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RESEARCH PAPER · Dalton Transactions · 2004

Selective complexation of uranium( iii ) over lanthanide( iii ) triflates by 2,2′:6′,2″-terpyridine. X-Ray crystal structures of [M(OTf) 3 (terpy) 2 ] and [M(OTf) 2 (terpy) 2 (py)][OTf] (M = Nd, Ce, U) and of polynuclear µ-oxo uranium( iv ) complexes resulting from hydrolysis

J.‐C. Berthet, M. Nierlich, Yannick Miquel, Charles Madic, M. Ephritikhine

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Selective complexation of uranium( iii ) over lanthanide( iii ) triflates by 2,2′:6′,2″-terpyridine. X-Ray crystal structures of [M(OTf) 3 (terpy) 2 ] and [M(OTf) 2 (terpy) 2 (py)][OTf] (M = Nd, Ce, U) and of polynuclear µ-oxo uranium( iv ) complexes resulting from hydrolysisOriginalThe distinct affinity of cyclopentadienyl ligands towards trivalent uranium over lanthanide ions. Evidence for cooperative ligation and back-bonding in the actinide complexes40Unprecedented reduction of the uranyl ion [UO2]2+ into a polyoxo uranium(iv) cluster: Synthesis and crystal structure of the first f-element oxide with a M6(µ3-O)8 core73Lanthanide( III )/Actinide( III ) Differentiation in the Cerium and Uranium Complexes [M(C5Me5)2(L)]0,+ (L=2,2′‐Bipyridine, 2,2′:6′,2′′‐Terpyridine): Structural, Magnetic, and Reactivity Studies108Polynuclear uranium(IV) compounds with (μ3-oxo)U3 or (μ4-oxo)U4 cores and compartmental Schiff base ligands31First characterization of an uranium(III) complex with a carbonyl-containing ligand: Syntheses and X-ray crystal structures of the homoleptic dimethylformamide complexes [M(dmf)n]I3 (M=Ce, Nd and n=8; M=La, Ce, U and n=9)25Scandium, yttrium, the lanthanides and the actinides9The vitality of uranium molecular chemistry at the dawn of the XXIst century314Diversity of triflate coordination modes in neodymocene complexes containing bulky bis(trimethylsilyl)cyclopentadienyl ligands12Actinide(III) and lanthanide(III) complexes with nitrogen ligands: Counterions and ligand substituent effects on the metal–ligand bond50Soft organic and metal-organic frameworks with porous architecture: From wheel-and-axle to ladder-and-platform design of host molecules77From Bent to Linear Uranium Metallocenes: Influence of Counterion, Solvent, and Metal Ion Oxidation State39DFT modeling of the relative affinity of nitrogen ligands for trivalent f elements: an energetic point of view33Cyanide Metallocenes of Trivalent f-Elements39Uranium and Lanthanide Complexes with the 2-Mercapto Benzothiazolate Ligand: Evidence for a Specific Covalent Binding Site in the Differentiation of Isostructural Lanthanide(III) and Actinide(III) Compounds43Anhydrous scandium, yttrium, lanthanide and actinide halide complexes with neutral oxygen and nitrogen donor ligands81Complexation and Separation of Lanthanides(III) and Actinides(III) by Heterocyclic N-Donors in Solutions490Synthesis of (C5Me5)2(C5Me4H)UMe, (C5Me5)2(C5H5)UMe, and (C5Me5)2UMe[CH(SiMe3)2] from Cationic Metallocenes for the Evaluation of Sterically Induced Reduction30Lanthanide(III) and Actinide(III) Complexes [M(BH4)2(THF)5][BPh4] and [M(BH4)2(18-crown-6)][BPh4] (M = Nd, Ce, U): Synthesis, Crystal Structure, and Density Functional Theory Investigation of the Covalent Contribution to Metal-Borohydride Bonding77A quantum chemistry investigation on the structure of lanthanide triflates Ln(OTf)3 where Ln = La, Ce, Nd, Eu, Gd, Er, Yb and Lu14Linear uranium metallocenes with polydentate aromatic nitrogen ligands18Chain-like and dinuclear coordination polymers in lanthanide (Nd, Eu) oxochloride complexes with 2,2′:6′,2′′-terpyridine: synthesis, XRD structure and magnetic properties38Development of highly selective compounds for solvent extraction processes: partitioning and transmutation of long-lived radionuclides from spent nuclear fuels20New polynuclear U( iv )–U( v ) complexes from U( iv ) mediated uranyl( v ) disproportionation71Coordination of 1,10-phenanthroline, 3,4,7,8-tetramethyl-1,10-phenanthroline and 2,4,6-tris(2-pyridyl)-1,3,5-triazine to MX3 (M=Ce, U; X=I, OSO2CF3) in pyridine and acetonitrile9The coordination and organometallic chemistry of UI3 and U{N(SiMe3)2}3: Synthetic reagents par excellence40Crystal structures of 2,2′:6′,2″-terpyridine uranyl chlorides molecular assemblies and their luminescence signatures242.13 Product Class 13: Organometallic Complexes of the Actinides2A Polyaromatic Terdentate Binding Unit with Fused 5,6-Membered Chelates for Complexing s-, p-, d-, and f-Block Cations17Activation of Small Molecules by Molecular Uranium Complexes119Selectivity of Azine Ligands Toward Lanthanide(III)/Actinide(III) Differentiation: A Relativistic DFT Based Rationalization60U–CN versus Ce–NC Coordination in Trivalent Complexes Derived from M[N(SiMe3)2]3(M = Ce, U)28Synthesis, Structural Characterization, and Carbonyl Addition Reactivity of a Terminal Cerium(III) Acetylide Complex12A Highly Triflated Rare‐Earth Ion in [Eu(O3SCF3)8]5−6Complexation of actinides Am(III), Th(IV), Pu(IV) and U(VI) with poly-N-dentate ligands SO3-Ph-BTP and SO3-Ph-BTBP0Ligand size dependence of U–N and U–O bond character in a series of uranyl hexaphyrin complexes: quantum chemical simulation and density based analysis14Actinide Pincer Chemistry5Luminescent and magnetic properties of mononuclear lanthanide thiocyanates with terpyridine as auxiliary ligand29Polypyridines, Picrates, Lanthanides: A Plethora of Stacks?0Complexes featuring a linear [N≡U≡N] core isoelectronic to the uranyl cation46Mildly-doped polythiophene with triflates for molecular recognition11N-Heterocyclic and Mesoionic Carbene Complexes of the Actinides2Reactivity of a dithorium oxo complex from adventitious water1

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  1. The distinct affinity of cyclopentadienyl ligands towards trivalent uranium over lanthanide ions. Evidence for cooperative ligation and back-bonding in the actinide complexes

    Dalton Transactions · 2005-01-01

    Thouraya Mehdoui, J.‐C. Berthet, P. Thuéry, M. Ephritikhine

    Read original paper ↗ ·

  2. Unprecedented reduction of the uranyl ion [UO2]2+ into a polyoxo uranium(iv) cluster: Synthesis and crystal structure of the first f-element oxide with a M6(µ3-O)8 core

    Chemical Communications · 2005-01-01

    J.‐C. Berthet, P. Thuéry, M. Ephritikhine

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  3. Lanthanide( III )/Actinide( III ) Differentiation in the Cerium and Uranium Complexes [M(C5Me5)2(L)]0,+ (L=2,2′‐Bipyridine, 2,2′:6′,2′′‐Terpyridine): Structural, Magnetic, and Reactivity Studies

    Chemistry - A European Journal · 2005-09-02

    Thouraya Mehdoui, J.‐C. Berthet, P. Thuéry, Lionel Salmon, Éric Rivière, M. Ephritikhine

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  4. Polynuclear uranium(IV) compounds with (μ3-oxo)U3 or (μ4-oxo)U4 cores and compartmental Schiff base ligands

    Polyhedron · 2005-11-24

    Lionel Salmon, P. Thuéry, M. Ephritikhine

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  5. First characterization of an uranium(III) complex with a carbonyl-containing ligand: Syntheses and X-ray crystal structures of the homoleptic dimethylformamide complexes [M(dmf)n]I3 (M=Ce, Nd and n=8; M=La, Ce, U and n=9)

    Polyhedron · 2005-12-22

    J.‐C. Berthet, P. Thuéry, M. Ephritikhine

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  6. Scandium, yttrium, the lanthanides and the actinides

    Annual Reports Section A (Inorganic Chemistry) · 2006-01-01

    S. A. Cotton

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  7. The vitality of uranium molecular chemistry at the dawn of the XXIst century

    Dalton Transactions · 2006-01-01

    M. Ephritikhine

    Read original paper ↗ ·

  8. Diversity of triflate coordination modes in neodymocene complexes containing bulky bis(trimethylsilyl)cyclopentadienyl ligands

    Inorganica Chimica Acta · 2006-02-25

    Peter B. Hitchcock, Alexander G. Hulkes, Michael F. Läppert, Andrey V. Protchenko

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  9. Actinide(III) and lanthanide(III) complexes with nitrogen ligands: Counterions and ligand substituent effects on the metal–ligand bond

    Journal of Molecular Structure THEOCHEM · 2006-05-27

    Dominique Guillaumont

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  10. Soft organic and metal-organic frameworks with porous architecture: From wheel-and-axle to ladder-and-platform design of host molecules

    Journal of Chemical Crystallography · 2006-08-02

    Dmitriy V. Soldatov

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  11. From Bent to Linear Uranium Metallocenes: Influence of Counterion, Solvent, and Metal Ion Oxidation State

    Organometallics · 2006-10-10

    J. Maynadié, J.‐C. Berthet, P. Thuéry, M. Ephritikhine

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  12. DFT modeling of the relative affinity of nitrogen ligands for trivalent f elements: an energetic point of view

    New Journal of Chemistry · 2007-01-01

    Laurence Petit, Claude Auguste Daul, Carlo Adamo, Pascale Maldivi

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  13. Cyanide Metallocenes of Trivalent f-Elements

    Organometallics · 2007-03-30

    J. Maynadié, J.‐C. Berthet, P. Thuéry, M. Ephritikhine

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  14. Uranium and Lanthanide Complexes with the 2-Mercapto Benzothiazolate Ligand: Evidence for a Specific Covalent Binding Site in the Differentiation of Isostructural Lanthanide(III) and Actinide(III) Compounds

    Organometallics · 2007-12-20

    Mathieu Roger, Lotfi Belkhırı, Thérèse Arliguie, P. Thuéry, Abdou Boucekkine, M. Ephritikhine

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  15. Anhydrous scandium, yttrium, lanthanide and actinide halide complexes with neutral oxygen and nitrogen donor ligands

    Coordination Chemistry Reviews · 2008-01-09

    Shashank Mishra

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  16. Complexation and Separation of Lanthanides(III) and Actinides(III) by Heterocyclic N-Donors in Solutions

    Chemical Reviews · 2008-09-24

    Zdenek J. Kolarik

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  17. Synthesis of (C5Me5)2(C5Me4H)UMe, (C5Me5)2(C5H5)UMe, and (C5Me5)2UMe[CH(SiMe3)2] from Cationic Metallocenes for the Evaluation of Sterically Induced Reduction

    Inorganic Chemistry · 2008-10-09

    William J. Evans, Justin R. Walensky, Filipp Furche, Joseph W. Ziller, Antonio G. DiPasquale, Arnold L. Rheingold

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  18. Lanthanide(III) and Actinide(III) Complexes [M(BH4)2(THF)5][BPh4] and [M(BH4)2(18-crown-6)][BPh4] (M = Nd, Ce, U): Synthesis, Crystal Structure, and Density Functional Theory Investigation of the Covalent Contribution to Metal-Borohydride Bonding

    Inorganic Chemistry · 2008-11-19

    Thérèse Arliguie, Lotfi Belkhırı, Salah‐Eddine Bouaoud, P. Thuéry, Claude Villiers, Abdou Boucekkine, M. Ephritikhine

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  19. A quantum chemistry investigation on the structure of lanthanide triflates Ln(OTf)3 where Ln = La, Ce, Nd, Eu, Gd, Er, Yb and Lu

    Dalton Transactions · 2010-01-01

    Douniazed Hannachi, Nadia Ouddaï, Henry Chermette

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  20. Linear uranium metallocenes with polydentate aromatic nitrogen ligands

    Dalton Transactions · 2010-01-01

    J.‐C. Berthet, J. Maynadié, P. Thuéry, M. Ephritikhine

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  21. Chain-like and dinuclear coordination polymers in lanthanide (Nd, Eu) oxochloride complexes with 2,2′:6′,2′′-terpyridine: synthesis, XRD structure and magnetic properties

    Dalton Transactions · 2011-01-01

    Jérôme Lhoste, A. Perez-Campos, Natacha Henry, Thierry Loiseau, Pierre Rabu, F. Abraham

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  22. Development of highly selective compounds for solvent extraction processes: partitioning and transmutation of long-lived radionuclides from spent nuclear fuels

    Elsevier eBooks · 2011-01-01

    Clément Hill

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  23. New polynuclear U( iv )–U( v ) complexes from U( iv ) mediated uranyl( v ) disproportionation

    Chemical Communications · 2011-11-18

    Victor Mougel, Jacques Pécaut, Marinella Mazzanti

    Read original paper ↗ ·

  24. Coordination of 1,10-phenanthroline, 3,4,7,8-tetramethyl-1,10-phenanthroline and 2,4,6-tris(2-pyridyl)-1,3,5-triazine to MX3 (M=Ce, U; X=I, OSO2CF3) in pyridine and acetonitrile

    Polyhedron · 2012-07-23

    J.‐C. Berthet, J.-M. Onno, Florence Gupta, Christelle Rivière, P. Thuéry, M. Nierlich, Charles Madic, M. Ephritikhine

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  25. The coordination and organometallic chemistry of UI3 and U{N(SiMe3)2}3: Synthetic reagents par excellence

    Coordination Chemistry Reviews · 2012-09-25

    Robert J. Baker

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  26. Crystal structures of 2,2′:6′,2″-terpyridine uranyl chlorides molecular assemblies and their luminescence signatures

    Polyhedron · 2012-11-29

    Jérôme Lhoste, Natacha Henry, Thierry Loiseau, Yannick Guyot, F. Abraham

    Read original paper ↗ ·

  27. 2.13 Product Class 13: Organometallic Complexes of the Actinides

    Haug Verlag in Georg Thieme Verlag KG eBooks · 2013-01-01

    R. J. Batrice, I.-S. R. Karmel, Moris S. Eisen

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  28. A Polyaromatic Terdentate Binding Unit with Fused 5,6-Membered Chelates for Complexing s-, p-, d-, and f-Block Cations

    Inorganic Chemistry · 2013-04-19

    Thi Nhu Y Hoang, Marie Humbert‐Droz, Thibault Dutronc, Laure Guénée, Céline Besnard, Claude Piguet

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  29. Activation of Small Molecules by Molecular Uranium Complexes

    Progress in inorganic chemistry · 2014-04-04

    Henry S. La Pierre, Karsten Meyer

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  30. Selectivity of Azine Ligands Toward Lanthanide(III)/Actinide(III) Differentiation: A Relativistic DFT Based Rationalization

    Inorganic Chemistry · 2014-04-22

    Abdallah Zaiter, Boudersa Amine, Yamina Bouzidi, Lotfi Belkhırı, Abdou Boucekkine, M. Ephritikhine

    Read original paper ↗ ·

  31. U–CN versus Ce–NC Coordination in Trivalent Complexes Derived from M[N(SiMe3)2]3(M = Ce, U)

    Inorganic Chemistry · 2014-06-16

    Alexandre Hervé, Yamina Bouzidi, J.‐C. Berthet, Lotfi Belkhırı, P. Thuéry, Abdou Boucekkine, M. Ephritikhine

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  32. Synthesis, Structural Characterization, and Carbonyl Addition Reactivity of a Terminal Cerium(III) Acetylide Complex

    Organometallics · 2014-10-28

    Jee Eon Kim, David S. Weinberger, Patrick J. Carroll, Eric J. Schelter

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  33. A Highly Triflated Rare‐Earth Ion in [Eu(O3SCF3)8]5−

    Chemistry - A European Journal · 2015-07-14

    Jörn Bruns, Sascha Krüger, Matthias Adlung, Claudia Wickleder, Oliver Niehaus, Rainer Pöttgen, Thorsten Klüner, Jessica Kräuter, Mathias Siegfried Wickleder

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  34. Complexation of actinides Am(III), Th(IV), Pu(IV) and U(VI) with poly-N-dentate ligands SO3-Ph-BTP and SO3-Ph-BTBP

    Unknown journal · 2016-12-12

    Łukasz Steczek

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  35. Ligand size dependence of U–N and U–O bond character in a series of uranyl hexaphyrin complexes: quantum chemical simulation and density based analysis

    Physical Chemistry Chemical Physics · 2017-01-01

    Poppy Di Pietro, Andrew Kerridge

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  36. Actinide Pincer Chemistry

    Elsevier eBooks · 2018-01-01

    Connor S. MacNeil, Tara K. K. Dickie, Paul G. Hayes

    Read original paper ↗ ·

  37. Luminescent and magnetic properties of mononuclear lanthanide thiocyanates with terpyridine as auxiliary ligand

    Inorganica Chimica Acta · 2018-11-09

    S.P. Petrosyants, Andrey B. Ilyukhin, Andrey Vyacheslavovich Gavrikov, Yana A. Mikhlina, Lada N. Puntus, Evgenia A. Varaksina, Nikolay Nikolaevich Efimov, Vladimir M. Novotortsev

    Read original paper ↗ ·

  38. Polypyridines, Picrates, Lanthanides: A Plethora of Stacks?

    Australian Journal of Chemistry · 2019-12-22

    Eric J. Chan, S. A. Cotton, Jack McB. Harrowfield, Brian W. Skelton, Alexandre N. Sobolev, ALLAN HENRY WHITE

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  39. Complexes featuring a linear [N≡U≡N] core isoelectronic to the uranyl cation

    Nature Chemistry · 2020-08-03

    Stefan S. Rudel, Holger Lars Deubner, Matthias Müller, Antti J. Karttunen, Florian Kraus

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  40. Mildly-doped polythiophene with triflates for molecular recognition

    Synthetic Metals · 2021-08-24

    Aicha Boujnah, Aïmen Boubaker, Adel Kalboussi, K. Lmimouni, Sébastien Pecqueur

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  41. N-Heterocyclic and Mesoionic Carbene Complexes of the Actinides

    Elsevier eBooks · 2021-08-30

    Stephan Hohloch, James R. Pankhurst

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  42. Reactivity of a dithorium oxo complex from adventitious water

    Dalton Transactions · 2025-01-01

    Pritam Mahawar, Steven P. Kelley, Justin R. Walensky

    Read original paper ↗ ·
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