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RESEARCH PAPER · Journal of Materials Chemistry · 2011

A new congruent-melting oxyborate, Pb 4 O(BO 3 ) 2 with optimally aligned BO 3 triangles adopting layered-type arrangement

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A new congruent-melting oxyborate, Pb 4 O(BO 3 ) 2 with optimally aligned BO 3 triangles adopting layered-type arrangementOriginalA new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O1222Cadmium-rare earth oxyborates Cd4ReO(BO3)3 (Re = Y, Gd, Lu): congruently melting compounds with large SHG responses65Li5Rb2B7O14: a new congruently melting compound with two kinds of B–O one-dimensional chains and short UV absorption edge25Synthesis, Crystal Structure, and Properties of a New Lead Barium Borate, Pb1.13Ba7.87B18O3610Electronic structure and optical properties of the nonlinear optical crystal Pb4O(BO3)2 by first-principles calculations10Pb8M(BO3)6 (M = Zn, Cd): Two new isostructural lead borates compounds with two-dimensional ∞[Pb8B6O18]2− layer structure11Synthesis, Crystal Structure, and Properties of a New Lead Aluminum Fluoride Borate, Pb6AlB2O7F710An unusual seven-connected lead borate constructed by different cluster building units of {B 6 } and {Pb 6 }19M2Cd3B16O28 (M = Rb, Cs): Two Isostructural Alkali Cadmium Borates with a New Type of Borate Layer29Na2Cd7B8O20: a new noncentrosymmetric compound with special [B3O7] units20Synthesis, crystal growth and characterization of a new noncentrosymmetric borophosphate: RbPbBP2O836Synthesis, structure, and characterization of a new promising nonlinear optical crystal: Cd5(BO3)3F42New Molybdenum(VI) Phosphates: Synthesis, Characterization, and Calculations of Centrosymmetric RbMoO2PO4and Noncentrosymmetric Rb4Mo5P2O2239New Fluoride Carbonates: Centrosymmetric KPb2(CO3)2F and Noncentrosymmetric K2.70Pb5.15(CO3)5F367Synthesis, crystal structure and optical properties of a new lithium dilead pentaborate, LiPb2B5O105Crystal structure, growth and characterization of LiPbB9O15: A new congruent melting nonlinear optical crystal26New Salt-Inclusion Borate, Li3Ca9(BO3)7·2[LiF]: A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles56Anion-Centered Tetrahedra in Inorganic Compounds242Na 11 B 21 O 36 X 2 (X=Cl, Br): Halogen Sodium Borates with a New Graphene‐Like Borate Double Layer38Facile Assembly of an Unusual Lead Borate with Different Cluster Building Units via a Hydrothermal Process38Synthesis, crystal structure and visible light emission of a new inorganic–organic hybrid pentaborate, [C6H14N][B5O6(OH)4]11Syntheses, crystal structures, and optical properties of Pb6B3O10X (X=F, Cl, Br)16Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)2F2Cl and Noncentrosymmetric NaBa4(AlB4O9)2Br350Pb2B3O5.5(OH)2 and [Pb3(B3O7)](NO3): Facile Syntheses of New Lead(II) Borates by Simply Changing the pH Values of the Reaction Systems55Synthesis, crystal structure, optical properties and theoretical calculations of a new potassium lead pentaborate, KPbB5O92Special ∞1[OPb2] Chains and ∞1[O2Pb3] Ribbons Based on OPb4 Anion-Centered Tetrahedra in Pb2(O4Pb8)(BO3)3Br3 and Pb2(O8Pb12)(BO3)2Br614A new mixed metal borate of BaPb[B5O9(OH)]·H2O with acentric structure18Synthesis, structures, optical properties and electronic structures of two mixed metal borates MBaB5O9 (M=Na, K)32Noncentrosymmetric Cubic CsCdBO3 with Bichromophore23Sr 4 B 10 O 18 (OH) 2 ·2H 2 O: a new UV nonlinear optical material with a [B 10 O 23 ] 16− building block53Ba 2 B 10 O 17 : a new centrosymmetric alkaline-earth metal borate with a deep-UV cut-off edge50Ba4(BO3)3(SiO4)·Ba3X (X = Cl, Br): new salt-inclusion borosilicate halides as potential deep UV nonlinear optical materials58BaPbSi 2 O 6 ·BaSO 4 : the first mixed anionic compound synthesized via BaSO 4 salt-inclusion8Exploring the influence of cationic skeletons on the arrangement of isolated BO 3 groups based on RbMgBO 3 , CsZn 4 (BO 3 ) 3 and Cs 4 Mg 4 (BO 3 ) 422Structural insights for the design of new borate–phosphates: synthesis, crystal structure and optical properties of Pb 4 O(BO 3 )(PO 4 ) and Bi 4 O 3 (BO 3 )(PO 4 )36Synthesis and characterization of Cd 4 YbO(BO 3 ) 3 – a congruent melting cadmium–ytterbium oxyborate with large nonlinear optical properties11Cs 3 Zn 6 B 9 O 21 : A Chemically Benign Member of the KBBF Family Exhibiting the Largest Second Harmonic Generation Response361Noncentrosymmetric versus Centrosymmetric: Influence of the Na+ Substitution on Structural Transition and Second-Harmonic Generation Property50The Effect of the Ratio of [M/(B+P)] on the Configuration of Anionic Groups: Synthesis of the Borate–Phosphate LiPb4(BO3)(PO4)215The structure hierarchy hypothesis44Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework36A facile strategy to adjust the density of planar triangle units in lead borate–nitrates16ACdCO 3 F (A = K and Rb): new noncentrosymmetric materials with remarkably strong second-harmonic generation (SHG) responses enhanced via π-interaction61Effect of cation substitution on structural transition: synthesis, characterization and theoretical studies of NaCa 4 B 3 O 9 , NaCaBO 3 , NaSrBO 3 and Li 4 CaB 2 O 618Na 3 B 4 O 7 X (X = Cl, Br): two new borate halides with a 1D Na-X (X = Cl, Br) chain formed by the face-sharing XNa 6 octahedra13PbGa 4 S 7 : a wide-gap nonlinear optical material91Synthesis and optical properties of the first lead borate bromide with isolated BO 3 groups: Pb 2 Ba 3 (BO 3 ) 3 Br26Theoretical perspective of the lone pair activity influence on band gap and SHG response of lead borates24A Facile Synthetic Route to a New SHG Material with Two Types of Parallel π‐Conjugated Planar Triangular Units287A Facile Synthetic Route to a New SHG Material with Two Types of Parallel π‐Conjugated Planar Triangular Units59Three Alkali Metal Lead Orthophosphates – Syntheses, Crystal Structures and Properties of APbPO4 (A = K, Rb, Cs)20Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS2 and Centric Ba8Hg4S5Se752A novel lead borate of NaPb4(H2O)(B5O9)2·BO3 with nonlinear optical property2Polymorphism of lead oxoborate1Polar Polymorphism: α-, β-, and γ-Pb2Ba4Zn4B14O31–Synthesis, Characterization, and Nonlinear Optical Properties79Linear optical and thermo-physical properties of polar K3B6O10Cl crystal21Two New Crystals in LimCsnBm+nO2(m+n) (m + n = 5, 7; m > n) Series: Noncentrosymmetric Li5Cs2B7O14 and Centrosymmetric Li4CsB5O1016Na4MgM2Se6 (M = Si, Ge): The First Noncentrosymmetric Compounds with Special Ethane-like [M2Se6]6– Units Exhibiting Large Laser-Damage Thresholds56New niobium selenites, ANbO(SeO3)2 (A = Na, K, Rb, and Cs): Effect of alkali metal cation size on the dimensionality and intraoctahedral distortion10Pb4(OH)4(BrO3)3(NO3): An Example of SHG Crystal in Metal Bromates Containing π-Conjugated Planar Triangle59Synthesis and characterization of CsSrCO 3 F – a beryllium-free new deep-ultraviolet nonlinear optical material34Li 3 Cs 2 M 2 B 3 P 6 O 24 (M = Pb, Sr): borophosphates with double six-membered ring of [BP 2 O 8 ] 3−22Nonlinear optical response mechanism of noncentrosymmetric lead borate Pb 6 [B 4 O 7 (OH) 2 ] 3 with three crystallographically independent [B 4 O 7 (OH) 2 ] 4− chains8Synthesis, structure, and electronic structure calculation of a new centrosymmetric borate Pb2O[BO2(OH)] based on anion-centered OPb4 tetrahedra6Na 2 ZnGe 2 S 6 : A New Infrared Nonlinear Optical Material with Good Balance between Large Second-Harmonic Generation Response and High Laser Damage Threshold302Synthesis, Characterization, and Theoretical Studies of (Pb4O)Pb2B6O14: A New Lead(II) Borate with Isolated Oxygen-Centered Pb4O Tetrahedra and Large Second Harmonic Generation Response41Structural and physical systematization of the nonlinear-optical borate crystals1Crystal Growth and Associated Properties of a Nonlinear Optical Crystal—Ba2Zn(BO3)226K3B3O4(OH)4·2H2O: A UV Nonlinear Optical Crystal with Isolated [B3O4(OH)4]3– Anion Groups21Hydrothermal synthesis of a new lead(II) borate (Pb4O)Pb2B6O14-II5SrNO3(OH)·H2O: A new member in strontium nitrate hydrate family with an ultraviolet cut-off edge7Experimental and ab initio studies of two UV nonlinear optical materials15Na 2 CdGe 2 Q 6 (Q = S, Se): two metal-mixed chalcogenides with phase-matching abilities and large second-harmonic generation responses78Na 6 Si 3 S 8 O: the first example of a sulfide silicate exhibiting unusual tri-polymerized [Si 3 S 8 O] 6− units without S–O bonds8New lead( ii ) borates in the PbO/PbF 2 /H 3 BO 3 ternary phase diagram: syntheses and structures of β-Pb 6 B 10 O 21 and Pb 4 B 8 O 164[O2Pb3]2(BO3)Br: An Oxidoborate Oxide Bromide with the ∞1[O2Pb3] Double Chains Based on Edge‐sharing OPb4 Tetrahedra2DFT-Based Comparative Study about the Influence of Fluorine and Hydroxyl Anions on Opto-Electric Properties of Borate Crystals: Choice for Better Anion13Insights of BO 3 –PO 4 replacement for the design and synthesis of a new borate–phosphate with unique 1∞[Zn 4 BO 11 ] chains and two new phosphates16Ion-induced structural and optical performance evolution in LBO-like crystals: experimental and theoretical investigation13Pb 2 BO 3 Br: a novel nonlinear optical lead borate bromine with a KBBF-type structure exhibiting strong nonlinear optical response113The first lead fluorooxoborate PbB 5 O 8 F: achieving the coexistence of large birefringence and deep-ultraviolet cut-off edge75Pb4(BO3)2(SO4) and Pb2[(BO2)(OH)](SO4): New lead(II) borate-sulfate mixed-anion compounds with two types of 3D network structures10The role of cations in second-order nonlinear optical materials based on π-conjugated [BO 3 ] 3− groups195Syntheses, Crystal Structures and Properties of Two Novel Mixed Anion Hybrids with Formulas of Pb 6 O 2 (BO 3 ) 2 (C 2 O 4 ) and Pb 4 (CO 3 ) 2 (C 2 O 4 )(OH) 21Assisting the Effective Design of Polar Iodates with Early Transition-Metal Oxide Fluoride Anions206Observation of proximities between spin-1/2 and quadrupolar nuclei in solids: Improved robustness to chemical shielding using adiabatic symmetry-based recoupling24Second-order nonlinear optical crystals with mixed anions250Two new mixed metal borates with the large birefringence in borates system confirmed by a disordered crystal optical calculation method6Pb 10 O 4 (BO 3 ) 3 I 3 : a new noncentrosymmetric oxyborate iodide synthesized by the straightforward hydrothermal method6Sn 2 B 7 O 12 F with a 2∞[B 14 O 24 ] 6− layer constructed from the unprecedented [B 7 O 16 ] 11− fundamental building block18Pb4B6O13: A Polar Lead Oxyborate with Uncommon ∞(B6O12)6– Layers Exhibiting a Large Second Harmonic Generation Response15A 0D Lead‐Free Hybrid Crystal with Ultralow Thermal Conductivity39Synthesis, Characterization and Optical Properties of Two Metal Borates Containing Two Types of Oxoboron Clusters2Ba 6 BO 3 Cl 9 and Pb 6 BO 4 Cl 7 : structural insights into ortho -borates with uncondensed BO 4 tetrahedra10Synthesis and characterization of three new rare-earth orthoborates: Ba 2 MgY 2 (BO 3 ) 4 , Ba 2 CdY 2 (BO 3 ) 4 , and Ba 2 CdSc(BO 3 ) 310α-, β-Pb4B2O7 and α-, β-Pb4B6O13: Polymorphism drives changes in structure and performance15Borates: A Rich Source for Optical Materials1090Ba 2.5 Pb 1.5 B 12 O 22 : structural transformation from a centrosymmetric to a noncentrosymmetric space group by introducing Pb into Ba 2 B 6 O 117Pb3Ba7B7O20F: A new nonlinear optical material exhibiting large second harmonic generation response induced by its unprecedented Pb-B-O framework13RbMT3(BO3)2O3 (M=Ba, Sr; T=Al, Ga): New Double‐Layered Oxyborates Constructed from [BO3] Triangles and [TO4] Tetrahedra13The promotion of TiO2 induction for finely tunable self-crystallized CsPbX3 (X = Cl, Br and I) nanocrystal glasses for LED backlighting display42Two lead borate-nitrates with anion-centered [OPb 4 ] tetrahedra and two types of π-conjugated planar units showing large birefringence20Effect of bond valence sum on the structural modeling of lead borate glass2A Cation-Driven Approach toward Deep-Ultraviolet Nonlinear Optical Materials17Cd8(BO3)4SiO4: Metal Cation Inducing the Formation of Isolated [BO3] and [SiO4] Units in Borate Silicate15Composition‐dependent structural role of lead in aluminoborate and galloborate glasses: A solid‐state NMR study7Synthesis, Characterization and Optical Properties of Two Novel Metal Borates1Noncentrosymmetric Crystal [C10H8NO2]2SiF6·H2O with Large Birefringence12Rational design of a series of non-centrosymmetric antiperovskite and double antiperovskite borate fluorides13Pb9O4(BO3)2(NO3)4: A Lead Borate–Nitrate Containing an Anion-Centered [O8Pb18]∞ Chain with Large Optical Anisotropy2Recent Progress in CsPbX3 (X = Cl, Br, and I) Perovskite Quantum Dot Glasses: Synthesis, Matrix Optimization, and Photonic Application Potentials36First-principles prediction of mechanical, electrical, and optical properties in borates MBO3 (M = Sc, Al, Ga, Ti)5

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  1. A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O12

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  2. Cadmium-rare earth oxyborates Cd4ReO(BO3)3 (Re = Y, Gd, Lu): congruently melting compounds with large SHG responses

    Journal of Materials Chemistry · 2012-01-01

    Guohong Zou, Zuju Ma, Kechen Wu, Ning Ye

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  3. Li5Rb2B7O14: a new congruently melting compound with two kinds of B–O one-dimensional chains and short UV absorption edge

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  4. Synthesis, Crystal Structure, and Properties of a New Lead Barium Borate, Pb1.13Ba7.87B18O36

    Chemistry Letters · 2012-07-31

    Hongping Wu, Shilie Pan, Dianzeng Jia, Zhaohui Chen, Hongwei Yu

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  5. Electronic structure and optical properties of the nonlinear optical crystal Pb4O(BO3)2 by first-principles calculations

    Journal of Solid State Chemistry · 2012-09-25

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  6. Pb8M(BO3)6 (M = Zn, Cd): Two new isostructural lead borates compounds with two-dimensional ∞[Pb8B6O18]2− layer structure

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  7. Synthesis, Crystal Structure, and Properties of a New Lead Aluminum Fluoride Borate, Pb6AlB2O7F7

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  8. An unusual seven-connected lead borate constructed by different cluster building units of {B 6 } and {Pb 6 }

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  9. M2Cd3B16O28 (M = Rb, Cs): Two Isostructural Alkali Cadmium Borates with a New Type of Borate Layer

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  10. Na2Cd7B8O20: a new noncentrosymmetric compound with special [B3O7] units

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  11. Synthesis, crystal growth and characterization of a new noncentrosymmetric borophosphate: RbPbBP2O8

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  12. Synthesis, structure, and characterization of a new promising nonlinear optical crystal: Cd5(BO3)3F

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  13. New Molybdenum(VI) Phosphates: Synthesis, Characterization, and Calculations of Centrosymmetric RbMoO2PO4and Noncentrosymmetric Rb4Mo5P2O22

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  14. New Fluoride Carbonates: Centrosymmetric KPb2(CO3)2F and Noncentrosymmetric K2.70Pb5.15(CO3)5F3

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  15. Synthesis, crystal structure and optical properties of a new lithium dilead pentaborate, LiPb2B5O10

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  16. Crystal structure, growth and characterization of LiPbB9O15: A new congruent melting nonlinear optical crystal

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  17. New Salt-Inclusion Borate, Li3Ca9(BO3)7·2[LiF]: A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles

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  18. Anion-Centered Tetrahedra in Inorganic Compounds

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  19. Na 11 B 21 O 36 X 2 (X=Cl, Br): Halogen Sodium Borates with a New Graphene‐Like Borate Double Layer

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  20. Facile Assembly of an Unusual Lead Borate with Different Cluster Building Units via a Hydrothermal Process

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  21. Synthesis, crystal structure and visible light emission of a new inorganic–organic hybrid pentaborate, [C6H14N][B5O6(OH)4]

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  22. Syntheses, crystal structures, and optical properties of Pb6B3O10X (X=F, Cl, Br)

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  23. Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)2F2Cl and Noncentrosymmetric NaBa4(AlB4O9)2Br3

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  24. Pb2B3O5.5(OH)2 and [Pb3(B3O7)](NO3): Facile Syntheses of New Lead(II) Borates by Simply Changing the pH Values of the Reaction Systems

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  25. Synthesis, crystal structure, optical properties and theoretical calculations of a new potassium lead pentaborate, KPbB5O9

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  26. Special ∞1[OPb2] Chains and ∞1[O2Pb3] Ribbons Based on OPb4 Anion-Centered Tetrahedra in Pb2(O4Pb8)(BO3)3Br3 and Pb2(O8Pb12)(BO3)2Br6

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  27. A new mixed metal borate of BaPb[B5O9(OH)]·H2O with acentric structure

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  28. Synthesis, structures, optical properties and electronic structures of two mixed metal borates MBaB5O9 (M=Na, K)

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  29. Noncentrosymmetric Cubic CsCdBO3 with Bichromophore

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  30. Sr 4 B 10 O 18 (OH) 2 ·2H 2 O: a new UV nonlinear optical material with a [B 10 O 23 ] 16− building block

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  31. Ba 2 B 10 O 17 : a new centrosymmetric alkaline-earth metal borate with a deep-UV cut-off edge

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  32. Ba4(BO3)3(SiO4)·Ba3X (X = Cl, Br): new salt-inclusion borosilicate halides as potential deep UV nonlinear optical materials

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  33. BaPbSi 2 O 6 ·BaSO 4 : the first mixed anionic compound synthesized via BaSO 4 salt-inclusion

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  34. Exploring the influence of cationic skeletons on the arrangement of isolated BO 3 groups based on RbMgBO 3 , CsZn 4 (BO 3 ) 3 and Cs 4 Mg 4 (BO 3 ) 4

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  35. Structural insights for the design of new borate–phosphates: synthesis, crystal structure and optical properties of Pb 4 O(BO 3 )(PO 4 ) and Bi 4 O 3 (BO 3 )(PO 4 )

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  36. Synthesis and characterization of Cd 4 YbO(BO 3 ) 3 – a congruent melting cadmium–ytterbium oxyborate with large nonlinear optical properties

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  37. Cs 3 Zn 6 B 9 O 21 : A Chemically Benign Member of the KBBF Family Exhibiting the Largest Second Harmonic Generation Response

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  38. Noncentrosymmetric versus Centrosymmetric: Influence of the Na+ Substitution on Structural Transition and Second-Harmonic Generation Property

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  39. The Effect of the Ratio of [M/(B+P)] on the Configuration of Anionic Groups: Synthesis of the Borate–Phosphate LiPb4(BO3)(PO4)2

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  40. The structure hierarchy hypothesis

    Mineralogical Magazine · 2014-08-01

    Frank Christopher Hawthorne

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  41. Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework

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  42. A facile strategy to adjust the density of planar triangle units in lead borate–nitrates

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  43. ACdCO 3 F (A = K and Rb): new noncentrosymmetric materials with remarkably strong second-harmonic generation (SHG) responses enhanced via π-interaction

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  44. Effect of cation substitution on structural transition: synthesis, characterization and theoretical studies of NaCa 4 B 3 O 9 , NaCaBO 3 , NaSrBO 3 and Li 4 CaB 2 O 6

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