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RESEARCH PAPER · Chemistry of Materials · 2002

Synthesis of Cyclical Diamine Templated Uranium Sulfates

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Synthesis of Cyclical Diamine Templated Uranium SulfatesOriginal22 New compounds and structures in the solid state221 New compounds and structures in the solid state1Structural diversity in organically templated uranium sulfatesElectronic supplementary information (ESI) available: three-dimensional packing diagrams for USO-6–USO-10. See http://www.rsc.org/suppdata/dt/b2/b209208e/97Reactant-Mediated Diversity in Uranyl Phosphonates58catena-Poly[tetramethylammonium [[(nitrato-κ2O,O′)dioxouranium]-μ3-sulfato]]13catena-Poly[1-methylpiperazinium [[aquadioxouranium(VI)]-di-μ-sulfato-κ4O:O′]]12The effects of linear diamine chain length in uranium sulfates48Synthesis, Structure, and Photoelectronic Effects of a Uranium−Zinc−Organic Coordination Polymer Containing Infinite Metal Oxide Sheets305Synthesis and structure of organically templated lanthanum sulfate [C4N3H16][La(SO4)3]·H2O57The first organically templated linear metal selenate50Controlled Structural Variations in Templated Uranium Sulfates68catena-Poly[cyclohexane-1,4-diammonium [[dioxo(sulfato-κ2O,O′)uranium(VI)]-μ-sulfato] dihydrate]14Poly[[1,4-bis-(3-aminopropyl)piperazinium] [[dioxouranium(VI)]-di-μ2,μ3-sulfato]]12[(Th2F5)(NC7H5O4)2(H2O)][NO3]: An Actinide−Organic Open Framework85Exploration of Composition Space in Templated Uranium Sulfates89Topological Evolution in Uranyl Dicarboxylates: Synthesis and Structures of One-Dimensional UO2(C6H8O4)(H2O)2 and Three-Dimensional UO2(C6H8O4)130New one-dimensional uranyl and neptunyl iodates: crystal structures of K3[(UO2)2(IO3)6](IO3)·H2O and K[NpO2(IO3)3]·1.5H2O22New linear and layered amine-templated lanthanum sulfates54Hydrothermal synthesis and structure of K6[(UO2)4(CrO4)7]·6H2O: A layered uranyl chromate with a new uranyl sheet topology30The effects of hydrofluoric acid addition on the hydrothermal synthesis of templated uranium sulfates46[N2C6H14]2[(UO2)6(H2O)2F2(PO4)2(HPO4)4]·4H2O: A New Microporous Uranium Phosphate Fluoride50The First Amine‐Templated Layered Metal Selenates23(C8H26N4)0.5[(UO2)2(SO4)3(H2O)]·2H2O, an organically templated uranyl sulfate with a novel layer type22Combinatorial topology of salts of inorganic oxoacids: zero-, one- and two-dimensional units with corner-sharing between coordination polyhedra103Synthesis and crystal structure of a new neodymium(III) selenate-selenite: Nd2(SeO4)(SeO3)2(H2O)217Comparative study of the flexibility of structural complexes in uranyl sulfates, chromates, and molybdates28Toward Templated Metal−Organic Frameworks: Synthesis, Structures, Thermal Properties, and Luminescence of Three Novel Lanthanide−Adipate Frameworks227Structural variation in organically templated uranium sulfate fluorides42Highly Porous Uranyl Selenate Nanotubules170[C2N2H10]1.5[Nd(SO4)3(H2O)]·2H2O: The first organically templated neodymium sulfate with a layer structure21(C7H20N2)[(UO2)2(SO4)3(H2O)]: an organically templated uranium sulfate with a novel layer topology18(C3H12N2)2[UO2(H2O)2(SO4)2]2·2H2O: an organically templated uranium sulfate with a novel dimer type14The Role of Amine Sulfates in Hydrothermal Uranium Chemistry63[H2en]2{La2M(SO4)6(H2O)2} (M=Co, Ni): First organically templated 3d–4f mixed metal sulfates38Three-dimensional porous framework formed by [Fe4Mo6O26]4− anions belts in brick-wall mode1Synthesis, Crystal Structure, and Magnetic Properties of a Three‐Dimensional Hydroxide Sulfate: Mn5(OH)8SO412Amine‐Templated Uranyl Selenates with Layered Structures. I Structural Diversity of Sheets with a U:Se ratio of 1:239Low‐Dimensional Structural Units in Amine‐Templated Uranyl Oxoselenates(VI): Synthesis and Crystal Structures of [C3H12N2][(UO2)(SeO4)2(H2O)2](H2O), [C5H16N2]2[(UO2)(SeO4)2(H2O)](NO3)2, [C4H12N][(UO2)(SeO4)(NO3)], and [C4H14N2][(UO2)(SeO4)2(H2O)]40Crystal Structure of (H3O)6[(UO2)5(SeO4)8(H2O)5](H2O)58Synthesis, Structure and Photoluminescent Studies of Two Novel Layered Uranium Coordination Polymers Constructed from UO(OH) Polyhedra and Pyridinedicarboxylates79Organically-templated metal sulfates, selenites and selenates194Two new 3D organically templated cerium sulfates, hydrothermal synthesis and structural characterization7Hydrothermal synthesis and crystal structure of a new inorganic/organic hybrid of scandium sulfate: (H2en)Sc2(SO4)4·(H2O)0.727Synthesis and structure of the first organic–inorganic hybrid tin (II) chlorosulfate: [C6N2H14][SnCl2SO4]2Organically Directed Iron Sulfate Chains: Structural Diversity Based on Hydrogen Bonding Interactions31Hydrothermal synthesis, crystal structure, and characterization of a new pseudo-two-dimensional uranyl oxyfluoride, [N(C2H5)4]2[(UO2)4(OH2)3F10]17A new dabco templated metal sulfate, (C6H14N2)[Mn (H2O)6](SO4)2. Chemical preparation, hydrogen-bonded structure and thermal decomposition33Hydrothermal synthesis, structure and thermal stability of diamine templated layered uranyl-vanadates23Actinide compounds containing hexavalent cations of the VI group elements (S, Se, Mo, Cr, W)26Organic–inorganic hybrid materials constructed from inorganic lanthanide sulfate skeletons and organic 4,5-imidazoledicarboxylic acid115Synthesis, crystal structure and optical properties of [Ag(UO2)3(OAc)9][Zn(H2O)4(CH3CH2OH)2]: A novel compound containing closed-shell 3d10, 4d10 and 5d10 metal ions31Synthesis, Structure, and Upconversion Studies on Organically Templated Uranium Phosphites31Novel two-dimensional uranyl–organic assemblages in the citrate and d (–)-citramalate families46Synthesis and structural characterization of four new organically-directed bismuth sulfates5(2,2′-bipy)[In2(OH)2(H2O)](SO4)2: The first indium sulfate with a layer structure8Uranyl Ion Complexes with Cucurbit[n]urils (n = 6, 7, and 8): A New Family of Uranyl-Organic Frameworks127Synthetic Approaches for Noncentrosymmetric Molybdates59Synthesis and Structural Characterization of Open-Framework Copper (II) Sulfates22Two novel uranyl–organic frameworks with cyclohexane-1,3-dicarboxylate ligands40Syntheses, structures, characterizations and charge-density matching of novel amino-templated uranyl selenates45Alternative approaches to structure description1Anion-topology approach0Basic concepts3Copyright Page0Dedication0Dimensional reduction in inorganic oxysalts0Graph theory applied to low-dimensional structural units in inorganic oxysalts2Preface0Structural Crystallography of Inorganic Oxysalts127Topology of framework structures in inorganic oxysalts0Synthesis and Crystal Structure of the First Two-dimensional Inorganic/Organic Composite Solid of Iron(III) Molybdate3Glycine-Templated Manganese Sulfate with New Topology and Canted Antiferromagnetism35A new series of pillared uranyl-vanadates based on uranophane-type sheets in the uranium-vanadium-linear alkyl diamine systems28Uranyl selenates with organic templates: Principles of structure and characteristics of self-organization23Two- and Three-Dimensional Open-Framework Uranium Arsenates: Synthesis, Structure, and Characterization18Actinyl Compounds with Hexavalent Elements (S, Cr, Se, Mo) – Structural Diversity, Nanoscale Chemistry, and Cellular Automata Modeling69New three-dimensional inorganic frameworks based on the uranophane-type sheet in monoamine templated uranyl-vanadates28Synthesis, characterization and magnetic properties of four new organically templated metal sulfates [C5H14N2][MII(H2O)6](SO4)2, (MII = Mn, Fe, Co, Ni)35Incorporation of Mn(II) and Fe(II) into Uranyl Carboxyphosphonates38Beyond Charge Density Matching: The Role of C–H···O Interactions in the Formation of Templated Vanadium Tellurites16A series of new rare earth sulfates based on lanthanide contraction and dual organic-amine templating effects12Isopropylammonium Layered Uranyl Chromates: Syntheses and Crystal Structures of [(CH3)2CHNH3]3[(UO2)3(CrO4)2O(OH)3] and[(CH3)2CHNH3]2[(UO2)2(CrO4)3(H2O)]30Structural topology and dimensional reduction in uranyl oxysalts: eight novel phases in the methylamine–(UO2)(NO3)2–H2SeO4–H2O system24Influence of the Organic Species and Oxoanion in the Synthesis of two Uranyl Sulfate Hydrates, (H3O)2[(UO2)2(SO4)3(H2O)]·7H2O and (H3O)2[(UO2)2(SO4)3(H2O)]·4H2O, and a Uranyl Selenate‐Selenite [C5H6N][(UO2)(SeO4)(HSeO3)]15Amine templating effect absent in uranyl sulfates synthesized with 1,4-n-butyldiamine14The synthesis, structure and magnetism studies of two manganese sulfates with a 3D zeolite GIS framework and 1D chain structure8Crystal Chemistry of Uranium Oxides and Minerals27Topologically and geometrically flexible structural units in seven new organically templated uranyl selenates and selenite–selenates22Coherent Fusion of Water Array and Protonated Amine in a Metal–Sulfate-Based Coordination Polymer for Proton Conduction18Reactions of metal salts with bronsted acidic ionic liquid: Formations of imidazole template metal sulfates or imidazole-metal complexes6Inorganic Synthesis of Actinides3Crystal-Chemical Features of U(VI) Compounds with Inorganic Complexes Derived from [(UO2)(TO4)(H2O)n], T = S, Cr, Se: Synthesis and Crystal Structures of Two New Uranyl Sulfates7Structural unit charge density and molecular cation templating effects on orientational geometric isomerism and interlayer spacing in 2-D uranyl sulfates11Open-framework sodium uranyl selenate and sodium uranyl sulfate with protonated morpholino-N-acetic acid13Effect of solution acidity on the structure of amino acid-bearing uranyl compounds7The role of 1-ethyl-3-methylimidazolium diethyl phosphate ionic liquid in uranyl phosphate compounds7Crystal chemistry of the M 2+ [(UO 2 )(T 6+ O 4 ) 2 (H 2 O)](H 2 O) 4 (M 2+ = Mg, Mn, Fe, Co, Ni and Zn; T 6+ = S, Se) compounds: the interplay between chemical composition, pH and structural architecture6Effect of Ionothermal Conditions on the Crystallization of Organically Templated Uranyl Sulfate Compounds6Hydrogen bond network and bond valence analysis on uranyl sulfate compounds with organic-based interstitial cations5Exploring the Role of Organic Functional Groups in the Ionothermal Synthesis of Uranyl Phosphate Materials3SYNTHESIS AND STRUCTURES OF NEW DISULFATOURANYLATES0Synthesis and Structures of New Disulfatouranylates0Organically Templated Uranyl Sulfates and Selenates: Structural Complexity and Crystal Chemical Restrictions for Isotypic Compounds Formation7

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  7. The effects of linear diamine chain length in uranium sulfates

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  8. Synthesis, Structure, and Photoelectronic Effects of a Uranium−Zinc−Organic Coordination Polymer Containing Infinite Metal Oxide Sheets

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  9. Synthesis and structure of organically templated lanthanum sulfate [C4N3H16][La(SO4)3]·H2O

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  11. Controlled Structural Variations in Templated Uranium Sulfates

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  12. catena-Poly[cyclohexane-1,4-diammonium [[dioxo(sulfato-κ2O,O′)uranium(VI)]-μ-sulfato] dihydrate]

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  13. Poly[[1,4-bis-(3-aminopropyl)piperazinium] [[dioxouranium(VI)]-di-μ2,μ3-sulfato]]

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  14. [(Th2F5)(NC7H5O4)2(H2O)][NO3]: An Actinide−Organic Open Framework

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  15. Exploration of Composition Space in Templated Uranium Sulfates

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  16. Topological Evolution in Uranyl Dicarboxylates: Synthesis and Structures of One-Dimensional UO2(C6H8O4)(H2O)2 and Three-Dimensional UO2(C6H8O4)

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  17. New one-dimensional uranyl and neptunyl iodates: crystal structures of K3[(UO2)2(IO3)6](IO3)·H2O and K[NpO2(IO3)3]·1.5H2O

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  18. New linear and layered amine-templated lanthanum sulfates

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  19. Hydrothermal synthesis and structure of K6[(UO2)4(CrO4)7]·6H2O: A layered uranyl chromate with a new uranyl sheet topology

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  20. The effects of hydrofluoric acid addition on the hydrothermal synthesis of templated uranium sulfates

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  21. [N2C6H14]2[(UO2)6(H2O)2F2(PO4)2(HPO4)4]·4H2O: A New Microporous Uranium Phosphate Fluoride

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  22. The First Amine‐Templated Layered Metal Selenates

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  23. (C8H26N4)0.5[(UO2)2(SO4)3(H2O)]·2H2O, an organically templated uranyl sulfate with a novel layer type

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  24. Combinatorial topology of salts of inorganic oxoacids: zero-, one- and two-dimensional units with corner-sharing between coordination polyhedra

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  25. Synthesis and crystal structure of a new neodymium(III) selenate-selenite: Nd2(SeO4)(SeO3)2(H2O)2

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  26. Comparative study of the flexibility of structural complexes in uranyl sulfates, chromates, and molybdates

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  32. (C3H12N2)2[UO2(H2O)2(SO4)2]2·2H2O: an organically templated uranium sulfate with a novel dimer type

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  33. The Role of Amine Sulfates in Hydrothermal Uranium Chemistry

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  34. [H2en]2{La2M(SO4)6(H2O)2} (M=Co, Ni): First organically templated 3d–4f mixed metal sulfates

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  35. Three-dimensional porous framework formed by [Fe4Mo6O26]4− anions belts in brick-wall mode

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  36. Synthesis, Crystal Structure, and Magnetic Properties of a Three‐Dimensional Hydroxide Sulfate: Mn5(OH)8SO4

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  37. Amine‐Templated Uranyl Selenates with Layered Structures. I Structural Diversity of Sheets with a U:Se ratio of 1:2

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  38. Low‐Dimensional Structural Units in Amine‐Templated Uranyl Oxoselenates(VI): Synthesis and Crystal Structures of [C3H12N2][(UO2)(SeO4)2(H2O)2](H2O), [C5H16N2]2[(UO2)(SeO4)2(H2O)](NO3)2, [C4H12N][(UO2)(SeO4)(NO3)], and [C4H14N2][(UO2)(SeO4)2(H2O)]

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  39. Crystal Structure of (H3O)6[(UO2)5(SeO4)8(H2O)5](H2O)5

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  40. Synthesis, Structure and Photoluminescent Studies of Two Novel Layered Uranium Coordination Polymers Constructed from UO(OH) Polyhedra and Pyridinedicarboxylates

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  44. Synthesis and structure of the first organic–inorganic hybrid tin (II) chlorosulfate: [C6N2H14][SnCl2SO4]

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  45. Organically Directed Iron Sulfate Chains: Structural Diversity Based on Hydrogen Bonding Interactions

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  46. Hydrothermal synthesis, crystal structure, and characterization of a new pseudo-two-dimensional uranyl oxyfluoride, [N(C2H5)4]2[(UO2)4(OH2)3F10]

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  47. A new dabco templated metal sulfate, (C6H14N2)[Mn (H2O)6](SO4)2. Chemical preparation, hydrogen-bonded structure and thermal decomposition

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  48. Hydrothermal synthesis, structure and thermal stability of diamine templated layered uranyl-vanadates

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  49. Actinide compounds containing hexavalent cations of the VI group elements (S, Se, Mo, Cr, W)

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  50. Organic–inorganic hybrid materials constructed from inorganic lanthanide sulfate skeletons and organic 4,5-imidazoledicarboxylic acid

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