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RESEARCH PAPER · The Canadian Mineralogist · 2002

CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. V. TOPOLOGICALLY DISTINCT URANYL DIMOLYBDATE SHEETS IN THE STRUCTURES OF Na2[(UO2)(MoO4)2] AND K2[(UO2)(MoO4)2](H2O)

Sergey V. Krivovichev, Robert J. Finch, Peter Carman Burns

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CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. V. TOPOLOGICALLY DISTINCT URANYL DIMOLYBDATE SHEETS IN THE STRUCTURES OF Na2[(UO2)(MoO4)2] AND K2[(UO2)(MoO4)2](H2O)OriginalCrystal Chemistry of Rubidium Uranyl Molybdates: Crystal Structures of Rb6[(UO2)(MoO4)4], Rb6[(UO2)2O(MoO4)4], Rb2[(UO2)(MoO4)2], Rb2[(UO2)2(MoO4)3] and Rb2[(UO2)6(MoO4)7(H2O)2]70CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. VII. AN IRIGINITE-TYPE SHEET OF POLYHEDRA IN THE STRUCTURE OF [(UO2)Mo2O7(H2O)2]26Combinatorial topology of uranyl molybdate sheets: syntheses and crystal structures of (C6H14N2)3[(UO2)5(MoO4)8](H2O)4 and (C2H10N2)[(UO2)(MoO4)2]68A novel rigid uranyl tungstate sheet in the structures of Na2[(UO2)W2O8] and α- and β-Ag2[(UO2)W2O8]34Synthesis and crystal structure of Li2[(UO2)(MoO4)2], a uranyl molybdate with chains of corner-sharing uranyl square bipyramids and MoO4 tetrahedra40Hydrothermal Preparation of Nickel(II)/Uranium(IV) Fluorides with One-, Two-, and Three-Dimensional Topologies17CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. VIII. CRYSTAL STRUCTURES OF Na3Tl3[(UO2)(MoO4)4], Na13-xTl3+x[(UO2)(MoO4)3]4(H2O)6+x (x = 0.1), Na3Tl5[(UO2)(MoO4)3]2(H2O)3 AND Na2[(UO2)(MoO4)2](H2O)463Direct Investigations of the Immobilization of Radionuclides in the Alteration Phases of Spent Nuclear Fuel4Synthesis, crystal structure and electrical characterization of two new potassium uranyl molybdates K2(UO2)2(MoO4)O2 and K8(UO2)8(MoO5)3O642Geometrical isomerism in uranyl chromates I. Crystal structures of (UO2)(CrO4)(H2O)2, [(UO2)(CrO4)(H2O)2](H2O) and [(UO2)(CrO4)(H2O)2]4(H2O)954CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. IX. A NOVEL URANYL MOLYBDATE SHEET IN THE STRUCTURE OF Tl2[(UO2)2O(MoO5)]16CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. X. THE CRYSTAL STRUCTURE OF Ag10[(UO2)8O8(Mo5O20)]15Two new lithium uranyl tungstates Li2(UO2)(WO4)2 and Li2(UO2)4(WO4)4O with framework based on the uranophane sheet anion topology32Combinatorial topology of salts of inorganic oxoacids: zero-, one- and two-dimensional units with corner-sharing between coordination polyhedra103Hydrothermal synthesis and crystal structure of Cs6[(UO2)4(W5O21)(OH)2(H2O)2]: a new polar uranyl tungstate19Comparative study of the flexibility of structural complexes in uranyl sulfates, chromates, and molybdates28Direct Investigations of the Immobilization of Radionuclides in the Alteration Products of Spent Nuclear Fuel2Lone electron pair stereoactivity, cation arrangements and distortion of heteropolyhedral sheets in the structures of Tl2[(UO2)(AO4)2] (A = Cr, Mo)34CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. XI. CRYSTAL STRUCTURES OF Cs2[(UO2)(MoO4)2] AND Cs2[(UO2)(MoO4)2](H2O)33Amine‐Templated Uranyl Selenates with Layered Structures. I Structural Diversity of Sheets with a U:Se ratio of 1:239Hydrothermal synthesis and crystal structures of new uranyl oxalate hydroxides: α- and β-[(UO2)2(C2O4)(OH)2(H2O)2] and [(UO2)2(C2O4)(OH)2(H2O)2]·H2O37U6+ MINERALS AND INORGANIC COMPOUNDS: INSIGHTS INTO AN EXPANDED STRUCTURAL HIERARCHY OF CRYSTAL STRUCTURES627Thermochemistry of alkali metal uranomolybdates3One-dimensional chains in uranyl tungstates: Syntheses and structures of A8[(UO2)4(WO4)4(WO5)2] (A=Rb, Cs) and Rb6[(UO2)2O(WO4)4]28The A1−xUNbO6−x/2 compounds (x=0, A=Li, Na, K, Cs and x=0.5, A=Rb, Cs): from layered to tunneled structure15Actinide compounds containing hexavalent cations of the VI group elements (S, Se, Mo, Cr, W)26Dimensional Reduction in Alkali Metal Uranyl Molybdates: Synthesis and Structure of Cs2[(UO2)O(MoO4)]32Corrosion Behavior of SUS316 Clad in Alkalis Molybdate Melt2THE STEREOCHEMISTRY AND CHEMICAL COMPOSITION OF INTERSTITIAL COMPLEXES IN URANYL-OXYSALT MINERALS75Crystal chemistry of selenates with mineral-like structures. VI. Hydrogen bonds in the crystal structure of [(H5O2)(H3O)(H2O)][(UO2)(SeO4)2]9NEPTUNYL COMPOUNDS: POLYHEDRON GEOMETRIES, BOND-VALENCE PARAMETERS, AND STRUCTURAL HIERARCHY77Alternative approaches to structure description1Anion-topology approach0Basic concepts3Copyright Page0Dedication0Dimensional reduction in inorganic oxysalts0Graph theory applied to low-dimensional structural units in inorganic oxysalts2Preface0Structural Crystallography of Inorganic Oxysalts127Topology of framework structures in inorganic oxysalts0From ∞1[(UO2)2O(MoO4)4]6− to ∞1[(UO2)2(MoO4)3(MoO5)]6− infinite chains in A6U2Mo4O21 (A=Na, K, Rb, Cs) compounds: Synthesis and crystal structure of Cs6[(UO2)2(MoO4)3(MoO5)]9Structural topology and dimensional reduction in uranyl oxysalts: eight novel phases in the methylamine–(UO2)(NO3)2–H2SeO4–H2O system24Systematic Evolution from Uranyl(VI) Phosphites to Uranium(IV) Phosphates43Single crystal growth and structural characterization of four complex uranium oxides: CaUO4, β-Ca3UO6, K4CaU3O12, and K4SrU3O1220Crystal Chemistry of Uranium Oxides and Minerals27Syntheses, Structures, and Comparisons of Thallium Uranium Phosphites, Mixed Phosphate-Phosphites, and Phosphate22High-Temperature Phase Transitions, Spectroscopic Properties, and Dimensionality Reduction in Rubidium Thorium Molybdate Family23Solid-state actinide acid phosphites from phosphorous acid melts3Thermodynamic properties and behaviour of A2[(UO2)(MoO4)2] compounds with A= Li, Na, K, Rb, and Cs7The structure hierarchy hypothesis44Single crystal growth and structural characterization of ternary transition-metal uranium oxides: MnUO4, FeUO4, and NiU2O617A facile and accurate preparation of pure UMoO6 and a crystallographic study of a Na–U-Mo–O intermediate5The structural effects of alkaline- and rare-earth element incorporation into thorium molybdates8Synthesis and properties of actinide dimolybdate complexes M2[AnO2(MoO4)2]·H2O (M = Rb, Cs; An = Np, Pu)4Inorganic X-ray Scintillators Based on a Previously Unnoticed but Intrinsically Advantageous Metal Center17Crystal Chemistry and Structural Complexity of Natural and Synthetic Uranyl Selenites24Extreme condition high temperature and high pressure studies of the K–U–Mo–O system7Crystal Chemistry and Structural Complexity of the Uranyl Molybdate Minerals and Synthetic Compounds9Actinide Sulfate Structures from Caustic Solvents1Results of 25-Year Studies of Uranium Compounds at the Department of Crystallography of St. Petersburg State University3Modular approach to the crystal structure of uranyl molybdates0Molybdate Complexes of An(VI) with Li + , Na + , and Ag + Outer-Sphere Cations: Electronic Absorption Spectra of Np(VI) and Pu(VI) Molybdate Complexes in Solid State and in Solutions0PROCESSING OF URANIUM-SILICIDE SPENT NUCLEAR FUEL IN MOLYBDENUM MELTS0Thermodynamic and electronic properties of the solid Na 2 O − MoO 3 − UO 3 system: A combined experimental and first-principles study1

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  1. Crystal Chemistry of Rubidium Uranyl Molybdates: Crystal Structures of Rb6[(UO2)(MoO4)4], Rb6[(UO2)2O(MoO4)4], Rb2[(UO2)(MoO4)2], Rb2[(UO2)2(MoO4)3] and Rb2[(UO2)6(MoO4)7(H2O)2]

    Journal of Solid State Chemistry · 2002-10-01

    Sergey V. Krivovichev, Peter Carman Burns

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  2. CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. VII. AN IRIGINITE-TYPE SHEET OF POLYHEDRA IN THE STRUCTURE OF [(UO2)Mo2O7(H2O)2]

    The Canadian Mineralogist · 2002-12-01

    Sergey V. Krivovichev, Peter Carman Burns

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  3. Combinatorial topology of uranyl molybdate sheets: syntheses and crystal structures of (C6H14N2)3[(UO2)5(MoO4)8](H2O)4 and (C2H10N2)[(UO2)(MoO4)2]

    Journal of Solid State Chemistry · 2003-01-01

    Sergey V. Krivovichev, Peter Carman Burns

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  4. A novel rigid uranyl tungstate sheet in the structures of Na2[(UO2)W2O8] and α- and β-Ag2[(UO2)W2O8]

    Solid State Sciences · 2003-02-01

    Sergey V. Krivovichev, Peter Carman Burns

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  5. Synthesis and crystal structure of Li2[(UO2)(MoO4)2], a uranyl molybdate with chains of corner-sharing uranyl square bipyramids and MoO4 tetrahedra

    Solid State Sciences · 2003-03-01

    Sergey V. Krivovichev, Peter Carman Burns

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  6. Hydrothermal Preparation of Nickel(II)/Uranium(IV) Fluorides with One-, Two-, and Three-Dimensional Topologies

    Inorganic Chemistry · 2003-03-25

    Amanda C. Bean, Tyler A. Sullens, Wolfgang Runde, Thomas E. Albrecht‐Schmitt

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  7. CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. VIII. CRYSTAL STRUCTURES OF Na3Tl3[(UO2)(MoO4)4], Na13-xTl3+x[(UO2)(MoO4)3]4(H2O)6+x (x = 0.1), Na3Tl5[(UO2)(MoO4)3]2(H2O)3 AND Na2[(UO2)(MoO4)2](H2O)4

    The Canadian Mineralogist · 2003-06-01

    Sergey V. Krivovichev, Peter Carman Burns

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  8. Direct Investigations of the Immobilization of Radionuclides in the Alteration Phases of Spent Nuclear Fuel

    Unknown journal · 2003-06-01

    Peter Carman Burns, USDOE Office of Science (SC) (US), Argonne National Chemical Technology Division, Robert J. Finch, David J. Wronkiewicz

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  9. Synthesis, crystal structure and electrical characterization of two new potassium uranyl molybdates K2(UO2)2(MoO4)O2 and K8(UO2)8(MoO5)3O6

    Journal of Solid State Chemistry · 2003-06-09

    S. Obbade, S. Yagoubi, C. Dion, Mohamed Saadi, F. Abraham

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  10. Geometrical isomerism in uranyl chromates I. Crystal structures of (UO2)(CrO4)(H2O)2, [(UO2)(CrO4)(H2O)2](H2O) and [(UO2)(CrO4)(H2O)2]4(H2O)9

    Zeitschrift für Kristallographie - Crystalline Materials · 2003-08-01

    Sergey V. Krivovichev, Peter Carman Burns

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  11. CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. IX. A NOVEL URANYL MOLYBDATE SHEET IN THE STRUCTURE OF Tl2[(UO2)2O(MoO5)]

    The Canadian Mineralogist · 2003-10-01

    Sergey V. Krivovichev, Peter Carman Burns

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  12. CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. X. THE CRYSTAL STRUCTURE OF Ag10[(UO2)8O8(Mo5O20)]

    The Canadian Mineralogist · 2003-12-01

    Sergey V. Krivovichev, Peter Carman Burns

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  13. Two new lithium uranyl tungstates Li2(UO2)(WO4)2 and Li2(UO2)4(WO4)4O with framework based on the uranophane sheet anion topology

    Journal of Solid State Chemistry · 2004-02-17

    S. Obbade, S. Yagoubi, C. Dion, Mohamed Saadi, F. Abraham

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  14. Combinatorial topology of salts of inorganic oxoacids: zero-, one- and two-dimensional units with corner-sharing between coordination polyhedra

    Crystallography Reviews · 2004-07-01

    Sergey V. Krivovichev

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  15. Hydrothermal synthesis and crystal structure of Cs6[(UO2)4(W5O21)(OH)2(H2O)2]: a new polar uranyl tungstate

    Journal of Solid State Chemistry · 2004-08-31

    Richard E. Sykora, Thomas E. Albrecht‐Schmitt

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  16. Comparative study of the flexibility of structural complexes in uranyl sulfates, chromates, and molybdates

    Radiochemistry · 2004-09-01

    Sergey V. Krivovichev

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  17. Direct Investigations of the Immobilization of Radionuclides in the Alteration Products of Spent Nuclear Fuel

    Unknown journal · 2004-12-27

    Peter Carman Burns, Robert J. Finch, David J. Wronkiewicz

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  18. Lone electron pair stereoactivity, cation arrangements and distortion of heteropolyhedral sheets in the structures of Tl2[(UO2)(AO4)2] (A = Cr, Mo)

    Zeitschrift für Kristallographie - Crystalline Materials · 2005-01-01

    Sergey V. Krivovichev, Andrew J. Locock, Peter Carman Burns

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  19. CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. XI. CRYSTAL STRUCTURES OF Cs2[(UO2)(MoO4)2] AND Cs2[(UO2)(MoO4)2](H2O)

    The Canadian Mineralogist · 2005-04-01

    Sergey V. Krivovichev, Peter Carman Burns

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  20. Amine‐Templated Uranyl Selenates with Layered Structures. I Structural Diversity of Sheets with a U:Se ratio of 1:2

    Zeitschrift für anorganische und allgemeine Chemie · 2005-08-29

    Sergey V. Krivovichev, Volker Kahlenberg, Ivan Gundarovich Tananaev, Boris F. Myasoedov

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  21. Hydrothermal synthesis and crystal structures of new uranyl oxalate hydroxides: α- and β-[(UO2)2(C2O4)(OH)2(H2O)2] and [(UO2)2(C2O4)(OH)2(H2O)2]·H2O

    Journal of Solid State Chemistry · 2005-10-03

    L. Duvieubourg, G. Nowogrocki, F. Abraham, S. Grandjean

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  22. U6+ MINERALS AND INORGANIC COMPOUNDS: INSIGHTS INTO AN EXPANDED STRUCTURAL HIERARCHY OF CRYSTAL STRUCTURES

    The Canadian Mineralogist · 2005-12-01

    Peter Carman Burns

    Read original paper ↗ ·

  23. Thermochemistry of alkali metal uranomolybdates

    Radiochemistry · 2006-01-01

    Evgeny V. Suleimanov, Nikolay G. Chernorukov, Alexey V. Golubev

    Read original paper ↗ ·

  24. One-dimensional chains in uranyl tungstates: Syntheses and structures of A8[(UO2)4(WO4)4(WO5)2] (A=Rb, Cs) and Rb6[(UO2)2O(WO4)4]

    Journal of Solid State Chemistry · 2006-05-25

    Evgeny V. Alekseev, Sergey V. Krivovichev, Wulf Depmeier, Thomas Armbruster, Hannelore Katzke, Evgeny V. Suleimanov, Evgeny V. Chuprunov

    Read original paper ↗ ·

  25. The A1−xUNbO6−x/2 compounds (x=0, A=Li, Na, K, Cs and x=0.5, A=Rb, Cs): from layered to tunneled structure

    Journal of Solid State Chemistry · 2006-06-22

    Suzy Surblé, S. Obbade, S. Saad, S. Yagoubi, C. Dion, F. Abraham

    Read original paper ↗ ·

  26. Actinide compounds containing hexavalent cations of the VI group elements (S, Se, Mo, Cr, W)

    Elsevier eBooks · 2007-01-01

    Sergey V. Krivovichev, Peter Carman Burns

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  27. Dimensional Reduction in Alkali Metal Uranyl Molybdates: Synthesis and Structure of Cs2[(UO2)O(MoO4)]

    Zeitschrift für anorganische und allgemeine Chemie · 2007-08-27

    Evgeny V. Alekseev, Sergey V. Krivovichev, Thomas Armbruster, Wulf Depmeier, Evgeny V. Suleimanov, Evgeny V. Chuprunov, Alexei V. Golubev

    Read original paper ↗ ·

  28. Corrosion Behavior of SUS316 Clad in Alkalis Molybdate Melt

    Transactions of the Atomic Energy Society of Japan · 2008-01-01

    Takayuki Nagai, Kotaro KIKUCHI, Yoshiharu Kano, Mineo Fukushima

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  29. THE STEREOCHEMISTRY AND CHEMICAL COMPOSITION OF INTERSTITIAL COMPLEXES IN URANYL-OXYSALT MINERALS

    The Canadian Mineralogist · 2008-04-01

    Mandy Schindler, Frank Christopher Hawthorne

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  30. Crystal chemistry of selenates with mineral-like structures. VI. Hydrogen bonds in the crystal structure of [(H5O2)(H3O)(H2O)][(UO2)(SeO4)2]

    Geology of Ore Deposits · 2008-12-01

    Sergey V. Krivovichev

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  31. NEPTUNYL COMPOUNDS: POLYHEDRON GEOMETRIES, BOND-VALENCE PARAMETERS, AND STRUCTURAL HIERARCHY

    The Canadian Mineralogist · 2008-12-01

    Tori Z. Forbes, C. Wallace, Peter Carman Burns

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  32. Alternative approaches to structure description

    Unknown journal · 2009-01-22

    Sergey V. Krivovichev

    Read original paper ↗ ·

  33. Anion-topology approach

    Unknown journal · 2009-01-22

    Sergey V. Krivovichev

    Read original paper ↗ ·

  34. Basic concepts

    Unknown journal · 2009-01-22

    Sergey V. Krivovichev

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  35. Copyright Page

    Unknown journal · 2009-01-22

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  36. Dedication

    Unknown journal · 2009-01-22

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  37. Dimensional reduction in inorganic oxysalts

    Unknown journal · 2009-01-22

    Sergey V. Krivovichev

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  38. Graph theory applied to low-dimensional structural units in inorganic oxysalts

    Unknown journal · 2009-01-22

    Sergey V. Krivovichev

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  39. Preface

    Unknown journal · 2009-01-22

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  40. Structural Crystallography of Inorganic Oxysalts

    Unknown journal · 2009-01-22

    Sergey V. Krivovichev

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  41. Topology of framework structures in inorganic oxysalts

    Unknown journal · 2009-01-22

    Sergey V. Krivovichev

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  42. From ∞1[(UO2)2O(MoO4)4]6− to ∞1[(UO2)2(MoO4)3(MoO5)]6− infinite chains in A6U2Mo4O21 (A=Na, K, Rb, Cs) compounds: Synthesis and crystal structure of Cs6[(UO2)2(MoO4)3(MoO5)]

    Journal of Solid State Chemistry · 2011-03-07

    S. Yagoubi, S. Obbade, S. Saad, F. Abraham

    Read original paper ↗ ·

  43. Structural topology and dimensional reduction in uranyl oxysalts: eight novel phases in the methylamine–(UO2)(NO3)2–H2SeO4–H2O system

    Structural Chemistry · 2012-05-05

    Vadim M. Kovrugin, Vladislav V. Gurzhiy, Sergey V. Krivovichev

    Read original paper ↗ ·

  44. Systematic Evolution from Uranyl(VI) Phosphites to Uranium(IV) Phosphates

    Inorganic Chemistry · 2012-05-30

    Eric M. Villa, Connor J. Marr, Laurent J. Jouffret, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

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  45. Single crystal growth and structural characterization of four complex uranium oxides: CaUO4, β-Ca3UO6, K4CaU3O12, and K4SrU3O12

    Solid State Sciences · 2012-12-27

    Cory Michael Read, Daniel E. Bugaris, Hans‐Conrad zur Loye

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  46. Crystal Chemistry of Uranium Oxides and Minerals

    Elsevier eBooks · 2013-01-01

    Sergey V. Krivovichev

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  47. Syntheses, Structures, and Comparisons of Thallium Uranium Phosphites, Mixed Phosphate-Phosphites, and Phosphate

    Crystal Growth & Design · 2013-03-08

    Eric M. Villa, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

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  48. High-Temperature Phase Transitions, Spectroscopic Properties, and Dimensionality Reduction in Rubidium Thorium Molybdate Family

    Inorganic Chemistry · 2014-03-06

    Bin Xiao, Thorsten M. Gesing, Philip Kegler, Giuseppe Modolo, Dirk Bosbach, Hartmut Schlenz, Evgeny V. Suleimanov, Evgeny V. Alekseev

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  49. Solid-state actinide acid phosphites from phosphorous acid melts

    Journal of Solid State Chemistry · 2014-03-23

    George N. Oh, Peter Carman Burns

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  50. Thermodynamic properties and behaviour of A2[(UO2)(MoO4)2] compounds with A= Li, Na, K, Rb, and Cs

    The Journal of Chemical Thermodynamics · 2014-07-28

    Maxim I. Lelet, Evgeny V. Suleimanov, Aleksey V. Golubev, Charles A. Geiger, Wulf Depmeier, Dirk Bosbach, Evgeny V. Alekseev

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