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RESEARCH PAPER · Inorganic Chemistry · 2000

Ligand Influences on the Structures of Molybdenum Oxide Networks

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Ligand Influences on the Structures of Molybdenum Oxide NetworksOriginalMolecular manipulation of solid state structure: influences of organic components on vanadium oxide architectures178Synthesis and Characterization of a New Layered Zinc Phosphate: (C3H4N2)3Zn4(HPO4)(PO4)2 with Imidazole Coordinating to Zn Atoms5Influences of secondary metal–ligand subunits on molybdenum oxide structures: the hydrothermal syntheses and structures of [M(tpytrz)2Mo4O13] (M = Fe, Co, Ni, Zn; tpytrz = tripyridyltriazine), [Ni(tpytrz)Mo2O7] and [Zn2(tpytrz)Mo2O8]54Structural Modulation of Molybdenyl Iodate Architectures by Alkali Metal Cations in AMoO3(IO3) (A = K, Rb, Cs): A Facile Route to New Polar Materials with Large SHG Responses337Organic−Inorganic Hybrid Materials: Hydrothermal Syntheses and Structural Characterization of Bimetallic Organophosphonate Oxides of the Type Mo/Cu/O/RPO32-/Organoimine95Solid state coordination chemistry: the hydrothermal synthesis and structure of a bimetallic oxide incorporating 2,2′:6′,2″-terpyridine (terpy), [{VO(terpy)}MoO4]8Further Evidence for the Tetraoxoiodate(V) Anion, IO43-: Hydrothermal Syntheses and Structures of Ba[(MoO2)6(IO4)2O4]·H2O and Ba3[(MoO2)2(IO6)2]·2H2O48New One-Dimensional Vanadyl Iodates: Hydrothermal Preparation, Structures, and NLO Properties of A[VO2(IO3)2] (A = K, Rb) and A[(VO)2(IO3)3O2] (A = NH4, Rb, Cs)161Sulfidation of Single Molecular Sheets of MoO3Pillared by Bipyridine in Nanohybrid MoO3(4,4‘-bipyridyl)0.539Large-Scale Organizations of MoO3 Nanoplatelets with Single-Crystalline MoO3(4,4‘-bipyridyl)0.546The synthesis and crystal structure of vanadium complexes: [VIVO2(phen)2]·6H2O and [2,2′-(bipy)2VVO2](H2BO3)·3H2O10Hydrothermal synthesis and crystal structure of an one-dimensional mixed-valence molybdenum oxide [Mo3O8(2,2′-bipy)2]14Modified Polyoxometalates: Hydrothermal Syntheses and Crystal Structures of Three Novel Reduced and Capped Keggin Derivatives Decorated by Transition Metal Complexes191Synthesis and structure of the two-dimensional bimetallic oxide [H4tphz]3[{Zn2(tphz)(H2O)4}{Mo5O15(O3PCH2CH2PO3)}4] · 14H2O: the hydrothermal conversion of tetra-2-pyridylpyrazine to tetrapyrido [2,3-a:3′,2′-c:2″,3″-h:3‴,2‴-j]phenazine (tphz)22The first polyoxometalate polymer constructed by assembly of the heptamolybdic anion and copper coordination groups19Hydrothermal synthesis and crystal structure of a novel 4,4′-bipyridine bridging dumbbell-like dimeric pentamolybdate: [4,4′-H2bipy]3[4,4′-Hbipy]2[(Mo5O17)2(4,4′-bipy)]7[C5H14N2][(MoO3)3(SO4)]·H2O: Sulfated α-Molybdena Chains44The first examples of benzidinium cations templated low-dimensional molybdates12One teflon ® -like channelled nanoporous polymer with a chiral and new uninodal 4-connected net: sorption and catalytic properties83Secondary metal–ligand cationic subunits {ML}n+ as structural determinants in the oxovanadium/phenylphosphonate/{ML}n+ system, where {ML} is a Cu2+/organonitrogen moiety34Directed Synthesis of Noncentrosymmetric Molybdates83Novel Multilamellar Mesostructured Molybdenum Oxide Nanofibers and Nanobelts: Synthesis and Characterization76One- and Two-Dimensional Coordination Polymers Constructed from Bicapped Keggin Mixed Molybdenum−Vanadium Heteropolyoxoanions and Polynuclear Copper(I) Clusters Bridged by Asymmetrical Bipyridine (2,4‘-bipy and 2,3‘-bipy) Ligands107Influence of metal ions on the structures of Keggin polyoxometalate-based solids: Hydrothermal syntheses, crystal structures and magnetic properties68Hydrothermal Synthesis and Characterization of Ethylenediamine-Containing Molybdenum Oxides0Influence of substituents on the structures of hybrid complexes constructed from tetranuclear copper(I) 1,2,4-triazolate clusters and octamolybdates31Polar Symmetry and Intercalation of New Multilayered Hybrid Molybdates: [M2(pzc)2(H2O)x][Mo5O16] (M = Co, Ni)19Controllable size, shape and morphology of molybdic acid self-aggregated with rhodamine B to construct functional material15Two pillared-layer architectures constructed from copper molybdate sheets and linear organonitrogen ligands3A Series of Inorganic−Organic Hybrid Composite Solids Based on Molybdenum Oxide Chains73Synthesis, Structure, and Magnetism of a Highly Thermally Stable Microporous Metal Organodiphosphonate with Reversible Dehydration/Rehydration Behavior27Highly adhesive layered molybdenum oxide thin films prepared on a silicon substrate using suitable buffer materials14Sequential transformations in assemblies based on octamolybdate clusters and 1,2-bis(4-pyridyl)ethane39A new molybdenum-oxide-based organic–inorganic hybrid framework templated by double-Keggin anions87Preparation and Characterization of a Layered Molybdenum Trioxide with Poly(o-anisidine) Hybrid Thin Film and Its Aldehydic Gases Sensing Properties22A Basket‐Like [Sr⊂P6MoV4MoVI14O73]10– Polyoxoanion Modified with {Cu(phen)(H2O)x} (x = 1–3) Fragments: Synthesis, Structure, Magnetic, and Electrochemical Properties54Metal-controlled self-assembly of arsenic–vanadium-cluster backbones with organic ligands32Self-assembly of polymer and molybdenum oxide into lamellar hybrid materials14VOCs sensing properties of layered organic–inorganic hybrid thin films: MoO3 with various interlayer organic components30Assembly of the Highest Connectivity Wells-Dawson Polyoxometalate Coordination Polymer: the Use of Organic Ligand Flexibility227Hydrogen Storage Properties of Rigid Three-Dimensional Hofmann Clathrate Derivatives: The Effects of Pore Size71Solid state coordination chemistry of molybdenum oxides with 1,2,3-triazole (Htrz): The crystal structures of [Cu(I)Cu(II)2(trz)2Mo4O13(OH)], [MoO3(Htrz)0.5] and [Cu(I)trz]34pH-Dependent Assembly of Hybrids Based on Wells-Dawson POM/Ag Chemistry159A three-dimensional organic–inorganic hybrid solid constructed from novel Mo–O–Zn bimetallic oxide networks linked via 3-amino-1,2,4-triazole11Preparation of Molybdic Acid Aggregates and Molybdenum Trioxide Powder with Controllable Size and Morphology1A Nano-Hybrid of Molybdenum Oxide Intercalated by Dithiocarbamate as an Oxidation Catalyst9Two new polyoxometalate-based organic-inorganic hybrids: synthesis, crystal structure and characterization5Assemblies of Copper Bis(triazole) Coordination Polymers Using the Same Keggin Polyoxometalate Template188Zn( ii ) and Cu( ii ) coordination polymers assembled from V-shaped tetracarboxylate ligands and N-donor ancillary ligands: syntheses, structures and properties48A new polyoxometalate-templated Mo/V-oxide-based organic–inorganic hybrid framework with a honeycomb-like structure50Assembly of two new polyoxometalate-templated supramolecular compounds by utilizing a ligand with a combination of rigidness and flexibility51Assembly of Multiply Chain-Modified Polyoxometalates: From One- to Three-Dimensional and from Finite to Infinite Track68Racemic twin crystals containing left- and right-handed polyoxometalate chains induced by the asymmetric coordination of metal–organic units13Alumina-membrane-assisted fabrication of porous hybrid molybdic acid/rhodamine B aggregates3Synthesis of Molybdenum Oxide Nanohybrids as Efficient Catalysts in Oxidation of Alcohols18Construction of Some Organic–Inorganic Hybrid Complexes Based on Polyoxometalates1A series of POM-based hybrid materials with different copper/aminotriazole motifs31Construction and property investigation of transition-metal complexes modified octamolybdate hybrid materials based on V-shaped organic ligands76Five 3D metal–organic frameworks constructed from V-shaped polycarboxylate acids and flexible imidazole-based ligands76Metal oxide-organic frameworks (MOOFs), a new series of coordination hybrids constructed from molybdenum(vi) oxide and bitopic 1,2,4-triazole linkers70Synthesis and structure of Na+-intercalated WO3(4,4′-bipyridyl)0.512Aqueous electrochemical insertion of Na+ into the tungsten oxide hybrid WO3(4,4′-bipyridyl)0.511A new pure Mo-oxide-based organic–inorganic hybrid framework templated by vanadium-substituted Keggin anions8Two new organic–inorganic supramolecular hybrids templated by the Wells–Dawson polyoxometalates9Synthesis, Structure, and Catalytic Performance in Cyclooctene Epoxidation of a Molybdenum Oxide/Bipyridine Hybrid Material: {[MoO3(bipy)][MoO3(H2O)]}n60A series of new organic–inorganic compounds templated by the [SiW12O40]4− polyanion14Hybrid Organic−Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications1755Two new organic–inorganic hybrid compounds based on metal–pyrazine coordination polymers and Keggin polyoxometalates: effect of metal ions on thestructure31Triazoles and tetrazoles: Prime ligands to generate remarkable coordination materials989Controllable self-assembly of four new metal–organic frameworks based on different phosphomolybdate clusters by altering the molar ratio of H3PO4 and Na2MoO489A series of POM-based entangled frameworks with the rigid ligand 1,4-bis(1-imidazolyl)benzene and different isomers of octamolybdate18Synthesis and characterization of two new triazolate–aliphatic dicarboxylate bridged Zn(II) coordination polymers based on 2D layer motifs with different crystal packing6Molybdenum oxide/bipyridine hybrid material {[MoO3(bipy)][MoO3(H2O)]}n as catalyst for the oxidation of secondary amines to nitrones31An Octanuclear Molybdenum(VI) Complex Containing Coordinatively Bound 4,4′-di-tert-Butyl-2,2′-Bipyridine, [Mo8O22(OH)4(di-tBu-bipy)4]: Synthesis, Structure, and Catalytic Epoxidation of Bio-Derived Olefins47A new Mo/V-oxide-based cationic species templated by Keggin polyoxotungstates (4-) and its catalytic activity in benzene hydroxylation7Synthesis, Structural Elucidation, and Application of a Pyrazolylpyridine–Molybdenum Oxide Composite as a Heterogeneous Catalyst for Olefin Epoxidation38One polyoxometalate-based hybrid 3-D network: synthesis, structure, photo- and electro-catalytic properties7Secondary spacer modulated assembly of polyoxometalate based metal–organic frameworks57An unprecedented 3D POM–Ag architecture with intertwined and homological helical structures52Nanostructured Inorganic–Organic Hybrid Semiconductor Materials3Hydrothermal Synthesis, Crystal Structure, and Catalytic Potential of a One-Dimensional Molybdenum Oxide/Bipyridinedicarboxylate Hybrid45Two Unusual 3D POM‐Ag Frameworks with Tetragonal and Dodecagonal Helical Channels46Hydrothermal syntheses and structures of bimetallic organoarsonate compounds of the Cu(II)-imine/V O /RAsO3− family5From 1D Chain to 3D Network: A New Family of Inorganic–Organic Hybrid Semiconductors MO3(L)x (M = Mo, W; L = Organic Linker) Built on Perovskite-like Structure Modules55Assembly of co-bimb-polyoxotungstate hybrids: from 1D chain to 3D framework influenced by the charge of Keggin anions25A new Keggin-templated heterometal-oxide-based organic–inorganic hybrid compound4Crystallization of Hybrid Molybdates based on Organic Bases2A new luminescent complex constructed by oxomolybdate and 3,5-di(4H-1,2,4-triazol-4-yl)benzoic acid via Mo–N bonds9Crystal Structure and Catalytic Behavior in Olefin Epoxidation of a One-Dimensional Tungsten Oxide/Bipyridine Hybrid22Synthesis and Structural Elucidation of Triazolylmolybdenum(VI) Oxide Hybrids and Their Behavior as Oxidation Catalysts40Assembly of sandwich-type 3-D supramolecular coordination polymers based on hexa-molybdenum chain and {PMo12O40} heteropolyanion8Self-assembly, bifunctional electrocatalytic behavior, and photocatalytic property of host–guest metal-oxide-based coordination polymers7Composition Space Analysis in the Development of Copper Molybdate Hybrids Decorated by a Bifunctional Pyrazolyl/1,2,4-Triazole Ligand31“Pinwheel” subunit-directed polyoxometalate-based hybrid compound [Cu(bimb) 2 ] 2 [β-Mo 8 O 26 ] with both helixes and chiral layers11Iron and Groups V- and VI-based MOFs5Metal oxide-triazole hybrids as heterogeneous or reaction-induced self-separating catalysts30Sonochemical Synthesis of a Nanosized Coordination Polymer with Catalytic Activity for Selective Epoxidation of Olefins7Synthesis, characterization and antibacterial properties of two POM-based supramolecular compounds with the natural active ingredient: (THB)3(H5PMo12O40) and (THB)3(H3PW12O40)13Layered Hybrid of Mo (VI)-Oxide Based On Electron-Rich Phenanthroline Organic Linkers1Behavior of Triazolylmolybdenum(VI) Oxide Hybrids as Oxidation Catalysts with Hydrogen Peroxide21Synthesis, structure and catalytic olefin epoxidation activity of a dinuclear oxo-bridged oxodiperoxomolybdenum(VI) complex containing coordinated 4,4′-bipyridinium24Triazolyl, Imidazolyl, and Carboxylic Acid Moieties in the Design of Molybdenum Trioxide Hybrids: Photophysical and Catalytic Behavior27Electron-rich phenanthroline as organic linkers in molybdenum oxide layered hybrid6Bicapped Keggin polyoxomolybdates: discrete species and experimental and theoretical investigations on the electronic delocalization in a chain compound8High-yield synthesis and catalytic response of chainlike hybrid materials of the [(MoO 3 ) m (2,2′-bipyridine) n ] family9Significant enhancement of conductance of a hybrid layered molybdate semiconductor by light or heat50A Linear Trinuclear Oxidodiperoxido‐molybdenum(VI) Complex with Single Triazole Bridges: Catalytic Activity in Epoxidation, Alcoholysis, and Acetalization Reactions19On the Border between Low-Nuclearity and One-Dimensional Solids: A Unique Interplay of 1,2,4-Triazolyl-Based {CuII5(OH)2} Clusters and MoVI-Oxide Matrix7Evidence of reduced species in molybdenum oxide-phenanthroline layered hybrids from structural, magnetic and X-ray photoelectron spectroscopy studies2A Comparative Study of Molybdenum Carbonyl and Oxomolybdenum Derivatives Bearing 1,2,3-Triazole or 1,2,4-Triazole in Catalytic Olefin Epoxidation8Molecular Passivation of MoO3: Band Alignment and Protection of Charge Transport Layers in Vacuum-Deposited Perovskite Solar Cells64Simple Hybrids Based on Mo or W Oxides and Diamines: Structure Determination and Catalytic Properties8Electrocatalytic Oxidation and Sensitive Determination of Paracetamol Based on Nanosheets Self‐assembled Lindgrenite Microflowers18Triazole‐Modified Molybdenum Oxide with High Proton Conductivity10Heterogeneous catalysis with an organic–inorganic hybrid based on MoO 3 chains decorated with 2,2′-biimidazole ligands15Synthesis and structural characterization of a new heterometallicmolybdate coordination polymer based on a µ3-bridging amino alcohol2Solvothermal and hydrothermal methods for preparative solid-state chemistry5Hybrid bronzes: mixed-valence organic–inorganic metal oxides as a tunable material platform19Electronic Structure of a Layered Organic–Inorganic Hybrid Material (WO3)2(4,4′-bipyridyl) Based on the First-principles Calculation3Pyrazine-bridged molybdenum(0) carbonyl and molybdenum(VI) oxide network solids as catalysts for epoxidation and sulfoxidation6A Hybrid Bronze Age: Progress and Potential in Mixed-Valence Organic–Inorganic Metal Oxides6Negative Compressibility Transitions in Hybrid Metal Oxides6Hydrothermal synthesis, characterization, and photocatalytic degradation of Rhodamine B dye of triazole modified molybdenum oxide0Dimensionality-driven optical and electronic evolution of naphthalenediimide-templated hybrid metal oxides0Understanding the activity-stability trade-off for low-cost vanadium-doped Co2C-Mo2C for efficient hydrogen evolution reaction in PEM water electrolysis5Proton Location in a Hybrid Molybdenum Bronze0

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  3. Influences of secondary metal–ligand subunits on molybdenum oxide structures: the hydrothermal syntheses and structures of [M(tpytrz)2Mo4O13] (M = Fe, Co, Ni, Zn; tpytrz = tripyridyltriazine), [Ni(tpytrz)Mo2O7] and [Zn2(tpytrz)Mo2O8]

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  4. Structural Modulation of Molybdenyl Iodate Architectures by Alkali Metal Cations in AMoO3(IO3) (A = K, Rb, Cs): A Facile Route to New Polar Materials with Large SHG Responses

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  5. Organic−Inorganic Hybrid Materials: Hydrothermal Syntheses and Structural Characterization of Bimetallic Organophosphonate Oxides of the Type Mo/Cu/O/RPO32-/Organoimine

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  6. Solid state coordination chemistry: the hydrothermal synthesis and structure of a bimetallic oxide incorporating 2,2′:6′,2″-terpyridine (terpy), [{VO(terpy)}MoO4]

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  9. Sulfidation of Single Molecular Sheets of MoO3Pillared by Bipyridine in Nanohybrid MoO3(4,4‘-bipyridyl)0.5

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  10. Large-Scale Organizations of MoO3 Nanoplatelets with Single-Crystalline MoO3(4,4‘-bipyridyl)0.5

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  14. Synthesis and structure of the two-dimensional bimetallic oxide [H4tphz]3[{Zn2(tphz)(H2O)4}{Mo5O15(O3PCH2CH2PO3)}4] · 14H2O: the hydrothermal conversion of tetra-2-pyridylpyrazine to tetrapyrido [2,3-a:3′,2′-c:2″,3″-h:3‴,2‴-j]phenazine (tphz)

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  15. The first polyoxometalate polymer constructed by assembly of the heptamolybdic anion and copper coordination groups

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  18. The first examples of benzidinium cations templated low-dimensional molybdates

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  19. One teflon ® -like channelled nanoporous polymer with a chiral and new uninodal 4-connected net: sorption and catalytic properties

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  21. Directed Synthesis of Noncentrosymmetric Molybdates

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  22. Novel Multilamellar Mesostructured Molybdenum Oxide Nanofibers and Nanobelts: Synthesis and Characterization

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  23. One- and Two-Dimensional Coordination Polymers Constructed from Bicapped Keggin Mixed Molybdenum−Vanadium Heteropolyoxoanions and Polynuclear Copper(I) Clusters Bridged by Asymmetrical Bipyridine (2,4‘-bipy and 2,3‘-bipy) Ligands

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  28. Controllable size, shape and morphology of molybdic acid self-aggregated with rhodamine B to construct functional material

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  29. Two pillared-layer architectures constructed from copper molybdate sheets and linear organonitrogen ligands

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  30. A Series of Inorganic−Organic Hybrid Composite Solids Based on Molybdenum Oxide Chains

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  31. Synthesis, Structure, and Magnetism of a Highly Thermally Stable Microporous Metal Organodiphosphonate with Reversible Dehydration/Rehydration Behavior

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  32. Highly adhesive layered molybdenum oxide thin films prepared on a silicon substrate using suitable buffer materials

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  33. Sequential transformations in assemblies based on octamolybdate clusters and 1,2-bis(4-pyridyl)ethane

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  35. Preparation and Characterization of a Layered Molybdenum Trioxide with Poly(o-anisidine) Hybrid Thin Film and Its Aldehydic Gases Sensing Properties

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  36. A Basket‐Like [Sr⊂P6MoV4MoVI14O73]10– Polyoxoanion Modified with {Cu(phen)(H2O)x} (x = 1–3) Fragments: Synthesis, Structure, Magnetic, and Electrochemical Properties

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