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RESEARCH PAPER · Chemistry of Materials · 2003

Reactant-Mediated Diversity in Uranyl Phosphonates

M.B. Doran, Alexander J. Norquist, Dermot O’Hare

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Reactant-Mediated Diversity in Uranyl PhosphonatesOriginalPoly[[1,4-bis-(3-aminopropyl)piperazinium] [[dioxouranium(VI)]-di-μ2,μ3-sulfato]]12Exploration of Composition Space in Templated Uranium Sulfates89The effects of hydrofluoric acid addition on the hydrothermal synthesis of templated uranium sulfates46A Microporous Zinc Phosphonocarboxylate with a Zeolite ABW Framework via the Trialkyl Phosphonocarboxylate Route: In situ Synthesis and Characterization of Na[Zn(O3PC2H4CO2)]·H2O38Structures and syntheses of layered and framework amine-bearing uranyl phosphate and uranyl arsenates40Structural variation in organically templated uranium sulfate fluorides42Water‐Insoluble Ag–U–Organic Assemblies with Photocatalytic Activity254The Role of Amine Sulfates in Hydrothermal Uranium Chemistry63Incorporation of Triazacyclononane into the Metal Phosphonate Backbones61Structures and Magnetic Properties of a Series of Metal Phosphonoacetates Synthesized from in Situ Hydrolysis of Triethyl Phosphonoacetate32Two Mixed-Valence Vanadium(III,IV) Phosphonoacetates with 16-Ring Channels: H2(DABCO)[VIVO(H2O)VIII(OH)(O3PCH2CO2)2]·2.5H2O and H2(PIP)[VIVO(H2O)VIII(OH)(O3PCH2CO2)2]·2.5H2O32Hydrothermal synthesis, crystal structure, and characterization of a new pseudo-two-dimensional uranyl oxyfluoride, [N(C2H5)4]2[(UO2)4(OH2)3F10]17A cis‐Dioxido Uranyl: Fluxional Carboxylate Activation from a Reversible Coordination Polymer33A cis‐Dioxido Uranyl: Fluxional Carboxylate Activation from a Reversible Coordination Polymer5In Situ Hydrothermal Reduction of Neptunium(VI) as a Route to Neptunium(IV) Phosphonates34Further Examples of the Failure of Surrogates to Properly Model the Structural and Hydrothermal Chemistry of Transuranium Elements: Insights Provided by Uranium and Neptunium Diphosphonates50Use of Bifunctional Phosphonates for the Preparation of Heterobimetallic 5f−3d Systems103Capitalizing on Differing Coordination Environments and Redox Potentials to Prepare an Ordered Heterobimetallic UVI/NpIV Diphosphonate40Capitalizing on Differing Coordination Environments and Redox Potentials to Prepare an Ordered Heterobimetallic UVI/NpIV Diphosphonate7Structural Variation within Homometallic Uranium(VI) Carboxyphosphonates: In Situ Ligand Synthesis, Directed Assembly, Metal−Ligand Coordination and Hydrogen Bonding82Actinide Polyoxometalates: Incorporation of Uranyl–Peroxo in U‐Shaped 36‐Tungsto‐8‐Phosphate96Uranyl Diphosphonates with Pillared Structures55Periodic Trends in Actinide Phosphonates: Divergence and Convergence between Thorium, Uranium, Neptunium, and Plutonium Systems47Homometallic Uranium(VI) Phosphonoacetates Containing Interlayer Dipyridines69Phosphonoacetate as a Ligand for Constructing Layered and Framework Alkali Metal Uranyl Compounds45Homometallic UO22+ diphosphonates assembled under ambient and hydrothermal conditions29Synthesis and Characterization of 1‐, 2‐, and 3‐Dimensional Bimetallic UO22+/Zn2+ Phosphonoacetates66A new clover-shaped trinuclear uranium(VI) complex: Synthesis, structure and photoluminescence property26Room temperature assembly of a uranyl carboxyphosphonate: Synthesis, characterization and UO22+ hydrolysis34Cerium(IV), Neptunium(IV), and Plutonium(IV) 1,2-Phenylenediphosphonates: Correlations and Differences between Early Transuranium Elements and Their Proposed Surrogates54Hydrothermal Synthesis and Structural Characterization of Organically Templated Uranyl Diphosphonate Compounds72Layered and Three-Dimensional Framework Cesium and Barium Uranyl Carboxyphenylphosphonates69Coordination Polymers and Frameworks in Uranyl Ion Complexes with Sulfonates and Cucurbit[6]uril32Metal-Controlled Assembly of Uranyl Diphosphonates toward the Design of Functional Uranyl Nanotubules77Layered Uranyl Coordination Polymers Rigidly Pillared by Diphosphonates36Uranium diphosphonates templated by interlayer organic amines22Correlations and Differences between Uranium(VI) Arsonates and Phosphonates25Sulfonate Complexes of Actinide Ions: Structural Diversity in Uranyl Complexes with 2-Sulfobenzoate71One- to three-dimensional uranyl–organic assemblies with 3-sulfophthalic and 5-sulfoisophthalic acids29Molecular and Polymeric Uranyl and Thorium Complexes with Sulfonate‐Containing Ligands33Three New Silver Uranyl Diphosphonates: Structures and Properties23New fluorochromatouranylates of alkali metals: Synthesis and structure6UO 2 2+ -amino hybrid materials: structural variation and photocatalysis properties29Hybrid Materials of the f-Elements Part I5Hybrid Materials of the f-Elements Part II5Probing the Influence of Phosphonate Bonding Modes to Uranium(VI) on Structural Topology and Stability: A Complementary Experimental and Computational Investigation51Structural chemistry of uranium phosphonates143Structural and spectroscopic characterization of two new layered uranyl(VI) p-xylenediphosphonate compounds synthesized via ionothermal method13Construction of Uranyl Organic Hybrids by Phosphonate and in Situ Generated Carboxyphosphonate Ligands39Crystal structure and characterization of a novel layered copper-lithium phosphonate with antiferromagnetic intrachain Cu(II)···Cu(II) interactions7Synthesis and structural characterization of five zinc bisphosphonate compounds8A supramolecular uranyl phosphonate [BTEA]2[(UO2)2(1,3-pbpH2)2F2]: Synthesis, structure, and spectroscopic characterization8The role of 1-ethyl-3-methylimidazolium diethyl phosphate ionic liquid in uranyl phosphate compounds7Features of Uranium Stereochemistry in Uranyl Oxofluorides6Cation directed formation of uranyl phosphonocarboxylates frameworks comprised of cross-linked chains1Uranyl ion coordination polymers with the dibenzobarrelene-based rac - and ( R , R )- trans -9,10-dihydro-9,10-ethanoanthracene-11,12-dicarboxylate ligands4Structural chemistry of mixed-ligand fluoride complexes of uranyl1Layered metal phosphonates: Structures and properties7

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  1. Poly[[1,4-bis-(3-aminopropyl)piperazinium] [[dioxouranium(VI)]-di-μ2,μ3-sulfato]]

    Acta Crystallographica Section E Structure Reports Online · 2003-08-23

    M.B. Doran, Alexander J. Norquist, Dermot O’Hare

    Read original paper ↗ ·

  2. Exploration of Composition Space in Templated Uranium Sulfates

    Inorganic Chemistry · 2003-10-04

    M.B. Doran, Alexander J. Norquist, Dermot O’Hare

    Read original paper ↗ ·

  3. The effects of hydrofluoric acid addition on the hydrothermal synthesis of templated uranium sulfates

    Dalton Transactions · 2004-01-01

    M.B. Doran, Ben E. Cockbain, Alexander J. Norquist, Dermot O’Hare

    Read original paper ↗ ·

  4. A Microporous Zinc Phosphonocarboxylate with a Zeolite ABW Framework via the Trialkyl Phosphonocarboxylate Route: In situ Synthesis and Characterization of Na[Zn(O3PC2H4CO2)]·H2O

    European Journal of Inorganic Chemistry · 2004-01-26

    Xian‐Ming Zhang

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  5. Structures and syntheses of layered and framework amine-bearing uranyl phosphate and uranyl arsenates

    Journal of Solid State Chemistry · 2004-06-21

    Andrew J. Locock, Peter Carman Burns

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  6. Structural variation in organically templated uranium sulfate fluorides

    Dalton Transactions · 2005-01-01

    M.B. Doran, Ben E. Cockbain, Dermot O’Hare

    Read original paper ↗ ·

  7. Water‐Insoluble Ag–U–Organic Assemblies with Photocatalytic Activity

    Chemistry - A European Journal · 2005-02-24

    Zhen‐Tao Yu, Zuolei Liao, Yusheng Jiang, Guanghua Li, Jie‐Sheng Chen

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  8. The Role of Amine Sulfates in Hydrothermal Uranium Chemistry

    Inorganic Chemistry · 2005-05-01

    Alexander J. Norquist, M.B. Doran, Dermot O’Hare

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  9. Incorporation of Triazacyclononane into the Metal Phosphonate Backbones

    Inorganic Chemistry · 2006-01-07

    Song‐Song Bao, Gang-Sheng Chen, Yin Wang, Yi‐Zhi Li, Li‐Min Zheng, Qin‐Hui Luo

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  10. Structures and Magnetic Properties of a Series of Metal Phosphonoacetates Synthesized from in Situ Hydrolysis of Triethyl Phosphonoacetate

    Crystal Growth & Design · 2006-05-12

    Juan‐Juan Hou, Xian‐Ming Zhang

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  11. Two Mixed-Valence Vanadium(III,IV) Phosphonoacetates with 16-Ring Channels: H2(DABCO)[VIVO(H2O)VIII(OH)(O3PCH2CO2)2]·2.5H2O and H2(PIP)[VIVO(H2O)VIII(OH)(O3PCH2CO2)2]·2.5H2O

    Inorganic Chemistry · 2006-09-07

    Xian‐Ming Zhang, Juan‐Juan Hou, Wei‐Xiong Zhang, Xiao‐Ming Chen

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  12. Hydrothermal synthesis, crystal structure, and characterization of a new pseudo-two-dimensional uranyl oxyfluoride, [N(C2H5)4]2[(UO2)4(OH2)3F10]

    Journal of Solid State Chemistry · 2006-11-14

    Kang Min Ok, Dermot O’Hare

    Read original paper ↗ ·

  13. A cis‐Dioxido Uranyl: Fluxional Carboxylate Activation from a Reversible Coordination Polymer

    Angewandte Chemie International Edition · 2007-07-19

    Anthony E. Vaughn, Charles Leslie Barnes, Paul B. Duval

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  14. A cis‐Dioxido Uranyl: Fluxional Carboxylate Activation from a Reversible Coordination Polymer

    Angewandte Chemie · 2007-07-19

    Anthony E. Vaughn, Charles Leslie Barnes, Paul B. Duval

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  15. In Situ Hydrothermal Reduction of Neptunium(VI) as a Route to Neptunium(IV) Phosphonates

    Inorganic Chemistry · 2007-11-21

    Travis H. Bray, Anna‐Gay D. Nelson, Geng Bang Jin, Richard Geoffrey Haire, Thomas E. Albrecht‐Schmitt

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  16. Further Examples of the Failure of Surrogates to Properly Model the Structural and Hydrothermal Chemistry of Transuranium Elements: Insights Provided by Uranium and Neptunium Diphosphonates

    Inorganic Chemistry · 2008-05-02

    Anna‐Gay D. Nelson, Travis H. Bray, Wei Zhan, Richard Geoffrey Haire, T.S. Sayler, Thomas E. Albrecht‐Schmitt

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  17. Use of Bifunctional Phosphonates for the Preparation of Heterobimetallic 5f−3d Systems

    Inorganic Chemistry · 2008-05-22

    A.N. Alsobrook, Wei Zhan, Thomas E. Albrecht‐Schmitt

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  18. Capitalizing on Differing Coordination Environments and Redox Potentials to Prepare an Ordered Heterobimetallic UVI/NpIV Diphosphonate

    Angewandte Chemie International Edition · 2008-07-09

    Anna‐Gay D. Nelson, Travis H. Bray, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  19. Capitalizing on Differing Coordination Environments and Redox Potentials to Prepare an Ordered Heterobimetallic UVI/NpIV Diphosphonate

    Angewandte Chemie · 2008-07-09

    Anna‐Gay D. Nelson, Travis H. Bray, Thomas E. Albrecht‐Schmitt

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  20. Structural Variation within Homometallic Uranium(VI) Carboxyphosphonates: In Situ Ligand Synthesis, Directed Assembly, Metal−Ligand Coordination and Hydrogen Bonding

    Inorganic Chemistry · 2008-07-31

    Karah E. Knope, Christopher L. Cahill

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  21. Actinide Polyoxometalates: Incorporation of Uranyl–Peroxo in U‐Shaped 36‐Tungsto‐8‐Phosphate

    Chemistry - A European Journal · 2008-09-24

    Sib Sankar Mal, Michael H. Dickman, Ulrich Kortz

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  22. Uranyl Diphosphonates with Pillared Structures

    Inorganic Chemistry · 2009-03-02

    Pius O. Adelani, Thomas E. Albrecht‐Schmitt

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  23. Periodic Trends in Actinide Phosphonates: Divergence and Convergence between Thorium, Uranium, Neptunium, and Plutonium Systems

    Inorganic Chemistry · 2009-04-06

    Anna‐Gay D. Nelson, Travis H. Bray, Forrest A. Stanley, Thomas E. Albrecht‐Schmitt

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  24. Homometallic Uranium(VI) Phosphonoacetates Containing Interlayer Dipyridines

    Inorganic Chemistry · 2009-06-22

    Karah E. Knope, Christopher L. Cahill

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  25. Phosphonoacetate as a Ligand for Constructing Layered and Framework Alkali Metal Uranyl Compounds

    Inorganic Chemistry · 2009-11-02

    A.N. Alsobrook, Thomas E. Albrecht‐Schmitt

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  26. Homometallic UO22+ diphosphonates assembled under ambient and hydrothermal conditions

    Dalton Transactions · 2010-01-01

    Karah E. Knope, Christopher L. Cahill

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  27. Synthesis and Characterization of 1‐, 2‐, and 3‐Dimensional Bimetallic UO22+/Zn2+ Phosphonoacetates

    European Journal of Inorganic Chemistry · 2010-01-29

    Karah E. Knope, Christopher L. Cahill

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  28. A new clover-shaped trinuclear uranium(VI) complex: Synthesis, structure and photoluminescence property

    Inorganic Chemistry Communications · 2010-05-01

    Di Sun, Na Zhang, Qin-Juan Xu, Rong‐Bin Huang, Lan‐Sun Zheng

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  29. Room temperature assembly of a uranyl carboxyphosphonate: Synthesis, characterization and UO22+ hydrolysis

    Inorganic Chemistry Communications · 2010-06-10

    Karah E. Knope, Christopher L. Cahill

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  30. Cerium(IV), Neptunium(IV), and Plutonium(IV) 1,2-Phenylenediphosphonates: Correlations and Differences between Early Transuranium Elements and Their Proposed Surrogates

    Inorganic Chemistry · 2010-10-04

    Juan Diwu, Shuao Wang, Zuolei Liao, Peter Carman Burns, Thomas E. Albrecht‐Schmitt

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  31. Hydrothermal Synthesis and Structural Characterization of Organically Templated Uranyl Diphosphonate Compounds

    Crystal Growth & Design · 2011-03-09

    Pius O. Adelani, Allen G. Oliver, Thomas E. Albrecht‐Schmitt

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  32. Layered and Three-Dimensional Framework Cesium and Barium Uranyl Carboxyphenylphosphonates

    Crystal Growth & Design · 2011-05-18

    Pius O. Adelani, Allen G. Oliver, Thomas E. Albrecht‐Schmitt

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  33. Coordination Polymers and Frameworks in Uranyl Ion Complexes with Sulfonates and Cucurbit[6]uril

    Crystal Growth & Design · 2011-10-26

    P. Thuéry

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  34. Metal-Controlled Assembly of Uranyl Diphosphonates toward the Design of Functional Uranyl Nanotubules

    Inorganic Chemistry · 2011-11-03

    Pius O. Adelani, Thomas E. Albrecht‐Schmitt

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  35. Layered Uranyl Coordination Polymers Rigidly Pillared by Diphosphonates

    Crystal Growth & Design · 2012-10-12

    Pius O. Adelani, Thomas E. Albrecht‐Schmitt

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  36. Uranium diphosphonates templated by interlayer organic amines

    Journal of Solid State Chemistry · 2012-10-24

    Anna‐Gay D. Nelson, Evgeny V. Alekseev, Thomas E. Albrecht‐Schmitt, Rodney Charles Ewing

    Read original paper ↗ ·

  37. Correlations and Differences between Uranium(VI) Arsonates and Phosphonates

    Inorganic Chemistry · 2012-10-25

    Pius O. Adelani, Laurent J. Jouffret, Jennifer E. S. Szymanowski, Peter Carman Burns

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  38. Sulfonate Complexes of Actinide Ions: Structural Diversity in Uranyl Complexes with 2-Sulfobenzoate

    Inorganic Chemistry · 2012-12-07

    P. Thuéry

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  39. One- to three-dimensional uranyl–organic assemblies with 3-sulfophthalic and 5-sulfoisophthalic acids

    CrystEngComm · 2013-01-01

    P. Thuéry

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  40. Molecular and Polymeric Uranyl and Thorium Complexes with Sulfonate‐Containing Ligands

    European Journal of Inorganic Chemistry · 2013-11-25

    P. Thuéry

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  41. Three New Silver Uranyl Diphosphonates: Structures and Properties

    Inorganic Chemistry · 2014-02-13

    Anna‐Gay D. Nelson, Zsolt Rak, Thomas E. Albrecht‐Schmitt, Udo Becker, Rodney Charles Ewing

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  42. New fluorochromatouranylates of alkali metals: Synthesis and structure

    Russian Journal of Inorganic Chemistry · 2014-08-01

    В. Н. Сережкин, Eugenia V. Peresypkina, Sergei A. Novikov, A.V. Virovets, Л. Б. Сережкина

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  43. UO 2 2+ -amino hybrid materials: structural variation and photocatalysis properties

    CrystEngComm · 2014-10-09

    Xue‐Ting Xu, Yanan Hou, Si‐Yue Wei, Xiaoxi Zhang, Feng‐Ying Bai, Lixian Sun, Zhan Shi, Yong-Heng Xing

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  44. Hybrid Materials of the f-Elements Part I

    Elsevier eBooks · 2015-01-01

    Korey Prescott Carter, Christopher L. Cahill

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  45. Hybrid Materials of the f-Elements Part II

    Elsevier eBooks · 2015-01-01

    Robert G. Surbella, Christopher L. Cahill

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  46. Probing the Influence of Phosphonate Bonding Modes to Uranium(VI) on Structural Topology and Stability: A Complementary Experimental and Computational Investigation

    Inorganic Chemistry · 2015-03-27

    Tao Zheng, Qun‐Yan Wu, Yang Gao, Daxiang Gui, Shiwen Qiu, Lanhua Chen, Daopeng Sheng, Juan Diwu, Wei‐Qun Shi, Zhifang Chai, Thomas E. Albrecht‐Schmitt, Shuao Wang

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  47. Structural chemistry of uranium phosphonates

    Coordination Chemistry Reviews · 2015-05-30

    Weiting Yang, T. Gannon Parker, Zhong‐Ming Sun

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  48. Structural and spectroscopic characterization of two new layered uranyl(VI) p-xylenediphosphonate compounds synthesized via ionothermal method

    Inorganica Chimica Acta · 2015-07-04

    Tao Zheng, Yang Gao, Lanhua Chen, Juan Diwu, Zhifang Chai, Thomas E. Albrecht‐Schmitt, Shuao Wang

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  49. Construction of Uranyl Organic Hybrids by Phosphonate and in Situ Generated Carboxyphosphonate Ligands

    Inorganic Chemistry · 2017-01-24

    Chao Liu, Weiting Yang, Ning Song Qu, Lei‐Jiao Li, Qing‐Jiang Pan, Zhong‐Ming Sun

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  50. Crystal structure and characterization of a novel layered copper-lithium phosphonate with antiferromagnetic intrachain Cu(II)···Cu(II) interactions

    Journal of Solid State Chemistry · 2017-01-24

    Mohammed S.M. Abdelbaky, Zakariae Amghouz, David Martínez‐Blanco, Santiago García‐Granda, José R. Garcı́a

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