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RESEARCH PAPER · Applied Catalysis B: Environmental · 2023

Deconvoluting the roles of polyolefin branching and unsaturation on depolymerization reactions over acid catalysts

Ana Carolina Jerdy, Luis M. Trevisi, Masud Monwar, Miguel Ángel González-Borja, Ron Abbott, Lance L. Lobban, Steven P. Crossley

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Deconvoluting the roles of polyolefin branching and unsaturation on depolymerization reactions over acid catalystsOriginalTransport limitations in polyolefin cracking at the single catalyst particle level66Toward Intrinsic Catalytic Rates and Selectivities of Zeolites in the Presence of Limiting Diffusion and Deactivation50Precise activation of C–C bonds for recycling and upcycling of plastics81Kinetic Modelling and Measurement of Catalyst Deactivation for the Catalytic Co-Pyrolysis of Pp and Pet with Hzsm-50Selective deoxygenation of polar polymers using metal supported on TiO 2 nanotubes4Catalytic Consequences of Hierarchical Pore Architectures within MFI and FAU Zeolites for Polyethylene Conversion54Assessment of transport phenomena in catalyst effectiveness for chemical polyolefin recycling45N2O deconstruction of polycyclooctene to generate carbonyl-functionalized macromonomers3Fe2O3, Al2O3, or sludge ash-catalyzed pyrolysis of typical 3D printing waste toward tackling plastic pollution26Shape selective cracking of polypropylene on an H- MFI type zeolite catalyst with recovery of cyclooctane solvent4Catalytic materials based on metals (ions) used in the upcycling of plastics and polymers into fuels and valuable chemicals as part of sustainable development23Influence of surface chemical modifications on enhancing the aging behavior of capacitor biaxially-oriented polypropylene thin film16Kinetic Modelling and Measurement of Catalyst Deactivation for the Catalytic Co-Pyrolysis of Pp and Pet with Hzsm-50Upgrading of waste polyolefins with non-noble metal catalysts21Synergistic Catalysis for Recycling and Upcycling of Plastics35Selective catalytic deoxygenation of 1-octanol from Fischer-Tropsch C10 mixed oil0Dehydration of Poly(vinyl alcohol-co-ethylene) Over Zeolites1Rational design of zeolite-based composite catalysts in catalytic cracking of polyethylene6Enhanced structural stability of Mo/ZSM-5 for regenerability improvement in shale gas aromatization: The effect of external acidity and defect density3Kinetic regulation of Brønsted and Lewis acidity in FAU-type zeolites for olefin-selective plastic waste cracking12Beyond conventional activation barriers: synergistic QM-MD/DFT exploration of fluorinated oxidizer-enhanced hydrocarbon decomposition0Monitoring Depolymerization in Mesopores Using Dynamic Properties of Polymeric Melt Accessed via Dielectric Spectroscopy0Reliability of milligram-scale high-throughput screening for evaluating polyolefin chemical recycling in the melt with heterogeneous catalysis3Decoupling Acidity from Micropore Confinement in an Amorphous–Crystalline Composite for Selective Polyolefin Waste Cracking14Efficient polyolefin upcycling to liquid fuels via Ru–zeolite physical mixtures and pathway control2Reaction‐Based Quantification of Surface Brønsted Acid Site Densities in Large‐Pore Zeolites and Their Consequences for Bulky Molecule Transformations3Site-selective dehydrogenation and protonation synergy for efficient polyolefin upcycling into aromatics0Engineering Zeolite Synthesis for the Green Energy Transformation1Impact of Site Identity, Location, and Accessibility on Polyethylene Conversion Rates and Product Selectivities over Metal-Free MFI Zeolites0Comprehensive quantitative analysis of polyolefin hydrogenolysis toward plastic waste management0Methodological Landscape of Acid Catalyst Screening for In Situ Plastic Pyrolysis: A Critical Review0TRAPDOR NMR Reveals How Surface Fluorination Changes the Conformation of Polyethylene Adsorbed on γ-Alumina0Upcycling lithium mine tailings into hierarchical core-shell catalysts for cascade deoxygenation and aromatization during biomass pyrolysis0

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33 direct citing papers saved.

  1. Transport limitations in polyolefin cracking at the single catalyst particle level

    Chemical Science · 2023-01-01

    Sebastian Rejman, Ina Vollmer, Maximilian J. Werny, Eelco T. C. Vogt, Florian Meirer, Bert Marc Weckhuysen

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  2. Toward Intrinsic Catalytic Rates and Selectivities of Zeolites in the Presence of Limiting Diffusion and Deactivation

    ACS Catalysis · 2023-09-26

    Cole W. Hullfish, Jun Zhi Tan, Hayat I. Adawi, Michele L. Sarazen

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  3. Precise activation of C–C bonds for recycling and upcycling of plastics

    Chemical Science · 2023-12-07

    Hongshun Ran, Shuo Zhang, Wenyi Ni, Yaxuan Jing

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  4. Kinetic Modelling and Measurement of Catalyst Deactivation for the Catalytic Co-Pyrolysis of Pp and Pet with Hzsm-5

    SSRN Electronic Journal · 2024-01-01

    Sean Timothy Okonsky, Jayarama Krishna J.V., Hilal Ezgi Toraman

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  5. Selective deoxygenation of polar polymers using metal supported on TiO 2 nanotubes

    Catalysis Science & Technology · 2024-01-01

    Dai‐Phat Bui, Laura A. Gomez, Ismael Alalq, Luis M. Trevisi, Ana Carolina Jerdy, Han K. Chau, Lance L. Lobban, Steven P. Crossley

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  6. Catalytic Consequences of Hierarchical Pore Architectures within MFI and FAU Zeolites for Polyethylene Conversion

    ACS Catalysis · 2024-04-30

    Jun Zhi Tan, Maaso Ortega, Sophia A. Miller, Cole W. Hullfish, Hojoon Kim, Sung Min Kim, Wenda Hu, Jian Zhi Hu, Johannes A. Lercher, Bruce E. Koel, Michele L. Sarazen

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  7. Assessment of transport phenomena in catalyst effectiveness for chemical polyolefin recycling

    Nature Chemical Engineering · 2024-08-28

    Shibashish D. Jaydev, Antonio José Martín, David Garcia, Katia Chikri, Javier Pérez‐Ramírez

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  8. N2O deconstruction of polycyclooctene to generate carbonyl-functionalized macromonomers

    Polymer Degradation and Stability · 2024-09-03

    Ikechukwu Martin Ogbu, Chien‐Hua Tu, Eli J. Fastow, Zachary R. Hinton, Karen I. Winey, Marisa C. Kozlowski

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  9. Fe2O3, Al2O3, or sludge ash-catalyzed pyrolysis of typical 3D printing waste toward tackling plastic pollution

    Journal of Hazardous Materials · 2024-10-03

    Ziting Lin, Jingyong Liu, Liangzhong Li, Haiming Cai, Sen Lin, Fatih Evrendilek, Siqi Chen, Xin Chen, Xin Chen, Xin Chen, Tao Chen, Yao He

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  10. Shape selective cracking of polypropylene on an H- MFI type zeolite catalyst with recovery of cyclooctane solvent

    RSC Sustainability · 2024-11-20

    Tomohiro Fukumasa, Yuya Kawatani, Hiroki Masuda, Ikuto Nakashita, Ryusei Hashiguchi, Masanori Takemoto, Satoshi Suganuma, Etsushi Tsuji, Toru Wakihara, Naonobu Katada

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  11. Catalytic materials based on metals (ions) used in the upcycling of plastics and polymers into fuels and valuable chemicals as part of sustainable development

    Materials Science and Engineering R Reports · 2024-11-23

    Kacper Pobłocki, Marta Pawlak, Joanna Drzeżdżon, Dagmara Jacewicz

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  12. Influence of surface chemical modifications on enhancing the aging behavior of capacitor biaxially-oriented polypropylene thin film

    Polymer Degradation and Stability · 2024-11-26

    Haider Muhamed Umran, Hasan Fisal Alesary, Hani Khalil Ismail, Feipeng Wang, Stephen Barton

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  13. Kinetic Modelling and Measurement of Catalyst Deactivation for the Catalytic Co-Pyrolysis of Pp and Pet with Hzsm-5

    SSRN Electronic Journal · 2025-01-01

    Sean Timothy Okonsky, J.V. Jayarama Krishna, Do Hyun Lee, Hilal Ezgi Toraman

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  14. Upgrading of waste polyolefins with non-noble metal catalysts

    Green Chemistry · 2025-01-01

    Jiahui Zhan, Ruihong Dai, Rongfei Cong, Yitong Dan, Hu Luo, Haozhi Zhou, Lin Xia, Shicheng Zhang, Hui Wang

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  15. Synergistic Catalysis for Recycling and Upcycling of Plastics

    ACS Catalysis · 2025-05-07

    Hongshun Ran, Xinyang Sun, Mengying Zheng, Yaxuan Jing

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  16. Selective catalytic deoxygenation of 1-octanol from Fischer-Tropsch C10 mixed oil

    Chinese Journal of Chemical Engineering · 2025-05-13

    Yongbin Shen, Qihe Ma, Hua Yuan, Chuang Liu, Likun Yang, Hao Huang, Bowen Shi, Zhenhua Li, Shunyu Liang, Liming Hu, Zhengping Dong

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  17. Dehydration of Poly(vinyl alcohol-co-ethylene) Over Zeolites

    Catalysis Letters · 2025-06-03

    Luis M. Trevisi, Mohammad Reza Razzaghi, Ana Carolina Jerdy, Dai‐Phat Bui, Steven P. Crossley, Lance L. Lobban

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  18. Rational design of zeolite-based composite catalysts in catalytic cracking of polyethylene

    Fuel · 2025-07-01

    Yanjun Li, Zhe Ma, Jingyuan Shang, Ting Wang, Xingong Zhang, Peng Xu, Chenzhao Wang, Xiang Feng, De Chen, Chaohe Yang, Xiaobo Chen

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  19. Enhanced structural stability of Mo/ZSM-5 for regenerability improvement in shale gas aromatization: The effect of external acidity and defect density

    Applied Catalysis B: Environmental · 2025-07-02

    Yangho Jeong, Hyeokjoon June, Jangeon Roh, Jin Seok, Dongwoo Jun, Eun Ji Choi, Minkee Choi, Do Heui Kim, Jeong Woo Han, Jong Hun Kang

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  20. Kinetic regulation of Brønsted and Lewis acidity in FAU-type zeolites for olefin-selective plastic waste cracking

    Chemical Engineering Journal · 2025-08-21

    Samira Motamednejad, Reza Panahi, Kourosh Tabar Heydar, Li Gao, Bingsen Zhang, Mozaffar Shakeri

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  21. Beyond conventional activation barriers: synergistic QM-MD/DFT exploration of fluorinated oxidizer-enhanced hydrocarbon decomposition

    Energetic Materials Frontiers · 2025-10-15

    Zhiqiang Wang, Tian Ma, Dezhou Guo, Yi Tong, Fenglei Huang

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  22. Monitoring Depolymerization in Mesopores Using Dynamic Properties of Polymeric Melt Accessed via Dielectric Spectroscopy

    Macromolecules · 2025-10-17

    R. Bharath Venkatesh, Jon M. Bingaman, Susannah L. Scott, Lynn M. Walker, Rachel A. Segalman

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  23. Reliability of milligram-scale high-throughput screening for evaluating polyolefin chemical recycling in the melt with heterogeneous catalysis

    Cell Reports Physical Science · 2025-12-01

    Brent Smeyers, Kseniia Vikanova, Jonathan Van Waeyenberg, Michiel Aerts, Toon Van Vaerenbergh, Oğuzhan Akin, Qing He, Andreas Eschenbacher, Robin John Varghese, Jules Henrotte, Anton Ginzburg, Kevin M. Van Geem, Bert F. Sels

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  24. Decoupling Acidity from Micropore Confinement in an Amorphous–Crystalline Composite for Selective Polyolefin Waste Cracking

    Journal of the American Chemical Society · 2025-12-29

    Qiaohui Ruan, Hailu Xia, Zanfeng Yuan, Zhuohan Lin, Xu Wang, Wenao Ouyang, Jian-Ping Zou, Yan Li

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  25. Efficient polyolefin upcycling to liquid fuels via Ru–zeolite physical mixtures and pathway control

    Chemical Engineering Journal · 2026-01-31

    Hyeongdong Jung, Junho Suh, Yong Hyun Lim, Hyungjoo Kim, Hyungjoo Kim, Inhak Song, Eunwon Lee, Jae‐Soon Choi, Jungup Bang, Do Heui Kim, Do Heui Kim

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  26. Reaction‐Based Quantification of Surface Brønsted Acid Site Densities in Large‐Pore Zeolites and Their Consequences for Bulky Molecule Transformations

    ChemCatChem · 2026-02-01

    Cole W. Hullfish, Jun Zhi Tan, Carson J. Repins, Michele L. Sarazen

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  27. Site-selective dehydrogenation and protonation synergy for efficient polyolefin upcycling into aromatics

    Chemical Engineering Journal · 2026-04-03

    Yusong Zhang, Yue Ding, Lei Zhang, Guozhao Ji, Yuan Gao, Aimin Li

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  28. Engineering Zeolite Synthesis for the Green Energy Transformation

    JACS Au · 2026-05-18

    Jie Zhu, Koki Muraoka, Toru Wakihara, Tatsuya Okubo

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  29. Impact of Site Identity, Location, and Accessibility on Polyethylene Conversion Rates and Product Selectivities over Metal-Free MFI Zeolites

    ACS Catalysis · 2026-07-23

    Cole W. Hullfish, Jun Zhi Tan, John V. Piorkowski, Carson J. Repins, Antara Bhowmick, Matthew J. Oh, Darius R. Ganza, Sonia E. Arumuganainar, Dongxia Liu, Bruce E. Koel, Michele L. Sarazen

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  30. Comprehensive quantitative analysis of polyolefin hydrogenolysis toward plastic waste management

    Nature Protocols · 2026-07-24

    Chao Meng, Yue Wang, Xun Wu, Akalanka Tennakoon, Anne M. LaPointe, Frédéric A. Perras, Long Qi, Baron Peters, Aaron David Sadow, Wenyu Huang

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  31. Methodological Landscape of Acid Catalyst Screening for In Situ Plastic Pyrolysis: A Critical Review

    ACS Catalysis · 2026-08-25

    Brent Smeyers, Soheil Valizadeh, Kseniia Vikanova, Bert F. Sels

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  32. TRAPDOR NMR Reveals How Surface Fluorination Changes the Conformation of Polyethylene Adsorbed on γ-Alumina

    Langmuir · 2026-08-28

    Samantha F. Ausman, Jinlei Cui, Nicholas A. Maciulis, Songi Han, Susannah L. Scott

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  33. Upcycling lithium mine tailings into hierarchical core-shell catalysts for cascade deoxygenation and aromatization during biomass pyrolysis

    Chemical Engineering Journal · 2026-09-14

    Chuan Peng, Song Jin, Surong Bai, Jinjin Wan, Jin Huang, Junfeng Zhang

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