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RESEARCH PAPER · Applied Catalysis B: Environmental · 2024

Promoted selectivity of photocatalytic CO2 reduction to C2H4 via hybrid CuxCoSy possessing dual unsaturated sites

Yu Nie, Yanfang Li, Chao An, Xin Tan, Zhuofeng Hu, Jinhua Ye, Tao Yu

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Promoted selectivity of photocatalytic CO2 reduction to C2H4 via hybrid CuxCoSy possessing dual unsaturated sitesOriginalAmorphous Strategy and Doping Copper on Metal-Organic Framework Surface for Enhanced Photocatalytic Co2 Reduction to C2h41A Unique Amorphous Porous BiSbOx Nanotube with Abundant Unsaturated Sb‐Stabilized BiO8−x Sites for Efficient CO2 Electroreduction in a Wide Potential Window17Enhanced charge separation of Cu-BTC@CuSe@TiO2 hollow octahedrons for efficient CO2 photoreduction with superior CO selectivity19Selective CO2 Photoreduction into CH4 Triggered by the Synergy between Oxygen Vacancy and Ru Substitution under Near‐Infrared Light Irradiation41Unlocking solar energy: Photocatalysts design for tuning the CO2 conversion into high-value (C2+) solar fuels54Amorphous Strategy and Doping Copper on Metal–Organic Framework Surface for Enhanced Photocatalytic CO 2 Reduction to C 2 H 412Construction of dual vacancies and frustrated Lewis Pairs-modified Bi2WO6 nanosheets for efficient photocatalytic conversion of CO2 to CO8Activation of Bi2MoO6/Zn0.5Cd0.5S charge transfer through interface chemical bonds and surface defects for photothermal catalytic CO2 reduction33Revealing the Effect of Electronic Configuration in Cu x Species on CO 2 Photoreduction Characteristic Products5Enhanced Selectivity in PMS Activation via Non-Metal Doping for Efficient 1 O 2 Generation in Emerging Organic Pollutants Degradation48Adsorption sites and interactions of pigments in molasses-based distillery effluent on starch-based composites: Ternary competitive adsorption and theoretical calculations13Porous organic polymers with shiftable active Co(II) sites for photocatalytic reduction of CO2 to C2H431Constructing an Active Sulfur‐Vacancy‐Rich Surface for Selective *CH3‐CH3 Coupling in CO2‐to‐C2H6 Conversion With 92% Selectivity59Optimizing charge carrier dynamics in photocatalysts for enhanced CO2 photoreduction: Fundamental principles, advanced strategies, and characterization techniques40Pt single atoms promoting the construction of asymmetric double sites to achieve highly selective photoreduction of CO2 to ethylene10Catalyzing a cleaner future: recent advancement in photocatalytic conversion for CO 2 -to-solar fuels11Engineering twin Cu 0.3 Zn 0.7 S for CO 2 photocatalytic reduction to ethylene2Construction of a red phosphorus-molybdenum dioxide electron-rich interface for efficient photocatalytic reduction of carbon dioxide25Advances in Cu-based catalysts for electroreduction of CO2 to C2H4 in flow cells11Stabilizing Unsaturated S at Interface for the Enhanced Photothermal Evolution of CH 4 From CO 20Regulation of the copper bulk phase within the Cu-CeO2 catalyst for the selectivity shift in electrochemical reduction of CO211Artificial Photothermal Synthesis of Hydrocarbons from CO 2 and H 2 O26Cadmium single atoms enhance full-spectrum solar photothermal-driven photocatalytic CO2 reduction in H2O vapor6Solar-driven nanocatalysts for CO2 upcycling: the structure-performance correlation13Synergistic effect of charge-transfer bridge and surface defects for highly efficient photothermal catalytic CO2 reduction over 2D/3D SrTiO3/Zn0.5Cd0.5S17Microenvironment-coordinated P1CoN3 single-atom sites for selective photocatalytic CO2 reduction to C2 products2Modular MOF-red phosphorus heterostructure for synergistic capture and photocatalytic reduction of dilute CO2 into ethane15Synergistic Mechanisms of Dual-Metal Single-Atoms Catalysts for Promoting CO 2 Photoreduction: Bifunctional, Intersite Distance, and Electronic Effects33Insights into the metal–organic framework-based materials for photocatalytic CO2 reduction6Sulfur electron bridge mediating CuInS2/CuS heterostructure for highly selective CO2 photoreduction to C2H49Gas-involved photo- and electro-catalysis roadmap towards 203025Engineering Cu/V asymmetric sites for photocatalytic CO2-to-C2H4 conversion by promoting C–C coupling: Achieving 98.24% selectivity through electronic synergy13Photocatalytic CO 2 Reduction to Multi‐Carbon Products16Synergistic Coupling of Interfacial Oxidation Sites and S-Scheme Heterojunction in Cu2WS4@SnIn4S8 Core–Shell Nanocomposites Boosting CO2 Photoreduction Efficiency6Piezo-photocatalytic coupling field driven efficient C2H4 synthesis: Proton-coupled electron transfer path optimization9Cu9S5/Gel-Derived TiO2 Composites for Efficient CO2 Adsorption and Conversion1Bimetallic cocatalysts driving electron extraction in COFs for photocatalytic hydrogen production21Insights into boosting molecular oxygen activation and deep toluene mineralization over in-doped SrSn(OH)6 photocatalyst via regulating orbital hybridization and charge redistribution1Hydrazine-Induced Sulfur Vacancies Promote Interfacial Charge Redistribution in ZnS/Gel-Derived TiO2 for Enhanced CO2 Activation and Methanation3Near-infrared driven semiconductor-based photocatalysis for energy and environmental applications: mechanisms, materials, and devices1Orbital-hybridized Fe 1 –O–Ti single-atom sites for synergistic proton supply and C–H formation in photocatalytic CO 2 methanation0Synergy of interfacial Co–S bonds and metal bond-connected Cu–Co dual sites for boosting photocatalytic CO2 reduction into ethylene10Near-unity CO2-to-ethylene photoconversion over low coordination single-atom catalysts17Synergistic Engineering of Oxygen Vacancies and Topological Surface States in Bi 2 Te 3 / TiO 2 ‐X Heterostructures for Highly Efficient Photothermal‐Driven CO 2 Photoreduction4Interfacial Ni–N bond in g-C3N4/CoNi2S4 for enhanced photocatalytic CO2 conversion6Sulfur vacancies boosting C2H4 selectivity of 2D/2D In2.77S4/CuInS2 S-scheme heterojunction for CO2 photoreduction2Research progress on photocatalyst–reactor codesign for the photoconversion of CO2 to C2+ compounds2Synergy in metal-nonmetal dual sites: Design, mechanisms, and perspectives toward CO2 photoreduction0Boosting C‐C Coupling for Efficient Ethylene Production via Interfacial Charge Engineering in In 2 S 3 /Co 3 S 4 S‑Scheme Photocatalyst4Escalating photo-to-thermal effects for efficient and selective photosynthesis of C2H4 from CO2 and H2O0Interface-engineered ZnO/PCN-224(Co)/Cu2O photocatalyst enables cascade CO2 conversion to C2H4 with high selectivity0Dual‐Site Photocatalysts for Selective CO 2 to C 2 + Conversion: Pathway Regulation and Machine Learning Guided Design0Activating slightly stronger adsorbed CO2 on CeO2 with concentrated sunlight to enable ethylene and propylene synthesis0Asymmetric Cu Valence Engineering in CuInS2 Enables Selective Photocatalytic CO2-to-C2H4 Conversion0Functional compartmentalization in asymmetric Co–Ni microenvironment for selective CO 2 ‐to‐ C 2 H 4 photoreduction0Covalent Linkage Engineering of a Bismuth Iodide Framework for Near‐Infrared‐Driven CO 2 ‐to‐C 2 Photoreduction in Aqueous Solution0

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  6. Amorphous Strategy and Doping Copper on Metal–Organic Framework Surface for Enhanced Photocatalytic CO 2 Reduction to C 2 H 4

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  7. Construction of dual vacancies and frustrated Lewis Pairs-modified Bi2WO6 nanosheets for efficient photocatalytic conversion of CO2 to CO

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  8. Activation of Bi2MoO6/Zn0.5Cd0.5S charge transfer through interface chemical bonds and surface defects for photothermal catalytic CO2 reduction

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