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RESEARCH PAPER · EES Catalysis · 2023

Boosting the catalytic performance of metal–zeolite catalysts in the hydrocracking of polyolefin wastes by optimizing the nanoscale proximity

Xinlei Han, Xinru Zhou, Tuo Ji, Feng Zeng, Weiping Deng, Zhenchen Tang, Rizhi Chen

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Boosting the catalytic performance of metal–zeolite catalysts in the hydrocracking of polyolefin wastes by optimizing the nanoscale proximityOriginalHierarchical FAU Zeolites Boosting the Hydrocracking of Polyolefin Waste into Liquid Fuels38Catalytic Consequences of Hierarchical Pore Architectures within MFI and FAU Zeolites for Polyethylene Conversion54Recent advances in polyolefin plastic waste upcycling via mild heterogeneous catalysis route from catalyst development to process design25Catalytic Upcycling of Polyolefins316The role of size and structure of catalytic active sites in polyolefin hydrogenolysis12Interfacial Reactions in Chemical Recycling and Upcycling of Plastics18Catalyst Accessibility and Acidity in the Hydrocracking of HDPE: A Comparative Study of H-USY, H-ZSM-5, and MCM-41 Modified with Ga and Al11Noble metal-free tandem catalysis enables efficient upcycling plastic waste into liquid fuel components22Engineering noble metal-free nickel catalysts for highly efficient liquid fuel production from waste polyolefins under mild conditions16Efficient Hydrogenolysis of Consumer-Grade High-Density Polyethylene Wastes over MgAl-Layered Double Oxide-Supported Ru Catalysts11Heterogeneous catalysis strategies for polyolefin plastic upcycling: co-reactant-assisted and direct transformation under mild conditions15Upgrading of waste polyolefins with non-noble metal catalysts21Reductive Upcycling of Polyolefins, Polyesters and Mixed Plastic Wastes to Valuable Chemicals: Bridging Chemical Catalysis With Plastic Waste Management35Polyolefin Recycling with Binary Cobalt–Nickel Nanosheets6Zeolites in the epoch of catalytic recycling plastic waste: Toward circular economy and sustainability20Advances in catalytic transformations of waste plastic resources with zeolites0Engineering porous Beta zeolite-encapsulated nickel catalyst for waste polyolefins upcycling26Investigating the Ag–Support Interaction in Silver Catalysts for Soot Combustion: The Importance of Coordination of Al3+ Ions in the Support2Hydrogen Spillover‐Induced Brønsted Acidity Enables Controllable Hydrocracking of Polyolefin Waste to Liquid Fuels32Hydrogen Spillover‐Induced Brønsted Acidity Enables Controllable Hydrocracking of Polyolefin Waste to Liquid Fuels4Methods for Carbon Mass Closure in Polyolefin Hydrocracking6High-Efficiency Hydrocracking of Polyolefin Plastics by Controlling Intimacy between Pt Clusters and Zeolite Acid Sites65Understanding the Surface Acidity Mediated Reaction Pathway in CO 2 Assisted Aromatization of Polyolefin Waste8Long-lived metal-zeolite catalysts for polyolefin aromatization via synergistic tandem dehydroaromatization and hydrogenolysis12Enhancing the Catalytic Performance of Zeolites via Metal Doping and Porosity Control8Synergy Effects in a Bimetallic Ru ─ Pt Alloy Catalyst for Low‐H 2 ‐Pressure Hydrogenolysis of Low‐Density Polyethylene3Plasma Catalysis for Plastic Waste Conversion into Value‐Added Products: Advancements and Perspectives11A review of recent advances in thermal-catalytic cracking of plastic waste8Synergy between acidity and Pt in Pt/HY zeolite for boosting the hydrocracking of polyethylene to C5-C7 liquid fuels0Single-Atom Ni on Tungsten Oxides Drives Hydrogen Spillover for Efficient Plastic Waste Upcycling13Enhancing Hydrocracking Catalyst Performance and Lifetime through Surfactant-Templated Mesoporosity in Pt/HUSY Zeolites4Catalytic solvothermal liquefaction of mixed polyolefin waste over USY-based zeolites: Selectivity, kinetics, and reusability0Catalytic solvothermal liquefaction of mixed polyolefin waste over USY-based zeolites: Selectivity, kinetics, and reusability0Catalytic valorization of polyolefins: from catalysts and processes to reactors0Acid sites in hydrogen-involved polyolefin upcycling: mechanistic insights and design principles0Efficient polyolefin upcycling to liquid fuels via Ru–zeolite physical mixtures and pathway control2Rational design of bifunctional catalysts for hydrocracking of polyethylene waste plastics to narrow-distributed liquid fuels4Process Simulation System for Optimizing Petroleum Hydrocracking Production0Acid Site Engineering of Ni/BEA Zeolites Enables Efficient Upcycling of Polyolefin Plastics to Liquid Fuels1Recent advancements in catalytic processes for plastic upcycling into fuels: a major step in sustainable waste management and energy production3Hydrogenolysis Versus Hydrocracking for Polyolefin Upcycling0Structure–performance relationships in heterogeneous catalysts for polyolefin plastic hydroconversion1Compressed CO 2 -Assisted Catalytic Hydrocracking of Polyethylene over Ru-Loaded Zeolites0Catalytic Upcycling of Polyolefins and Polystyrene: Integrating Active Site Design With Mass Transfer Considerations4Oxidative Extrusion of Polypropylene Melts: Impact of Chain-End and In-Chain Functionalization on Thermal Properties, Crystal Structure, and Crystallization Kinetics1Phosphorus-modified plate-like ZSM-5 for oriented regulation of product distribution in catalytic plastic cracking0iPDA-Assisted Design of Hierarchical Beta Zeolites for the Sustainable Upcycling of Polyethylene to Naphtha with Ultra-Low Pt Loading1Hydrocracking of LDPE to liquid fuel over HY zeolite supported Ni catalyst: synergistic effect among metal, porosity and acidity1Engineering Zeolite Synthesis for the Green Energy Transformation1Catalyst reusability in plastic-to-fuel conversion: Deactivation mechanisms, regeneration pathways, and scale-up implications3Machine learning induced tandem catalysis for high-value recovery of polyolefins: pathways, mechanisms and products0Bifunctional nanocatalyst design for polyolefin hydrocracking2Catalytic solvothermal upcycling of mixed polyolefin waste into gasoline-range liquid fuels: Solvent-assisted selectivity and coke kinetics over zeolite-based catalysts0Bridging barriers: Integrated process intensification and catalytic strategies for valorizing waste polyolefin plastics to hydrocarbon products0Insects as a waste-to-lipids platform for sustainable aviation fuel: Production, upgrading, and sustainability0

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  1. Hierarchical FAU Zeolites Boosting the Hydrocracking of Polyolefin Waste into Liquid Fuels

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  2. Catalytic Consequences of Hierarchical Pore Architectures within MFI and FAU Zeolites for Polyethylene Conversion

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    Jun Zhi Tan, Maaso Ortega, Sophia A. Miller, Cole W. Hullfish, Hojoon Kim, Sung Min Kim, Wenda Hu, Jian Zhi Hu, Johannes A. Lercher, Bruce E. Koel, Michele L. Sarazen

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  3. Recent advances in polyolefin plastic waste upcycling via mild heterogeneous catalysis route from catalyst development to process design

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  4. Catalytic Upcycling of Polyolefins

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  5. The role of size and structure of catalytic active sites in polyolefin hydrogenolysis

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  6. Interfacial Reactions in Chemical Recycling and Upcycling of Plastics

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  7. Catalyst Accessibility and Acidity in the Hydrocracking of HDPE: A Comparative Study of H-USY, H-ZSM-5, and MCM-41 Modified with Ga and Al

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  8. Noble metal-free tandem catalysis enables efficient upcycling plastic waste into liquid fuel components

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  9. Engineering noble metal-free nickel catalysts for highly efficient liquid fuel production from waste polyolefins under mild conditions

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  10. Efficient Hydrogenolysis of Consumer-Grade High-Density Polyethylene Wastes over MgAl-Layered Double Oxide-Supported Ru Catalysts

    ACS Sustainable Chemistry & Engineering · 2024-11-20

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  11. Heterogeneous catalysis strategies for polyolefin plastic upcycling: co-reactant-assisted and direct transformation under mild conditions

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  12. Upgrading of waste polyolefins with non-noble metal catalysts

    Green Chemistry · 2025-01-01

    Jiahui Zhan, Ruihong Dai, Rongfei Cong, Yitong Dan, Hu Luo, Haozhi Zhou, Lin Xia, Shicheng Zhang, Hui Wang

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  13. Reductive Upcycling of Polyolefins, Polyesters and Mixed Plastic Wastes to Valuable Chemicals: Bridging Chemical Catalysis With Plastic Waste Management

    Advanced Sustainable Systems · 2025-03-20

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  14. Polyolefin Recycling with Binary Cobalt–Nickel Nanosheets

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  15. Zeolites in the epoch of catalytic recycling plastic waste: Toward circular economy and sustainability

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  16. Advances in catalytic transformations of waste plastic resources with zeolites

    Scientia Sinica Chimica · 2025-04-08

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  17. Engineering porous Beta zeolite-encapsulated nickel catalyst for waste polyolefins upcycling

    Applied Catalysis B: Environmental · 2025-04-08

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  18. Investigating the Ag–Support Interaction in Silver Catalysts for Soot Combustion: The Importance of Coordination of Al3+ Ions in the Support

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  19. Hydrogen Spillover‐Induced Brønsted Acidity Enables Controllable Hydrocracking of Polyolefin Waste to Liquid Fuels

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  20. Hydrogen Spillover‐Induced Brønsted Acidity Enables Controllable Hydrocracking of Polyolefin Waste to Liquid Fuels

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  21. Methods for Carbon Mass Closure in Polyolefin Hydrocracking

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  22. High-Efficiency Hydrocracking of Polyolefin Plastics by Controlling Intimacy between Pt Clusters and Zeolite Acid Sites

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  23. Understanding the Surface Acidity Mediated Reaction Pathway in CO 2 Assisted Aromatization of Polyolefin Waste

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  24. Long-lived metal-zeolite catalysts for polyolefin aromatization via synergistic tandem dehydroaromatization and hydrogenolysis

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  25. Enhancing the Catalytic Performance of Zeolites via Metal Doping and Porosity Control

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  26. Synergy Effects in a Bimetallic Ru ─ Pt Alloy Catalyst for Low‐H 2 ‐Pressure Hydrogenolysis of Low‐Density Polyethylene

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  27. Plasma Catalysis for Plastic Waste Conversion into Value‐Added Products: Advancements and Perspectives

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  29. Synergy between acidity and Pt in Pt/HY zeolite for boosting the hydrocracking of polyethylene to C5-C7 liquid fuels

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  30. Single-Atom Ni on Tungsten Oxides Drives Hydrogen Spillover for Efficient Plastic Waste Upcycling

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  31. Enhancing Hydrocracking Catalyst Performance and Lifetime through Surfactant-Templated Mesoporosity in Pt/HUSY Zeolites

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  32. Catalytic solvothermal liquefaction of mixed polyolefin waste over USY-based zeolites: Selectivity, kinetics, and reusability

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  33. Catalytic solvothermal liquefaction of mixed polyolefin waste over USY-based zeolites: Selectivity, kinetics, and reusability

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  34. Catalytic valorization of polyolefins: from catalysts and processes to reactors

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  35. Acid sites in hydrogen-involved polyolefin upcycling: mechanistic insights and design principles

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  36. Efficient polyolefin upcycling to liquid fuels via Ru–zeolite physical mixtures and pathway control

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  37. Rational design of bifunctional catalysts for hydrocracking of polyethylene waste plastics to narrow-distributed liquid fuels

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  39. Acid Site Engineering of Ni/BEA Zeolites Enables Efficient Upcycling of Polyolefin Plastics to Liquid Fuels

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  40. Recent advancements in catalytic processes for plastic upcycling into fuels: a major step in sustainable waste management and energy production

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  41. Hydrogenolysis Versus Hydrocracking for Polyolefin Upcycling

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  42. Structure–performance relationships in heterogeneous catalysts for polyolefin plastic hydroconversion

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  43. Compressed CO 2 -Assisted Catalytic Hydrocracking of Polyethylene over Ru-Loaded Zeolites

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  44. Catalytic Upcycling of Polyolefins and Polystyrene: Integrating Active Site Design With Mass Transfer Considerations

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  45. Oxidative Extrusion of Polypropylene Melts: Impact of Chain-End and In-Chain Functionalization on Thermal Properties, Crystal Structure, and Crystallization Kinetics

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  46. Phosphorus-modified plate-like ZSM-5 for oriented regulation of product distribution in catalytic plastic cracking

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  47. iPDA-Assisted Design of Hierarchical Beta Zeolites for the Sustainable Upcycling of Polyethylene to Naphtha with Ultra-Low Pt Loading

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  48. Hydrocracking of LDPE to liquid fuel over HY zeolite supported Ni catalyst: synergistic effect among metal, porosity and acidity

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  49. Engineering Zeolite Synthesis for the Green Energy Transformation

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  50. Catalyst reusability in plastic-to-fuel conversion: Deactivation mechanisms, regeneration pathways, and scale-up implications

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