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RESEARCH PAPER · Journal of the American Chemical Society · 2010

Soluble Semiconductors AAsSe2 (A = Li, Na) with a Direct-Band-Gap and Strong Second Harmonic Generation: A Combined Experimental and Theoretical Study

Tarun K. Bera, Joon Ik Jang, Jung-Hwan Song, Christos D. Malliakas, Arthur J Freeman, John B. Ketterson, Mercouri G. Kanatzidis

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Soluble Semiconductors AAsSe2 (A = Li, Na) with a Direct-Band-Gap and Strong Second Harmonic Generation: A Combined Experimental and Theoretical StudyOriginalChemInform Abstract: Soluble Semiconductors AAsSe2 (A: Li, Na) with a Direct‐Band‐Gap and Strong Second Harmonic Generation: A Combined Experimental and Theoretical Study.0Arsenic-Containing Chalcophosphate Molecular Anions17Hydrazine-hydrothermal method to synthesize three-dimensional chalcogenide framework for photocatalytic hydrogen generation132(Ag2TeS3)2·A2S6 (A = Rb, Cs): Layers of Silver Thiotellurite Intergrown with Alkali-Metal Polysulfides28Novel Polyselenidoarsenate and Selenidoarsenate: Solvothermal Synthesis and Characterization of [Co(phen)3][As2Se2(μ-Se3)(μ-Se5)] and [Co(phen)3]2[As8Se14]30In-Phase Alignments of Asymmetric Building Units in Ln 4 GaSbS 9 (Ln = Pr, Nd, Sm, Gd−Ho) and Their Strong Nonlinear Optical Responses in Middle IR212Synthesis, Characterization, and Structure–Property Relationships in Two New Polar Oxides: Zn2(MoO4)(SeO3) and Zn2(MoO4)(TeO3)80Stabilization of Noncondensed (AsIIIS3)3– Anions by Coordinating to [MnII(phen)]2+ Complex Cations: a Mixed-Valent Thioarsenate (III, V) {[Mn(phen)]3(AsVS4)(AsIIIS3)}n·nH2O Showing the Coexistence of Antiferromagnetic Order, Photoluminescence, and Nonlinear Optical Properties60Thallium Chalcogenide-Based Wide-Band-Gap Semiconductors: TlGaSe2 for Radiation Detectors97Solvothermal Synthesis and Characterization of Polyselenidoarsenate Salts of Transition Metal Complex Cations37BiO(IO3): A New Polar Iodate that Exhibits an Aurivillius-Type (Bi2O2)2+ Layer and a Large SHG Response503“A” Cation Polarity Control in ACuTe2O7 (A = Sr2+, Ba2+, or Pb2+)52Synthesis, crystal structures, and optical properties of NaCdPnS3 (Pn=As, Sb)49Tl2Hg3Q4 (Q = S, Se, and Te): High-Density, Wide-Band-Gap Semiconductors54Strongly Nonlinear Optical Chalcogenide Thin Films of APSe6 (A=K, Rb) from Spin‐Coating51Strongly Nonlinear Optical Chalcogenide Thin Films of APSe6 (A=K, Rb) from Spin‐Coating8New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)50Structural Diversity, Optical and Magnetic Properties of a Series of Manganese Thioarsenates with 1,10-Phenanthroline or 2,2′-Bipyridine Ligands: Using Monodentate Methylamine as an Alkalinity Regulator47LiGaGe2Se6: A New IR Nonlinear Optical Material with Low Melting Point110Large Crystal Growth and New Crystal Exploration of Mid-Infrared Second-Order Nonlinear Optical Materials56pH-induced solvothermal synthesis and characterization of two novel thioarsenate compounds: Three-dimensional (1,2-pdaH2)0.5As5S8 containing ψ-As(iii)S4 and two-dimensional (NH4)2As8S1312Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites60Strong Kleinman-Forbidden Second Harmonic Generation in Chiral Sulfide: La 4 InSbS 9167BaGa2GeX6(X=S, Se): New mid-IR nonlinear optical crystals with large band gaps111Two New Noncentrosymmetric (NCS) Polar Oxides: Syntheses, Characterization, and Structure–Property Relationships in BaMTe2O7 (M = Mg2+ or Zn2+)50First-principles studies on linear and nonlinear optical effects in Ln4GaSbS9 (Ln=Ce–Nd, Sm, Gd–Tm, Lu)9Na2EuAs2S5, NaEuAsS4, and Na4Eu(AsS4)2: Controlling the Valency of Arsenic in Polysulfide Fluxes22Crystal Growth and Characterization of the X-ray and γ-ray Detector Material Cs2Hg6S746Understanding Fluxes as Media for Directed Synthesis: In Situ Local Structure of Molten Potassium Polysulfides57Phase-Change Materials Exhibiting Tristability: Interconverting Forms of Crystalline α-, β-, and Glassy K2ZnSn3S830Solvent effect on condensation of pyramidal [AsSe3]3–: solvothermal syntheses of new selenidoarsenates containing transition metal(II) complexes with 1,10-phenanthroline8Novel single-crystal's voltage-dependent effect and magnetic order of Ln2ZrQ5 (Ln = La, Sm, Gd; Q = S, Se) semiconductors31Nanoscale Stabilization of New Phases in the PbTe–Sb2Te3 System: PbmSb2nTem+3n Nanocrystals40Syntheses, crystal and electronic structures, and characterizations of the mixed anions compounds Ba4In2Te2Q5 (Q = S, Se)6Growing Crystalline Chalcogenidoarsenates in Surfactants: From Zero-Dimensional Cluster to Three-Dimensional Framework285Effect of lanthanide contraction on the Ln/Sb/Se/dien system: solvothermal syntheses and characterizations of lanthanide(III)-selenidoantimonate complexes with diethylenetriamine as a co-ligand7Li2Se-As2Se3 pseudobinary join in the Li-As-Se system and properties of LiAsSe20Ab initio study of elasticity, piezoelectricity, and nonlinear optical performance in monoclinic NaAsSe226Chemical ordering rather than random alloying in SbAs18Metal Chalcogenides: A Rich Source of Nonlinear Optical Materials680Broadband studies of the strong mid-infrared nonlinear optical responses of KPSe_627Cs2MIIMIV3Q8 (Q = S, Se, Te): An Extensive Family of Layered Semiconductors with Diverse Band Gaps96Solvothermal syntheses, crystal structures, and properties of lanthanide(III) thioarsenates [Ln(dien)2(μ-1κ,2κ2-AsS4)]n (Ln==Sm, Eu, Gd) and [Ln(dien)2(1κ2-AsS4)] (Ln==Tb, Dy, Ho)10Clusters [Co(As3S3)2]2–, [Ni(As3S3)2]2–, and [{Co(en)}6(μ3-S)4(AsS3)4]2– with Co–As or Ni–As Bonds: Solvothermal Syntheses and Characterizations of Thioarsenates Containing Transition-Metal Complexes30Crystalline and Glassy Phases in the Cs/Bi/As/S System8Synthesis, structure, physicochemical characterization and electronic structure of thio-lithium super ionic conductors, Li4GeS4 and Li4SnS439Alkahest for V 2 VI 3 Chalcogenides: Dissolution of Nine Bulk Semiconductors in a Diamine-Dithiol Solvent Mixture205(enH 2 ) 4.5 [In(As V S 4 ) 3 ][As 2 III (μ-S 2 )S 3 ]Cl and (enH 2 )MnAs III As V S 6 : two thioarsenates( iii , v ) with mixed-valent optical properties16Copper substitutions in synthetic miargyrite α-AgSbS2 mineral: Synthesis, characterization and dielectrical properties6Computational design of inorganic nonlinear optical crystals based on a genetic algorithm93Influence of the cation size on the second harmonic generation response of chiral A(VO 2 ) 2 (PO 4 )·3H 2 O (A = K + , NH 4 + and Rb + )3LiPbSb3S6: A Semiconducting Sulfosalt with Very Low Thermal Conductivity24Analysis of Deep‐UV Nonlinear Optical Borates: Approaching the End213LiSbS2‐mC16: Structure Determination from X‐ray Powder Diffraction Data9Li2CdGeS4, A Diamond-Like Semiconductor with Strong Second-Order Optical Nonlinearity in the Infrared and Exceptional Laser Damage Threshold193Multipolar second-harmonic generation from films of chalcogenide glasses1First-principles materials applications and design of nonlinear optical crystals259Deep-Ultraviolet Transparent Phosphates RbBa 2 (PO 3 ) 5 and Rb 2 Ba 3 (P 2 O 7 ) 2 Show Nonlinear Optical Activity from Condensation of [PO 4 ] 3– Units354(NH4)4Sn2S6·3H2O: Crystal Structure, Thermal Decomposition, and Precursor for Textured Thin Film21Syntheses, structures, optical properties, and electronic structures of KBaMSe 3 (M = As, Sb)22Optical Nonlinearity in Cu2CdSnS4 and α/β-Cu2ZnSiS4: Diamond-like Semiconductors with High Laser-Damage Thresholds87Novel One-, Two-, and Three-Dimensional Selenidostannates Templated by Iron(II) Complex Cation23Surfactant-thermal method to prepare two novel two-dimensional Mn–Sb–S compounds for photocatalytic applications32Development of nonlinear optical materials promoted by density functional theory simulations32Synthesis, structures, optical properties and electronic structures of PbGa2Q4 (Q=S, Se) crystals13First-principles calculation of the bulk photovoltaic effect in the polar compounds LiAsS2, LiAsSe2, and NaAsSe261Syntheses, structures, and optical properties of Ba 4 Ga 4 SnSe 12 and Ba 6 Ga 2 SnSe 1119A series of new lanthanoid thioarsenates: insights into the influence of lanthanide contraction on the formation of new lanthanoid thioarsenates25Ba 2 GeS 4 and Mg 2 SnS 4 : synthesis, structures, optical properties and electronic structures41BaGa 2 SnSe 6 : a new phase-matchable IR nonlinear optical material with strong second harmonic generation response58Infrared nonlinear optical properties of lithium-containing diamond-like semiconductors Li 2 ZnGeSe 4 and Li 2 ZnSnSe 457PbGa 4 S 7 : a wide-gap nonlinear optical material91Phase-Change Behavior and Nonlinear Optical Second and Third Harmonic Generation of the One-Dimensional K(1–x)CsxPSe6 and Metastable β-CsPSe662Predicting and Designing Optical Properties of Inorganic Materials71Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS2 and Centric Ba8Hg4S5Se752Syntheses, crystal structures, and NLO properties of the quaternary sulfides RE3Sb0.33SiS7 (RE=La, Pr)24Hybrid Germanium Iodide Perovskite Semiconductors: Active Lone Pairs, Structural Distortions, Direct and Indirect Energy Gaps, and Strong Nonlinear Optical Properties945Metal Thiophosphates with Good Mid-infrared Nonlinear Optical Performances: A First-Principles Prediction and Analysis441Ba2AsGaSe5: A New Quaternary Selenide with the Novel [AsGaSe5]4– Cluster and Interesting Photocatalytic Properties37Crystal structures and non-linear optics of several types of bimetallic assemblies comprising chiral Cu(II) complexes7Syntheses, crystal structures and physical properties of three new chalcogenides: NaGaGe 3 Se 8 , K 3 Ga 3 Ge 7 S 20 , and K 3 Ga 3 Ge 7 Se 2018First-Principles Materials Design of High-Performing Bulk Photovoltaics with the Li Nb O 3 Structure33K 2 Sn 2 ZnSe 6 , Na 2 Ge 2 ZnSe 6 , and Na 2 In 2 GeSe 6 : a new series of quaternary selenides with intriguing structural diversity and nonlinear optical properties32Thioarsenate anions acting as ligands: Solvothermal syntheses, crystal structures and characterizations of transition metal complexes of thioarsenate and polyethyleneamine ligands7Ba4Ga2Se8: A ternary selenide containing chains and discrete Se22− units14First principle calculation of physical properties of barium based chalcogenides BaM 4 S 7 (M = Ga, Al); a DFT, DFT-D and hybrid functional HSE06 study37Midinfrared Nonlinear Optical Thiophosphates from LiZnPS4 to AgZnPS4: A Combined Experimental and Theoretical Study100Organic–Inorganic Perovskites: Structural Versatility for Functional Materials Design2907Na 2 Hg 3 M 2 S 8 (M = Si, Ge, and Sn): New Infrared Nonlinear Optical Materials with Strong Second Harmonic Generation Effects and High Laser-Damage Thresholds186Na 2 BaMQ 4 (M=Ge, Sn; Q=S, Se): Infrared Nonlinear Optical Materials with Excellent Performances and that Undergo Structural Transformations202Na2BaMQ4 (M=Ge, Sn; Q=S, Se): Infrared Nonlinear Optical Materials with Excellent Performances and that Undergo Structural Transformations44Electronic structure of layered quaternary chalcogenide materials for band-gap engineering: The example of Cs2MIIM3IVQ814Trigonal Planar [HgSe3]4– Unit: A New Kind of Basic Functional Group in IR Nonlinear Optical Materials with Large Susceptibility and Physicochemical Stability196A molecular layer “fabric” with orthogonally woven coordination polymer chains9Substantial optical dielectric enhancement by volume compression in LiAsSe21Solvothermal syntheses, crystal structures, and properties of new lanthanide compounds based on tetraselenidoantimonate and tetraethylenepentamine mixed ligands1Shift current bulk photovoltaic effect in polar materials—hybrid and oxide perovskites and beyond391A High Laser Damage Threshold and a Good Second-Harmonic Generation Response in a New Infrared NLO Material: LiSm3SiS725Recent studies of nonlinear chalcogenide crystals for the mid-IR148Solvothermal syntheses and characterization of three new silver(I)/copper(I)-thioarsenates based on As2+/As3+ ions9Analysis and prediction of mid-IR nonlinear optical metal sulfides with diamond-like structures336Non‐centrosymmetric Selenides AZn4In5Se12 (A=Rb, Cs): Synthesis, Characterization and Nonlinear Optical Properties47Recent achievements on middle and far-infrared second-order nonlinear optical materials433Li 2 CdGeSe 4 and Li 2 CdSnSe 4 : biaxial nonlinear optical materials with strong infrared second-order responses and laser-induced damage thresholds influenced by photoluminescence54Screening novel candidates for mid-IR nonlinear optical materials from I 3 –V–VI 4 compounds51Tailored synthesis of nonlinear optical quaternary chalcohalides: Ba 4 Ge 3 S 9 Cl 2 , Ba 4 Si 3 Se 9 Cl 2 and Ba 4 Ge 3 Se 9 Cl 252Theoretical perspectives on the structure, electronic, and optical properties of titanosilicates Li 2 M 4 [(TiO)Si 4 O 12 ] (M = K + , Rb + )13Thioborates: potential nonlinear optical materials with rich structural chemistry51Two excellent phase-matchable infrared nonlinear optical materials based on 3D diamond-like frameworks: RbGaSn 2 Se 6 and RbInSn 2 Se 639Superpolyhedron-Built Second Harmonic Generation Materials Exhibit Large Mid-Infrared Conversion Efficiencies and High Laser-Induced Damage Thresholds101Noncentrosymmetric chalcogenides BaZnSiSe4 and BaZnGeSe4 featuring one-dimensional structures56Discovery-Synthesis, Design, and Prediction of Chalcogenide Phases208Mid-Infrared Nonlinear Optical Materials Based on Metal Chalcogenides: Structure–Property Relationship338Li2HgMS4 (M = Si, Ge, Sn): New Quaternary Diamond-Like Semiconductors for Infrared Laser Frequency Conversion64Pb0.65Mn2.85Ga3S8 and Pb0.72Mn2.84Ga2.95Se8: Two Quaternary Metal Chalcognides with Open-Tunnel-Framework Structures Displaying Intense Second Harmonic Generation Responses and Interesting Magnetic Properties17Magnetically Frustrated Quaternary Chalcogenides with Interpenetrating Diamond Lattices18Reactive Fluxes0Hg-Based Infrared Nonlinear Optical Material KHg4Ga5Se12 Exhibits Good Phase-Matchability and Exceptional Second Harmonic Generation Response101The Power of Heterometalation through Lithium for Helix Chain-Based Noncentrosymmetric Metal–Organic Frameworks with Tunable Second-Harmonic Generation Effects19First principle study of nonlinear optical crystals15Hydrazine-solvothermal methods to synthesize polymeric thioarsenates from one-dimensional chains to a three-dimensional framework8K 2 MnGe 3 S 8 : a new multifunctional semiconductor featuring [MnGe 3 S 8 ] 2− layers and demonstrating interesting nonlinear optical response and antiferromagnetic properties33Synthesis, Structure, and Optical Properties of Antiperovskite-Derived Ba2MQ3X (M = As, Sb; Q = S, Se; X = Cl, Br, I) Chalcohalides27Non-Centrosymmetric RbNaMgP 2 O 7 with Unprecedented Thermo-Induced Enhancement of Second Harmonic Generation239Pushing Nonlinear Optical Oxides into the Mid-Infrared Spectral Region Beyond 10 μm: Design, Synthesis, and Characterization of La3SnGa5O14145Exploring the Surfactant–Thermal Synthesis of Crystalline Functional Thioarsenates48Synthesis, Crystal Structures, Optical Properties and Theoretical Calculations of Two Metal Chalcogenides Ba2AlSbS5 and Ba2GaBiSe59Nonbonding Electrons Driven Strong SHG Effect in Hg2GeSe4: Experimental and Theoretical Investigations61Prediction and Characterization of NaGaS2, A High Thermal Conductivity Mid-Infrared Nonlinear Optical Material for High-Power Laser Frequency Conversion38V-doping in a potential nonlinear optical material Sr2Nb2O7 for increasing the SHG response: A first-principles study2Accurate determination of low-symmetry Bravais unit cells by EBSD5A review on structure-performance relationship toward the optimal design of infrared nonlinear optical materials with balanced performances253Effect of wavefunction delocalization on shift current generation14Recent progress on new infrared nonlinear optical materials with application prospect133Investigations of electronic and nonlinear optical properties of single alkali metal adsorbed graphene, graphyne and graphdiyne systems by first-principles calculations155ABaSbQ 3 (A = Li, Na; Q = S, Se): diverse arrangement modes of isolated SbQ 3 ligands regulating the magnitudes of birefringences50Ag 7 TaSe 6 : a new noncentrosymmetric selenide with fascinating “three in one” coordination modes and a strong second harmonic generation response13Investigation on two new antimony-based quaternary chalcogenides: Na 6 CdSb 4 S 10 and Na 3 CdSbSe 41SnGa 2 GeSe 6 , a benign addition to the AMIII2M IV Q 6 family: synthesis, crystal structure and nonlinear optical performance20Broadening Frontiers of Infrared Nonlinear Optical Materials with π-Conjugated Trigonal-Planar Groups67Theoretical Design of Layered AlGaS3 as a New Nonlinear Optical Material with a Strong Second Harmonic Generation Response5Two Non-π-Conjugated Deep-UV Nonlinear Optical Sulfates268Sr 6 Cd 2 Sb 6 O 7 S 10 : Strong SHG Response Activated by Highly Polarizable Sb/O/S Groups124Sr6Cd2Sb6O7S10: Strong SHG Response Activated by Highly Polarizable Sb/O/S Groups22Mixed-Anion Inorganic Compounds: A Favorable Candidate for Infrared Nonlinear Optical Materials140In Praise and in Search of Highly-Polarizable Semiconductors1Design of a Multifunctional Indium–Organic Framework: Fluorescent Sensing of Nitro Compounds, Physical Adsorption, and Photocatalytic Degradation of Organic Dyes83Effect of DFT methods on electronic structure and K-absorption spectra of InPS4: detailed studies of the optical, thermoelectric and elastic properties4Structural Phase Transition, Optical and Electrical Property Evolutions of Thiospinel AgIn5S8 under High Pressure17How To Maximize Birefringence and Nonlinearity of π-Conjugated Cyanurates327

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  1. ChemInform Abstract: Soluble Semiconductors AAsSe2 (A: Li, Na) with a Direct‐Band‐Gap and Strong Second Harmonic Generation: A Combined Experimental and Theoretical Study.

    ChemInform · 2010-05-20

    Tarun K. Bera, Joon Ik Jang, Jung‐Hwan Song, Christos D. Malliakas, Arthur J Freeman, John B. Ketterson, Mercouri G. Kanatzidis

    Read original paper ↗ ·

  2. Arsenic-Containing Chalcophosphate Molecular Anions

    Inorganic Chemistry · 2010-09-08

    Collin D. Morris, Mercouri G. Kanatzidis

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  3. Hydrazine-hydrothermal method to synthesize three-dimensional chalcogenide framework for photocatalytic hydrogen generation

    Journal of Solid State Chemistry · 2010-09-18

    Yi Liu, Pushkar D. Kanhere, Chui Ling Wong, Yuefeng Tian, Yuhua Feng, Freddy Boey, Tom Wu, Hongyu Chen, Timothy John White, Zhong Chen, Qichun Zhang

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  4. (Ag2TeS3)2·A2S6 (A = Rb, Cs): Layers of Silver Thiotellurite Intergrown with Alkali-Metal Polysulfides

    Inorganic Chemistry · 2010-09-22

    Sandy L. Nguyen, Joon Ik Jang, John B. Ketterson, Mercouri G. Kanatzidis

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  5. Novel Polyselenidoarsenate and Selenidoarsenate: Solvothermal Synthesis and Characterization of [Co(phen)3][As2Se2(μ-Se3)(μ-Se5)] and [Co(phen)3]2[As8Se14]

    Inorganic Chemistry · 2011-02-20

    Jing Zhao, Jingjing Liang, Jiangfang Chen, Yingli Pan, Yong Zhang, Dingxian Jia

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  6. In-Phase Alignments of Asymmetric Building Units in Ln 4 GaSbS 9 (Ln = Pr, Nd, Sm, Gd−Ho) and Their Strong Nonlinear Optical Responses in Middle IR

    Journal of the American Chemical Society · 2011-03-03

    Mei‐Chun Chen, Long-Hua Li, Yu‐Biao Chen, Ling Chen

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  7. Synthesis, Characterization, and Structure–Property Relationships in Two New Polar Oxides: Zn2(MoO4)(SeO3) and Zn2(MoO4)(TeO3)

    Inorganic Chemistry · 2011-05-10

    Sau Doan Nguyen, Sang-Hwan Kim, P. Shiv Halasyamani

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  8. Stabilization of Noncondensed (AsIIIS3)3– Anions by Coordinating to [MnII(phen)]2+ Complex Cations: a Mixed-Valent Thioarsenate (III, V) {[Mn(phen)]3(AsVS4)(AsIIIS3)}n·nH2O Showing the Coexistence of Antiferromagnetic Order, Photoluminescence, and Nonlinear Optical Properties

    Inorganic Chemistry · 2011-05-20

    Guang‐Ning Liu, Xiao‐Ming Jiang, Mei‐Feng Wu, Guan‐E Wang, Guo‐Cong Guo, Jin‐Shun Huang

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  9. Thallium Chalcogenide-Based Wide-Band-Gap Semiconductors: TlGaSe2 for Radiation Detectors

    Chemistry of Materials · 2011-05-31

    Simon Johnsen, Zhifu Liu, John A. Peters, Jung-Hwan Song, Sebastian Chirambatte Peter, Christos D. Malliakas, Nam Ki Cho, Hosub Jin, Arthur J Freeman, Bruce W. Wessels, Mercouri G. Kanatzidis

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  10. Solvothermal Synthesis and Characterization of Polyselenidoarsenate Salts of Transition Metal Complex Cations

    Inorganic Chemistry · 2011-07-06

    Dingxian Jia, Jing Zhao, Yingli Pan, Weiwei Tang, Bing Wu, Yong Zhang

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  11. BiO(IO3): A New Polar Iodate that Exhibits an Aurivillius-Type (Bi2O2)2+ Layer and a Large SHG Response

    Journal of the American Chemical Society · 2011-07-21

    Sau Doan Nguyen, Jeongho Yeon, Sang-Hwan Kim, P. Shiv Halasyamani

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  12. “A” Cation Polarity Control in ACuTe2O7 (A = Sr2+, Ba2+, or Pb2+)

    Inorganic Chemistry · 2011-07-29

    Jeongho Yeon, Sang-Hwan Kim, Michael A. Hayward, P. Shiv Halasyamani

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  13. Synthesis, crystal structures, and optical properties of NaCdPnS3 (Pn=As, Sb)

    Journal of Alloys and Compounds · 2011-09-11

    Yuandong Wu, Wolfgang Bensch

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  14. Tl2Hg3Q4 (Q = S, Se, and Te): High-Density, Wide-Band-Gap Semiconductors

    Chemistry of Materials · 2011-09-16

    Simon Johnsen, Sebastian Chirambatte Peter, Sandy L. Nguyen, Jung-Hwan Song, Hosub Jin, Arthur J Freeman, Mercouri G. Kanatzidis

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  15. Strongly Nonlinear Optical Chalcogenide Thin Films of APSe6 (A=K, Rb) from Spin‐Coating

    Angewandte Chemie International Edition · 2011-09-20

    In Jae Chung, Myung‐Gil Kim, Joon Ik Jang, Jiaqing He, John B. Ketterson, Mercouri G. Kanatzidis

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  16. Strongly Nonlinear Optical Chalcogenide Thin Films of APSe6 (A=K, Rb) from Spin‐Coating

    Angewandte Chemie · 2011-09-20

    In Jae Chung, Myung‐Gil Kim, Joon Ik Jang, Jiaqing He, John B. Ketterson, Mercouri G. Kanatzidis

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  17. New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)

    Inorganic Chemistry · 2011-12-06

    Jeongho Yeon, Sang-Hwan Kim, Sau Doan Nguyen, Hana Lee, P. Shiv Halasyamani

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  18. Structural Diversity, Optical and Magnetic Properties of a Series of Manganese Thioarsenates with 1,10-Phenanthroline or 2,2′-Bipyridine Ligands: Using Monodentate Methylamine as an Alkalinity Regulator

    Inorganic Chemistry · 2011-12-08

    Guang‐Ning Liu, Guo‐Cong Guo, Feng Chen, Shuai‐Hua Wang, Jing Zhi Sun, Jin‐Shun Huang

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  19. LiGaGe2Se6: A New IR Nonlinear Optical Material with Low Melting Point

    Inorganic Chemistry · 2011-12-21

    Dajiang Mei, Wenlong Yin, Kai Feng, Zheshuai Lin, Lei Bai, Jiyong Yao, Yicheng Wu

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  20. Large Crystal Growth and New Crystal Exploration of Mid-Infrared Second-Order Nonlinear Optical Materials

    Structure and bonding · 2012-01-01

    Xiao‐Ming Jiang, Sheng‐Ping Guo, Hui‐Yi Zeng, Ming‐Jian Zhang, Guo‐Cong Guo

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  21. pH-induced solvothermal synthesis and characterization of two novel thioarsenate compounds: Three-dimensional (1,2-pdaH2)0.5As5S8 containing ψ-As(iii)S4 and two-dimensional (NH4)2As8S13

    CrystEngComm · 2012-01-01

    Ke‐Zhao Du, Mei‐Ling Feng, Jian‐Rong Li, Xiao‐Ying Huang

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  22. Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites

    Structure and bonding · 2012-01-01

    Fang Kong, Chuan‐Fu Sun, Bing‐Ping Yang, Jiang‐Gao Mao

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  23. Strong Kleinman-Forbidden Second Harmonic Generation in Chiral Sulfide: La 4 InSbS 9

    Journal of the American Chemical Society · 2012-01-10

    Hua‐Jun Zhao, Yongfan Zhang, Ling Chen

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  24. BaGa2GeX6(X=S, Se): New mid-IR nonlinear optical crystals with large band gaps

    Journal of Solid State Chemistry · 2012-01-30

    Xinsong Lin, Yifeng Guo, Ning Ye

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  25. Two New Noncentrosymmetric (NCS) Polar Oxides: Syntheses, Characterization, and Structure–Property Relationships in BaMTe2O7 (M = Mg2+ or Zn2+)

    Inorganic Chemistry · 2012-02-01

    Jeongho Yeon, Sang-Hwan Kim, Sau Doan Nguyen, Hana Lee, P. Shiv Halasyamani

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  26. First-principles studies on linear and nonlinear optical effects in Ln4GaSbS9 (Ln=Ce–Nd, Sm, Gd–Tm, Lu)

    Journal of Solid State Chemistry · 2012-03-05

    Liujiang Zhou, Ling Chen, Junqian Li, Li‐Ming Wu

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  27. Na2EuAs2S5, NaEuAsS4, and Na4Eu(AsS4)2: Controlling the Valency of Arsenic in Polysulfide Fluxes

    Inorganic Chemistry · 2012-03-13

    Tarun K. Bera, Mercouri G. Kanatzidis

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  28. Crystal Growth and Characterization of the X-ray and γ-ray Detector Material Cs2Hg6S7

    Crystal Growth & Design · 2012-05-09

    Hao Li, John A. Peters, Zhifu Liu, Maria Sebastian, Christos D. Malliakas, John Androulakis, Li‐Dong Zhao, In Jae Chung, Sandy L. Nguyen, Simon Johnsen, Bruce W. Wessels, Mercouri G. Kanatzidis

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  29. Understanding Fluxes as Media for Directed Synthesis: In Situ Local Structure of Molten Potassium Polysulfides

    Journal of the American Chemical Society · 2012-05-14

    Daniel P. Shoemaker, Duck Young Chung, John F. Mitchell, Travis H. Bray, L. Soderholm, Peter J. Chupas, Mercouri G. Kanatzidis

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  30. Phase-Change Materials Exhibiting Tristability: Interconverting Forms of Crystalline α-, β-, and Glassy K2ZnSn3S8

    Inorganic Chemistry · 2012-07-17

    Z.H. Fard, Mercouri G. Kanatzidis

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  31. Solvent effect on condensation of pyramidal [AsSe3]3–: solvothermal syntheses of new selenidoarsenates containing transition metal(II) complexes with 1,10-phenanthroline

    Journal of Coordination Chemistry · 2012-08-10

    Ruihong Chen, Weiwei Tang, Wenqing Jiang, Yong Zhang, Dingxian Jia

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  32. Novel single-crystal's voltage-dependent effect and magnetic order of Ln2ZrQ5 (Ln = La, Sm, Gd; Q = S, Se) semiconductors

    Dalton Transactions · 2012-12-19

    Sheng‐Ping Guo, Guan‐E Wang, Ming‐Jian Zhang, Mei‐Feng Wu, Guang‐Ning Liu, Xiao‐Ming Jiang, Guo‐Cong Guo, Jin‐Shun Huang

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  33. Nanoscale Stabilization of New Phases in the PbTe–Sb2Te3 System: PbmSb2nTem+3n Nanocrystals

    Journal of the American Chemical Society · 2012-12-28

    Ronald B. Soriano, Indika U. Arachchige, Christos D. Malliakas, Jinsong Wu, Mercouri G. Kanatzidis

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  34. Syntheses, crystal and electronic structures, and characterizations of the mixed anions compounds Ba4In2Te2Q5 (Q = S, Se)

    CrystEngComm · 2013-01-01

    Zhong‐Zhen Luo, Chensheng Lin, Wen‐Dan Cheng, Yi Jin Yang, Yuan‐Bing Li, Hao Zhang, Weilong Zhang, Zhangzhen He

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  35. Growing Crystalline Chalcogenidoarsenates in Surfactants: From Zero-Dimensional Cluster to Three-Dimensional Framework

    Journal of the American Chemical Society · 2013-01-11

    Wei‐Wei Xiong, Eashwer Athresh, Yu Ting Ng, Junfeng Ding, Tom Wu, Qichun Zhang

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  36. Effect of lanthanide contraction on the Ln/Sb/Se/dien system: solvothermal syntheses and characterizations of lanthanide(III)-selenidoantimonate complexes with diethylenetriamine as a co-ligand

    Journal of Coordination Chemistry · 2013-01-17

    Ruihong Chen, Weiwei Tang, Wenqing Jiang, Yong Zhang, Dingxian Jia

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  37. Li2Se-As2Se3 pseudobinary join in the Li-As-Se system and properties of LiAsSe2

    Inorganic Materials · 2013-02-17

    E.E. Semrad, Vasyl I. Sidey, Andriy M. Solomon

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  38. Ab initio study of elasticity, piezoelectricity, and nonlinear optical performance in monoclinic NaAsSe2

    Journal of Alloys and Compounds · 2013-03-25

    Zuju Ma, Kechen Wu, Rongjian Sa, Qiaohong Li, Yongfan Zhang

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  39. Chemical ordering rather than random alloying in SbAs

    Physical Review B · 2013-03-26

    Daniel P. Shoemaker, Thomas C. Chasapis, Dat Do, Melanie C. Francisco, Duck Young Chung, S. D. Mahanti, Anna Llobet, Mercouri G. Kanatzidis

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  40. Metal Chalcogenides: A Rich Source of Nonlinear Optical Materials

    Chemistry of Materials · 2013-08-09

    In Jae Chung, Mercouri G. Kanatzidis

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  41. Broadband studies of the strong mid-infrared nonlinear optical responses of KPSe_6

    Optical Materials Express · 2013-08-12

    Joon Ik Jang, Alyssa S. Haynes, Felix O. Saouma, Calford Odhiambo Otieno, Mercouri G. Kanatzidis

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  42. Cs2MIIMIV3Q8 (Q = S, Se, Te): An Extensive Family of Layered Semiconductors with Diverse Band Gaps

    Chemistry of Materials · 2013-08-13

    Collin D. Morris, Hao Li, Hosub Jin, Christos D. Malliakas, John A. Peters, Pantelis N. Trikalitis, Arthur J Freeman, Bruce W. Wessels, Mercouri G. Kanatzidis

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  43. Solvothermal syntheses, crystal structures, and properties of lanthanide(III) thioarsenates [Ln(dien)2(μ-1κ,2κ2-AsS4)]n (Ln==Sm, Eu, Gd) and [Ln(dien)2(1κ2-AsS4)] (Ln==Tb, Dy, Ho)

    Journal of Solid State Chemistry · 2013-08-17

    Fang Wang, Chunying Tang, Ruihong Chen, Yong Zhang, Dingxian Jia

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  44. Clusters [Co(As3S3)2]2–, [Ni(As3S3)2]2–, and [{Co(en)}6(μ3-S)4(AsS3)4]2– with Co–As or Ni–As Bonds: Solvothermal Syntheses and Characterizations of Thioarsenates Containing Transition-Metal Complexes

    Inorganic Chemistry · 2013-09-24

    Chunying Tang, Fang Wang, Wenqing Jiang, Yong Zhang, Dingxian Jia

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  45. Crystalline and Glassy Phases in the Cs/Bi/As/S System

    Inorganic Chemistry · 2013-09-24

    Tarun K. Bera, Ratnasabapathy G. Iyer, Christos D. Malliakas, Mercouri G. Kanatzidis

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  46. Synthesis, structure, physicochemical characterization and electronic structure of thio-lithium super ionic conductors, Li4GeS4 and Li4SnS4

    Journal of Alloys and Compounds · 2013-10-14

    Joseph H. MacNeil, Danielle M. Massi, Jian‐Han Zhang, Kimberly A. Rosmus, Carl D. Brunetta, Taylor A. Gentile, Jennifer A. Aitken

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  47. Alkahest for V 2 VI 3 Chalcogenides: Dissolution of Nine Bulk Semiconductors in a Diamine-Dithiol Solvent Mixture

    Journal of the American Chemical Society · 2013-10-15

    David H. Webber, Richard L. Brutchey

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  48. (enH 2 ) 4.5 [In(As V S 4 ) 3 ][As 2 III (μ-S 2 )S 3 ]Cl and (enH 2 )MnAs III As V S 6 : two thioarsenates( iii , v ) with mixed-valent optical properties

    Dalton Transactions · 2013-12-02

    Ke‐Zhao Du, Mei‐Ling Feng, Xing‐Hui Qi, Zuju Ma, Long-Hua Li, Jian‐Rong Li, Cheng‐Feng Du, Guo‐Dong Zou, Xiao‐Ying Huang

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  49. Copper substitutions in synthetic miargyrite α-AgSbS2 mineral: Synthesis, characterization and dielectrical properties

    Materials Chemistry and Physics · 2013-12-15

    Antonio Galdámez, F. López‐Vergara, Nicolás Veloso, V. Manrı́quez, Ricardo E. Ávila

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  50. Computational design of inorganic nonlinear optical crystals based on a genetic algorithm

    CrystEngComm · 2014-01-01

    Zhenxing Fang, Jing Chie Lin, Rong Liu, Ping Liu, Yi Li, Xin Huang, Kaining Ding, Lixin Ning, Yongfan Zhang

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