, In; Q = S, Se) System17ACd 4 Ga 5 Te 12 (A = K, Rb, Cs): Tellurides with a Strong Nonlinear Optical Response and Purple Emission24Breaking Through the Trade‐Off Between Wide Band Gap and Large SHG Coefficient in Mercury‐Based Chalcogenides for IR Nonlinear Optical Application49Regulating the key performance parameters for Hg-based IR NLO chalcogenides via bandgap engineering strategy26Ga-based IR nonlinear optical materials: Synthesis, structures, and properties65

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  1. ChemInform Abstract: Sulfides with Strong Nonlinear Optical Activity and Thermochromism: ACd4Ga5S12 (A: K, Rb, Cs).

    ChemInform · 2012-10-18

    Hua Lin, Liujiang Zhou, Ling Chen

    Read original paper ↗ ·

  2. Synthesis, structure, optical property, and electronic structure of Ba7AgGa5Se15

    Journal of Alloys and Compounds · 2013-03-14

    Wenlong Yin, Ran He, Kai Feng, Wenyu Hao, Jiyong Yao, Yicheng Wu

    Read original paper ↗ ·

  3. Functionalization Based on the Substitutional Flexibility: Strong Middle IR Nonlinear Optical Selenides AXII4XIII5Se12

    Journal of the American Chemical Society · 2013-07-31

    Hua Lin, Ling Chen, Liujiang Zhou, Li‐Ming Wu

    Read original paper ↗ ·

  4. Synthesis, Structure and Bonding, Optical Properties of Ba4MTrQ6 (M=Cu, Ag; Tr=Ga, In; Q=S, Se)

    Chemistry - An Asian Journal · 2014-02-12

    Xiao‐Wu Lei, Min Yang, Sheng‐Qing Xia, Xiao‐Cun Liu, Mingyan Pan, Xin Li, Xu‐Tang Tao

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  5. Syntheses and characterization of one-dimensional alkali metal antimony(III) thiostannates(IV), A2Sb2Sn3S10 (A=K, Rb, Cs)

    Journal of Solid State Chemistry · 2014-10-24

    Jinu P. Yohannan, Kanamaluru Vidyasagar

    Read original paper ↗ ·

  6. Synthesis, structures, optical properties and electronic structures of PbGa2Q4 (Q=S, Se) crystals

    Journal of Molecular Structure · 2014-11-17

    Kui Wu, Shilie Pan, Hongping Wu, Zhihua Yang

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  7. [Mn 2 Ga 4 Sn 4 S 20 ] 8− T3 supertetrahedral nanocluster directed by a series of transition metal complexes

    Dalton Transactions · 2014-12-03

    Cheng‐Yang Yue, Xiao‐Wu Lei, Lijuan Feng, Chen Wang, Ya-Ping Gong, Xinying Liu

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  8. An investigation of new infrared nonlinear optical material: BaCdSnSe 4 , and three new related centrosymmetric compounds: Ba 2 SnSe 4 , Mg 2 GeSe 4 , and Ba 2 Ge 2 S 6

    Dalton Transactions · 2015-01-01

    Kui Wu, Xin Su, Zhihua Yang, Shilie Pan

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  9. Second Harmonic Generation Response Optimized at Various Optical Wavelength Ranges through a Series of Cubic Chalcogenides Ba6Ag2.67+4δSn4.33−δS16–xSex

    Chemistry of Materials · 2015-01-30

    Wei-Han Lai, Alyssa S. Haynes, Laszlo Frazer, Yu-Ming Chang, Te-Kun Liu, Jyun-Fan Lin, I. C. Liang, Hwo‐Shuenn Sheu, John B. Ketterson, Mercouri G. Kanatzidis, Kuei‐Fang Hsu

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  10. Strongest Second Harmonic Generation in the Polar R3MTQ7 Family: Atomic Distribution Induced Nonlinear Optical Cooperation

    Chemistry of Materials · 2015-02-16

    Yong‐Fang Shi, Yukun Chen, Mei‐Chun Chen, Li‐Ming Wu, Hua Lin, Liujiang Zhou, Ling Chen

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  11. Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS2 and Centric Ba8Hg4S5Se7

    Inorganic Chemistry · 2015-03-05

    Kui Wu, Xin Su, Shilie Pan, Zhihua Yang

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  12. Strong IR NLO Material Ba4MGa4Se10Cl2: Highly Improved Laser Damage Threshold via Dual Ion Substitution Synergy

    Advanced Optical Materials · 2015-03-18

    Yan‐Yan Li, Pengfei Liu, Lei Hu, Ling Chen, Hua Lin, Liujiang Zhou, Li‐Ming Wu

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  13. Syntheses, crystal structures, and NLO properties of the quaternary sulfides RE3Sb0.33SiS7 (RE=La, Pr)

    Journal of Solid State Chemistry · 2015-04-02

    Hua‐Jun Zhao

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  14. Syntheses, Characterization, and Optical Properties of Centrosymmetric Ba3(BS3)1.5(MS3)0.5 and Noncentrosymmetric Ba3(BQ3)(SbQ3)

    Inorganic Chemistry · 2015-04-30

    Yanyan Li, Bingxuan Li, Ge Zhang, Liujiang Zhou, Hua Lin, Jinni Shen, Chengyi Zhang, Ling Chen, Li‐Ming Wu

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  15. Syntheses, crystal structures and physical properties of three new chalcogenides: NaGaGe 3 Se 8 , K 3 Ga 3 Ge 7 S 20 , and K 3 Ga 3 Ge 7 Se 20

    Dalton Transactions · 2015-11-09

    Xiaoshuang Li, Chao Li, Pifu Gong, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  16. AXII4XIII5Te 12 (A = Rb, Cs; X II = Mn, Zn, Cd; X III = Ga, In): quaternary semiconducting tellurides with very low thermal conductivities

    Dalton Transactions · 2016-01-01

    Hua Lin, Hong Chen, Yujun Zheng, Ju‐Song Yu, Li‐Ming Wu

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  17. BaCdSnS 4 and Ba 3 CdSn 2 S 8 : syntheses, structures, and non-linear optical and photoluminescence properties

    Dalton Transactions · 2016-01-01

    Ni Zhen, Kui Wu, Ying Wang, Qiang Li, Wenhui Gao, Dianwei Hou, Zhihua Yang, Huaidong Jiang, Yongjun Dong, Shilie Pan

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  18. Pb 5 Ga 6 ZnS 15 : a noncentrosymmetric framework with chains of T2-supertetrahedra

    Dalton Transactions · 2016-01-01

    Ruihuan Duan, Ju‐Song Yu, Hua Lin, Yujun Zheng, Hua‐Jun Zhao, Shangxiong Huangfu, Muhammad Ali Khan, Ling Chen, Li‐Ming Wu

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  19. Structure, optical spectroscopy properties and thermochromism of Sm 3 Fe 5 O 12 garnets

    Journal of Materials Chemistry C · 2016-01-01

    Huanhuan Liu, Long Yuan, Shan Wang, Hairui Fang, Yuan Zhang, Changmin Hou, Shouhua Feng

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  20. Syntheses, structures, physical and electronic properties of quaternary semiconductors: Cs[RE 9 Cd 4 Se 18 ] (RE = Tb–Tm)

    Dalton Transactions · 2016-01-01

    Hua Lin, Hong Chen, Pengfei Liu, Ju‐Song Yu, Yujun Zheng, Khan Muhammad Ali, Ling Chen, Li‐Ming Wu

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  21. The effect of indium substitution on the structure and NLO properties of Ba 6 Cs 2 Ga 10 Se 20 Cl 4

    Inorganic Chemistry Frontiers · 2016-01-01

    Yanyan Li, Pengfei Liu, Hua Lin, Meitian Wang, Ling Chen

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  22. (Cs6Cl)6Cs3[Ga53Se96]: A Unique Long Period-Stacking Structure of Layers Made from Ga2Se6 Dimers via Cis or Trans Intralayer Linking

    Inorganic Chemistry · 2016-01-21

    Hua Lin, Hong Chen, Zixiong Lin, Hua‐Jun Zhao, Pengfei Liu, Ju‐Song Yu, Ling Chen

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  23. Syntheses and structural characterization of non-centrosymmetric Na2M2M'S6 (M, M′=Ga, In, Si, Ge, Sn, Zn, Cd) sulfides

    Journal of Solid State Chemistry · 2016-03-14

    Jinu P. Yohannan, Kanamaluru Vidyasagar

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  24. Syntheses, structural variants and characterization of AInM′S4 (A=alkali metals, Tl; M′ = Ge, Sn) compounds; facile ion-exchange reactions of layered NaInSnS4 and KInSnS4 compounds

    Journal of Solid State Chemistry · 2016-03-30

    Jinu P. Yohannan, Kanamaluru Vidyasagar

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  25. SrMnO3 Thermochromic Behavior Governed by Size-Dependent Structural Distortions

    Inorganic Chemistry · 2016-04-01

    Irma N. González-Jiménez, Esteban Climent‐Pascual, Almudena Torres‐Pardo, María Hernando, A.E. Sánchez, Francisco Fernández-Martínez, María Teresa Fernández-Díaz, José María González-Calbet, Alicia de Andrés, Áurea Varela, M. Parras

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  26. Na 2 Hg 3 M 2 S 8 (M = Si, Ge, and Sn): New Infrared Nonlinear Optical Materials with Strong Second Harmonic Generation Effects and High Laser-Damage Thresholds

    Chemistry of Materials · 2016-04-05

    Kui Wu, Zhihua Yang, Shilie Pan

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  27. Strong Infrared NLO Tellurides with Multifunction: CsXII4In5Te12 (XII = Mn, Zn, Cd)

    Inorganic Chemistry · 2016-04-12

    Hua Lin, Yi Liu, Liujiang Zhou, Hua‐Jun Zhao, Ling Chen

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  28. Na 2 BaMQ 4 (M=Ge, Sn; Q=S, Se): Infrared Nonlinear Optical Materials with Excellent Performances and that Undergo Structural Transformations

    Angewandte Chemie International Edition · 2016-04-21

    Kui Wu, Zhihua Yang, Shilie Pan

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  29. Na2BaMQ4 (M=Ge, Sn; Q=S, Se): Infrared Nonlinear Optical Materials with Excellent Performances and that Undergo Structural Transformations

    Angewandte Chemie · 2016-04-21

    Kui Wu, Zhihua Yang, Shilie Pan

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  30. Na 2 ZnGe 2 S 6 : A New Infrared Nonlinear Optical Material with Good Balance between Large Second-Harmonic Generation Response and High Laser Damage Threshold

    Journal of the American Chemical Society · 2016-05-19

    Guangmao Li, Kui Wu, Qiong Liu, Zhihua Yang, Shilie Pan

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  31. A High Laser Damage Threshold and a Good Second-Harmonic Generation Response in a New Infrared NLO Material: LiSm3SiS7

    Crystals · 2016-09-23

    Ni Zhen, Leyan Nian, Guangmao Li, Kui Wu, Shilie Pan

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  32. Quaternary non-centrosymmetric sulfide Y 4 GaSbS 9 : Syntheses, structures, optical properties and theoretical studies

    Journal of Solid State Chemistry · 2016-10-15

    Yue Wang, Xiaochuan Zou, Xia Feng, Yong‐Fang Shi, Li‐Ming Wu

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  33. Syntheses, structures, and properties of sulfides constructed by SbS 4 teeter-totter polyhedra: Ba 3 La 4 Ga 2 Sb 2 S 15 and BaLa 3 GaSb 2 S 10

    Inorganic Chemistry Frontiers · 2016-11-15

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  34. Analysis and prediction of mid-IR nonlinear optical metal sulfides with diamond-like structures

    Coordination Chemistry Reviews · 2016-11-22

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  35. Non‐centrosymmetric Selenides AZn4In5Se12 (A=Rb, Cs): Synthesis, Characterization and Nonlinear Optical Properties

    Chemistry - An Asian Journal · 2016-12-01

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  36. Infrared SHG Materials CsM3Se6 (M = Ga/Sn, In/Sn): Phase Matchability Controlled by Dipole Moment of the Asymmetric Building Unit

    Chemistry of Materials · 2016-12-26

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  37. Recent achievements on middle and far-infrared second-order nonlinear optical materials

    Coordination Chemistry Reviews · 2016-12-27

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  38. Alkali earth MO x ( x = 6, 7, 9, 12) polyhedra tuned cadmium selenites with different dimensions and diverse SeO 3 2− coordinations

    CrystEngComm · 2017-01-01

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  39. BaCu 2 M IV Q 4 (M IV = Si, Ge, and Sn; Q = S, Se): synthesis, crystal structures, optical performances and theoretical calculations

    RSC Advances · 2017-01-01

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  40. Centrosymmetric to noncentrosymmetric structural transformation of new quaternary selenides induced by isolated dimeric [Sn 2 Se 4 ] units: from Ba 8 Ga 2 Sn 7 Se 18 to Ba 10 Ga 2 Sn 9 Se 22

    RSC Advances · 2017-01-01

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  41. Na 2 CdGe 2 Q 6 (Q = S, Se): two metal-mixed chalcogenides with phase-matching abilities and large second-harmonic generation responses

    Dalton Transactions · 2017-01-01

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  42. Syntheses and characterization of three new sulfides with large band gaps: acentric Ba 4 Ga 4 SnS 12 , centric Ba 12 Sn 4 S 23 and Ba 7 Sn 3 S 13

    Dalton Transactions · 2017-01-01

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  43. Tailored synthesis of nonlinear optical quaternary chalcohalides: Ba 4 Ge 3 S 9 Cl 2 , Ba 4 Si 3 Se 9 Cl 2 and Ba 4 Ge 3 Se 9 Cl 2

    Dalton Transactions · 2017-01-01

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  44. The first quaternary diamond-like semiconductor with 10-membered LiS 4 rings exhibiting excellent nonlinear optical performances

    Chemical Communications · 2017-01-01

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  45. Two excellent phase-matchable infrared nonlinear optical materials based on 3D diamond-like frameworks: RbGaSn 2 Se 6 and RbInSn 2 Se 6

    Dalton Transactions · 2017-01-01

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  46. Superpolyhedron-Built Second Harmonic Generation Materials Exhibit Large Mid-Infrared Conversion Efficiencies and High Laser-Induced Damage Thresholds

    Chemistry of Materials · 2017-01-30

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  47. Mid-Infrared Nonlinear Optical Materials Based on Metal Chalcogenides: Structure–Property Relationship

    Crystal Growth & Design · 2017-03-15

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  48. Li2HgMS4 (M = Si, Ge, Sn): New Quaternary Diamond-Like Semiconductors for Infrared Laser Frequency Conversion

    Crystals · 2017-04-12

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  49. Na2ZnSn2S6: A mixed-metal thiostannate with large second-harmonic generation response activated by penta-tetrahedral [ZnSn4S14]10− clusters

    Science China Technological Sciences · 2017-05-12

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  50. Ba 6 Zn 7 Ga 2 S 16 : A Wide Band Gap Sulfide with Phase-Matchable Infrared NLO Properties

    Chemistry of Materials · 2017-05-31

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