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RESEARCH PAPER · Chemistry of Materials · 2024

Hydrogenolysis of Polyethylene by Metal–Organic Framework Confined Single-Site Ruthenium Catalysts

Manav Chauhan, Chhaya Thadhani, Bharti Rana, Poorvi Gupta, Biplab Ghosh, Kuntal Manna

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Hydrogenolysis of Polyethylene by Metal–Organic Framework Confined Single-Site Ruthenium CatalystsOriginalSyntheses, molecular structures and properties of (Ph4P)2[trans-O2RuCl4]·CH2Cl2 and [(Ph3P)2N]2[trans-O2RuCl4]·CH2Cl20A 2D microporous ‘flexible-robust’ MOF for efficient natural gas purification with C2s/CH4 and CO2/CH4 separations22Ru-Catalyzed Polyethylene Hydrogenolysis under Quasi-Supercritical Conditions25MOF Catalysts for Plastic Depolymerization4MOF Catalysts for Plastic Depolymerization52Metal–Organic Framework for Plastic Depolymerization and Upcycling5A multi-responsive pH stable-MOF for prevalent Hg( i ), Hg( ii ) and organochlorine pesticide detection0Enhancing selectivity and yield in polyethylene hydrogenolysis using goal-aware Bayesian algorithm execution0Pt( ii ) single sites in mixed-metal ZIF-8/67 versus PtAuCo@ZIF-67 for electrocatalytic methanol oxidation in fuel cells3Regioselective hydroboration of alkenes by metal-organic framework confined mononuclear bipyridyl–iron hydride catalyst3Leveraging Conformational Dynamics of MOFs to Overcome Conversion‐Selectivity Trade‐Off in CO 2 Hydrogenation to Ethanol0Leveraging Conformational Dynamics of MOFs to Overcome Conversion‐Selectivity Trade‐Off in CO 2 Hydrogenation to Ethanol1Controlling Polyolefin Hydrogenolysis Selectivity by Engineering Single-Site Nickel(II) Hydride Active Catalytic Species0Catalytic Hydrogenolysis of Polyethylene-Based Plastics into Fuels Using Ruthenium Catalysts Supported on Micro/Mesoporous Carbons0Unrecyclable Polyethylene as a Catalytic Metal Support for Organic Reactions0Emerging Catalytic Platforms for Plastic Waste Recycling and Upcycling Over MOFs and COFs: Catalyst Engineering and Reaction Mechanisms0

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  1. Syntheses, molecular structures and properties of (Ph4P)2[trans-O2RuCl4]·CH2Cl2 and [(Ph3P)2N]2[trans-O2RuCl4]·CH2Cl2

    Zeitschrift für Naturforschung B · 2025-03-01

    Zhi‐Cui Zhang, Yan-Ping Jiao, Dandan Lu, Ai‐Quan Jia, Qian‐Feng Zhang

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  2. A 2D microporous ‘flexible-robust’ MOF for efficient natural gas purification with C2s/CH4 and CO2/CH4 separations

    Chemical Engineering Journal · 2025-03-31

    Shyam Chand Pal, Janaki Behera, Tengfei Zhang, Raka Ahmed, Arun Pal, Jia‐Xin Wang, Arun Kumar Manna, Bin Li, Madhab C. Das

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  3. Ru-Catalyzed Polyethylene Hydrogenolysis under Quasi-Supercritical Conditions

    JACS Au · 2025-04-16

    Sung Min Kim, Boda Yang, Oliver Y. Gutiérrez, Wei Zhang, Carlos Lizandara‐Pueyo, Piyush Ingale, Ivana Jevtovikj, Reni Grauke, János Szanyi, Huamin Wang, Stephan A. Schunk, Johannes A. Lercher

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  4. MOF Catalysts for Plastic Depolymerization

    Angewandte Chemie · 2025-04-30

    Bao‐Nguyen T. Nguyen, Tristan Tsai Yuan Tan, Ken‐ichi Otake, Susumu Kitagawa, Jason Y. C. Lim

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  5. MOF Catalysts for Plastic Depolymerization

    Angewandte Chemie International Edition · 2025-04-30

    Bao‐Nguyen T. Nguyen, Tristan Tsai Yuan Tan, Ken‐ichi Otake, Susumu Kitagawa, Jason Y. C. Lim

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  6. Metal–Organic Framework for Plastic Depolymerization and Upcycling

    Crystals · 2025-10-16

    K.-S. Lee, Sumin Han, Minse Kim, Byoung-su Kim, Jeong‐Ann Park, Kwang Suk Lim, Suk‐Jin Ha, Hyun‐Ouk Kim

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  7. A multi-responsive pH stable-MOF for prevalent Hg( i ), Hg( ii ) and organochlorine pesticide detection

    Journal of Materials Chemistry A · 2026-01-01

    Janaki Behera, Supriya Mondal, Arun Kumar Manna, Madhab C. Das

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  8. Enhancing selectivity and yield in polyethylene hydrogenolysis using goal-aware Bayesian algorithm execution

    Digital Discovery · 2026-01-01

    Makenna L. Pennel, Akash Ramdas, Sean Gasiorowski, Sathya R. Chitturi, Willie Neiswanger, Nicholas Broadbent, Mike Dunne, Felipe H. da Jornada, Daniel Ratner, Christopher J. Tassone, Matteo Cargnello

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  9. Pt( ii ) single sites in mixed-metal ZIF-8/67 versus PtAuCo@ZIF-67 for electrocatalytic methanol oxidation in fuel cells

    Dalton Transactions · 2026-01-01

    Behnaz Habibagahi, S. Jafar Hoseini, Mehrangiz Bahrami, Elvira De Giglio, Maria Chiara Sportelli, Piero Mastrorilli, S. Masoud Nabavizadeh, Wei Chen

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  10. Regioselective hydroboration of alkenes by metal-organic framework confined mononuclear bipyridyl–iron hydride catalyst

    Inorganica Chimica Acta · 2026-01-14

    Aditya Kumar, Rahul Kalita, Poorvi Gupta, Bharti Rana, Manav Chauhan, Kuntal Manna

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  11. Leveraging Conformational Dynamics of MOFs to Overcome Conversion‐Selectivity Trade‐Off in CO 2 Hydrogenation to Ethanol

    Angewandte Chemie · 2026-05-11

    Manav Chauhan, Rahul Kalita, Aditya Kumar, Bharti Rana, Swapnaneel Sarmah, Kuntal Manna

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  12. Leveraging Conformational Dynamics of MOFs to Overcome Conversion‐Selectivity Trade‐Off in CO 2 Hydrogenation to Ethanol

    Angewandte Chemie International Edition · 2026-05-11

    Manav Chauhan, Rahul Kalita, Aditya Kumar, Bharti Rana, Shilpi Sarmah, Kuntal Manna

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  13. Controlling Polyolefin Hydrogenolysis Selectivity by Engineering Single-Site Nickel(II) Hydride Active Catalytic Species

    ACS Catalysis · 2026-06-08

    Bharti Rana, Manav Chauhan, Poorvi Gupta, A Rajendra Kumar, Chhaya Thadhani, Rahul Kalita, Kuntal Manna

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  14. Catalytic Hydrogenolysis of Polyethylene-Based Plastics into Fuels Using Ruthenium Catalysts Supported on Micro/Mesoporous Carbons

    Energy & Fuels · 2026-07-07

    Antigoni G. Margellou, Eleftherios Tosounidis, Kyriazis C. Rekos, Konstantinos S. Triantafyllidis

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  15. Unrecyclable Polyethylene as a Catalytic Metal Support for Organic Reactions

    Advanced Synthesis & Catalysis · 2026-08-10

    Susi Hervàs−Arnandis, Miguel Espinosa, Miguel Sanz‐Abad, Judit Oliver–Meseguer, Antonio Leyva‐Pérez

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  16. Emerging Catalytic Platforms for Plastic Waste Recycling and Upcycling Over MOFs and COFs: Catalyst Engineering and Reaction Mechanisms

    Small · 2026-09-03

    Zixuan Zhang, Yawen Shi, Xiaohui Tang, Yingjie Liu, Mei Li, Hua Wang, Shengbo Zhang

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