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RESEARCH PAPER · Inorganic Chemistry · 2001

Excision of Uranium Oxide Chains and Ribbons in the Novel One-Dimensional Uranyl Iodates K2[(UO2)3(IO3)4O2] and Ba[(UO2)2(IO3)2O2](H2O)

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Excision of Uranium Oxide Chains and Ribbons in the Novel One-Dimensional Uranyl Iodates K2[(UO2)3(IO3)4O2] and Ba[(UO2)2(IO3)2O2](H2O)OriginalA New Oxoanion: [IO4]3-Containing I(V) with a Stereochemically Active Lone-Pair in the Silver Uranyl Iodate Tetraoxoiodate(V), Ag4(UO2)4(IO3)2(IO4)2O282ChemInform Abstract: Excision of Uranium Oxide Chains and Ribbons in the Novel One‐Dimensional Uranyl Iodates K2 [(UO2)3(IO3)4O2] and Ba[(UO2)2(IO3)2O2] (H2O).022 New compounds and structures in the solid state2Structural Modulation of Molybdenyl Iodate Architectures by Alkali Metal Cations in AMoO3(IO3) (A = K, Rb, Cs): A Facile Route to New Polar Materials with Large SHG Responses337Hydrothermal Syntheses, Structures, and Properties of the New Uranyl Selenites Ag2(UO2)(SeO3)2, M[(UO2)(HSeO3)(SeO3)] (M = K, Rb, Cs, Tl), and Pb(UO2)(SeO3)284Hydrothermal Synthesis and Structure of a New One-Dimensional, Mixed-Metal U(VI) Iodate, Cs2[(UO2)(CrO4)(IO3)2]53Further Evidence for the Tetraoxoiodate(V) Anion, IO43-: Hydrothermal Syntheses and Structures of Ba[(MoO2)6(IO4)2O4]·H2O and Ba3[(MoO2)2(IO6)2]·2H2O48New Structural Arrangements in Three Ca Uranyl Carbonate Compounds with Multiple Anionic Species22Mixed-Metal Uranium(VI) Iodates: Hydrothermal Syntheses, Structures, and Reactivity of Rb[UO2(CrO4)(IO3)(H2O)], A2[UO2(CrO4)(IO3)2] (A = K, Rb, Cs), and K2[UO2(MoO4)(IO3)2]70Expanding the Remarkable Structural Diversity of Uranyl Tellurites: Hydrothermal Preparation and Structures of K[UO2Te2O5(OH)], Tl3{(UO2)2[Te2O5(OH)](Te2O6)}·2H2O, β-Tl2[UO2(TeO3)2], and Sr3[UO2(TeO3)2](TeO3)257Variable Dimensionality and New Uranium Oxide Topologies in the Alkaline-Earth Metal Uranyl Selenites AE[(UO2)(SeO3)2] (AE=Ca, Ba) and Sr[(UO2)(SeO3)2] · 2H2O49Aqueous Reactions of U(VI) at High Chloride Concentrations: Syntheses and Structures of New Uranyl Chloride Polymers42Hydrothermal Preparation, Structures, and NLO Properties of the Rare Earth Molybdenyl Iodates, RE(MoO2)(IO3)4(OH) [RE = Nd, Sm, Eu]114Synthesis and characterization of a channel framework in K 3 Am 3 (IO 3 ) 12 ·HIO 332Structural characterization of the first hydrothermally synthesized plutonium compound, PuO2(IO3)2·H2O55Cation−Cation Interactions in Neptunyl(V) Compounds: Hydrothermal Preparation and Structural Characterization of NpO2(IO3) and α- and β-AgNpO2(SeO3)87Do Secondary and Tertiary Ammonium Cations Act as Structure-Directing Agents in the Formation of Layered Uranyl Selenites?48Structural and Spectroscopic Trends in Actinyl Iodates of Uranium, Neptunium, and Plutonium53New one-dimensional uranyl and neptunyl iodates: crystal structures of K3[(UO2)2(IO3)6](IO3)·H2O and K[NpO2(IO3)3]·1.5H2O22CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. X. THE CRYSTAL STRUCTURE OF Ag10[(UO2)8O8(Mo5O20)]15Intercalation of KCl into layered neptunyl and plutonyl iodates19Hydrothermal synthesis, structure, and catalytic properties of UO2Sb2O425Synthesis and crystal structures of the layered uranyl tellurites A2[(UO2)3(TeO3)2O2] (A=K, Rb, Cs)18Hydrothermal synthesis, structure, Raman spectroscopy, and self-irradiation studies of 248Cm(IO3)342A New Inorganic−Organic Hybrid Copper Iodate with Potentially Large Void Volume11Crystal chemistry and ion-exchange properties of the layered uranyl iodate K[UO2(IO3)3]40Hydrothermal synthesis and structural characterization of a novel NLO compound, La(MoO2)(OH)(IO3)442Actinide Materials Adopt Curvature: Nanotubules and Nanospheres71Actinoidchemie mit Krümmung: Nanoröhren und Nanokugeln19Synthesis, Structure, and Spectroscopic Properties of Am(IO3)3 and the Photoluminescence Behavior of Cm(IO3)348Molten salt flux synthesis and structure of the new layered uranyl tellurite, K4[(UO2)5(TeO3)2O5]22U6+ MINERALS AND INORGANIC COMPOUNDS: INSIGHTS INTO AN EXPANDED STRUCTURAL HIERARCHY OF CRYSTAL STRUCTURES627The vitality of uranium molecular chemistry at the dawn of the XXIst century314Extended networks, porous sheets, and chiral frameworks. Thorium materials containing mixed geometry anions: Structures and properties of Th(SeO3)(SeO4), Th(IO3)2(SeO4)(H2O)3·H2O, and Th(CrO4)(IO3)244Synthesis, structure, and property of a uranium–potassium–organic coordination polymer containing infinite metal oxide sheets16Syntheses, spectroscopic and X-ray structure analyses of two dioxouranium (VI) complexes: supramolecular framework built from O—H…O, C—H…O and stacking interactions11Structural Polarity Induced by Cooperative Hydrogen Bonding and Lone-Pair Alignment in the Molecular Uranyl Iodate Na2[UO2(IO3)4(H2O)]18Intercalation of Iodic Acid into the Layered Uranyl Iodate, UO2(IO3)2(H2O)26Actinide compounds with heavy oxoanions containing a stereochemically active lone-pair of electrons2New iodate materials as potential laser matrices. Preparation and characterisation of α-M(IO3)3 (M=Y, Dy) and β-M(IO3)3 (M=Y, Ce, Pr, Nd, Eu, Gd, Tb, Dy, Ho, Er). Structural evolution as a function of the Ln3+ cationic radius41Promising Material for Infrared Nonlinear Optics: NaI3O8 Salt Containing an Octaoxotriiodate(V) Anion Formed from Condensation of [IO3]− Ions229Promising Material for Infrared Nonlinear Optics: NaI3O8 Salt Containing an Octaoxotriiodate(V) Anion Formed from Condensation of [IO3]− Ions26TOF-2: A Large 1D Channel Thorium Organic Framework140Hydrothermal synthesis and structure characterization of the first organically templated metal iodates2THE STEREOCHEMISTRY AND CHEMICAL COMPOSITION OF INTERSTITIAL COMPLEXES IN URANYL-OXYSALT MINERALS75Hydrothermal Synthesis and X‐ray Crystal Structure of Four Inorganic‐Organic Hybrid Compounds in Vanadium /Copper Iodate Family0Luminescence studies of Nd3+- and Yb3+-doped α-Y(IO3)3 and β-Y(IO3)3, transparent host matrix in the mid- and beginning of the far-infrared9Incorporation of iodine into uranophane formed during the corrosion of spent nuclear fuel12Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: new methods for constructing porous materials113Syntheses, crystal structures, and properties of three new lanthanum( iii ) vanadium iodates56Uranium*34Polarity and Chirality in Uranyl Borates: Insights into Understanding the Vitrification of Nuclear Waste and the Development of Nonlinear Optical Materials104Reinterpretation of Three Crystal Structures of Alkali Oxoiodate(V) – Description of the [I3O8]–Anion and the Infinite 2D [I3O8–]∞Anion43Explorations of New Second-Order Nonlinear Optical Materials in the KI-MII -IV-O Systems43Polar or Non-Polar? Syntheses, Crystal Structures, and Optical Properties of Three New Palladium(II) Iodates45Incorporation of Mn(II) and Fe(II) into Uranyl Carboxyphosphonates38Structures and properties of functional metal iodates72Facile Routes to ThIV, UIV, and NpIV Phosphites and Phosphates23Systematic Evolution from Uranyl(VI) Phosphites to Uranium(IV) Phosphates43Crystal Chemistry of Uranium Oxides and Minerals27Structural changes within the alkaline earth uranyl phosphites9From Order to Disorder and Back Again: In Situ Hydrothermal Redox Reactions of Uranium Phosphites and Phosphates28Syntheses, Structures, and Comparisons of Thallium Uranium Phosphites, Mixed Phosphate-Phosphites, and Phosphate22The crystal chemistry of uranium carboxylates394Ab initio calculation of structural, electronic and optical properties of Hg(IO3)27MOFs of Uranium and the Actinides95Optical properties of Nd 3+ and Yb 3+ -doped AgM(IO 3 ) 4 metal iodates: transparent host matrices for mid-IR lasers and nonlinear materials40Recent advances on second-order NLO materials based on metal iodates328A Revised and Expanded Structure Hierarchy of Natural and Synthetic Hexavalent Uranium Compounds172Inorganic Synthesis of Actinides3Mild Periodic Acid Flux and Hydrothermal Methods for the Synthesis of Crystalline f-Element-Bearing Iodate Compounds20Wide‐Bandgap Rare‐Earth Iodate Single Crystals for Superior X‐Ray Detection and Imaging21Crystal structure and Hirshfeld surface analysis of bis(benzoylacetonato)(ethanol)dioxidouranium(VI)1

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  1. A New Oxoanion: [IO4]3-Containing I(V) with a Stereochemically Active Lone-Pair in the Silver Uranyl Iodate Tetraoxoiodate(V), Ag4(UO2)4(IO3)2(IO4)2O2

    Journal of the American Chemical Society · 2001-08-15

    Amanda C. Bean, Charles F. Campana, Ohyun Kwon, Thomas E. Albrecht‐Schmitt

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  2. ChemInform Abstract: Excision of Uranium Oxide Chains and Ribbons in the Novel One‐Dimensional Uranyl Iodates K2 [(UO2)3(IO3)4O2] and Ba[(UO2)2(IO3)2O2] (H2O).

    ChemInform · 2001-11-06

    Amanda C. Bean, Michael Ruf, Thomas E. Albrecht‐Schmitt

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  3. 22 New compounds and structures in the solid state

    Annual Reports Section A (Inorganic Chemistry) · 2002-01-01

    Martin P. Attfield

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  4. Structural Modulation of Molybdenyl Iodate Architectures by Alkali Metal Cations in AMoO3(IO3) (A = K, Rb, Cs): A Facile Route to New Polar Materials with Large SHG Responses

    Journal of the American Chemical Society · 2002-02-08

    Richard E. Sykora, Kang Min Ok, P. Shiv Halasyamani, Thomas E. Albrecht‐Schmitt

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  5. Hydrothermal Syntheses, Structures, and Properties of the New Uranyl Selenites Ag2(UO2)(SeO3)2, M[(UO2)(HSeO3)(SeO3)] (M = K, Rb, Cs, Tl), and Pb(UO2)(SeO3)2

    Inorganic Chemistry · 2002-02-13

    Philip M. Almond, Thomas E. Albrecht‐Schmitt

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  6. Hydrothermal Synthesis and Structure of a New One-Dimensional, Mixed-Metal U(VI) Iodate, Cs2[(UO2)(CrO4)(IO3)2]

    Inorganic Chemistry · 2002-04-02

    Richard E. Sykora, Daniel M. Wells, Thomas E. Albrecht‐Schmitt

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  7. Further Evidence for the Tetraoxoiodate(V) Anion, IO43-: Hydrothermal Syntheses and Structures of Ba[(MoO2)6(IO4)2O4]·H2O and Ba3[(MoO2)2(IO6)2]·2H2O

    Inorganic Chemistry · 2002-04-17

    Richard E. Sykora, Daniel M. Wells, Thomas E. Albrecht‐Schmitt

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  8. New Structural Arrangements in Three Ca Uranyl Carbonate Compounds with Multiple Anionic Species

    Journal of Solid State Chemistry · 2002-06-01

    Yaping Li, Peter Carman Burns

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  9. Mixed-Metal Uranium(VI) Iodates: Hydrothermal Syntheses, Structures, and Reactivity of Rb[UO2(CrO4)(IO3)(H2O)], A2[UO2(CrO4)(IO3)2] (A = K, Rb, Cs), and K2[UO2(MoO4)(IO3)2]

    Inorganic Chemistry · 2002-09-11

    Richard E. Sykora, Steven M. McDaniel, Daniel M. Wells, Thomas E. Albrecht‐Schmitt

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  10. Expanding the Remarkable Structural Diversity of Uranyl Tellurites: Hydrothermal Preparation and Structures of K[UO2Te2O5(OH)], Tl3{(UO2)2[Te2O5(OH)](Te2O6)}·2H2O, β-Tl2[UO2(TeO3)2], and Sr3[UO2(TeO3)2](TeO3)2

    Inorganic Chemistry · 2002-09-18

    Philip M. Almond, Thomas E. Albrecht‐Schmitt

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  11. Variable Dimensionality and New Uranium Oxide Topologies in the Alkaline-Earth Metal Uranyl Selenites AE[(UO2)(SeO3)2] (AE=Ca, Ba) and Sr[(UO2)(SeO3)2] · 2H2O

    Journal of Solid State Chemistry · 2002-11-01

    Philip M. Almond, Shane M. Peper, Eric Bakker, Thomas E. Albrecht‐Schmitt

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  12. Aqueous Reactions of U(VI) at High Chloride Concentrations: Syntheses and Structures of New Uranyl Chloride Polymers

    Inorganic Chemistry · 2002-11-19

    Amanda C. Bean, Youwen Xu, Janet A. Danis, Thomas E. Albrecht‐Schmitt, Brian L. Scott, Wolfgang Runde

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  13. Hydrothermal Preparation, Structures, and NLO Properties of the Rare Earth Molybdenyl Iodates, RE(MoO2)(IO3)4(OH) [RE = Nd, Sm, Eu]

    Inorganic Chemistry · 2002-12-10

    Thomas C. Shehee, Richard E. Sykora, Kang Min Ok, P. Shiv Halasyamani, Thomas E. Albrecht‐Schmitt

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  14. Synthesis and characterization of a channel framework in K 3 Am 3 (IO 3 ) 12 ·HIO 3

    Chemical Communications · 2003-01-01

    Wolfgang Runde, Amanda C. Bean, Brian L. Scott

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  15. Structural characterization of the first hydrothermally synthesized plutonium compound, PuO2(IO3)2·H2O

    Chemical Communications · 2003-01-16

    Wolfgang Runde, Amanda C. Bean, Thomas E. Albrecht‐Schmitt, Brian L. Scott

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  16. Cation−Cation Interactions in Neptunyl(V) Compounds: Hydrothermal Preparation and Structural Characterization of NpO2(IO3) and α- and β-AgNpO2(SeO3)

    Inorganic Chemistry · 2003-05-09

    Thomas E. Albrecht‐Schmitt, Philip M. Almond, Richard E. Sykora

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  17. Do Secondary and Tertiary Ammonium Cations Act as Structure-Directing Agents in the Formation of Layered Uranyl Selenites?

    Inorganic Chemistry · 2003-08-12

    Philip M. Almond, Thomas E. Albrecht‐Schmitt

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  18. Structural and Spectroscopic Trends in Actinyl Iodates of Uranium, Neptunium, and Plutonium

    Inorganic Chemistry · 2003-08-12

    Amanda C. Bean, Brian L. Scott, Thomas E. Albrecht‐Schmitt, Wolfgang Runde

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  19. New one-dimensional uranyl and neptunyl iodates: crystal structures of K3[(UO2)2(IO3)6](IO3)·H2O and K[NpO2(IO3)3]·1.5H2O

    Journal of Solid State Chemistry · 2003-10-25

    Richard E. Sykora, Amanda C. Bean, Brian L. Scott, Wolfgang Runde, Thomas E. Albrecht‐Schmitt

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  20. CRYSTAL CHEMISTRY OF URANYL MOLYBDATES. X. THE CRYSTAL STRUCTURE OF Ag10[(UO2)8O8(Mo5O20)]

    The Canadian Mineralogist · 2003-12-01

    Sergey V. Krivovichev, Peter Carman Burns

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  21. Intercalation of KCl into layered neptunyl and plutonyl iodates

    Journal of Solid State Chemistry · 2003-12-19

    Amanda C. Bean, Brian L. Scott, Thomas E. Albrecht‐Schmitt, Wolfgang Runde

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  22. Hydrothermal synthesis, structure, and catalytic properties of UO2Sb2O4

    Journal of Solid State Chemistry · 2004-02-11

    Richard E. Sykora, Joseph E. King, Andreas J. Illies, Thomas E. Albrecht‐Schmitt

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  23. Synthesis and crystal structures of the layered uranyl tellurites A2[(UO2)3(TeO3)2O2] (A=K, Rb, Cs)

    Journal of Solid State Chemistry · 2004-10-13

    Jonathan D. Woodward, Philip M. Almond, Thomas E. Albrecht‐Schmitt

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  24. Hydrothermal synthesis, structure, Raman spectroscopy, and self-irradiation studies of 248Cm(IO3)3

    Journal of Solid State Chemistry · 2004-11-12

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  25. A New Inorganic−Organic Hybrid Copper Iodate with Potentially Large Void Volume

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  26. Crystal chemistry and ion-exchange properties of the layered uranyl iodate K[UO2(IO3)3]

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  27. Hydrothermal synthesis and structural characterization of a novel NLO compound, La(MoO2)(OH)(IO3)4

    Journal of Alloys and Compounds · 2005-01-11

    Xuean Chen, Xinan Chang, Hegui Zang, Qian Wang, Weiqiang Xiao

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  28. Actinide Materials Adopt Curvature: Nanotubules and Nanospheres

    Angewandte Chemie International Edition · 2005-07-06

    Thomas E. Albrecht‐Schmitt

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  29. Actinoidchemie mit Krümmung: Nanoröhren und Nanokugeln

    Angewandte Chemie · 2005-07-06

    Thomas E. Albrecht‐Schmitt

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  30. Synthesis, Structure, and Spectroscopic Properties of Am(IO3)3 and the Photoluminescence Behavior of Cm(IO3)3

    Inorganic Chemistry · 2005-07-06

    Richard E. Sykora, Zerihun Assefa, Richard Geoffrey Haire, Thomas E. Albrecht‐Schmitt

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  31. Molten salt flux synthesis and structure of the new layered uranyl tellurite, K4[(UO2)5(TeO3)2O5]

    Journal of Solid State Chemistry · 2005-08-11

    Jonathan D. Woodward, Thomas E. Albrecht‐Schmitt

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  32. U6+ MINERALS AND INORGANIC COMPOUNDS: INSIGHTS INTO AN EXPANDED STRUCTURAL HIERARCHY OF CRYSTAL STRUCTURES

    The Canadian Mineralogist · 2005-12-01

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  33. The vitality of uranium molecular chemistry at the dawn of the XXIst century

    Dalton Transactions · 2006-01-01

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  34. Extended networks, porous sheets, and chiral frameworks. Thorium materials containing mixed geometry anions: Structures and properties of Th(SeO3)(SeO4), Th(IO3)2(SeO4)(H2O)3·H2O, and Th(CrO4)(IO3)2

    Journal of Solid State Chemistry · 2006-02-08

    Tyler A. Sullens, Philip M. Almond, Jessica A. Byrd, James V. Beitz, Travis H. Bray, Thomas E. Albrecht‐Schmitt

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  35. Synthesis, structure, and property of a uranium–potassium–organic coordination polymer containing infinite metal oxide sheets

    Journal of Molecular Structure · 2006-03-01

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  36. Syntheses, spectroscopic and X-ray structure analyses of two dioxouranium (VI) complexes: supramolecular framework built from O—H…O, C—H…O and stacking interactions

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  37. Structural Polarity Induced by Cooperative Hydrogen Bonding and Lone-Pair Alignment in the Molecular Uranyl Iodate Na2[UO2(IO3)4(H2O)]

    Inorganic Chemistry · 2006-08-19

    Travis H. Bray, James V. Beitz, Amanda C. Bean, Yaqin Yu, Thomas E. Albrecht‐Schmitt

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  38. Intercalation of Iodic Acid into the Layered Uranyl Iodate, UO2(IO3)2(H2O)

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  39. Actinide compounds with heavy oxoanions containing a stereochemically active lone-pair of electrons

    Elsevier eBooks · 2007-01-01

    Richard E. Sykora, Tatiana Y. Shvareva, Thomas E. Albrecht‐Schmitt

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  40. New iodate materials as potential laser matrices. Preparation and characterisation of α-M(IO3)3 (M=Y, Dy) and β-M(IO3)3 (M=Y, Ce, Pr, Nd, Eu, Gd, Tb, Dy, Ho, Er). Structural evolution as a function of the Ln3+ cationic radius

    Solid State Sciences · 2007-04-15

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  41. Promising Material for Infrared Nonlinear Optics: NaI3O8 Salt Containing an Octaoxotriiodate(V) Anion Formed from Condensation of [IO3]− Ions

    Angewandte Chemie International Edition · 2007-10-02

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  42. Promising Material for Infrared Nonlinear Optics: NaI3O8 Salt Containing an Octaoxotriiodate(V) Anion Formed from Condensation of [IO3]− Ions

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  43. TOF-2: A Large 1D Channel Thorium Organic Framework

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  44. Hydrothermal synthesis and structure characterization of the first organically templated metal iodates

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  45. THE STEREOCHEMISTRY AND CHEMICAL COMPOSITION OF INTERSTITIAL COMPLEXES IN URANYL-OXYSALT MINERALS

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  46. Hydrothermal Synthesis and X‐ray Crystal Structure of Four Inorganic‐Organic Hybrid Compounds in Vanadium /Copper Iodate Family

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  47. Luminescence studies of Nd3+- and Yb3+-doped α-Y(IO3)3 and β-Y(IO3)3, transparent host matrix in the mid- and beginning of the far-infrared

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  48. Incorporation of iodine into uranophane formed during the corrosion of spent nuclear fuel

    Radiochimica Acta · 2009-01-01

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  49. Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: new methods for constructing porous materials

    Chemical Communications · 2010-01-01

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  50. Syntheses, crystal structures, and properties of three new lanthanum( iii ) vanadium iodates

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