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RESEARCH PAPER · Applied Catalysis B: Environmental · 2022

Ni/SiO2 catalysts for polyolefin deconstruction via the divergent hydrogenolysis mechanism

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Ni/SiO2 catalysts for polyolefin deconstruction via the divergent hydrogenolysis mechanismOriginalDual-Pathway Polyolefin Upcycling over an Unexpectedly Bifunctional Low-Loading Ru/TiO2-Anatase Catalyst54Catalytic hydroconversion processes for upcycling plastic waste to fuels and chemicals94Recent Advances in Catalytic Chemical Recycling of Polyolefins104Mechanistic Insights into Processive Polyethylene Hydrogenolysis throughIn SituNMR25Deconvoluting the roles of polyolefin branching and unsaturation on depolymerization reactions over acid catalysts34A two-stage strategy for upcycling chlorine-contaminated plastic waste141Investigation into the Reaction Pathways and Catalyst Deactivation for Polyethylene Hydrogenolysis over Silica-Supported Cobalt Catalysts58Hydrogen-free catalytic depolymerization of waste polyolefins at mild temperatures43Structure–Property Relationships for Nickel Aluminate Catalysts in Polyethylene Hydrogenolysis with Low Methane Selectivity61Upcycling of polyethylenes by catalysis0Two Mesoporous Domains Are Better Than One for Catalytic Deconstruction of Polyolefins62Treasuring trash: Pt/SrTiO3 catalysts process plastic waste into high-value materials25Quantifying synergy for mixed end-scission and random-scission catalysts in polymer upcycling12Boosting the catalytic performance of metal–zeolite catalysts in the hydrocracking of polyolefin wastes by optimizing the nanoscale proximity56Valorizing spent mushroom substrate into syngas by the thermo-chemical process30Influence of Pore Length on Hydrogenolysis of Polyethylene within a Mesoporous Support Architecture17Valorisation of Plastic Waste via Catalytic Hydrocracking: a Technological Survey4Rapid Polyolefin Plastic Hydrogenolysis Mediated by Single-Site Heterogeneous Electrophilic/Cationic Organo-group IV Catalysts19Catalytic pyrolysis of polypropylene waste for liquid fuels production using Ni/Al-MOF-derived catalysts14Synergistic catalysis for promoting selective C–C/C–O cleavage in plastic waste: structure–activity relationship and rational design of heterogeneous catalysts for liquid hydrocarbon production18Sustainable high-density polyethylene via chemical recycling: From modification to polymerization methods45Engineering non-noble Ni/WOx-ZrO2 towards boosted fuels production by catalytic upcycling of polyethylene at mild conditions32Review on Catalytic Depolymerization of Polyolefin Waste by Hydrogenolysis: State-of-the-Art and Outlook57Catalytic Hydrogenolysis of Polyethylene Under Reactive Separation46Microwave-intensified catalytic upcycling of plastic waste into hydrogen and carbon nanotubes over self-dispersing bimetallic catalysts80Upcycling Waste Plastics with a C–C Backbone by Heterogeneous Catalysis45Enhanced hydroconversion of polyethylene via dual-functional catalysis: Exploiting ZSM-22 pore-mouth catalysis and Ru electronic effect24Unlocking naphtha from polyolefins using Ni-based hydrocracking catalysts59Polystyrene Hydrogenolysis to High-Quality Lubricants Using Ni/SiO230Layered Double Hydroxide Derivatives for Polyolefin Upcycling103Conversion of Polyethylene to Low-Molecular-Weight Oil Products at Moderate Temperatures Using Nickel/Zeolite Nanocatalysts6Complete hydrogenolysis of mixed plastic wastes101Effect of reaction media on hydrogenolysis of polyethylene plastic waste: Polymer-surface interactions in small alkane/polymer blends35Polyethylene hydrogenolysis over bimetallic catalyst with suppression of methane formation15Recent advances in polyolefin plastic waste upcycling via mild heterogeneous catalysis route from catalyst development to process design25Parameter selection for the hydroconversion of waste polyethylene plastic under mild conditions: A comprehensive evaluation8Catalytic Upcycling of Polyolefins316The role of size and structure of catalytic active sites in polyolefin hydrogenolysis12Tracking Chain Populations and Branching Structure during Polyethylene Deconstruction Processes12Selective Hydrogenolysis Conversion of Polyethylene into Alkyl Oil Over Iridium‐based Catalyst9Ultra‐Narrow Alkane Product Distribution in Polyethylene Waste Hydrocracking by Zeolite Micro‐Mesopore Diffusion Optimization12Ultra‐Narrow Alkane Product Distribution in Polyethylene Waste Hydrocracking by Zeolite Micro‐Mesopore Diffusion Optimization66Efficient polycarbonate plastic upcycling into jet fuel cycloalkanes over a bifunctional MoCo/NiC hetero-catalyst12Noble metal-free tandem catalysis enables efficient upcycling plastic waste into liquid fuel components22Hydrogenolysis of Polyethylene by Metal–Organic Framework Confined Single-Site Ruthenium Catalysts16Engineering noble metal-free nickel catalysts for highly efficient liquid fuel production from waste polyolefins under mild conditions16Hydrogen-free upcycling of polyethylene waste to methylated aromatics over Ni/ZSM-5 under mild conditions19Challenges and opportunities in catalytic hydrogenolysis of oxygenated plastics waste: polyesters, polycarbonates, and epoxy resins44Unraveling the role of water in mechanism changes for economically viable catalytic plastic upcycling43Elucidating the effect of nanocube support morphology on the hydrogenolysis of polypropylene over Ni/CeO 2 catalysts7Reaction engineering of the hydrogenolysis of liquid n-Alkanes: Comparison of flow and batch reaction systems2Recent Progress in Polyolefin Plastic: Polyethylene and Polypropylene Transformation and Depolymerization Techniques22Bimetallic NiFe/Al 2 O 3 catalyst for efficient hydrogenolysis of polyethylene into aviation fuel range alkanes12Complementary acid site mechanisms in hydrogen-free polyethylene upcycling: elucidating the distinct roles of Brønsted and Lewis sites in Ce-modified zeolites14Optimization of nickel-based catalysts for hydrogenolysis of light paraffins using machine learning5Relationship between catalyst structure and activity in CO 2 methanation of Ru-based catalysts: recent progress and future prospects17Selective hydrocracking of polyolefin waste into branched liquid fuels over a non-noble metal bifunctional Ni–W/ZrO 2 catalyst4Synergistic effect of acidic sites and mesoporous confinement in Ce-doped Ru/SBA-15 catalysts for efficient hydrogenolysis of low-density polyethylene to liquid fuels7Upgrading of waste polyolefins with non-noble metal catalysts21Mechanistic Insights into Polypropylene Hydrogenolysis Using Ni/Al2O3 Catalysts17Recovery of chemicals and energy through thermo-chemical processing of plastic waste33Tandem Catalysis for Plastic Depolymerization: In Situ Hydrogen Generation via Methanol Aqueous Phase Reforming for Sustainable Polyethylene Hydrogenolysis2Tandem Catalysis for Plastic Depolymerization: In Situ Hydrogen Generation via Methanol Aqueous Phase Reforming for Sustainable Polyethylene Hydrogenolysis27A Mini-review on Development for the Direct Catalytic Hydroconversion of Polypropylene to Liquid and Gaseous Hydrocarbons for Fuels and Chemicals1Recent advancements in upcycling of polyolefins by hydrocracking: Effect of various heterogeneous catalysts and reaction parameters8Advances and Challenges in Low‐Temperature Upcycling of Waste Polyolefins via Tandem Catalysis25Advances and Challenges in Low‐Temperature Upcycling of Waste Polyolefins via Tandem Catalysis2Reductive Upcycling of Polyolefins, Polyesters and Mixed Plastic Wastes to Valuable Chemicals: Bridging Chemical Catalysis With Plastic Waste Management35Polyolefin Recycling with Binary Cobalt–Nickel Nanosheets6Ru-Catalyzed Polyethylene Hydrogenolysis under Quasi-Supercritical Conditions25Hydrogen Spillover‐Induced Brønsted Acidity Enables Controllable Hydrocracking of Polyolefin Waste to Liquid Fuels32Hydrogen Spillover‐Induced Brønsted Acidity Enables Controllable Hydrocracking of Polyolefin Waste to Liquid Fuels4Catalytic Upcycling of Polyethylene into Naphtha Using Commercial Heterogeneous Catalysts3Hydrogenolysis of LDPE over Ni-catalyst promoted by n-hexane solvent7Plastic-waste hydrogenolysis over two-dimensional MXene-supported ruthenium catalysts with tunable interlayer spacing3Methods for Carbon Mass Closure in Polyolefin Hydrocracking6Tuning Catalytic Reactivity via Wetting Control through Oxygen Vacancies: Ru Clusters on Anatase TiO2 and CeO2 Supports22Dual-catalyst system without supported metals toward polyethylene waste upcycling3The silent partner in catalysis: How support architectures dictate efficiency in polyolefin hydrogenolysis1Stable single-site organonickel catalyst preferentially hydrogenolyses branched polyolefin C–C bonds12Long-lived metal-zeolite catalysts for polyolefin aromatization via synergistic tandem dehydroaromatization and hydrogenolysis12Single-site catalyst cuts branched polyolefins to pieces2Polymer Upcycling by Catalytic Hydrogenolysis: The Role of Polyolefin Short-Chain Branching3Synergy Effects in a Bimetallic Ru ─ Pt Alloy Catalyst for Low‐H 2 ‐Pressure Hydrogenolysis of Low‐Density Polyethylene3Polyethylene hydrogenolysis to liquid products over bimetallic catalysts with favorable environmental footprint and economics17Advances of rare earth-based catalysts for recycling CO 2 and plastic waste17Surface and Interface Properties of Metal Species for Waste Plastic Hydroconversion6Catalytic Oxidation of Commodity Plastics: Advances in Polyethylene and Polystyrene Valorization5Selective polyethylene hydrocracking to liquid and gaseous hydrocarbons over Co–Ni catalysts supported on H-BEA zeolite10Research progress in metal-zeolite bifunctional systems for upcycling of waste polyolefins3Data-Driven Discovery of Bimetallic Nanoparticles Catalysts for the Hydrogenolysis of Polyethylene3Mechanistic insights into plastic degradation via catalytic bond breaking: a comprehensive review1Research progress of high value utilization of waste polyethylene plastics6Carbon–carbon bond cleavage for lignin and plastics deconstruction0Catalytic valorization of polyolefins: from catalysts and processes to reactors0Enhancing aromatic yield by zeolites in polypropylene hydrocracking to jet fuel over Ru 1 -ZrO 2 without forming CH 40Highly selective hydrocracking of polypropylene to gasoline-range fuels over the Pt/MCM-22 catalyst0Solvent-free recycling of polystyrene waste into valuable mono-aromatics over a Ni/NbO x catalyst0Acid sites in hydrogen-involved polyolefin upcycling: mechanistic insights and design principles0Efficient polyolefin upcycling to liquid fuels via Ru–zeolite physical mixtures and pathway control2Rational design of bifunctional catalysts for hydrocracking of polyethylene waste plastics to narrow-distributed liquid fuels4Recent advancements in catalytic processes for plastic upcycling into fuels: a major step in sustainable waste management and energy production3Techno-economic analysis and life cycle assessment for the catalytic hydrogenolysis and hydrocracking of polyethylene6Catalytic Upcycling of Polyolefins and Polystyrene: Integrating Active Site Design With Mass Transfer Considerations4Hydrogen-rich gas and value-added hydrocarbon production from LDPE via microwave-assisted catalytic pyrolysis using Ni and Zn supported catalysts0Engineering Interfacial Compatibility and Dynamic Active Hydrogen Pools to Accelerate Polyolefin Hydrogenolysis0Impact of Small-Alkane Solvents on Polyolefin Hydrogenolysis over a Ruthenium Catalyst0Hydrocracking of polypropylene over Ni-loaded two-dimensional zeolite catalysts for LPG-rich hydrocarbon production0Ni Supported on Urea‐Modified LaFeO 3 Perovskite for Efficient Hydrogenolysis of Polyethylene Plastics2Ambient-pressure conversion of plastic waste to jet fuel cycloalkanes by tandem hydropyrolysis and vapour-phase hydrogenation2Catalytic pyrolysis of plastic waste: A sustainable approach for liquid oil and carbon black production0Controlling Polyolefin Hydrogenolysis Selectivity by Engineering Single-Site Nickel(II) Hydride Active Catalytic Species0Selective hydrogenolysis of waste polyolefins to aviation fuel over a Co‑modified Ni/SiO2 catalyst1Catalytic Hydrogenolysis of Polyethylene-Based Plastics into Fuels Using Ruthenium Catalysts Supported on Micro/Mesoporous Carbons0Metal-Acid Balance Enables Earth-Abundant Metal Upcycling of Polyolefins to Jet Fuel0Bridging barriers: Integrated process intensification and catalytic strategies for valorizing waste polyolefin plastics to hydrocarbon products0Role of molybdenum promotion in Ni/SiO2 catalysts for Polyolefins Hydrogenolysis0Efficient and Selective Low-Temperature Polypropylene Hydrogenolysis Using Zr-Doped Mixed Metal Oxides Catalysts0Challenges in polyolefin re/upcycling catalysis specific to polymer feedstock0Adsorption of Polyolefins from Alkanes on Alumina and Silica0

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  1. Dual-Pathway Polyolefin Upcycling over an Unexpectedly Bifunctional Low-Loading Ru/TiO2-Anatase Catalyst

    Applied Catalysis B: Environmental · 2022-08-17

    Linxiao Chen, J. Moreira, Laura C. Meyer, Oliver Y. Gutiérrez, János Szanyi

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  2. Catalytic hydroconversion processes for upcycling plastic waste to fuels and chemicals

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  3. Recent Advances in Catalytic Chemical Recycling of Polyolefins

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  4. Mechanistic Insights into Processive Polyethylene Hydrogenolysis throughIn SituNMR

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  5. Deconvoluting the roles of polyolefin branching and unsaturation on depolymerization reactions over acid catalysts

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  6. A two-stage strategy for upcycling chlorine-contaminated plastic waste

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  7. Investigation into the Reaction Pathways and Catalyst Deactivation for Polyethylene Hydrogenolysis over Silica-Supported Cobalt Catalysts

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  8. Hydrogen-free catalytic depolymerization of waste polyolefins at mild temperatures

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  9. Structure–Property Relationships for Nickel Aluminate Catalysts in Polyethylene Hydrogenolysis with Low Methane Selectivity

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  10. Upcycling of polyethylenes by catalysis

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  11. Two Mesoporous Domains Are Better Than One for Catalytic Deconstruction of Polyolefins

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  12. Treasuring trash: Pt/SrTiO3 catalysts process plastic waste into high-value materials

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  13. Quantifying synergy for mixed end-scission and random-scission catalysts in polymer upcycling

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  14. Boosting the catalytic performance of metal–zeolite catalysts in the hydrocracking of polyolefin wastes by optimizing the nanoscale proximity

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  15. Valorizing spent mushroom substrate into syngas by the thermo-chemical process

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    Taewoo Lee, Dongho Choi, Jonghyun Park, Yiu Fai Tsang, Kun‐Yi Andrew Lin, Sungyup Jung, Eilhann E. Kwon

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  16. Influence of Pore Length on Hydrogenolysis of Polyethylene within a Mesoporous Support Architecture

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  17. Valorisation of Plastic Waste via Catalytic Hydrocracking: a Technological Survey

    CHIMIA International Journal for Chemistry · 2023-12-20

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  18. Rapid Polyolefin Plastic Hydrogenolysis Mediated by Single-Site Heterogeneous Electrophilic/Cationic Organo-group IV Catalysts

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  19. Catalytic pyrolysis of polypropylene waste for liquid fuels production using Ni/Al-MOF-derived catalysts

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  20. Synergistic catalysis for promoting selective C–C/C–O cleavage in plastic waste: structure–activity relationship and rational design of heterogeneous catalysts for liquid hydrocarbon production

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  23. Review on Catalytic Depolymerization of Polyolefin Waste by Hydrogenolysis: State-of-the-Art and Outlook

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  27. Enhanced hydroconversion of polyethylene via dual-functional catalysis: Exploiting ZSM-22 pore-mouth catalysis and Ru electronic effect

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  29. Polystyrene Hydrogenolysis to High-Quality Lubricants Using Ni/SiO2

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  30. Layered Double Hydroxide Derivatives for Polyolefin Upcycling

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  31. Conversion of Polyethylene to Low-Molecular-Weight Oil Products at Moderate Temperatures Using Nickel/Zeolite Nanocatalysts

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  32. Complete hydrogenolysis of mixed plastic wastes

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  33. Effect of reaction media on hydrogenolysis of polyethylene plastic waste: Polymer-surface interactions in small alkane/polymer blends

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  34. Polyethylene hydrogenolysis over bimetallic catalyst with suppression of methane formation

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  35. Recent advances in polyolefin plastic waste upcycling via mild heterogeneous catalysis route from catalyst development to process design

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  36. Parameter selection for the hydroconversion of waste polyethylene plastic under mild conditions: A comprehensive evaluation

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  37. Catalytic Upcycling of Polyolefins

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  38. The role of size and structure of catalytic active sites in polyolefin hydrogenolysis

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  39. Tracking Chain Populations and Branching Structure during Polyethylene Deconstruction Processes

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  40. Selective Hydrogenolysis Conversion of Polyethylene into Alkyl Oil Over Iridium‐based Catalyst

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  41. Ultra‐Narrow Alkane Product Distribution in Polyethylene Waste Hydrocracking by Zeolite Micro‐Mesopore Diffusion Optimization

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  43. Efficient polycarbonate plastic upcycling into jet fuel cycloalkanes over a bifunctional MoCo/NiC hetero-catalyst

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  44. Noble metal-free tandem catalysis enables efficient upcycling plastic waste into liquid fuel components

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  46. Engineering noble metal-free nickel catalysts for highly efficient liquid fuel production from waste polyolefins under mild conditions

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  47. Hydrogen-free upcycling of polyethylene waste to methylated aromatics over Ni/ZSM-5 under mild conditions

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  48. Challenges and opportunities in catalytic hydrogenolysis of oxygenated plastics waste: polyesters, polycarbonates, and epoxy resins

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  49. Unraveling the role of water in mechanism changes for economically viable catalytic plastic upcycling

    Nature Communications · 2024-11-29

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  50. Elucidating the effect of nanocube support morphology on the hydrogenolysis of polypropylene over Ni/CeO 2 catalysts

    Journal of Materials Chemistry A · 2024-12-10

    Donald R. Inns, Megan Carr, Mounib Bahri, Ajay Tomer, Troy D. Manning, Nigel D. Browning, Simon A. Kondrat, John B. Claridge, Alexandros P. Katsoulidis, Matthew J. Rosseinsky

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