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RESEARCH PAPER · Journal of the American Chemical Society · 1999

The First Open Framework Actinide Material (C4N2H12)U2O4F6 (MUF-1)

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The First Open Framework Actinide Material (C4N2H12)U2O4F6 (MUF-1)OriginalFrom Molecules to Frameworks: Variable Dimensionality in the UO2(CH3COO)2·2H2O/HF(aq)/Piperazine System. Syntheses, Structures, and Characterization of Zero-Dimensional (C4N2H12)UO2F4·3H2O, One-Dimensional (C4N2H12)2U2F12·H2O, Two-Dimensional (C4N2H12)2(U2O4F5)4·11H2O, and Three-Dimensional (C4N2H12)U2O4F679Anorganische Materialien mit offenen Gerüsten298ChemInform Abstract: The First Open Framework Actinide Material (C4N2H12) U2O4F6 (MUF‐1).1Anorganische Chemie 19991A New Porous Three-Dimensional Lanthanide Coordination Polymer170Hydrothermal Synthesis of (C6N2H14)2(UVI2UIVO4F12), a Mixed-Valent One-Dimensional Uranium Oxyfluoride63Low-Dimensional Organically Templated Uranium Fluorides (C5H14N2)2U2F12·2H2O and (C2H10N2)U2F10: Hydrothermal Syntheses, Structures, and Magnetic Properties67Molecular and electronic structure of AnIVFeII(CN)6·xH2O (An = Th, U, Np) compounds: an X-ray absorption spectroscopy investigation13Hydrothermal Syntheses of Layered Uranium Oxyfluorides: Illustrations of Dimensional Reduction43Hydrothermal Syntheses, Structures, and Fluorescence Spectroscopy of New One-Dimensional Uranium Oxyfluorides Built from Edge-Sharing [UO2F5] Pentagonal Bipyramids78Novel Open-Framework Material: Cerium Oxyfluoride with CeO6F2 Dodecahedron20Chapter 1 The zeolite scene—An overview54Synthesis and characterisation of (C4N2H12)(UO2)2(PO3H)2{PO2(OH)H}2: a three dimensionally connected actinide framework46Hydrothermal Synthesis, Structure, and Magnetic Properties of a Layered Organically Templated Uranium Aquofluoride: [C5H14N2][U2F10(H2O)]44Structural Relationships, Interconversion, and Optical Properties of the Uranyl Iodates, UO2(IO3)2and UO2(IO3)2(H2O): A Comparison of Reactions under Mild and Supercritical Conditions115Hydrothermal Syntheses, Structures, and Magnetic Properties of the U(IV) Fluorides (C5H14N2)2U2F12·5H2O and (NH4)7U6F3143Organically Templated Zirconium Fluorides: Hydrothermal Syntheses, Structural Relationships, and Thermal Behavior of (C2H10N2)Zr2F10·H2O and (C4H12N2)ZrF6·H2O22Excision of Uranium Oxide Chains and Ribbons in the Novel One-Dimensional Uranyl Iodates K2[(UO2)3(IO3)4O2] and Ba[(UO2)2(IO3)2O2](H2O)73A New Oxoanion: [IO4]3-Containing I(V) with a Stereochemically Active Lone-Pair in the Silver Uranyl Iodate Tetraoxoiodate(V), Ag4(UO2)4(IO3)2(IO4)2O282A New Modification of Monoaquadifluorouranyl Hydrate6New Tellurites: Syntheses, Structures, and Characterization of K2Te4O9·3.2H2O, KGaTe6O14, and KGaTe2O6·1.8H2O49Cation Effects on the Formation of the One-Dimensional Uranyl Iodates A2[(UO2)3(IO3)4O2] (A=K, Rb, Tl) and AE[(UO2)2(IO3)2O2] (H2O) (AE=Sr, Ba, Pb)53Poly(tetrafluoroethylene) Impregnation for Ion-Exchange Reactions with Layered Ce(IV) Fluorides8[NC 4 H 12 ] 2 [(UO 2 ) 6 (H 2 O) 2 (SO 4 ) 7 ]: the first organically templated actinide sulfate with a three-dimensional framework structure102The first organically templated thorium compounds, [C 4 N 2 H 12 ] 0.5 [ThF 5 ] and [C 5 N 2 H 14 ][ThF 6 ]·0.5H 2 O29The First Organically Templated Layered Cerium Phosphate-Hydrogen Sulfate: [enH2]0.5[CeIII(PO4)(HSO4)(OH2)]15Organically templated uranium(vi) sulfates: understanding phase stability using composition space83Incorporation of uranium( vi ) into metal–organic framework solids, [UO 2 (C 4 H 4 O 4 )]·H 2 O, [UO 2 F(C 5 H 6 O 4 )]·2H 2 O, and [(UO 2 ) 1.5 (C 8 H 4 O 4 ) 2 ] 2 [(CH 3 ) 2 NCOH 2 ]·H 2 O98The Actinides34A Novel Open Framework Uranyl Molybdate: Synthesis and Structure of (NH4)4[(UO2)5(MoO4)7](H2O)567Hydrothermal Preparation of Nickel(II)/Uranium(IV) Fluorides with One-, Two-, and Three-Dimensional Topologies17Variable Dimensionality in the UO2(CH3CO2)2·2H2O/HF/Isonicotinic Acid System: Synthesis and Structures of Zero-, One-, and Two-Dimensional Uranium Isonicotinates56The effects of linear diamine chain length in uranium sulfates48Synthesis, Structure, and Photoelectronic Effects of a Uranium−Zinc−Organic Coordination Polymer Containing Infinite Metal Oxide Sheets305Controlled Structural Variations in Templated Uranium Sulfates68[(Th2F5)(NC7H5O4)2(H2O)][NO3]: An Actinide−Organic Open Framework852D Chiral Uranyl( VI ) Coordination Polymers with Second‐Harmonic Generation Response and Ferroelectric Properties78Exploration of Composition Space in Templated Uranium Sulfates89Topological Evolution in Uranyl Dicarboxylates: Synthesis and Structures of One-Dimensional UO2(C6H8O4)(H2O)2 and Three-Dimensional UO2(C6H8O4)130Synthesis and characterization of two novel mixed metal tellurates: KGaTeO 5 ·H 2 O and K 3 GaTe 2 O 8 (OH) 2 ·H 2 O12[N2C6H14]2[(UO2)6(H2O)2F2(PO4)2(HPO4)4]·4H2O: A New Microporous Uranium Phosphate Fluoride50[N(CH2CH2NH3)3][U3O2F13]·2H2O: A Novel Organically Templated Mixed-Valent Uranium Oxyfluoride with a Hybrid Network Structure32Hydrothermal Synthesis and Characterization of [(UO2)2F8(H2O)2Zn2(4,4‘-bpy)2]·(4,4‘-bpy), a Mixed-Metal Uranyl Aquofluoride with a Pillared Layer Structure51[N(CH3)4][(UO2)2F5]: A new organically templated open-framework uranium oxide fluoride (MUF-2)38UF3(H2O)(C2O4)0.5: A Fluorooxalate of Tetravalent Uranium with a Three-Dimensional Framework Structure16Directed Synthesis of Noncentrosymmetric Molybdates Using Composition Space Analysis72Product evolution in the Np(IV) fluorophosphate system15Synthesis and characterization of zeolite mazzite analogue in Na2O–Al2O3–SiO2–Piperazine–H2O20Hydrothermal synthesis, structure and thermal stability of diamine templated layered uranyl-vanadates23Organically templated uranium( iv ) fluorooxalates with layer structures: (H 4 TREN)[U 2 F 6 (C 2 O 4 ) 3 ]·4H 2 O (TREN = tris(2-aminoethyl)amine) and (H 4 APPIP)[U 2 F 6 (C 2 O 4 ) 3 ]·4H 2 O (APPIP = 1,4-bis(3-amino-propyl)piperazine)6The role of temperature in the solvothermal synthesis of hybrid vanadium oxyfluorides41A Crown Ether as Template for Microporous and Nanostructured Uranium Compounds90A Crown Ether as Template for Microporous and Nanostructured Uranium Compounds11Offene Gerüststrukturen von Übergangsmetallen24Open‐Framework Structures of Transition‐Metal Compounds380Synthesis and structure of [C6H14N2][(UO2)4(HPO4)2(PO4)2(H2O)]·H2O: An expanded open-framework amine-bearing uranyl phosphate12Highly Porous Polysilsesquioxane Networks via Hydrosilylative Polymerization of Macrocyclic Oligomeric Silsesquioxanes24An Open-Framework Thorium Sulfate Hydrate with 11.5 Å Voids42Glycine-Templated Manganese Sulfate with New Topology and Canted Antiferromagnetism35Phosphonoacetate as a Ligand for Constructing Layered and Framework Alkali Metal Uranyl Compounds45Catalytic performance of the high and low temperature polymorphs of (C 6 N 2 H 16 ) 0.5 [(VO)(HAsO 4 )F]: structural, thermal, spectroscopic and magnetic studies12Amine templated two- and three-dimensional uranyl sulfates24Synthesis, Structure, and Solid-State Transformation Studies of Phosphonoacetate Based Hybrid Compounds of Uranium and Thorium48Oxo Boron Clusters and Their Open Frameworks128Modular Metal Chalcogenide Chemistry: Secondary Building Blocks as a Basis of the Silicate‐Type Framework Structure of CsLiU(PS4)213Syntheses, structures and luminescent properties of two one-dimensional uranium oxyfluorides12Uranyl Bearing Hybrid Materials: Synthesis, Speciation, and Solid-State Structures418Bisactinyl halogenated complexes: relativistic density functional theory calculation and experimental synthesis9From an Open Framework to a Layered and a Hexagonal Tungsten Oxide Structure: Controlled Transformation Reactions of an Extended Solid-State Material, Cs3Ga7(SeO3)12 to Ga(OH)(SeO3) and KGa3(SeO4)2(OH)613Crystal structures of tetravalent uranium fluorides obtained in the presence of hydrazine from uranyl source7Heterometallic zinc uranium oxyfluorides incorporating imidazole ligands3Insight into the Uranyl Oxyfluoride Topologies through the Synthesis, Crystal Structure, and Evidence of a New Oxyfluoride Layer in [(UO2)4F13][Sr3(H2O)8](NO3)·H2O6Synthesis and Study of the First Zeolitic Uranium Borate22Piperazine as a versatile organic structure-directing agent for zeolite synthesis: effect of SiO2/Al2O3 ratio on phase selectivity11Solubilité et fluoration d’oxydes d’uranium en milieu liquide ionique0Three-dimensional metal-halide open frameworks56Recent advances in the synthesis and applications of mordenite zeolite – review128Hydrothermal Synthesis and Structural Investigation of a Crystalline Uranyl Borosilicate3Features of Uranium Stereochemistry in Uranyl Oxofluorides6Solvothermal and hydrothermal methods for preparative solid-state chemistry5

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  1. From Molecules to Frameworks: Variable Dimensionality in the UO2(CH3COO)2·2H2O/HF(aq)/Piperazine System. Syntheses, Structures, and Characterization of Zero-Dimensional (C4N2H12)UO2F4·3H2O, One-Dimensional (C4N2H12)2U2F12·H2O, Two-Dimensional (C4N2H12)2(U2O4F5)4·11H2O, and Three-Dimensional (C4N2H12)U2O4F6

    Journal of the American Chemical Society · 1999-10-30

    Susan M. Walker, P. Shiv Halasyamani, S. J. Allen, Dermot O’Hare

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  2. Anorganische Materialien mit offenen Gerüsten

    Angewandte Chemie · 1999-11-15

    Anthony Kevin Cheetham, Gérard Férey, Thierry Loiseau

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  3. ChemInform Abstract: The First Open Framework Actinide Material (C4N2H12) U2O4F6 (MUF‐1).

    ChemInform · 1999-12-14

    P. Shiv Halasyamani, S. M. Walker, Dermot O’Hare

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  4. Anorganische Chemie 1999

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  5. A New Porous Three-Dimensional Lanthanide Coordination Polymer

    Inorganic Chemistry · 2000-07-26

    Long Pan, E. Brice Woodlock, Xiaotai Wang, Chong Zheng

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  6. Hydrothermal Synthesis of (C6N2H14)2(UVI2UIVO4F12), a Mixed-Valent One-Dimensional Uranium Oxyfluoride

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    Simon Allen, Stephen H. Barlow, P. Shiv Halasyamani, J. Frederick W. Mosselmans, Dermot O’Hare, Susan M. Walker, Richard I. Walton

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  7. Low-Dimensional Organically Templated Uranium Fluorides (C5H14N2)2U2F12·2H2O and (C2H10N2)U2F10: Hydrothermal Syntheses, Structures, and Magnetic Properties

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    Philip M. Almond, Laura Deakin, Melissa J. Porter, Arthur Mar, Thomas E. Albrecht‐Schmitt

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  8. Molecular and electronic structure of AnIVFeII(CN)6·xH2O (An = Th, U, Np) compounds: an X-ray absorption spectroscopy investigation

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    Isabelle Bonhoure, Christophe Den Auwer, Christophe Cartier, Philippe Moisy, J.‐C. Berthet, Charles Madic

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  9. Hydrothermal Syntheses of Layered Uranium Oxyfluorides: Illustrations of Dimensional Reduction

    Inorganic Chemistry · 2000-10-26

    Catherine E. Talley, Amanda C. Bean, Thomas E. Albrecht‐Schmitt

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  10. Hydrothermal Syntheses, Structures, and Fluorescence Spectroscopy of New One-Dimensional Uranium Oxyfluorides Built from Edge-Sharing [UO2F5] Pentagonal Bipyramids

    Journal of Solid State Chemistry · 2000-11-01

    Philip M. Almond, Catherine E. Talley, Amanda C. Bean, Shane M. Peper, Thomas E. Albrecht‐Schmitt

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  11. Novel Open-Framework Material: Cerium Oxyfluoride with CeO6F2 Dodecahedron

    Chemistry of Materials · 2000-11-28

    Ranbo Yu, Dan Wang, Nobuhiro Kumada, Nobukazu Kinomura

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  12. Chapter 1 The zeolite scene—An overview

    Studies in surface science and catalysis · 2001-01-01

    Theo L. M. Maesen, Bonnie Marcus

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  13. Synthesis and characterisation of (C4N2H12)(UO2)2(PO3H)2{PO2(OH)H}2: a three dimensionally connected actinide framework

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    M.B. Doran, Susan M. Walker, Dermot O’Hare

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  14. Hydrothermal Synthesis, Structure, and Magnetic Properties of a Layered Organically Templated Uranium Aquofluoride: [C5H14N2][U2F10(H2O)]

    Inorganic Chemistry · 2001-01-17

    Philip M. Almond, Laura Deakin, Arthur Mar, Thomas E. Albrecht‐Schmitt

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  15. Structural Relationships, Interconversion, and Optical Properties of the Uranyl Iodates, UO2(IO3)2and UO2(IO3)2(H2O): A Comparison of Reactions under Mild and Supercritical Conditions

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  16. Hydrothermal Syntheses, Structures, and Magnetic Properties of the U(IV) Fluorides (C5H14N2)2U2F12·5H2O and (NH4)7U6F31

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  17. Organically Templated Zirconium Fluorides: Hydrothermal Syntheses, Structural Relationships, and Thermal Behavior of (C2H10N2)Zr2F10·H2O and (C4H12N2)ZrF6·H2O

    Journal of Solid State Chemistry · 2001-06-01

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  18. Excision of Uranium Oxide Chains and Ribbons in the Novel One-Dimensional Uranyl Iodates K2[(UO2)3(IO3)4O2] and Ba[(UO2)2(IO3)2O2](H2O)

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  19. A New Oxoanion: [IO4]3-Containing I(V) with a Stereochemically Active Lone-Pair in the Silver Uranyl Iodate Tetraoxoiodate(V), Ag4(UO2)4(IO3)2(IO4)2O2

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  20. A New Modification of Monoaquadifluorouranyl Hydrate

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  21. New Tellurites: Syntheses, Structures, and Characterization of K2Te4O9·3.2H2O, KGaTe6O14, and KGaTe2O6·1.8H2O

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  22. Cation Effects on the Formation of the One-Dimensional Uranyl Iodates A2[(UO2)3(IO3)4O2] (A=K, Rb, Tl) and AE[(UO2)2(IO3)2O2] (H2O) (AE=Sr, Ba, Pb)

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  23. Poly(tetrafluoroethylene) Impregnation for Ion-Exchange Reactions with Layered Ce(IV) Fluorides

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  24. [NC 4 H 12 ] 2 [(UO 2 ) 6 (H 2 O) 2 (SO 4 ) 7 ]: the first organically templated actinide sulfate with a three-dimensional framework structure

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  25. The first organically templated thorium compounds, [C 4 N 2 H 12 ] 0.5 [ThF 5 ] and [C 5 N 2 H 14 ][ThF 6 ]·0.5H 2 O

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  26. The First Organically Templated Layered Cerium Phosphate-Hydrogen Sulfate: [enH2]0.5[CeIII(PO4)(HSO4)(OH2)]

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  27. Organically templated uranium(vi) sulfates: understanding phase stability using composition space

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  28. Incorporation of uranium( vi ) into metal–organic framework solids, [UO 2 (C 4 H 4 O 4 )]·H 2 O, [UO 2 F(C 5 H 6 O 4 )]·2H 2 O, and [(UO 2 ) 1.5 (C 8 H 4 O 4 ) 2 ] 2 [(CH 3 ) 2 NCOH 2 ]·H 2 O

    Dalton Transactions · 2003-01-01

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  29. The Actinides

    Elsevier eBooks · 2003-01-01

    Carol J. Burns, Mary P. Neu, Hakim Boukhalfa, Keith E. Gutowski, Nicholas J. Bridges, Robin Don Rogers

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  30. A Novel Open Framework Uranyl Molybdate: Synthesis and Structure of (NH4)4[(UO2)5(MoO4)7](H2O)5

    Inorganic Chemistry · 2003-03-14

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  31. Hydrothermal Preparation of Nickel(II)/Uranium(IV) Fluorides with One-, Two-, and Three-Dimensional Topologies

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  32. Variable Dimensionality in the UO2(CH3CO2)2·2H2O/HF/Isonicotinic Acid System: Synthesis and Structures of Zero-, One-, and Two-Dimensional Uranium Isonicotinates

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  33. The effects of linear diamine chain length in uranium sulfates

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  34. Synthesis, Structure, and Photoelectronic Effects of a Uranium−Zinc−Organic Coordination Polymer Containing Infinite Metal Oxide Sheets

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  35. Controlled Structural Variations in Templated Uranium Sulfates

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  36. [(Th2F5)(NC7H5O4)2(H2O)][NO3]: An Actinide−Organic Open Framework

    Journal of the American Chemical Society · 2003-09-26

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  37. 2D Chiral Uranyl( VI ) Coordination Polymers with Second‐Harmonic Generation Response and Ferroelectric Properties

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  38. Exploration of Composition Space in Templated Uranium Sulfates

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  39. Topological Evolution in Uranyl Dicarboxylates: Synthesis and Structures of One-Dimensional UO2(C6H8O4)(H2O)2 and Three-Dimensional UO2(C6H8O4)

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  40. Synthesis and characterization of two novel mixed metal tellurates: KGaTeO 5 ·H 2 O and K 3 GaTe 2 O 8 (OH) 2 ·H 2 O

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  41. [N2C6H14]2[(UO2)6(H2O)2F2(PO4)2(HPO4)4]·4H2O: A New Microporous Uranium Phosphate Fluoride

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  42. [N(CH2CH2NH3)3][U3O2F13]·2H2O: A Novel Organically Templated Mixed-Valent Uranium Oxyfluoride with a Hybrid Network Structure

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  43. Hydrothermal Synthesis and Characterization of [(UO2)2F8(H2O)2Zn2(4,4‘-bpy)2]·(4,4‘-bpy), a Mixed-Metal Uranyl Aquofluoride with a Pillared Layer Structure

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  44. [N(CH3)4][(UO2)2F5]: A new organically templated open-framework uranium oxide fluoride (MUF-2)

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  45. UF3(H2O)(C2O4)0.5: A Fluorooxalate of Tetravalent Uranium with a Three-Dimensional Framework Structure

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  46. Directed Synthesis of Noncentrosymmetric Molybdates Using Composition Space Analysis

    Inorganic Chemistry · 2006-06-10

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  47. Product evolution in the Np(IV) fluorophosphate system

    Journal of Solid State Chemistry · 2006-09-30

    Travis H. Bray, Tyler A. Sullens, Tatiana Y. Shvareva, Richard E. Sykora, Richard Geoffrey Haire, Thomas E. Albrecht‐Schmitt

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  48. Synthesis and characterization of zeolite mazzite analogue in Na2O–Al2O3–SiO2–Piperazine–H2O

    Journal of Porous Materials · 2006-12-07

    Hui Xu, Peng Dong, Luhan Liu, J.-G. Wang, Feng Deng, Jinxiang Dong

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  49. Hydrothermal synthesis, structure and thermal stability of diamine templated layered uranyl-vanadates

    Journal of Solid State Chemistry · 2006-12-13

    Murielle Rivenet, Nicolas Vigier, Pascal Roussel, F. Abraham

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  50. Organically templated uranium( iv ) fluorooxalates with layer structures: (H 4 TREN)[U 2 F 6 (C 2 O 4 ) 3 ]·4H 2 O (TREN = tris(2-aminoethyl)amine) and (H 4 APPIP)[U 2 F 6 (C 2 O 4 ) 3 ]·4H 2 O (APPIP = 1,4-bis(3-amino-propyl)piperazine)

    Dalton Transactions · 2007-01-01

    Chih-Min Wang, Yi‐Ying Wu, Pei-Lin Chen, Kwang‐Hwa Lii

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