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RESEARCH PAPER · Inorganic Chemistry · 2009

Synthesis, Structure, and Properties of the Noncentrosymmetric Hydrated Borate Na2B5O8(OH)·2H2O

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Synthesis, Structure, and Properties of the Noncentrosymmetric Hydrated Borate Na2B5O8(OH)·2H2OOriginalChemInform Abstract: Synthesis, Structure, and Properties of the Noncentrosymmetric Hydrate Borate Na2B5O8(OH)·2H2O.0Amine-Templated Aluminoborates Exhibiting Graphite and Diamond Nets35Flux growth and morphology analysis of Na3VO2B6O11 crystals9Growth of Bi2ZnOB2O6 crystal by the Czochralski method17Syntheses, structures and properties of three nonmetal borates with salicylic acid and organic amines9Non-centrosymmetric sodium borate: Crystal growth, characterization and properties on Na2B4O12H1019Synthesis, structure, and properties of a novel hydrated borate Rb4[B4O5(OH)4]2·3H2O13Synthesis, structure, and properties of Li2Pb2CuB4O10 with isolated [CuB4O10]6− units10A congruently melting and deep UV nonlinear optical material: Li3Cs2B5O10104Crystal growth and optical properties of a noncentrosymmetric haloid borate, K3B6O10Br91Synthesis, crystal structure and optical properties of a new lead fluoride borate with isolated [B9O21]15− unit25Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties84K3B6O10Cl: A New Structure Analogous to Perovskite with a Large Second Harmonic Generation Response and Deep UV Absorption Edge670Synthesis, structure characterization and optical properties of a new tripotassium cadmium pentaborate, K3CdB5O1033New bidentate non-centrosymmetric borate–malate: Synthesis, structure and characterization of RbB(dl-C4H4O5)2·H2O20A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks72Synthesis, crystal structure and optical properties of a new lead bismuth borate8A new congruent-melting oxyborate, Pb 4 O(BO 3 ) 2 with optimally aligned BO 3 triangles adopting layered-type arrangement112A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O1222A novel deep UV nonlinear optical crystal Ba3B6O11F2, with a new fundamental building block, B6O14 group180Li5Rb2B7O14: a new congruently melting compound with two kinds of B–O one-dimensional chains and short UV absorption edge25Second-harmonic generating properties of polar noncentrosymmetric aluminoborate solid solutions, Al5−xGaxBO9 (0.0 ≤x≤ 0.5)12UV Nonlinear Optical Crystal Ba2[B6O9(OH)4] Featuring Unique Chiral Layers with a New B18O42 Circle Based on BO3 and BO4 Units97Structure, growth and properties of a novel polar material, KSr4B3O921Synthesis, crystal structure and properties of a new lead fluoride borate, Pb3OBO3F17Pb4VBO8: Synthesis, Crystal Structure, and Properties5Synthesis, crystal structure and optical properties of a new orthorhombic phase, Na3ZnB5O1014Synthesis, structure and characterization of layered Ca[B(C6H6O7)2](H2O)4⋅HCl3Synthesis, crystal structure and characterization of a new compound, Li3NaBaB6O1226Chemistry of Polar Transition-Metal Oxides1New tartratoborates: synthesis, structure, and characterization of non-centrosymmetric ASr[C4H2O6B(OH)2]·4H2O (A = K+, Rb+)29Synthesis, crystal growth and characterization of a new noncentrosymmetric borophosphate: RbPbBP2O836New Molybdenum(VI) Phosphates: Synthesis, Characterization, and Calculations of Centrosymmetric RbMoO2PO4and Noncentrosymmetric Rb4Mo5P2O2239Syntheses, crystal structures, and optical properties of Pb6B3O10X (X=F, Cl, Br)16Ba3M2[B3O6(OH)]2[B4O7(OH)2] (M=Al, Ga): Two Novel UV Nonlinear Optical Metal Borates Containing Two Types of Oxoboron Clusters123A new polymorph of Cd 3 B 2 O 6 : synthesis, crystal structure and phase transformation18Noncentrosymmetric versus Centrosymmetric: Influence of the Na+ Substitution on Structural Transition and Second-Harmonic Generation Property50Hydrothermal phase stability study of Li2B4O70Reinvestigation and Characterization of the Magnesium Borate Fluoride Mg5(BO3)F12Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework36Zn 4 B 3 O 9 C 2 H 8 N 2 : an organic–inorganic hybrid borate with a novel graphene-like layer8An Acentric Calcium Borate Ca2[B5O9]·(OH)·H2O: Synthesis, Structure, and Nonliner Optical Property94Synthesis, crystal structure, and properties of an interesting elliptical vanadoborate housing crystal: [Ni(en)2]6[(VO)12O6B18O39(OH)3]·5H2O12An unusual density evolution between SrCdB 2 O 5 polymorphs6Effect of cation substitution on structural transition: synthesis, characterization and theoretical studies of NaCa 4 B 3 O 9 , NaCaBO 3 , NaSrBO 3 and Li 4 CaB 2 O 618Na 3 B 4 O 7 X (X = Cl, Br): two new borate halides with a 1D Na-X (X = Cl, Br) chain formed by the face-sharing XNa 6 octahedra13Hydrogen-bonded assemblies of two organically templated borates: syntheses and crystal structures of [(1,10-phen)(H3BO3)2] and [2-EtpyH][(B5O6(OH)4]2Two New Crystals in LimCsnBm+nO2(m+n) (m + n = 5, 7; m > n) Series: Noncentrosymmetric Li5Cs2B7O14 and Centrosymmetric Li4CsB5O1016Syntheses and crystal structures of two new sodium borates [Na2(H2O)3][B5O8(OH)2] and Na[enH2][B7O10(OH)4]2Alkali metal–alkaline earth metal borate crystal LiBa 3 (OH)(B 9 O 16 )[B(OH) 4 ] as a new deep-UV nonlinear optical material34IR Spectra of Minerals and Related Compounds, and Reference Samples’ Data21Synthesis, structure and properties of nonlinear optical crystal Li(H 2 O) 4 B(OH) 4 ·2H 2 O5Deep Ultraviolet Nonlinear Optical Materials644A new non-centrosymmetry compound: Synthesis, crystal structure and electronic structure study of hydrated sodium borate Na2[BO2(OH)]·H2O3Synthesis and characterization of inorganic nonlinear optical material: Potassium sodium hydroxide borate hydrate (KSB) single crystal10Solvent-controlled syntheses of mixed-alkali-metal borates exhibiting UV nonlinear optical properties23Structure comparison and optical properties of Na 7 Mg 4.5 (P 2 O 7 ) 4 : a sodium magnesium phosphate with isolated P 2 O 7 units16Two tartratoborates with hybrid anionic groups from unusual condensation reactions9Growth and characterization of cyclohexylaminium hydrogen phthalate hemihydrate nonlinear optical single crystals15Growth, optical, electrical and mechanical properties of sodium hydrogen oxalate hydrate (NaHC2O4·H2O) single crystal for NLO applications25A new mixed alkali metal borate: LiCs[B5O8(OH)]·H2O11Synthesis, structure and characterization of a new nonlinear optical calcium borate [Ca2B5O9]·[H(OH)2]6A Crystallographic Review of Alkali Borate Salts and Ab Initio Study of Borate Ions/Molecules10Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals258Why Some Noncentrosymmetric Borates Do Not Make Good Nonlinear Optical Materials: A Case Study with K3B5O8(OH)222Improved photo-dechlorination at polar photocatalysts K 3 B 6 O 10 X (X = Cl, Br) by halogen atoms-modulated polarization9Two Deep Ultraviolet Hydrated Borate Crystals: Centrosymmetric LiRbB5O8(OH)·H2O and Non-Centrosymmetric K2B5O8(OH)·2H2O8The halogen atoms induced different oxygen vacancies in RbNa2B6O10X (X = Cl, Br) for the enhanced photo-dechlorination properties8IR Spectra of Minerals and Related Compounds, and Reference Samples Data3Sr5[BO2(OH)]3(OH)3F: First hydroxyborate fluoride with the [BO2(OH)]2− unit2Computationally assisted multistage design and prediction driving the discovery of deep-ultraviolet nonlinear optical materials41Five new rubidium borates with 0D clusters, 1D chains, 2D layers and 3D frameworks15Comments on the paper “Synthesis and characterization of inorganic nonlinear optical material: Potassium sodium hydroxide borate hydrate (KSB) single crystal”2An Overview on Recent Trends in Deep‐Ultraviolet (DUV) and Ultraviolet (UV) Nonlinear Optical Crystals25K, Rb-hydroxyborates series with deep-ultraviolet KRbB 5 O 8 (OH) possessing moderate second harmonic generation response0Shooting short-wavelength nonlinear optical materials with targeted balance performances in hydroxyborates through first-principles high-throughput screening4Syntheses, structures and properties of two new members of the pentaborate family: NaKB 5 O 8 (OH)·H 2 O and KB 5 O 8 ·2H 2 O3Structural modification of hydroxyborates by adjusting the number of shared oxygen atoms and hydroxyl groups for further performance enhancement1Nucleation kinetics, FTIR, DFT and Hirshfeld surface analysis of sodium hydrogen oxalate hydrate (NaHC2O4∙H2O) single crystal4Topological diversity of layered pentaborates: Synthesis, characterization, thermal behavior and optical properties of Ag2[B5O8(OH)] with a new type structure1Two Acentric Borates with 2-/3-D Frameworks: Syntheses, Structures, and Nonlinear Optical Properties0

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  1. ChemInform Abstract: Synthesis, Structure, and Properties of the Noncentrosymmetric Hydrate Borate Na2B5O8(OH)·2H2O.

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  2. Amine-Templated Aluminoborates Exhibiting Graphite and Diamond Nets

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  3. Flux growth and morphology analysis of Na3VO2B6O11 crystals

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  4. Growth of Bi2ZnOB2O6 crystal by the Czochralski method

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  5. Syntheses, structures and properties of three nonmetal borates with salicylic acid and organic amines

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  6. Non-centrosymmetric sodium borate: Crystal growth, characterization and properties on Na2B4O12H10

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  7. Synthesis, structure, and properties of a novel hydrated borate Rb4[B4O5(OH)4]2·3H2O

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  8. Synthesis, structure, and properties of Li2Pb2CuB4O10 with isolated [CuB4O10]6− units

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  9. A congruently melting and deep UV nonlinear optical material: Li3Cs2B5O10

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  10. Crystal growth and optical properties of a noncentrosymmetric haloid borate, K3B6O10Br

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  11. Synthesis, crystal structure and optical properties of a new lead fluoride borate with isolated [B9O21]15− unit

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  12. Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties

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  13. K3B6O10Cl: A New Structure Analogous to Perovskite with a Large Second Harmonic Generation Response and Deep UV Absorption Edge

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  14. Synthesis, structure characterization and optical properties of a new tripotassium cadmium pentaborate, K3CdB5O10

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  15. New bidentate non-centrosymmetric borate–malate: Synthesis, structure and characterization of RbB(dl-C4H4O5)2·H2O

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  16. A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks

    Crystal Growth & Design · 2011-07-15

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  17. Synthesis, crystal structure and optical properties of a new lead bismuth borate

    Inorganica Chimica Acta · 2011-10-16

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  18. A new congruent-melting oxyborate, Pb 4 O(BO 3 ) 2 with optimally aligned BO 3 triangles adopting layered-type arrangement

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  19. A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O12

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  20. A novel deep UV nonlinear optical crystal Ba3B6O11F2, with a new fundamental building block, B6O14 group

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  21. Li5Rb2B7O14: a new congruently melting compound with two kinds of B–O one-dimensional chains and short UV absorption edge

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  22. Second-harmonic generating properties of polar noncentrosymmetric aluminoborate solid solutions, Al5−xGaxBO9 (0.0 ≤x≤ 0.5)

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  23. UV Nonlinear Optical Crystal Ba2[B6O9(OH)4] Featuring Unique Chiral Layers with a New B18O42 Circle Based on BO3 and BO4 Units

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  24. Structure, growth and properties of a novel polar material, KSr4B3O9

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  25. Synthesis, crystal structure and properties of a new lead fluoride borate, Pb3OBO3F

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  26. Pb4VBO8: Synthesis, Crystal Structure, and Properties

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  27. Synthesis, crystal structure and optical properties of a new orthorhombic phase, Na3ZnB5O10

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  28. Synthesis, structure and characterization of layered Ca[B(C6H6O7)2](H2O)4⋅HCl

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  29. Synthesis, crystal structure and characterization of a new compound, Li3NaBaB6O12

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  30. Chemistry of Polar Transition-Metal Oxides

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  31. New tartratoborates: synthesis, structure, and characterization of non-centrosymmetric ASr[C4H2O6B(OH)2]·4H2O (A = K+, Rb+)

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  32. Synthesis, crystal growth and characterization of a new noncentrosymmetric borophosphate: RbPbBP2O8

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  33. New Molybdenum(VI) Phosphates: Synthesis, Characterization, and Calculations of Centrosymmetric RbMoO2PO4and Noncentrosymmetric Rb4Mo5P2O22

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  34. Syntheses, crystal structures, and optical properties of Pb6B3O10X (X=F, Cl, Br)

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  35. Ba3M2[B3O6(OH)]2[B4O7(OH)2] (M=Al, Ga): Two Novel UV Nonlinear Optical Metal Borates Containing Two Types of Oxoboron Clusters

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  36. A new polymorph of Cd 3 B 2 O 6 : synthesis, crystal structure and phase transformation

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  37. Noncentrosymmetric versus Centrosymmetric: Influence of the Na+ Substitution on Structural Transition and Second-Harmonic Generation Property

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  38. Hydrothermal phase stability study of Li2B4O7

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  39. Reinvestigation and Characterization of the Magnesium Borate Fluoride Mg5(BO3)F

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  42. An Acentric Calcium Borate Ca2[B5O9]·(OH)·H2O: Synthesis, Structure, and Nonliner Optical Property

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  43. Synthesis, crystal structure, and properties of an interesting elliptical vanadoborate housing crystal: [Ni(en)2]6[(VO)12O6B18O39(OH)3]·5H2O

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  44. An unusual density evolution between SrCdB 2 O 5 polymorphs

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  46. Na 3 B 4 O 7 X (X = Cl, Br): two new borate halides with a 1D Na-X (X = Cl, Br) chain formed by the face-sharing XNa 6 octahedra

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  47. Hydrogen-bonded assemblies of two organically templated borates: syntheses and crystal structures of [(1,10-phen)(H3BO3)2] and [2-EtpyH][(B5O6(OH)4]

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  49. Syntheses and crystal structures of two new sodium borates [Na2(H2O)3][B5O8(OH)2] and Na[enH2][B7O10(OH)4]

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  50. Alkali metal–alkaline earth metal borate crystal LiBa 3 (OH)(B 9 O 16 )[B(OH) 4 ] as a new deep-UV nonlinear optical material

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