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RESEARCH PAPER · Journal of Organometallic Chemistry · 2011

Synthesis, crystal structures and thermal behaviour of organic–inorganic hybrids incorporating a chiral diamine

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Synthesis, crystal structures and thermal behaviour of organic–inorganic hybrids incorporating a chiral diamineOriginalNoncentrosymmetry in new 2-methylpiperazinediium hexaaquazinc(II) bis(sulfate)42-Dihydromethylpiperazinediium-M II (M II = Cu II , Fe II , Co II , Zn II ) double sulfates and their catalytic activity in diastereoselective nitroaldol (Henry) reaction49The structural transformation of monoclinic [(R)-C5H14N2][Cu(SO4)2(H2O)4]·2H2O into orthorhombic [(R)-C5H14N2]2[Cu(H2O)6](SO4)3: crystal structures and thermal behavior3A new organically templated magnesium sulfate: structure, spectroscopic analysis, and thermal behaviour7Crystal architecture and thermal decomposition of two new organically templated cadmium sulfates3Ferroelectricity based on coordination compound: Transition metal Co(II) sulfates templated by homochiral 2-methylpiperazine (C5H14N2)[Co(H2O)6](SO4)29Structural features, thermal behavior and biological activities of two new organically templated (CoII, NiII) sulfates12Synthesis, structural characterization, IR- and Raman spectroscopy, magnetic properties of new organically templated metal sulfates with 4-aminopyridinium20Structural characterization and physicochemical features of a new arsenate salt templated by mono and di-protonated 4-aminopyridine cations: (C 5 H 7 N 2 )(C 5 H 8 N 2 )[AsO 4 ]·H 2 O12Phase Transition Originating from Disorder–Order Transformation Coupled with Reorientation in the Organic–Inorganic Hybrid Compound (C4H14N2)[Cd2(H2O)6(SO4)3]7Synthesis, crystal structure and thermal study of the hybrid nickel sulfate: C6N2H16[Ni(H2O)6(SO4)2].2H2O0Crystal packing, high-temperature phase transition, second-order nonlinear optical and biological activities in a hybrid material: [(S) C7H16N2][CuBr4]12Synthesis, Characterization, and Optical Properties of Organic–Inorganic Hybrid Layered Materials: A Solvent-Free Ligand-Controlled Dimensionality Approach Based on Metal Sulfates and Aromatic Diamines21Synthesis, characterization and temperature-triggered phase transition of organic-inorganic hybrid compound: (C6H18N2)(HSO4)211The synthesis, structure, thermal stability and optical properties of organic-inorganic hybrid [(4-ethoxyanilinum)(18-crown-6)][BF4] crystals8Design, synthesis and physico-chemical studies of a Co(II)/Co(III) mixed-valence complex: An experimental and DFT approach25Exploration of new chiral hybrid semiconducting palladium halide complexes: [(R)/(S)-2-Methylpiperazinediium]PdCl49New Cobalt and Nickel Sulfates Templated with N,N'-Dimethyletethylenediammonium Cation: Synthesis, Crystal Structures, and Topological Features1Double sulfates with 1-methylpiperazinediium and divalent cations: Synthesis, structures, spectroscopic characterization, thermal stability, and topological features of (C5H14N2)[M(H2O)6](SO4)2∙H2O (M = Mg, Mn, Fe, Co, Ni, Zn, and Cd) and (C5H14N2)(SO4)∙H2O2

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  1. Noncentrosymmetry in new 2-methylpiperazinediium hexaaquazinc(II) bis(sulfate)

    Journal of Coordination Chemistry · 2012-03-13

    Houcine Naı̈li

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  2. 2-Dihydromethylpiperazinediium-M II (M II = Cu II , Fe II , Co II , Zn II ) double sulfates and their catalytic activity in diastereoselective nitroaldol (Henry) reaction

    Dalton Transactions · 2012-09-19

    Houcine Naı̈li, Fadhel Hajlaoui, Tahar Mhiri, Tatiana C. O. Mac Leod, Maximilian N. Kopylovich, Kamran T. Mahmudov⧫, Armando J. L. Pombeiro

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  3. The structural transformation of monoclinic [(R)-C5H14N2][Cu(SO4)2(H2O)4]·2H2O into orthorhombic [(R)-C5H14N2]2[Cu(H2O)6](SO4)3: crystal structures and thermal behavior

    Phase Transitions · 2013-05-23

    Salem Saïd, Noureddine Mhadhbi, Fadhel Hajlaoui, S. Yahyaoui, Alexander J. Norquist, Tahar Mhiri, Thierry Bataille, Houcine Naı̈li

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  4. A new organically templated magnesium sulfate: structure, spectroscopic analysis, and thermal behaviour

    Chemical Papers · 2013-06-21

    Dhouha Ben Hassan, Walid Rekik, Houcine Naı̈li, Tahar Mhiri

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  5. Crystal architecture and thermal decomposition of two new organically templated cadmium sulfates

    Journal of Structural Chemistry · 2013-11-01

    Raja Jlassi, Walid Rekik, Houcine Naı̈li, Tahar Mhiri, Thierry Bataille

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  6. Ferroelectricity based on coordination compound: Transition metal Co(II) sulfates templated by homochiral 2-methylpiperazine (C5H14N2)[Co(H2O)6](SO4)2

    Chinese Chemical Letters · 2014-06-01

    Li-Zhuang Chen, Deng‐Deng Huang, Qi-Jian Pan, Fang‐Ming Wang

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  7. Structural features, thermal behavior and biological activities of two new organically templated (CoII, NiII) sulfates

    Journal of Organometallic Chemistry · 2016-02-21

    Salem Saïd, Rihab Ben Abdallah Kolsi, Houcine Naı̈li

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  8. Synthesis, structural characterization, IR- and Raman spectroscopy, magnetic properties of new organically templated metal sulfates with 4-aminopyridinium

    Journal of Molecular Structure · 2016-05-11

    Tamara J. Bednarchuk, Vasyl Kinzhybalo, Oleksandr Bednarchuk, A. Pietraszko

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  9. Structural characterization and physicochemical features of a new arsenate salt templated by mono and di-protonated 4-aminopyridine cations: (C 5 H 7 N 2 )(C 5 H 8 N 2 )[AsO 4 ]·H 2 O

    Physica E Low-dimensional Systems and Nanostructures · 2016-11-28

    Noureddine Mhadhbi, Houcine Naı̈li, Khaled Jarraya

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  10. Phase Transition Originating from Disorder–Order Transformation Coupled with Reorientation in the Organic–Inorganic Hybrid Compound (C4H14N2)[Cd2(H2O)6(SO4)3]

    European Journal of Inorganic Chemistry · 2016-12-09

    Rong Mu, Chun‐Hong Chen, Li Zhang, Dianzeng Jia, Guan‐Cheng Xu

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  11. Synthesis, crystal structure and thermal study of the hybrid nickel sulfate: C6N2H16[Ni(H2O)6(SO4)2].2H2O

    Journal of Physics Conference Series · 2018-03-01

    F A I Ngopoh, N Hamdi, Souad Chaouch, Mohammed Lachkar, I. da Silva, Brahim El Bali

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  12. Crystal packing, high-temperature phase transition, second-order nonlinear optical and biological activities in a hybrid material: [(S) C7H16N2][CuBr4]

    Journal of Molecular Structure · 2018-05-05

    Ines Ben Hadj Sadok, Fadhel Hajlaoui, Hanen Ben Ayed, Nasreddine Ennaceur, Monçef Nasri, Nathalie Audebrand, Thierry Bataille, Nabil Zouari

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  13. Synthesis, Characterization, and Optical Properties of Organic–Inorganic Hybrid Layered Materials: A Solvent-Free Ligand-Controlled Dimensionality Approach Based on Metal Sulfates and Aromatic Diamines

    Crystal Growth & Design · 2018-06-26

    A. González Guillén, Marcin Oszajca, Katarzyna Luberda‐Durnaś, Marlena Gryl, Stanisław Bartkiewicz, Andrzej Miniewicz, Wiesław Łasocha

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  14. Synthesis, characterization and temperature-triggered phase transition of organic-inorganic hybrid compound: (C6H18N2)(HSO4)2

    Journal of Molecular Structure · 2018-08-20

    Yingying Zhang, Chunhong Chen, Guan‐Cheng Xu, Wen‐Bo Xin

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  15. The synthesis, structure, thermal stability and optical properties of organic-inorganic hybrid [(4-ethoxyanilinum)(18-crown-6)][BF4] crystals

    Journal of Molecular Structure · 2020-06-08

    Chuanying Shen, Fan Wei Meng, Tiantian Kang, Duan-Liang Wang, Jinfeng Zhang, Na-Na Zhang, Jiyang Wang

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  16. Design, synthesis and physico-chemical studies of a Co(II)/Co(III) mixed-valence complex: An experimental and DFT approach

    Journal of Molecular Structure · 2021-04-07

    Intissar Hamdi, Noureddine Mhadhbi, Noureddine Issaoui, Andreas Roodt, Mark M. Turnbull, Houcine Naı̈li

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  17. Exploration of new chiral hybrid semiconducting palladium halide complexes: [(R)/(S)-2-Methylpiperazinediium]PdCl4

    Materials Research Bulletin · 2023-03-26

    Bochra Ben Salah, Fadhel Hajlaoui, Karim Karoui, Nathalie Audebrand, Thierry Roisnel, Stéphane Freslon, Nabil Zouari, F. Jomni

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  18. New Cobalt and Nickel Sulfates Templated with N,N'-Dimethyletethylenediammonium Cation: Synthesis, Crystal Structures, and Topological Features

    Crystallography Reports · 2025-06-01

    Dmitri O. Charkin, V. E. Kireev, Н. В. Сомов, Dmitri N. Dmitriev, A. M. Banaru, Sergey M. Aksenov

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  19. Double sulfates with 1-methylpiperazinediium and divalent cations: Synthesis, structures, spectroscopic characterization, thermal stability, and topological features of (C5H14N2)[M(H2O)6](SO4)2∙H2O (M = Mg, Mn, Fe, Co, Ni, Zn, and Cd) and (C5H14N2)(SO4)∙H2O

    Polyhedron · 2025-09-05

    Dmitri O. Charkin, Alevtina N. Gosteva, Vadim A. Kireev, A. M. Banaru, Dmitri N. Dmitriev, Dina V. Deyneko, Nikita Sergeyevich Tsvetov, Ivan Gundarovich Tananaev, Sergey M. Aksenov

    Read original paper ↗ ·