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RESEARCH PAPER · Inorganic Chemistry · 2001

Syntheses and Crystal Structures of Two Topologically Related Modifications of Cs2[(UO2)2(MoO4)3]

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Syntheses and Crystal Structures of Two Topologically Related Modifications of Cs2[(UO2)2(MoO4)3]OriginalDirect Investigation of the Immobilization of Radionuclides in the Alteration Phases of Spent Nuclear Fuel122 New compounds and structures in the solid state2CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. VI. NEW URANYL MOLYBDATE UNITS IN THE STRUCTURES OF Cs4[(UO2)3O(MoO4)2(MoO5)] AND Cs6[(UO2)(MoO4)4]59ChemInform Abstract: Syntheses and Crystal Structures of Two Topologically Related Modifications of Cs2[(UO2)2(MoO4)3].1Crystal Structures of Three Framework Alkali Metal Uranyl Phosphate Hydrates65Crystal Chemistry of Rubidium Uranyl Molybdates: Crystal Structures of Rb6[(UO2)(MoO4)4], Rb6[(UO2)2O(MoO4)4], Rb2[(UO2)(MoO4)2], Rb2[(UO2)2(MoO4)3] and Rb2[(UO2)6(MoO4)7(H2O)2]70CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. VII. AN IRIGINITE-TYPE SHEET OF POLYHEDRA IN THE STRUCTURE OF [(UO2)Mo2O7(H2O)2]2621 New compounds and structures in the solid state1Advances in Understanding of the Crystal Chemistry of Hexavalent Uranium2Combinatorial topology of uranyl molybdate sheets: syntheses and crystal structures of (C6H14N2)3[(UO2)5(MoO4)8](H2O)4 and (C2H10N2)[(UO2)(MoO4)2]68Synthesis and crystal structure of Li2[(UO2)(MoO4)2], a uranyl molybdate with chains of corner-sharing uranyl square bipyramids and MoO4 tetrahedra40Hydrothermal Preparation of Nickel(II)/Uranium(IV) Fluorides with One-, Two-, and Three-Dimensional Topologies17CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. VIII. CRYSTAL STRUCTURES OF Na3Tl3[(UO2)(MoO4)4], Na13-xTl3+x[(UO2)(MoO4)3]4(H2O)6+x (x = 0.1), Na3Tl5[(UO2)(MoO4)3]2(H2O)3 AND Na2[(UO2)(MoO4)2](H2O)463Synthesis, crystal structure and electrical characterization of two new potassium uranyl molybdates K2(UO2)2(MoO4)O2 and K8(UO2)8(MoO5)3O642Geometrical isomerism in uranyl chromates I. Crystal structures of (UO2)(CrO4)(H2O)2, [(UO2)(CrO4)(H2O)2](H2O) and [(UO2)(CrO4)(H2O)2]4(H2O)954Structures and synthesis of framework Rb and Cs uranyl arsenates and their relationships with their phosphate analogues31CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. IX. A NOVEL URANYL MOLYBDATE SHEET IN THE STRUCTURE OF Tl2[(UO2)2O(MoO5)]16The First Sodium Uranyl Chromate, Na4[(UO2)(CrO4)3]: Synthesis and Crystal Structure Determination39Structures and syntheses of framework triuranyl diarsenate hydrates45CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. X. THE CRYSTAL STRUCTURE OF Ag10[(UO2)8O8(Mo5O20)]15Hydrothermal synthesis and structure of K6[(UO2)4(CrO4)7]·6H2O: A layered uranyl chromate with a new uranyl sheet topology30Cation−Cation Interactions between Uranyl Cations in a Polar Open-Framework Uranyl Periodate136Two new lithium uranyl tungstates Li2(UO2)(WO4)2 and Li2(UO2)4(WO4)4O with framework based on the uranophane sheet anion topology32Structures and syntheses of layered and framework amine-bearing uranyl phosphate and uranyl arsenates40Combinatorial topology of salts of inorganic oxoacids: zero-, one- and two-dimensional units with corner-sharing between coordination polyhedra103Comparative study of the flexibility of structural complexes in uranyl sulfates, chromates, and molybdates28Phase transitions and high-temperature crystal chemistry of polymorphous modifications of Cs2(UO2)2(MoO4)25Synthesis and crystal structure of Cu2{(UO2)3[(S,Cr)O4]5}(H2O)179Synthesis and Crystal Structures of α‐ and β‐Mg2[(UO2)3(SeO4)5](H2O)1639Chiral open-framework uranyl molybdates. 1. Topological diversity: synthesis and crystal structure of [(C2H5)2NH2]2[(UO2)4(MoO4)5(H2O)](H2O)53Synthesis and crystal structures of M2[(UO2)3(SeO4)5](H2O)16 (M=Co, Zn)28Lone electron pair stereoactivity, cation arrangements and distortion of heteropolyhedral sheets in the structures of Tl2[(UO2)(AO4)2] (A = Cr, Mo)34Nanoscale Tubules in Uranyl Selenates122Nanoscale Tubules in Uranyl Selenates144CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. XI. CRYSTAL STRUCTURES OF Cs2[(UO2)(MoO4)2] AND Cs2[(UO2)(MoO4)2](H2O)33Crystal Structure of Tl2[(UO2)2(MoO4)3] and Crystal Chemistry of the Compounds M2[(UO2)2(MoO4)3] (M = Tl, Rb, Cs)15Hydrothermal synthesis and crystal structures of new uranyl oxalate hydroxides: α- and β-[(UO2)2(C2O4)(OH)2(H2O)2] and [(UO2)2(C2O4)(OH)2(H2O)2]·H2O37U6+ MINERALS AND INORGANIC COMPOUNDS: INSIGHTS INTO AN EXPANDED STRUCTURAL HIERARCHY OF CRYSTAL STRUCTURES627[N(CH3)4][(UO2)2F5]: A new organically templated open-framework uranium oxide fluoride (MUF-2)38The A1−xUNbO6−x/2 compounds (x=0, A=Li, Na, K, Cs and x=0.5, A=Rb, Cs): from layered to tunneled structure15Actinide compounds containing hexavalent cations of the VI group elements (S, Se, Mo, Cr, W)26Crystal chemistry of uranium oxocompounds: an overview21An organic–inorganic hybrid uranyl nicotinate molybdate polymer and its fluorescent property16Dimensional Reduction in Alkali Metal Uranyl Molybdates: Synthesis and Structure of Cs2[(UO2)O(MoO4)]32Synthesis, Structure, and Infrared Spectroscopy of the First Np5+ Neptunyl Silicates, Li6(NpO2)4(H2Si2O7)(HSiO4)2(H2O)4 and K3(NpO2)3(Si2O7)19THE STEREOCHEMISTRY AND CHEMICAL COMPOSITION OF INTERSTITIAL COMPLEXES IN URANYL-OXYSALT MINERALS75NEPTUNYL COMPOUNDS: POLYHEDRON GEOMETRIES, BOND-VALENCE PARAMETERS, AND STRUCTURAL HIERARCHY77Alternative approaches to structure description1Anion-topology approach0Basic concepts3Copyright Page0Dedication0Dimensional reduction in inorganic oxysalts0Graph theory applied to low-dimensional structural units in inorganic oxysalts2Preface0Structural Crystallography of Inorganic Oxysalts127Topology of framework structures in inorganic oxysalts0[Hg5O2(OH)4][(UO2)2(AsO4)2]: A complex mercury(II) uranyl arsenate6Does Iodate Incorporate into Layered Uranyl Phosphates Under Hydrothermal Conditions?18Uranyl selenates with organic templates: Principles of structure and characteristics of self-organization23Crystal and molecular structure of a crystal solvate of cesium tris(pivaloyltrifluoroacetonato)dioxouranate, Cs[UO2(Bu t COCHCOCF3)3]·1.5C6H6·H2O2Uranium surroundings in borosilicate glass from neutron and x-ray diffraction and RMC modelling14Synthesis and Research of Uranium Minerals That Form in the Disposals of Waste Radioactive Products and Under Natural Conditions0From ∞1[(UO2)2O(MoO4)4]6− to ∞1[(UO2)2(MoO4)3(MoO5)]6− infinite chains in A6U2Mo4O21 (A=Na, K, Rb, Cs) compounds: Synthesis and crystal structure of Cs6[(UO2)2(MoO4)3(MoO5)]9Polymorphism in Alkali Metal Uranyl Nitrates: Synthesis and Crystal Structure of γ‐K(UO2)(NO3)316In-Situ Raman Spectroscopy Studies of Room-Temperature and Hydrothermal Reactions1Structural topology and dimensional reduction in uranyl oxysalts: eight novel phases in the methylamine–(UO2)(NO3)2–H2SeO4–H2O system24Crystal Chemistry of Uranium Oxides and Minerals27CrVI→CrV Transition in Uranyl Chromium Compounds: Synthesis and High‐temperature X‐ray Diffraction Study of Cs2[(UO2)2(CrO4)3]24Structure study of new uranium loaded borosilicate glasses15Unexpected Structural Complexity in Cesium Thorium Molybdates18Single crystal growth and structural characterization of ternary transition-metal uranium oxides: MnUO4, FeUO4, and NiU2O617pH Controlled Pathway and Systematic Hydrothermal Phase Diagram for Elaboration of Synthetic Lead Nickel Selenites18A2MnU3O11 (A = K, Rb) and Li3.2Mn1.8U6O22: Three New Alkali-Metal Manganese Uranium(VI) Oxides Related to Natrotantite11The structural effects of alkaline- and rare-earth element incorporation into thorium molybdates8Giant Volume Change and Topological Gaps in Temperature‐ and Pressure‐Induced Phase Transitions: Experimental and Computational Study of ThMo2O811A Revised and Expanded Structure Hierarchy of Natural and Synthetic Hexavalent Uranium Compounds172Synthesis and crystal structure of Ag2[(UO2)6(MoO4)7(H2O)2](H2O)25Synthesis and crystal structure of β-CuSe2O5, a new polymorph of copper diselenite8Selective Se-for-S substitution in Cs-bearing uranyl compounds19Microporous uranyl chromates successively formed by evaporation from acidic solution9Unexpected Behavior of Np in Oxo-selenate/Oxo-selenite Systems9Flux crystal growth: a versatile technique to reveal the crystal chemistry of complex uranium oxides49A Novel Family of Np(VI) Oxysalts: Crystal Structures, Calorimetry, Thermal Behavior, and Comparison with U(VI) Compounds9Chemically induced symmetry breaking in the crystal structure of guanidinium uranyl sulfate10Chemically-induced structural variations of a family of Cs2[(AnO2)2(TO4)3] (An = U, Np; T = S, Se, Cr, Mo) compounds: Thermal behavior, calorimetry studies and spectroscopy characterization of Cs uranyl sulfate and selenate7Extreme condition high temperature and high pressure studies of the K–U–Mo–O system7Successive Crystallization of Organically Templated Uranyl Sulfates: Synthesis and Crystal Structures of [pyH](H3O)[(UO2)3(SO4)4(H2O)2], [pyH]2[(UO2)6(SO4)7(H2O)], and [pyH]2[(UO2)2(SO4)3]3The Role of Acidity in the Synthesis of Novel Uranyl Selenate and Selenite Compounds and Their Structures2Crystal Chemistry and Structural Complexity of the Uranyl Molybdate Minerals and Synthetic Compounds9Trivalent Cations Slow Electron Transfer to Macrocyclic Heterobimetallic Complexes13Results of 25-Year Studies of Uranium Compounds at the Department of Crystallography of St. Petersburg State University3Modular approach to the crystal structure of uranyl molybdates0Molybdate Complexes of An(VI) with Li + , Na + , and Ag + Outer-Sphere Cations: Electronic Absorption Spectra of Np(VI) and Pu(VI) Molybdate Complexes in Solid State and in Solutions0

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  1. Direct Investigation of the Immobilization of Radionuclides in the Alteration Phases of Spent Nuclear Fuel

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  2. 22 New compounds and structures in the solid state

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  3. CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. VI. NEW URANYL MOLYBDATE UNITS IN THE STRUCTURES OF Cs4[(UO2)3O(MoO4)2(MoO5)] AND Cs6[(UO2)(MoO4)4]

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  4. ChemInform Abstract: Syntheses and Crystal Structures of Two Topologically Related Modifications of Cs2[(UO2)2(MoO4)3].

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  5. Crystal Structures of Three Framework Alkali Metal Uranyl Phosphate Hydrates

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  6. Crystal Chemistry of Rubidium Uranyl Molybdates: Crystal Structures of Rb6[(UO2)(MoO4)4], Rb6[(UO2)2O(MoO4)4], Rb2[(UO2)(MoO4)2], Rb2[(UO2)2(MoO4)3] and Rb2[(UO2)6(MoO4)7(H2O)2]

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  7. CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. VII. AN IRIGINITE-TYPE SHEET OF POLYHEDRA IN THE STRUCTURE OF [(UO2)Mo2O7(H2O)2]

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  8. 21 New compounds and structures in the solid state

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  9. Advances in Understanding of the Crystal Chemistry of Hexavalent Uranium

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  10. Combinatorial topology of uranyl molybdate sheets: syntheses and crystal structures of (C6H14N2)3[(UO2)5(MoO4)8](H2O)4 and (C2H10N2)[(UO2)(MoO4)2]

    Journal of Solid State Chemistry · 2003-01-01

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  11. Synthesis and crystal structure of Li2[(UO2)(MoO4)2], a uranyl molybdate with chains of corner-sharing uranyl square bipyramids and MoO4 tetrahedra

    Solid State Sciences · 2003-03-01

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  12. Hydrothermal Preparation of Nickel(II)/Uranium(IV) Fluorides with One-, Two-, and Three-Dimensional Topologies

    Inorganic Chemistry · 2003-03-25

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  13. CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. VIII. CRYSTAL STRUCTURES OF Na3Tl3[(UO2)(MoO4)4], Na13-xTl3+x[(UO2)(MoO4)3]4(H2O)6+x (x = 0.1), Na3Tl5[(UO2)(MoO4)3]2(H2O)3 AND Na2[(UO2)(MoO4)2](H2O)4

    The Canadian Mineralogist · 2003-06-01

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  14. Synthesis, crystal structure and electrical characterization of two new potassium uranyl molybdates K2(UO2)2(MoO4)O2 and K8(UO2)8(MoO5)3O6

    Journal of Solid State Chemistry · 2003-06-09

    S. Obbade, S. Yagoubi, C. Dion, Mohamed Saadi, F. Abraham

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  15. Geometrical isomerism in uranyl chromates I. Crystal structures of (UO2)(CrO4)(H2O)2, [(UO2)(CrO4)(H2O)2](H2O) and [(UO2)(CrO4)(H2O)2]4(H2O)9

    Zeitschrift für Kristallographie - Crystalline Materials · 2003-08-01

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  16. Structures and synthesis of framework Rb and Cs uranyl arsenates and their relationships with their phosphate analogues

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  17. CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. IX. A NOVEL URANYL MOLYBDATE SHEET IN THE STRUCTURE OF Tl2[(UO2)2O(MoO5)]

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  18. The First Sodium Uranyl Chromate, Na4[(UO2)(CrO4)3]: Synthesis and Crystal Structure Determination

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  19. Structures and syntheses of framework triuranyl diarsenate hydrates

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    Andrew J. Locock, Peter Carman Burns

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  20. CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. X. THE CRYSTAL STRUCTURE OF Ag10[(UO2)8O8(Mo5O20)]

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  21. Hydrothermal synthesis and structure of K6[(UO2)4(CrO4)7]·6H2O: A layered uranyl chromate with a new uranyl sheet topology

    Journal of Solid State Chemistry · 2003-12-31

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  22. Cation−Cation Interactions between Uranyl Cations in a Polar Open-Framework Uranyl Periodate

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  23. Two new lithium uranyl tungstates Li2(UO2)(WO4)2 and Li2(UO2)4(WO4)4O with framework based on the uranophane sheet anion topology

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    S. Obbade, S. Yagoubi, C. Dion, Mohamed Saadi, F. Abraham

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  24. Structures and syntheses of layered and framework amine-bearing uranyl phosphate and uranyl arsenates

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  25. Combinatorial topology of salts of inorganic oxoacids: zero-, one- and two-dimensional units with corner-sharing between coordination polyhedra

    Crystallography Reviews · 2004-07-01

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  26. Comparative study of the flexibility of structural complexes in uranyl sulfates, chromates, and molybdates

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  27. Phase transitions and high-temperature crystal chemistry of polymorphous modifications of Cs2(UO2)2(MoO4)

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  28. Synthesis and crystal structure of Cu2{(UO2)3[(S,Cr)O4]5}(H2O)17

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  29. Synthesis and Crystal Structures of α‐ and β‐Mg2[(UO2)3(SeO4)5](H2O)16

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  30. Chiral open-framework uranyl molybdates. 1. Topological diversity: synthesis and crystal structure of [(C2H5)2NH2]2[(UO2)4(MoO4)5(H2O)](H2O)

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  31. Synthesis and crystal structures of M2[(UO2)3(SeO4)5](H2O)16 (M=Co, Zn)

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  32. Lone electron pair stereoactivity, cation arrangements and distortion of heteropolyhedral sheets in the structures of Tl2[(UO2)(AO4)2] (A = Cr, Mo)

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  33. Nanoscale Tubules in Uranyl Selenates

    Angewandte Chemie · 2005-01-11

    Sergey V. Krivovichev, Volker Kahlenberg, Reinhard Kaindl, Edgar Mersdorf, Ivan Gundarovich Tananaev, Boris F. Myasoedov

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  34. Nanoscale Tubules in Uranyl Selenates

    Angewandte Chemie International Edition · 2005-01-11

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  35. CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. XI. CRYSTAL STRUCTURES OF Cs2[(UO2)(MoO4)2] AND Cs2[(UO2)(MoO4)2](H2O)

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  36. Crystal Structure of Tl2[(UO2)2(MoO4)3] and Crystal Chemistry of the Compounds M2[(UO2)2(MoO4)3] (M = Tl, Rb, Cs)

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  37. Hydrothermal synthesis and crystal structures of new uranyl oxalate hydroxides: α- and β-[(UO2)2(C2O4)(OH)2(H2O)2] and [(UO2)2(C2O4)(OH)2(H2O)2]·H2O

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  38. U6+ MINERALS AND INORGANIC COMPOUNDS: INSIGHTS INTO AN EXPANDED STRUCTURAL HIERARCHY OF CRYSTAL STRUCTURES

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  39. [N(CH3)4][(UO2)2F5]: A new organically templated open-framework uranium oxide fluoride (MUF-2)

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  40. The A1−xUNbO6−x/2 compounds (x=0, A=Li, Na, K, Cs and x=0.5, A=Rb, Cs): from layered to tunneled structure

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  41. Actinide compounds containing hexavalent cations of the VI group elements (S, Se, Mo, Cr, W)

    Elsevier eBooks · 2007-01-01

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  42. Crystal chemistry of uranium oxocompounds: an overview

    Elsevier eBooks · 2007-01-01

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  43. An organic–inorganic hybrid uranyl nicotinate molybdate polymer and its fluorescent property

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  44. Dimensional Reduction in Alkali Metal Uranyl Molybdates: Synthesis and Structure of Cs2[(UO2)O(MoO4)]

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  45. Synthesis, Structure, and Infrared Spectroscopy of the First Np5+ Neptunyl Silicates, Li6(NpO2)4(H2Si2O7)(HSiO4)2(H2O)4 and K3(NpO2)3(Si2O7)

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  46. THE STEREOCHEMISTRY AND CHEMICAL COMPOSITION OF INTERSTITIAL COMPLEXES IN URANYL-OXYSALT MINERALS

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  47. NEPTUNYL COMPOUNDS: POLYHEDRON GEOMETRIES, BOND-VALENCE PARAMETERS, AND STRUCTURAL HIERARCHY

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  48. Alternative approaches to structure description

    Unknown journal · 2009-01-22

    Sergey V. Krivovichev

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  49. Anion-topology approach

    Unknown journal · 2009-01-22

    Sergey V. Krivovichev

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  50. Basic concepts

    Unknown journal · 2009-01-22

    Sergey V. Krivovichev

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