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RESEARCH PAPER · Nature Catalysis · 2023

Ultrasmall amorphous zirconia nanoparticles catalyse polyolefin hydrogenolysis

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Ultrasmall amorphous zirconia nanoparticles catalyse polyolefin hydrogenolysisOriginalPromoted Selectivity of Photocatalytic Co2 Reduction to C2h4 Via Hybrid Cucoxsy Possessing Dual Unsaturated Sites0Stable and efficient planar Cu/Cu 2 O film catalysts1Mechanistic Insights into Processive Polyethylene Hydrogenolysis throughIn SituNMR25Strategies for Designing the Catalytic Environment Beyond the Active site of Heterogeneous Supported Metal Catalysts18A two-stage strategy for upcycling chlorine-contaminated plastic waste141Investigation into the Reaction Pathways and Catalyst Deactivation for Polyethylene Hydrogenolysis over Silica-Supported Cobalt Catalysts58Hydrogen-free catalytic depolymerization of waste polyolefins at mild temperatures43SMSI-induced charge transfer for selective hydrogenolysis of polyolefins76Enhanced catalytic ozonation performance by CuOx nanoclusters/TiO2 nanotube and an insight into the catalytic mechanism20Two Mesoporous Domains Are Better Than One for Catalytic Deconstruction of Polyolefins62Treasuring trash: Pt/SrTiO3 catalysts process plastic waste into high-value materials25Activity of Silica-Alumina for the Conversion of Polyethylene into Tunable Aromatics Below Pyrolytic Temperatures20From Plastic Waste to Treasure: Selective Upcycling through Catalytic Technologies100Quantifying synergy for mixed end-scission and random-scission catalysts in polymer upcycling12Boosting the catalytic performance of metal–zeolite catalysts in the hydrocracking of polyolefin wastes by optimizing the nanoscale proximity56Excavating the Potential of Photo‐ and Electroupcycling Platforms Toward a Sustainable Future for Waste Plastics11Influence of Pore Length on Hydrogenolysis of Polyethylene within a Mesoporous Support Architecture17Solution combustion synthesis of Ce-free high entropy fluorite oxides: Formation, oxygen vacancy and long-term thermal stability13Isoreticular Metal–Organic Frameworks Confined Mononuclear Ru-Hydrides Enable Highly Efficient Shape-Selective Hydrogenolysis of Polyolefins39Consumer Grade Polyethylene Recycling via Hydrogenolysis on Ultrafine Supported Ruthenium Nanoparticles2Consumer Grade Polyethylene Recycling via Hydrogenolysis on Ultrafine Supported Ruthenium Nanoparticles38Amorphous Strategy and Doping Copper on Metal-Organic Framework Surface for Enhanced Photocatalytic Co2 Reduction to C2h41Efficient Degradation of Oxidized Polyethylene Containing Ester Bonds by Cutinase or Lipase in Aqueous Phase0Characterization and Stability of ZrO2-SiO2 Nanofluids from Local Minerals Indonesia as Green Nanofluids to Application Radiator Cooling System4Promoted selectivity of photocatalytic CO2 reduction to C2H4 via hybrid CuxCoSy possessing dual unsaturated sites56Supramolecular/Dynamic Covalent Design of High‐Performance Pressure‐Sensitive Adhesive from Natural Low‐Molecular‐Weight Compounds43Engineering non-noble Ni/WOx-ZrO2 towards boosted fuels production by catalytic upcycling of polyethylene at mild conditions32Catalytic Hydrogenolysis of Polyethylene Under Reactive Separation46Catalytic conversion of mixed polyolefins under mild atmospheric pressure48Microwave-intensified catalytic upcycling of plastic waste into hydrogen and carbon nanotubes over self-dispersing bimetallic catalysts80Population Balance Equations for Reactive Separation in Polymer Upcycling20Catalytic Strategies for the Upcycling of Polyolefin Plastic Waste30Enhanced Charge Transfer Process and Photocatalytic Activity over a Phosphonate‐based MOF via Amorphization Strategy20Enhanced Charge Transfer Process and Photocatalytic Activity over a Phosphonate‐based MOF via Amorphization Strategy82Enhanced biodegradation activity toward polyethylene by fusion protein of anchor peptide and Streptomyces sp. strain K30 latex clearing protein13Stable Interfacial Ruthenium Species for Highly Efficient Polyolefin Upcycling104Highly Active and Sulfur-Tolerant Ruthenium Phosphide Catalyst for Efficient Reductive Amination of Carbonyl Compounds22Barium incorporated zirconium dioxide nanostructures synthesized by sol-gel route and investigation of their structural, thermal and spectroscopic characteristic in the stabilized tetragonal phase0Amorphous Fe0.7Cu0.3Ox as a Bifunctional Catalyst for Selective Hydration of Nitriles to Amides in Water14Chemical Upcycling of Polyolefin Plastics Using Structurally Well-defined Catalysts35Influence of Autoclave Liner on Polyethylene Hydrogenolysis Selectivity7Catalytic chemical recycling and upcycling of polyolefin plastics27Recent advances in polyolefin plastic waste upcycling via mild heterogeneous catalysis route from catalyst development to process design25Active species in chloroaluminate ionic liquids catalyzing low-temperature polyolefin deconstruction22Amorphous Strategy and Doping Copper on Metal–Organic Framework Surface for Enhanced Photocatalytic CO 2 Reduction to C 2 H 412Chemical recycling of post-consumer polyester wastes using a tertiary amine organocatalyst9Pyrolytic Depolymerization of Polyolefins Catalysed by Zirconium‐based UiO‐66 Metal–Organic Frameworks38Pyrolytic Depolymerization of Polyolefins Catalysed by Zirconium‐based UiO‐66 Metal–Organic Frameworks10Engineering defective organic–inorganic heterojunctions as an alternative approach to precious metal modification in ultrasensitive H2S gas detection at room temperature17Insight into the Competitive Adsorption Behavior of Polymer Chains in Silica Nanopores by Small-Angle Neutron Scattering3Catalytic Upcycling of Polyolefins316The role of size and structure of catalytic active sites in polyolefin hydrogenolysis12Selective Hydrogenolysis Conversion of Polyethylene into Alkyl Oil Over Iridium‐based Catalyst9Effect of cadmium content on the stabilization of tetragonal phase of zirconium dioxide nanostructure prepared by Sol-Gel method0Lewis Acidic VOx Engineered PdAu Nanocatalysts for Efficient Formic Acid Dehydrogenation28Selective Upcycling of Polyolefins into High-Value Nitrogenated Chemicals80ZrO 2 Promoted the Depolymerization of Lignin into Phenolic Monomers over 15Ni/SiO 2 –Al 2 O 3 –ZrO 2 Catalyst15Upcycling Polyethylene into Poly(3-hydroxybutyrate) via a Chemo-Enzymatic-Microbial Cascade0Review of key issues and potential strategies in bio-degradation of polyolefins5Efficient polycarbonate plastic upcycling into jet fuel cycloalkanes over a bifunctional MoCo/NiC hetero-catalyst12Noble metal-free tandem catalysis enables efficient upcycling plastic waste into liquid fuel components22Polyethylene Recycling via Water Activation by Ball Milling5Polyethylene Recycling via Water Activation by Ball Milling23Hydrogenolysis of Polyethylene by Metal–Organic Framework Confined Single-Site Ruthenium Catalysts16High-gravity-assisted rapid and controlled synthesis of hollow zirconia nanoparticles for dye and phosphate adsorption3One-pot catalytic conversion of polyethylene wastes to gasoline through a dual-catalyst system41Hyperpolarisation techniques0Enhancing the Conversion Efficiency of Polyethylene to Methane through Codoping of Mn Atoms into Ru Centers and CeO2 Supports37Unraveling the role of water in mechanism changes for economically viable catalytic plastic upcycling43Polyethylene hydrogenolysis by dilute RuPt alloy to achieve H2-pressure-independent low methane selectivity70Kinetic Models for Polymer Upcycling by Tag-and-Cut Strategies6Parahydrogen-enhanced magnetic resonance identification of intermediates in [Fe]-hydrogenase catalysis13Photothermal Catalytic Recycling of Polyester Over Magnetic Ni−MnO x Nanocatalyst16Microwave‐Powered Liquid Metal Degradation of Polyolefins30C−H Bond Activation by Sulfated Zirconium Oxide is Mediated by a Sulfur‐Centered Lewis Superacid8C−H Bond Activation by Sulfated Zirconium Oxide is Mediated by a Sulfur‐Centered Lewis Superacid2Complementary acid site mechanisms in hydrogen-free polyethylene upcycling: elucidating the distinct roles of Brønsted and Lewis sites in Ce-modified zeolites14Effective production of liquid/wax fuels from polyethylene plastics using Ru/Al 2 O 3 catalysts10Highly adaptable oxidative upcycling of polyolefins to multifunctional chemicals containing oxygen and nitrogen9Oxygen Vacancies in β-MoO 3 Mediate Imine Synthesis via Reductive Coupling of Nitro Compounds and Alcohols11Selective hydrocracking of polyolefin waste into branched liquid fuels over a non-noble metal bifunctional Ni–W/ZrO 2 catalyst4Synergistic effect of acidic sites and mesoporous confinement in Ce-doped Ru/SBA-15 catalysts for efficient hydrogenolysis of low-density polyethylene to liquid fuels7Upgrading of waste polyolefins with non-noble metal catalysts21Conversion of Polypropylene to Light Olefins by HMFI Catalysts below Pyrolytic Temperature: Catalytic, Spectroscopic, and Theoretical Studies3Mechanistic Insights into Polypropylene Hydrogenolysis Using Ni/Al2O3 Catalysts17In-situ Fe2O3 generation-induced tunable proton transfer enhancement of Zr-modified sepiolite for energy-efficient and sustainable amine-based CO2 capture5Heat Transfer Performance Analysis of Green Nanofluids as Coolant in Automotive Radiator for Motorcycle Engine2Polymer Molecular Weight Distributions: A Tutorial on Transformations between Number Density, Mass Density, and Linear/Logarithmic Axes4Effective Methane Suppression in Upcycling of Polyethylene into Fuels via Alloying Platinum with Ruthenium Supported on ZSM-5 Zeolite17Highly selective upcycling of plastic mixture waste by microwave-assisted catalysis over Zn/b-ZnO68Catalytic deconstruction of organic additive-containing plastics44Inherent loss of parahydrogen-induced polarization for systems with magnetically equivalent nuclei in magnetic field cycling experiments0Upgrading polyolefin plastics: experiences from petroleum refining and distinct characteristics19Reductive Upcycling of Polyolefins, Polyesters and Mixed Plastic Wastes to Valuable Chemicals: Bridging Chemical Catalysis With Plastic Waste Management35Upcycling polyolefins to methane-free liquid fuel by a Ru1-ZrO2 catalyst47Unexpected activity of MgO nanoclusters for the reductive-coupling synthesis of organonitrogen chemicals with C = N bonds24Unconventional Parahydrogen-Induced Hyperpolarization Effects in Chemistry and Catalysis: From Photoreactions to Enzymes18Engineering porous Beta zeolite-encapsulated nickel catalyst for waste polyolefins upcycling26Enhancing Waste Plastic Hydrogenolysis on Ru/CeO 2 Through Concurrent Incorporation of Fe Single Atoms and FeO x Nanoclusters27Enhancing Waste Plastic Hydrogenolysis on Ru/CeO 2 Through Concurrent Incorporation of Fe Single Atoms and FeO x Nanoclusters4Constructing Matching Interfaces by Amorphous Engineering for Enhanced Lithium Ion Transport in Quasi‐Solid‐State Lithium–Iodine Batteries4Constructing Matching Interfaces by Amorphous Engineering for Enhanced Lithium Ion Transport in Quasi‐Solid‐State Lithium–Iodine Batteries25A Broad-Spectrum Catalyst for Aliphatic Polymer Breakdown4Population Balance Models for Catalytic Depolymerization: From Elementary Steps to Multiphase Reactors8Coordinating cracking and hydrogenation of polyethylene waste via acid-metal site isolation for selective hydrocarbon production10Advances in solid-state NMR for the studies of mesoporous solids: fast magic angle spinning and dynamic nuclear polarization7A Minimalist Design for a Dual-Catalyst System for High-Efficiency Conversion of Waste Plastics into Liquid Fuel Products27Amorphous metal-organic frameworks: From synthesis strategies to emerging applications16Understanding the Effect of Platinum Particle Size on Ethane Dehydrogenation and Hydrogenolysis: Particle-Based Microkinetic Modeling at Finite Conversion10Selective electrified polyethylene upcycling by pore-modulated pyrolysis25Methods for Carbon Mass Closure in Polyolefin Hydrocracking6MOF-Derived Oxygen-Vacancy-Rich ZrO2/UiO-66-NH2 for Efficient Visible-Light-Driven Oxidation of Benzyl Alcohol19Surface structure effects on the methylcyclohexane dehydrogenation over Ni catalysts predicted by density functional theory2CO-promoted polyethylene hydrogenolysis with renewable formic acid as hydrogen donor20Dual-catalyst system without supported metals toward polyethylene waste upcycling3Glassy dynamics and a growing structural length scale in supercooled nanoparticles0The silent partner in catalysis: How support architectures dictate efficiency in polyolefin hydrogenolysis1Upgrading Natural Ores for Efficient Photothermal Polyester Recycling21Impact of Acid Sites in ZSM-5 Zeolites on the Selective Catalytic Oxi-Upcycling of High-Density Polyethylene to Dicarboxylic Acid under Mild Conditions16Stable single-site organonickel catalyst preferentially hydrogenolyses branched polyolefin C–C bonds12Net-Zero Upcycling of Mixed Polyolefins by Spatially Homogeneous Joule Heating7Deep cracking of polyethylene to light olefins0From Grafting to Embedding: A first principles exploration of zirconia cluster integration in amorphous silica0The role of catalyst acidity and microstructure on light olefin selectivity in polyethylene deconstruction in short contact time pulse Joule-heated reactors3Fine regulation of Ru species improved the polyethylene hydrogenolysis performance over Ru/Al 2 O 3 catalyst5Selective hydrogenation of nitriles to primary and secondary amines via Ni0/Ni2+ dual sites7The Non-Negligible Effect of Activating Zn on a Bimetallic Carbon for the Degradation of Acesulfame0Fractionated degradation and valorization of polypropylene waste into sulfonate surfactants2A review of recent advances in thermal-catalytic cracking of plastic waste8Microfluidic-spun pea protein aerogel fibers for photocatalytic antibacterial activity and banana preservation3Surface and Interface Properties of Metal Species for Waste Plastic Hydroconversion6Synergy between acidity and Pt in Pt/HY zeolite for boosting the hydrocracking of polyethylene to C5-C7 liquid fuels0Data-Driven Discovery of Bimetallic Nanoparticles Catalysts for the Hydrogenolysis of Polyethylene3Catalytic valorization of polyolefins: from catalysts and processes to reactors0Controlled Formation Of Metastable Nanocrystalline ZrO 2 From Indonesian Zircon For Catalyst Support Applications0Synergistic dual-interface engineering of hierarchical Co3O4/SiO2 nanosheets for boosted photo-ozonation of dichloromethane1Synergistic pore-acidity engineering of hierarchical ZSM-5 for hydrogen-free upcycling of Polyethylene to C8–C12 Methylated Aromatics1Tuning ruthenium states for enhanced polyethylene hydroconversion over HZSM-5 catalysts0Upcycling waste polyoxymethylene to value-added chemicals using reusable polymeric acid catalysts at ppm levels2Efficient depolymerization of polystyrene waste into styrene monomers over the microwave-assisted Zn/b-ZnO catalyst system1Acid sites in hydrogen-involved polyolefin upcycling: mechanistic insights and design principles0Recycling of polyolefins using recycled PVC under sunlight7Tandem hydropyrolysis–hydrogenolysis of polyolefin wastes over morphology‐tuned Co 3 O 4 for jet‐fuel hydrocarbons0A semi-flow reactor design diverts catalytic hydrogenolysis of polyolefins to metastable kinetic products1Mechanistic Insights into Light Alkane Dehydrogenation over Coordinatively Unsaturated Zr Sites on Zirconia2Recent advancements in catalytic processes for plastic upcycling into fuels: a major step in sustainable waste management and energy production3Thermo-chemical upgrading of waste polyethylene and polypropylene plastics0Hydrogenolysis Versus Hydrocracking for Polyolefin Upcycling0One-pot co-upcycling of mixed polyolefin waste6Cleavage Alkylation Coupling with Versatile Amide-Based Eutectic Catalytic Systems0

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