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RESEARCH PAPER · Inorganic Chemistry · 1998

New Layered Uranium(VI) Molybdates: Syntheses and Structures of (NH3(CH2)3NH3)(H3O)2(UO2)3(MoO4)5, C(NH2)3(UO2)(OH)(MoO4), (C4H12N2)(UO2)(MoO4)2, and (C5H14N2)(UO2)(MoO4)2·H2O

P. Shiv Halasyamani, Robin J. Francis, Susan M. Walker, Dermot O’Hare

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New Layered Uranium(VI) Molybdates: Syntheses and Structures of (NH3(CH2)3NH3)(H3O)2(UO2)3(MoO4)5, C(NH2)3(UO2)(OH)(MoO4), (C4H12N2)(UO2)(MoO4)2, and (C5H14N2)(UO2)(MoO4)2·H2OOriginalThe First Open Framework Actinide Material (C4N2H12)U2O4F6 (MUF-1)80From Molecules to Frameworks: Variable Dimensionality in the UO2(CH3COO)2·2H2O/HF(aq)/Piperazine System. Syntheses, Structures, and Characterization of Zero-Dimensional (C4N2H12)UO2F4·3H2O, One-Dimensional (C4N2H12)2U2F12·H2O, Two-Dimensional (C4N2H12)2(U2O4F5)4·11H2O, and Three-Dimensional (C4N2H12)U2O4F679Hydrothermal Synthesis of (C6N2H14)2(UVI2UIVO4F12), a Mixed-Valent One-Dimensional Uranium Oxyfluoride63Ligand Influences on the Structures of Molybdenum Oxide Networks126Hydrothermal Syntheses of Layered Uranium Oxyfluorides: Illustrations of Dimensional Reduction43Hydrothermal Syntheses, Structures, and Fluorescence Spectroscopy of New One-Dimensional Uranium Oxyfluorides Built from Edge-Sharing [UO2F5] Pentagonal Bipyramids78Hydrothermal Synthesis, Structure, and Magnetic Properties of a Layered Organically Templated Uranium Aquofluoride: [C5H14N2][U2F10(H2O)]44Synthesis and Crystal Structure of Ammonium Dimolybdatouranylate Monohydrate (NH4)2[UO2(MoO4)2] · H2O20Structural Relationships, Interconversion, and Optical Properties of the Uranyl Iodates, UO2(IO3)2and UO2(IO3)2(H2O): A Comparison of Reactions under Mild and Supercritical Conditions115Hydrothermal Syntheses, Structures, and Magnetic Properties of the U(IV) Fluorides (C5H14N2)2U2F12·5H2O and (NH4)7U6F3143Organically Templated Zirconium Fluorides: Hydrothermal Syntheses, Structural Relationships, and Thermal Behavior of (C2H10N2)Zr2F10·H2O and (C4H12N2)ZrF6·H2O22Excision of Uranium Oxide Chains and Ribbons in the Novel One-Dimensional Uranyl Iodates K2[(UO2)3(IO3)4O2] and Ba[(UO2)2(IO3)2O2](H2O)73A New Oxoanion: [IO4]3-Containing I(V) with a Stereochemically Active Lone-Pair in the Silver Uranyl Iodate Tetraoxoiodate(V), Ag4(UO2)4(IO3)2(IO4)2O282Hydrothermal synthesis of the first organically templated open-framework uranium phosphate66Cation Effects on the Formation of the One-Dimensional Uranyl Iodates A2[(UO2)3(IO3)4O2] (A=K, Rb, Tl) and AE[(UO2)2(IO3)2O2] (H2O) (AE=Sr, Ba, Pb)53Syntheses and Crystal Structures of Two Topologically Related Modifications of Cs2[(UO2)2(MoO4)3]94[NC 4 H 12 ] 2 [(UO 2 ) 6 (H 2 O) 2 (SO 4 ) 7 ]: the first organically templated actinide sulfate with a three-dimensional framework structure102The first organically templated thorium compounds, [C 4 N 2 H 12 ] 0.5 [ThF 5 ] and [C 5 N 2 H 14 ][ThF 6 ]·0.5H 2 O29CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. V. TOPOLOGICALLY DISTINCT URANYL DIMOLYBDATE SHEETS IN THE STRUCTURES OF Na2[(UO2)(MoO4)2] AND K2[(UO2)(MoO4)2](H2O)65Organically templated uranium(vi) sulfates: understanding phase stability using composition space83Synthesis of Cyclical Diamine Templated Uranium Sulfates103Combinatorial topology of uranyl molybdate sheets: syntheses and crystal structures of (C6H14N2)3[(UO2)5(MoO4)8](H2O)4 and (C2H10N2)[(UO2)(MoO4)2]68Incorporation of uranium( vi ) into metal–organic framework solids, [UO 2 (C 4 H 4 O 4 )]·H 2 O, [UO 2 F(C 5 H 6 O 4 )]·2H 2 O, and [(UO 2 ) 1.5 (C 8 H 4 O 4 ) 2 ] 2 [(CH 3 ) 2 NCOH 2 ]·H 2 O98Structural diversity in organically templated uranium sulfatesElectronic supplementary information (ESI) available: three-dimensional packing diagrams for USO-6–USO-10. See http://www.rsc.org/suppdata/dt/b2/b209208e/97Reactant-Mediated Diversity in Uranyl Phosphonates58Hydrothermal Preparation of Nickel(II)/Uranium(IV) Fluorides with One-, Two-, and Three-Dimensional Topologies17Variable Dimensionality in the UO2(CH3CO2)2·2H2O/HF/Isonicotinic Acid System: Synthesis and Structures of Zero-, One-, and Two-Dimensional Uranium Isonicotinates56Synthesis and crystal structure of two new uranyl oxychloro-vanadate layered compounds: M7(UO2)8(VO4)2O8Cl with M=Rb, Cs27CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. VIII. CRYSTAL STRUCTURES OF Na3Tl3[(UO2)(MoO4)4], Na13-xTl3+x[(UO2)(MoO4)3]4(H2O)6+x (x = 0.1), Na3Tl5[(UO2)(MoO4)3]2(H2O)3 AND Na2[(UO2)(MoO4)2](H2O)463The effects of linear diamine chain length in uranium sulfates48The First Sodium Uranyl Chromate, Na4[(UO2)(CrO4)3]: Synthesis and Crystal Structure Determination39Exploration of Composition Space in Templated Uranium Sulfates89Topological Evolution in Uranyl Dicarboxylates: Synthesis and Structures of One-Dimensional UO2(C6H8O4)(H2O)2 and Three-Dimensional UO2(C6H8O4)130Oxygen and nitrogen Lewis base adducts of [UO2(OTf)2]. Crystal structures of polypyridine complexes with out-of-plane uranyl equatorial coordination81The effects of hydrofluoric acid addition on the hydrothermal synthesis of templated uranium sulfates46[N2C6H14]2[(UO2)6(H2O)2F2(PO4)2(HPO4)4]·4H2O: A New Microporous Uranium Phosphate Fluoride50Structures and syntheses of layered and framework amine-bearing uranyl phosphate and uranyl arsenates40Combinatorial topology of salts of inorganic oxoacids: zero-, one- and two-dimensional units with corner-sharing between coordination polyhedra103Molecular structure of the uranyl mineral andersonite—a Raman spectroscopic study70Comparative study of the flexibility of structural complexes in uranyl sulfates, chromates, and molybdates28Synthesis and crystal structure of Cu2{(UO2)3[(S,Cr)O4]5}(H2O)179Molecular structure of the uranyl mineral uranopilite—a Raman spectroscopic study52Synthesis and Crystal Structures of α‐ and β‐Mg2[(UO2)3(SeO4)5](H2O)1639Chiral open-framework uranyl molybdates. 1. Topological diversity: synthesis and crystal structure of [(C2H5)2NH2]2[(UO2)4(MoO4)5(H2O)](H2O)53Selective complexation of uranium( iii ) over lanthanide( iii ) triflates by 2,2′:6′,2″-terpyridine. X-Ray crystal structures of [M(OTf) 3 (terpy) 2 ] and [M(OTf) 2 (terpy) 2 (py)][OTf] (M = Nd, Ce, U) and of polynuclear µ-oxo uranium( iv ) complexes resulting from hydrolysis42Synthesis and crystal structures of M2[(UO2)3(SeO4)5](H2O)16 (M=Co, Zn)28Structural variation in organically templated uranium sulfate fluorides42Highly Porous Uranyl Selenate Nanotubules170Development of an environmentally friendly protective coating for the depleted uranium-0.75wt.% titanium alloy15The Role of Amine Sulfates in Hydrothermal Uranium Chemistry63Study of the NpO2+2-H2O-CrO2−4 System. The Synthesis, Crystal Structure, and Properties of the Neptunium(VI) Chromate [(NpO2)(CrO4)(H2O)] ⋅ 4H2O4[N(CH3)4][(UO2)2F5]: A new organically templated open-framework uranium oxide fluoride (MUF-2)38Development of an environmentally friendly protective coating for the depleted uranium–0.75wt.% titanium alloy8One-dimensional chains in uranyl tungstates: Syntheses and structures of A8[(UO2)4(WO4)4(WO5)2] (A=Rb, Cs) and Rb6[(UO2)2O(WO4)4]28An XRD, SEM and TG study of a uranopilite from Australia6Crystal Engineering with the Uranyl Cation II. Mixed Aliphatic Carboxylate/Aromatic Pyridyl Coordination Polymers: Synthesis, Crystal Structures, and Sensitized Luminescence163Hydrothermal synthesis, crystal structure, and characterization of a new pseudo-two-dimensional uranyl oxyfluoride, [N(C2H5)4]2[(UO2)4(OH2)3F10]17New Layered Uranium Phosphate Fluorides: Syntheses, Structures, Characterizations, and Ion-Exchange Properties of A(UO2)F(HPO4)·xH2O (A = Cs+, Rb+, K+; x = 0−1)88Hydrothermal synthesis, structure and thermal stability of diamine templated layered uranyl-vanadates23[(CH3)2NH(CH2)2NH(CH3)2][(UO2)2F2(HPO4)2]: a new organically templated layered uranium phosphate fluoride - synthesis, structure, characterization, and ion-exchange reactions9Actinide compounds containing hexavalent cations of the VI group elements (S, Se, Mo, Cr, W)26Synthesis and property of three novel organically templated layered cerium materials6An organic–inorganic hybrid uranyl nicotinate molybdate polymer and its fluorescent property16Novel two-dimensional uranyl–organic assemblages in the citrate and d (–)-citramalate families46Energetic N,N,N′,N′‐Tetraaminopiperazinium Salts21Two novel uranyl–organic frameworks with cyclohexane-1,3-dicarboxylate ligands40Alternative approaches to structure description1Anion-topology approach0Basic concepts3Copyright Page0Dedication0Dimensional reduction in inorganic oxysalts0Graph theory applied to low-dimensional structural units in inorganic oxysalts2Preface0Structural Crystallography of Inorganic Oxysalts127Topology of framework structures in inorganic oxysalts0Oxo ligand functionalization in the uranyl ion (UO22+)335A new series of pillared uranyl-vanadates based on uranophane-type sheets in the uranium-vanadium-linear alkyl diamine systems28Uranyl selenates with organic templates: Principles of structure and characteristics of self-organization23Hydrothermal Synthesis and Crystal Structures of Actinide Compounds2Synthesis and structure of Cs[UO2(SeO4)(OH)] · nH2O (n = 1.5 or 1)6Actinyl Compounds with Hexavalent Elements (S, Cr, Se, Mo) – Structural Diversity, Nanoscale Chemistry, and Cellular Automata Modeling69New three-dimensional inorganic frameworks based on the uranophane-type sheet in monoamine templated uranyl-vanadates28A congruently melting and deep UV nonlinear optical material: Li3Cs2B5O10104Li4Cs3B7O14: Synthesis, Crystal Structure, and Optical Properties84A New Lithium Rubidium Borate Li6Rb5B11O22 with Isolated B11O22 Building Blocks72Growth, thermal and optical properties of a novel nonlinear optical material K 3 B 6 O 10 Cl57Synthesis and characterization of uranyl chromate sheet compounds containing edge-sharing dimers of uranyl pentagonal bipyramids19A new congruent-melting oxyborate, Pb 4 O(BO 3 ) 2 with optimally aligned BO 3 triangles adopting layered-type arrangement112Mixed-ligand coordination of the (UO2)2+ cation and apophyllite topology of uranyl chlorochromate layer in the structure of ((CH3)2CHNH3)[(UO2)(CrO4)Cl(H2O)]18A novel deep UV nonlinear optical crystal Ba3B6O11F2, with a new fundamental building block, B6O14 group180Amine-templated polymeric Mg formates: crystalline scaffolds exhibiting extensive hydrogen bonding48Unprecedented layer topology in the crystal structure of a new organically templated uranyl selenite-selenate19UV Nonlinear Optical Crystal Ba2[B6O9(OH)4] Featuring Unique Chiral Layers with a New B18O42 Circle Based on BO3 and BO4 Units97Isopropylammonium Layered Uranyl Chromates: Syntheses and Crystal Structures of [(CH3)2CHNH3]3[(UO2)3(CrO4)2O(OH)3] and[(CH3)2CHNH3]2[(UO2)2(CrO4)3(H2O)]30Systematic Evolution from Uranyl(VI) Phosphites to Uranium(IV) Phosphates43Structural Versatility of Uranyl(VI) Nitrate Complexes That Involve the Diamide Ligand Et2N(C=O)(CH2)n(C=O)NEt2 (0 ≤ n ≤ 6)29Synthesis, Crystal Structure, and Properties of a New Lead Barium Borate, Pb1.13Ba7.87B18O3610Amine templating effect absent in uranyl sulfates synthesized with 1,4-n-butyldiamine14Electronic structure and optical properties of the nonlinear optical crystal Pb4O(BO3)2 by first-principles calculations10From 1D Chain to 3D Framework Uranyl Diphosphonates: Syntheses, Crystal Structures, and Selective Ion Exchange82Crystal structure and formula revision of deliensite, Fe[(UO2)2(SO4)2(OH)2](H2O)717Crystal Chemistry of Uranium Oxides and Minerals27(H2en)0.5[BiO(OH)2(H2O)]: The first organic templated layered bismuthate5Syntheses, Structures, and Comparisons of Thallium Uranium Phosphites, Mixed Phosphate-Phosphites, and Phosphate22First Organic–Inorganic Uranyl Chloroselenate: Synthesis, Crystal Structure and Spectroscopic Characteristics2New fluorochromatouranylates of alkali metals: Synthesis and structure6From Two-Dimensional Layers to Three-Dimensional Frameworks: Expanding the Structural Diversity of Uranyl Compounds by Cation–Cation Interactions21A facile and accurate preparation of pure UMoO6 and a crystallographic study of a Na–U-Mo–O intermediate5Dehydration-driven evolution of topological complexity in ethylamonium uranyl selenates18Uranyl Sulfate Nanotubules Templated by N-phenylglycine16Specific Features of the Crystal Chemistry of Layered Uranyl Compounds with the Ratio UO2: TO4 = 5 : 8 (T = S6+, Cr6+, Se6+, Mo6+)9Synthesis and Crystal Structures of New Layered Uranyl Compounds Containing Dimers [(UO2)2O8] of Edge-Linked Pentagonal Bipyramids7Preparation and Crystal Structure of a New Uranyl Sulfate Templated by a Bis‐isothiouronium Cation1Organically Templated Layered Uranyl Molybdate [C3H9NH+]4[(UO2)3(MoO4)5] Structurally Based on Mineral-Related Modular Units6Mixed-Valence NpV/AnVI Molybdate Complexes with Single-Charge Outer-Sphere Cations2Crystal Chemistry and Structural Complexity of the Uranyl Molybdate Minerals and Synthetic Compounds9Results of 25-Year Studies of Uranium Compounds at the Department of Crystallography of St. Petersburg State University3Modular approach to the crystal structure of uranyl molybdates0Molybdate Complexes of An(VI) with Li + , Na + , and Ag + Outer-Sphere Cations: Electronic Absorption Spectra of Np(VI) and Pu(VI) Molybdate Complexes in Solid State and in Solutions0

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  2. From Molecules to Frameworks: Variable Dimensionality in the UO2(CH3COO)2·2H2O/HF(aq)/Piperazine System. Syntheses, Structures, and Characterization of Zero-Dimensional (C4N2H12)UO2F4·3H2O, One-Dimensional (C4N2H12)2U2F12·H2O, Two-Dimensional (C4N2H12)2(U2O4F5)4·11H2O, and Three-Dimensional (C4N2H12)U2O4F6

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  3. Hydrothermal Synthesis of (C6N2H14)2(UVI2UIVO4F12), a Mixed-Valent One-Dimensional Uranium Oxyfluoride

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  6. Hydrothermal Syntheses, Structures, and Fluorescence Spectroscopy of New One-Dimensional Uranium Oxyfluorides Built from Edge-Sharing [UO2F5] Pentagonal Bipyramids

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  11. Organically Templated Zirconium Fluorides: Hydrothermal Syntheses, Structural Relationships, and Thermal Behavior of (C2H10N2)Zr2F10·H2O and (C4H12N2)ZrF6·H2O

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  12. Excision of Uranium Oxide Chains and Ribbons in the Novel One-Dimensional Uranyl Iodates K2[(UO2)3(IO3)4O2] and Ba[(UO2)2(IO3)2O2](H2O)

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  13. A New Oxoanion: [IO4]3-Containing I(V) with a Stereochemically Active Lone-Pair in the Silver Uranyl Iodate Tetraoxoiodate(V), Ag4(UO2)4(IO3)2(IO4)2O2

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  15. Cation Effects on the Formation of the One-Dimensional Uranyl Iodates A2[(UO2)3(IO3)4O2] (A=K, Rb, Tl) and AE[(UO2)2(IO3)2O2] (H2O) (AE=Sr, Ba, Pb)

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  16. Syntheses and Crystal Structures of Two Topologically Related Modifications of Cs2[(UO2)2(MoO4)3]

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  19. CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. V. TOPOLOGICALLY DISTINCT URANYL DIMOLYBDATE SHEETS IN THE STRUCTURES OF Na2[(UO2)(MoO4)2] AND K2[(UO2)(MoO4)2](H2O)

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  22. Combinatorial topology of uranyl molybdate sheets: syntheses and crystal structures of (C6H14N2)3[(UO2)5(MoO4)8](H2O)4 and (C2H10N2)[(UO2)(MoO4)2]

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  23. Incorporation of uranium( vi ) into metal–organic framework solids, [UO 2 (C 4 H 4 O 4 )]·H 2 O, [UO 2 F(C 5 H 6 O 4 )]·2H 2 O, and [(UO 2 ) 1.5 (C 8 H 4 O 4 ) 2 ] 2 [(CH 3 ) 2 NCOH 2 ]·H 2 O

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  24. Structural diversity in organically templated uranium sulfatesElectronic supplementary information (ESI) available: three-dimensional packing diagrams for USO-6–USO-10. See http://www.rsc.org/suppdata/dt/b2/b209208e/

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  26. Hydrothermal Preparation of Nickel(II)/Uranium(IV) Fluorides with One-, Two-, and Three-Dimensional Topologies

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  27. Variable Dimensionality in the UO2(CH3CO2)2·2H2O/HF/Isonicotinic Acid System: Synthesis and Structures of Zero-, One-, and Two-Dimensional Uranium Isonicotinates

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  28. Synthesis and crystal structure of two new uranyl oxychloro-vanadate layered compounds: M7(UO2)8(VO4)2O8Cl with M=Rb, Cs

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  29. CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. VIII. CRYSTAL STRUCTURES OF Na3Tl3[(UO2)(MoO4)4], Na13-xTl3+x[(UO2)(MoO4)3]4(H2O)6+x (x = 0.1), Na3Tl5[(UO2)(MoO4)3]2(H2O)3 AND Na2[(UO2)(MoO4)2](H2O)4

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  30. The effects of linear diamine chain length in uranium sulfates

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  31. The First Sodium Uranyl Chromate, Na4[(UO2)(CrO4)3]: Synthesis and Crystal Structure Determination

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  32. Exploration of Composition Space in Templated Uranium Sulfates

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  33. Topological Evolution in Uranyl Dicarboxylates: Synthesis and Structures of One-Dimensional UO2(C6H8O4)(H2O)2 and Three-Dimensional UO2(C6H8O4)

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  34. Oxygen and nitrogen Lewis base adducts of [UO2(OTf)2]. Crystal structures of polypyridine complexes with out-of-plane uranyl equatorial coordination

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  35. The effects of hydrofluoric acid addition on the hydrothermal synthesis of templated uranium sulfates

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    M.B. Doran, Ben E. Cockbain, Alexander J. Norquist, Dermot O’Hare

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  36. [N2C6H14]2[(UO2)6(H2O)2F2(PO4)2(HPO4)4]·4H2O: A New Microporous Uranium Phosphate Fluoride

    Chemistry of Materials · 2004-01-30

    M.B. Doran, Clair L. Stuart, Alexander J. Norquist, Dermot O’Hare

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  37. Structures and syntheses of layered and framework amine-bearing uranyl phosphate and uranyl arsenates

    Journal of Solid State Chemistry · 2004-06-21

    Andrew J. Locock, Peter Carman Burns

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  38. Combinatorial topology of salts of inorganic oxoacids: zero-, one- and two-dimensional units with corner-sharing between coordination polyhedra

    Crystallography Reviews · 2004-07-01

    Sergey V. Krivovichev

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  39. Molecular structure of the uranyl mineral andersonite—a Raman spectroscopic study

    Journal of Molecular Structure · 2004-07-06

    Ray L. Frost, Onuma Carmody, Kristy L. Erickson, Matt L. Weier, Jiřı́ Čejka

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  40. Comparative study of the flexibility of structural complexes in uranyl sulfates, chromates, and molybdates

    Radiochemistry · 2004-09-01

    Sergey V. Krivovichev

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  41. Synthesis and crystal structure of Cu2{(UO2)3[(S,Cr)O4]5}(H2O)17

    Radiochemistry · 2004-09-01

    Sergey V. Krivovichev, Peter Carman Burns

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  42. Molecular structure of the uranyl mineral uranopilite—a Raman spectroscopic study

    Journal of Molecular Structure · 2004-10-21

    Ray L. Frost, Onuma Carmody, Kristy L. Erickson, Matt L. Weier, Dermot O. Henry, Jirí Čejka

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  43. Synthesis and Crystal Structures of α‐ and β‐Mg2[(UO2)3(SeO4)5](H2O)16

    Zeitschrift für anorganische und allgemeine Chemie · 2004-12-01

    Sergey V. Krivovichev, Volker Kahlenberg

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  44. Chiral open-framework uranyl molybdates. 1. Topological diversity: synthesis and crystal structure of [(C2H5)2NH2]2[(UO2)4(MoO4)5(H2O)](H2O)

    Microporous and Mesoporous Materials · 2004-12-16

    Sergey V. Krivovichev, Christopher L. Cahill, Еvgeny V. Nazarchuk, Peter Carman Burns, Thomas Armbruster, Wulf Depmeier

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  45. Selective complexation of uranium( iii ) over lanthanide( iii ) triflates by 2,2′:6′,2″-terpyridine. X-Ray crystal structures of [M(OTf) 3 (terpy) 2 ] and [M(OTf) 2 (terpy) 2 (py)][OTf] (M = Nd, Ce, U) and of polynuclear µ-oxo uranium( iv ) complexes resulting from hydrolysis

    Dalton Transactions · 2004-12-22

    J.‐C. Berthet, M. Nierlich, Yannick Miquel, Charles Madic, M. Ephritikhine

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  46. Synthesis and crystal structures of M2[(UO2)3(SeO4)5](H2O)16 (M=Co, Zn)

    Journal of Alloys and Compounds · 2004-12-31

    Sergey V. Krivovichev, Volker Kahlenberg

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  47. Structural variation in organically templated uranium sulfate fluorides

    Dalton Transactions · 2005-01-01

    M.B. Doran, Ben E. Cockbain, Dermot O’Hare

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  48. Highly Porous Uranyl Selenate Nanotubules

    Journal of the American Chemical Society · 2005-01-06

    Sergey V. Krivovichev, Volker Kahlenberg, Ivan Gundarovich Tananaev, Reinhard Kaindl, Edgar Mersdorf, Boris F. Myasoedov

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  49. Development of an environmentally friendly protective coating for the depleted uranium-0.75wt.% titanium alloy

    Electrochimica Acta · 2005-02-17

    Donald F. Roeper, Devicharan Chidambaram, Clive R. Clayton, Gary P. Halada

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  50. The Role of Amine Sulfates in Hydrothermal Uranium Chemistry

    Inorganic Chemistry · 2005-05-01

    Alexander J. Norquist, M.B. Doran, Dermot O’Hare

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