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RESEARCH PAPER · Angewandte Chemie International Edition · 2004

The Lone‐Pair Cation I5+ in a Hexagonal Tungsten Oxide‐Like Framework: Synthesis, Structure, and Second‐Harmonic Generating Properties of Cs2I4O11

Kang Min Ok, P. Shiv Halasyamani

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The Lone‐Pair Cation I5+ in a Hexagonal Tungsten Oxide‐Like Framework: Synthesis, Structure, and Second‐Harmonic Generating Properties of Cs2I4O11OriginalThe Lone‐Pair Cation I5+ in a Hexagonal Tungsten Oxide‐Like Framework: Synthesis, and Second‐Harmonic Generating Properties of Cs2I4O11.020 New compounds and structures in the solid state5Synthesis and characterisation of Fe(IO3)3 nanosized powder25New Metal Iodates: Syntheses, Structures, and Characterizations of Noncentrosymmetric La(IO3)3 and NaYI4O12 and Centrosymmetric β-Cs2I4O11 and Rb2I6O15(OH)2·H2O125LiMoO3(IO3): A new molybdenyl iodate based on WO3-type sheets with large SHG response75Development and characterization of nanocomposite materials36Phase Transition in Tl2TeO3: Influence and Origin of the Thallium Lone Pair Distortion16Biosynthesis and biological activity of enniatins49Deuteration Effect of Ferroelectricity and Permittivity on Homochiral Zinc Coordination Compound47Hydrothermal synthesis and structure characterization of the first organically templated metal iodates2Hydrothermal Synthesis, Structural Characterisations, and Photoluminescence Properties of Four Inorganic‐Organic Hybrid Compounds in the Indium/Gallium Iodate Family11Hydrothermal Synthesis and X‐ray Crystal Structure of Four Inorganic‐Organic Hybrid Compounds in Vanadium /Copper Iodate Family0Soluble Direct‐Band‐Gap Semiconductors LiAsS2 and NaAsS2: Large Electronic Structure Effects from Weak As⋅⋅⋅S Interactions and Strong Nonlinear Optical Response32Soluble Direct‐Band‐Gap Semiconductors LiAsS2 and NaAsS2: Large Electronic Structure Effects from Weak As⋅⋅⋅S Interactions and Strong Nonlinear Optical Response194A New Organically Templated Noncentrosymmetric Bismuth Chloride: Synthesis, Structure, and Characterization of [N(CH3)2H2][(CH3)2NH(CH2)2NH(CH3)2][BiCl6]7Alignment of Lone Pairs in a New Polar Material: Synthesis, Characterization, and Functional Properties of Li2Ti(IO3)6307Non-centrosymmetric coordination polymers based on thallium and acetylenedicarboxylate22New Polar Oxides: Synthesis, Characterization, Calculations, and Structure−Property Relationships in RbSe2V3O12 and TlSe2V3O12125Polar or Nonpolar? A+ Cation Polarity Control in A2Ti(IO3)6(A = Li, Na, K, Rb, Cs, Tl)306BaNbO(IO3)5: A New Polar Material with a Very Large SHG Response331A Series of New Infrared NLO Semiconductors, ZnY6Si2S14, AlxDy3(SiyAl1−y)S7, and Al0.33Sm3SiS7134New Noncentrosymmetric Material - [N(CH3)4]ZnCl3: Polar Chains of Aligned ZnCl4 Tetrahedra63Three New Coordination Compounds with Push‐Pull Ligand p‐Aminobenzonitrile (4ABN)11Syntheses and crystal structures of four new silver(i) iodates with d 0 -transition metal cations45$^3_\infty$[Tl2Zn(ADC)2(H2O)2]: the First Coordination Polymer with Acetylenedicarboxylate (ADC2–) as Bridging Ligand containing two Different Metal Ions4Anionic templating in a new layered bismuth tellurium oxychloride, Bi3Te4O10Cl529Syntheses, crystal structures, and properties of three new lanthanum( iii ) vanadium iodates56NaVO2(IO3)2(H2O): A Unique Layered Material Produces A Very Strong SHG Response143Lone Pairs as Chemical Scissors in New Antimony Oxychlorides, Sb2ZnO3Cl2 and Sb16Cd8O25Cl1445Reinterpretation of Three Crystal Structures of Alkali Oxoiodate(V) – Description of the [I3O8]–Anion and the Infinite 2D [I3O8–]∞Anion43Explorations of New Second-Order Nonlinear Optical Materials in the KI-MII -IV-O Systems43First‐Principles Studies on Novel Polar Oxide ZnSnO3; Pressure‐Induced Phase Transition and Electric Properties56Noncentrosymmetric Inorganic Oxide Materials: Synthetic Strategies and Characterisation Techniques8New Noncentrosymmetric Tellurite Phosphate Material: Synthesis, Characterization, and Calculations of Te2O(PO4)295A3V5O14 (A = K+, Rb+, or Tl+), New Polar Oxides with a Tetragonal Tungsten Bronze Related Structural Topology: Synthesis, Structure, and Functional Properties76Polar or Non-Polar? Syntheses, Crystal Structures, and Optical Properties of Three New Palladium(II) Iodates45Synthesis, Crystal Structure, and Magnetic Properties of the Copper Selenite Chloride Cu5(SeO3)4Cl241A series of new alkali metal indium iodates with isolated or extended anions22Explorations of New Second-Order Nonlinear Optical Materials in the Potassium Vanadyl Iodate System268New Quaternary Tellurite and Selenite: Synthesis, Structure, and Characterization of Centrosymmetric InVTe2O8 and Noncentrosymmetric InVSe2O887Synthesis, Characterization, and Structure–Property Relationships in Two New Polar Oxides: Zn2(MoO4)(SeO3) and Zn2(MoO4)(TeO3)80Syntheses and Characterization of New Mid-Infrared Transparency Compounds: Centric Ba2BiGaS5 and Acentric Ba2BiInS595Structures and properties of functional metal iodates72BiO(IO3): A New Polar Iodate that Exhibits an Aurivillius-Type (Bi2O2)2+ Layer and a Large SHG Response503Polymorphism of BaTeMo 2 O 9 : A New Polar Polymorph and the Phase Transformation186Coordination Polymers with Tetrafluoroterephthalate as Bridging Ligand49Crystal Structure and Magnetic Properties of Two New Antiferromagnetic Spin Dimer Compounds; FeTe3O7X (X = Cl, Br)22PbPt(IO3)6(H2O): a new polar material with two types of stereoactive lone-pairs and a very large SHG response80Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites60ZnIO3(OH): a new layered noncentrosymmetric polar iodate – hydrothermal synthesis, crystal structure, and second-harmonic generating (SHG) properties36Crystal structures and second-order NLO properties of borogermanates59Two New Noncentrosymmetric (NCS) Polar Oxides: Syntheses, Characterization, and Structure–Property Relationships in BaMTe2O7 (M = Mg2+ or Zn2+)50Cation Size Effect on the Framework Structures in a Series of New Alkali-Metal Indium Selenites, AIn(SeO3)2 (A = Na, K, Rb, and Cs)28Synthesis, Structure, and Characterization of New Li+ – d0 –Lone-Pair – Oxides: Noncentrosymmetric Polar Li6(Mo2O5)3(SeO3)6 and Centrosymmetric Li2(MO3)(TeO3) (M = Mo6+ or W6+)47Supramolecular Polymers with [Co(en)3]3+Cores (en = ethylenediamine)5A combination of multiple chromophores enhances second-harmonic generation in a nonpolar noncentrosymmetric oxide: CdTeMoO681Chemistry of Polar Transition-Metal Oxides1K4TM4(V2O7)2(IO3)4(H2O) (TM = Zn, Ni, Co): a series of quinary mixed metal–vanadium(v)–iodates18Pb2TiOF(SeO3)2Cl and Pb2NbO2(SeO3)2Cl: small changes in structure induced a very large SHG enhancement117Synthesis and crystal structure of Fe6Ca2(SeO3)9Cl4 – a porous oxohalide11Synthesis, crystal growth, and characterization of the orthorhombic BaTeW2O9: a new polymorph of BaTeW2O925Tl(VO)2O2(IO3)3: a new polar material with a strong SHG response26ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units53Synthesis, Structure, and Characterization of Two New Polar Sodium Tungsten Selenites: Na2(WO3)3(SeO3)·2H2O and Na6(W6O19)(SeO3)247New Bismuth Selenium Oxides: Syntheses, Structures, and Characterizations of Centrosymmetric Bi2(SeO3)2(SeO4) and Bi2(TeO3)2(SeO4) and Noncentrosymmetric Bi(SeO3)(HSeO3)53Zn2(VO4)(IO3): A Novel Polar Zinc(II) Vanadium(V) Iodate with a Large SHG Response94A new strontium antimonateIII Sr5Sb22O38: Synthesis, crystal structure and characterizations9Na1.4InTe3.6O9.4: New Variant of a Hexagonal Tungsten Oxide (HTO)-Like Layered Framework Containing Both a Main-Group Cation, In3+, and a Lone-Pair Cation, Te4+14Explorations of a Series of Second Order Nonlinear Optical Materials Based on Monovalent Metal Gold(III) Iodates33Practical Applications of Polyvalent Iodine Compounds0A new polymorph of Cd 3 B 2 O 6 : synthesis, crystal structure and phase transformation18Ba4(BO3)3(SiO4)·Ba3X (X = Cl, Br): new salt-inclusion borosilicate halides as potential deep UV nonlinear optical materials58Noncentrosymmetric YVSe2O8 and Centrosymmetric YVTe2O8: Macroscopic Centricities Influenced by the Size of Lone Pair Cation Linkers63Explorations of New Second-Order Nonlinear Optical Materials in the Ternary Rubidium Iodate System: Noncentrosymmetric β-RbIO3(HIO3)2 and Centrosymmetric Rb3(IO3)3(I2O5)(HIO3)4(H2O)59α-AgI3O8 and β-AgI3O8 with Large SHG Responses: Polymerization of IO3 Groups into the I3O8 Polyiodate Anion113Li2CdGeS4, A Diamond-Like Semiconductor with Strong Second-Order Optical Nonlinearity in the Infrared and Exceptional Laser Damage Threshold193Acentric Pseudo-Kagome Structures: The Solid Solution (Co 1– x Ni x ) 3 Sb 4 O 6 F 625Rich Structural Chemistry in Scandium Selenium/Tellurium Oxides: Mixed-Valent Selenite–Selenates, Sc2(SeO3)2(SeO4) and Sc2(TeO3)(SeO3)(SeO4), and Ternary Tellurite, Sc2(TeO3)341How Lewis Acidity of the Cationic Framework Affects KNaNbOF5 Polymorphism19Crystal Structure and Magnetic Properties of the S = 1/2 Quantum Spin System Cu7(TeO3)6F2 with Mixed Dimensionality16Synthesis, crystal structure and optical properties of two new layered cadmium iodates: Cd(IO3)X (X=Cl, OH)13Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons67Synthesis and Crystal Structure of the Iron(III) Oxotellurate(IV) Phosphate Oxide Chloride Fe11(TeO3)2(TeO4)3(PO4)2O4Cl35Rich Structural Chemistry in New Alkali Metal Yttrium Tellurites: Three-Dimensional Frameworks of NaYTe4O10, KY(TeO3)2, RbY(TeO3)2, and a Novel Variant of Hexagonal Tungsten Bronze, CsYTe3O823An unusual density evolution between SrCdB 2 O 5 polymorphs6BaBi(SeO 3 ) 2 Cl: a new polar material showing high second-harmonic generation efficiency enhanced by constructive alignment of chloride ions36Recent advances on second-order NLO materials based on metal iodates328Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS2 and Centric Ba8Hg4S5Se752Cs(TaO 2 ) 3 (SeO 3 ) 2 and Cs(TiOF) 3 (SeO 3 ) 2 : Structural and Second Harmonic Generation Changes Induced by the Different d 0 -TM Coordination Octahedra67Pb4(OH)4(BrO3)3(NO3): An Example of SHG Crystal in Metal Bromates Containing π-Conjugated Planar Triangle59Rb 2 SeOCl 4 ·H 2 O: a polar material among the alkali metal selenite halides with a strong SHG response18K2Au(IO3)5 and β‐KAu(IO3)4: Polar Materials with Strong SHG Responses Originating from Synergistic Effect of AuO4 and IO3 Units18KSbI6O18: An antimony iodate semiconductor material with cyclic chiral S6-symmetric hexaiodate7New Series of Polar and Nonpolar Platinum Iodates A2Pt(IO3)6 (A = H3O, Na, K, Rb, Cs)33Rb2Na(NO3)3: A Congruently Melting UV-NLO Crystal with a Very Strong Second-Harmonic Generation Response71Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation382Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation129LnBSb2O8 (Ln = Sm, Eu, Gd, Tb): A Series of Lanthanide Boroantimonates with Unusual 3D Anionic Structures15Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect238Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect71Photoconversion Mechanisms and the Origin of Second-Harmonic Generation in Metal Iodates with Wide Transparency, NaLn(IO3)4 (Ln = La, Ce, Sm, and Eu) and NaLa(IO3)4:Ln3+ (Ln = Sm and Eu)32Two Barium Gold Iodates: Syntheses, Structures, and Properties of Polar BaAu(IO3)5 and Nonpolar HBa4Au(IO3)12 Materials5ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap140ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap36M(IO3)(HPO4)(H2O) (M = Sc, Fe, Ga, In): Introduction of Phosphate Anions into Metal Iodates16Acentric La3(IO3)8(OH) and La(IO3)2(NO3): Partial Substitution of Iodate Anions in La(IO3)3 by Hydroxide or Nitrate Anion55Influence of A-site cations on germanium iodates as mid-IR nonlinear optical materials: A 2 Ge(IO 3 ) 6 (A = Li, K, Rb and Cs) and BaGe(IO 3 ) 6 ·H 2 O43Pb 3 (SeO 3 )Br 4 : a new nonlinear optical material with enhanced SHG response designed via an ion-substitution strategy36Industrial Applications2Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)2(IO3)4O, Ba3[(MoO2)2(IO3)4O(OH)4]·2H2O, and Sr[(MoO2)6(IO4)2O4]·H2O24PbCdF(SeO 3 )(NO 3 ): A Nonlinear Optical Material Produced by Synergistic Effect of Four Functional Units52A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions137A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions23Adjustable optical nonlinearity in d 10 cations containing chalcogenides via dp hybridization interaction13LiMg(IO 3 ) 3 : an excellent SHG material designed by single-site aliovalent substitution68Lone pair effects on ternary infrared nonlinear optical materials19Synthesis and structure of a new mixed metal iodate Ba 3 Ga 2 (IO 3 ) 1217Synthesis, structure and characterization of M(IO 3 ) 2 (HIO 3 ) (M = Ca, Sr) as new anhydrous alkaline earth metal bis-iodate hydrogeniodate compounds16Microwave Synthesis and Up-Conversion Properties of SHG-Active α-(La, Er)(IO3)3 Nanocrystals14TB-mBJ calculation of structural, electronic and optical properties of two monovalent iodates AIO3 (A=Tl, α-Rb)9HBa2.5(IO3)6(I2O5) and HBa(IO3)(I4O11): Explorations of Second-Order Nonlinear Optical Materials in the Alkali-Earth Polyiodate System49Two Polar Molybdenum(VI) Iodates(V) with Large Second-Harmonic Generation Responses67REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion125REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion62Synthesis and Crystal Structure of a New Iodate (Pb0.6Ba0.4)(Pb0.4Ba0.6)[IO3]4 Analogous to Sr[IO3]22Five New Silver Rare‐Earth Iodates, AgLn(IO3)4 (Ln=Pr, Sm, Dy, Er and Tm): Synthesis, Structures and Properties6A new iodate-phosphate Pb 2 (IO 3 )(PO 4 ) achieving great improvement in birefringence activated by (IO 3 ) − groups53[O 2 Pb 3 ] 2 (BO 3 )I: a new lead borate iodide with 1∞[O 2 Pb 3 ] double chains6Bi 4 O(I 3 O 10 )(IO 3 ) 3 (SeO 4 ): trimeric condensation of IO 4 3− monomers into the I 3 O 10 5− polymeric anion observed in a three-component mixed-anion NLO material20New polymorphism for BaTi(IO 3 ) 6 with two polymorphs crystallizing in the same space group11Preparation and multiferroicity of a novel two-dimensional material NiH 2 SeO 47CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework132CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework22K2Na(IO3)2(I3O8) with Strong Second Harmonic Generation Response Activated by Two Types of Isolated Iodate Anions46A review on phase transition and structure-performance relationship of second-order nonlinear optical polymorphs107Effect of iodic acid concentration in preparation of zinc iodate: Experimental characterization of Zn(IO3)2, and its physical properties from density functional theory18From Ag2Zr(IO3)6 to LaZr(IO3)5F2: A Case of Constructing Wide‐band‐gap Birefringent Materials through Chemical Cosubstitution11AB 11 O 16 (OH) 2 (A = K and Cs): interpenetrating 2D layers with large birefringence7The first actinide polyiodate: a complex multifunctional compound with promising X-ray luminescence properties and proton conductivity17[GaF(H 2 O)][IO 3 F]: a promising NLO material obtained by anisotropic polycation substitution42Ba 2 [FeF 4 (IO 3 ) 2 ]IO 3 : a promising nonlinear optical material achieved by chemical-tailoring-induced structure evolution8Na 7 (IO 3 )(SO 4 ) 3 : the first noncentrosymmetric alkaline-metal iodate-sulfate with isolated [IO 3 ] and [SO 4 ] units28On the crystal chemistry of inorganic nitrides: crystal-chemical parameters, bonding behavior, and opportunities in the exploration of their compositional space17SrTi(IO 3 ) 6 ·2H 2 O and SrSn(IO 3 ) 6 : distinct arrangements of lone pair electrons leading to large birefringences11Ba3Sb2(PO4)4 and Cd3Sb2(PO4)4(H2O)2: Two New Antimonous Phosphates with Distinct [Sb(PO4)2] Structure Types and Enhanced Birefringence37Cd3(IO3)(IO4)F2·0.1CdO: A Nonlinear-Optical Crystal with the Introduction of Fluoride into Iodate Containing Both [IO3]− and [IO4]3– Groups18A New Anhydrous Polar Rare-Earth Iodate Fluoride, Ce(IO3)2F2, Exhibiting a Large Second-Harmonic-Generation Effect and Improved Overall Performance35APPLICATION OF HYPERVALENT IODINE COMPOUNDS IN ADVANCED GREEN TECHNOLOGIES7APPLICATION OF HYPERVALENT IODINE COMPOUNDS IN ADVANCED GREEN TECHNOLOGIES (IN PRESS)3[ o ‐C 5 H 4 NHOH] 2 [I 7 O 18 (OH)]⋅3 H 2 O: An Organic–Inorganic Hybrid SHG Material Featuring an [I 7 O 18 (OH)] Branched Polyiodate Chain86

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  1. The Lone‐Pair Cation I5+ in a Hexagonal Tungsten Oxide‐Like Framework: Synthesis, and Second‐Harmonic Generating Properties of Cs2I4O11.

    ChemInform · 2004-12-01

    Kang Min Ok, P. Shiv Halasyamani

    Read original paper ↗ ·

  2. 20 New compounds and structures in the solid state

    Annual Reports Section A (Inorganic Chemistry) · 2005-01-01

    Gary B. Hix

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  3. Synthesis and characterisation of Fe(IO3)3 nanosized powder

    Journal of Alloys and Compounds · 2005-10-03

    Christine Galez, Yannick Mugnier, J. Bouillot, Yannick Lambert, Ronan Le Dantec

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  4. New Metal Iodates: Syntheses, Structures, and Characterizations of Noncentrosymmetric La(IO3)3 and NaYI4O12 and Centrosymmetric β-Cs2I4O11 and Rb2I6O15(OH)2·H2O

    Inorganic Chemistry · 2005-11-01

    Kang Min Ok, P. Shiv Halasyamani

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  5. LiMoO3(IO3): A new molybdenyl iodate based on WO3-type sheets with large SHG response

    Journal of Alloys and Compounds · 2006-05-03

    Xuean Chen, Li Zhang, Xinan Chang, Haiping Xue, Hegui Zang, Weiqiang Xiao, Xuemei Song, Hui Yu Yan

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  6. Development and characterization of nanocomposite materials

    Materials Science and Engineering C · 2006-09-09

    Julien Eschbach, Didier Rouxel, Brice Vincent, Yannick Mugnier, Christine Galez, Ronan Le Dantec, P. Bourson, J. K. Krüger, Omar Elmazria, P. Alnot

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  7. Phase Transition in Tl2TeO3: Influence and Origin of the Thallium Lone Pair Distortion

    Inorganic Chemistry · 2006-12-15

    Franziska Rieger, Anja‐Verena Mudring

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  8. Biosynthesis and biological activity of enniatins

    Die Pharmazie · 2007-08-01

    S Firáková, Bohumil Proksa, M. Šturdíková

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  9. Deuteration Effect of Ferroelectricity and Permittivity on Homochiral Zinc Coordination Compound

    Crystal Growth & Design · 2007-08-18

    Qiong Ye, Yu‐Mei Song, Da‐Wei Fu, Guo-Xi Wang, Ren-Gen Xiong, Philip Wai Hong Chan, Songping D. Huang

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  10. Hydrothermal synthesis and structure characterization of the first organically templated metal iodates

    Inorganica Chimica Acta · 2008-03-11

    Xiaomin Liu, Guanghua Li, Yawei Hu, Yang Yu, Minghui Bi, Zhan Shi, Shouhua Feng

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  11. Hydrothermal Synthesis, Structural Characterisations, and Photoluminescence Properties of Four Inorganic‐Organic Hybrid Compounds in the Indium/Gallium Iodate Family

    European Journal of Inorganic Chemistry · 2008-04-21

    Xiaomin Liu, Guanghua Li, Bin Hu, Yang Yu, Yawei Hu, Minghui Bi, Zhan Shi, Shouhua Feng

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  12. Hydrothermal Synthesis and X‐ray Crystal Structure of Four Inorganic‐Organic Hybrid Compounds in Vanadium /Copper Iodate Family

    Zeitschrift für anorganische und allgemeine Chemie · 2008-06-10

    Xiaomin Liu, Guanghua Li, Minghui Bi, Yawei Hu, Yang Yu, Zhan Shi, Shouhua Feng

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  13. Soluble Direct‐Band‐Gap Semiconductors LiAsS2 and NaAsS2: Large Electronic Structure Effects from Weak As⋅⋅⋅S Interactions and Strong Nonlinear Optical Response

    Angewandte Chemie · 2008-08-28

    Tarun Kumar Bera, Jung‐Hwan Song, Arthur J Freeman, Joon Ik Jang, John B. Ketterson, Mercouri G. Kanatzidis

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  14. Soluble Direct‐Band‐Gap Semiconductors LiAsS2 and NaAsS2: Large Electronic Structure Effects from Weak As⋅⋅⋅S Interactions and Strong Nonlinear Optical Response

    Angewandte Chemie International Edition · 2008-08-29

    Tarun Kumar Bera, Jung‐Hwan Song, Arthur J Freeman, Joon Ik Jang, John B. Ketterson, Mercouri G. Kanatzidis

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  15. A New Organically Templated Noncentrosymmetric Bismuth Chloride: Synthesis, Structure, and Characterization of [N(CH3)2H2][(CH3)2NH(CH2)2NH(CH3)2][BiCl6]

    Bulletin of the Korean Chemical Society · 2008-11-20

    Min Kyung Kim

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  16. Alignment of Lone Pairs in a New Polar Material: Synthesis, Characterization, and Functional Properties of Li2Ti(IO3)6

    Journal of the American Chemical Society · 2009-02-04

    Hong‐Young Chang, Sang‐Hwan Kim, P. Shiv Halasyamani, Kang Min Ok

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  17. Non-centrosymmetric coordination polymers based on thallium and acetylenedicarboxylate

    Solid State Sciences · 2009-03-21

    Ruth Ahlers, Uwe Ruschewitz

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  18. New Polar Oxides: Synthesis, Characterization, Calculations, and Structure−Property Relationships in RbSe2V3O12 and TlSe2V3O12

    Chemistry of Materials · 2009-03-24

    Hong Chang, Sang‐Hwan Kim, Kang Min Ok, P. Shiv Halasyamani

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  19. Polar or Nonpolar? A+ Cation Polarity Control in A2Ti(IO3)6(A = Li, Na, K, Rb, Cs, Tl)

    Journal of the American Chemical Society · 2009-04-22

    Hong‐Young Chang, Sang‐Hwan Kim, Kang Min Ok, P. Shiv Halasyamani

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  20. BaNbO(IO3)5: A New Polar Material with a Very Large SHG Response

    Journal of the American Chemical Society · 2009-06-22

    Chuan‐Fu Sun, Chun‐Li Hu, Xiang Xu, Ji‐Bei Ling, Ting Hu, Fang Kong, Xifa Long, Jiang‐Gao Mao

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  21. A Series of New Infrared NLO Semiconductors, ZnY6Si2S14, AlxDy3(SiyAl1−y)S7, and Al0.33Sm3SiS7

    Inorganic Chemistry · 2009-07-09

    Sheng‐Ping Guo, Guo‐Cong Guo, Ming‐Sheng Wang, Jian‐Ping Zou, Gang Xu, Guojian Wang, Xifa Long, Jin‐Shun Huang

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  22. New Noncentrosymmetric Material - [N(CH3)4]ZnCl3: Polar Chains of Aligned ZnCl4 Tetrahedra

    Inorganic Chemistry · 2009-08-05

    Myung‐Ho Choi, Sang‐Hwan Kim, Hong‐Young Chang, P. Shiv Halasyamani, Kang Min Ok

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  23. Three New Coordination Compounds with Push‐Pull Ligand p‐Aminobenzonitrile (4ABN)

    Zeitschrift für anorganische und allgemeine Chemie · 2009-08-28

    A. Lamann-Glees, Uwe Ruschewitz

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  24. Syntheses and crystal structures of four new silver(i) iodates with d 0 -transition metal cations

    Dalton Transactions · 2009-12-03

    Chuan‐Fu Sun, Chun‐Li Hu, Fang Kong, Bing‐Ping Yang, Jiang‐Gao Mao

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  25. $^3_\infty$[Tl2Zn(ADC)2(H2O)2]: the First Coordination Polymer with Acetylenedicarboxylate (ADC2–) as Bridging Ligand containing two Different Metal Ions

    Zeitschrift für anorganische und allgemeine Chemie · 2009-12-22

    Ruth Ahlers, Uwe Ruschewitz

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  26. Anionic templating in a new layered bismuth tellurium oxychloride, Bi3Te4O10Cl5

    Dalton Transactions · 2010-01-01

    Min Kyung Kim, Vinna Jo, Dong Woo Lee, Kang Min Ok

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  27. Syntheses, crystal structures, and properties of three new lanthanum( iii ) vanadium iodates

    Dalton Transactions · 2010-01-01

    Chuan‐Fu Sun, Ting Hu, Xiang Xu, Jiang‐Gao Mao

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  28. NaVO2(IO3)2(H2O): A Unique Layered Material Produces A Very Strong SHG Response

    Chemistry of Materials · 2010-01-12

    Bing‐Ping Yang, Chun‐Li Hu, Xiang Xu, Chuan‐Fu Sun, Jian‐Han Zhang, Jiang‐Gao Mao

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  29. Lone Pairs as Chemical Scissors in New Antimony Oxychlorides, Sb2ZnO3Cl2 and Sb16Cd8O25Cl14

    Inorganic Chemistry · 2010-02-11

    Vinna Jo, Min Kyung Kim, Dong Woo Lee, Il‐Wun Shim, Kang Min Ok

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  30. Reinterpretation of Three Crystal Structures of Alkali Oxoiodate(V) – Description of the [I3O8]–Anion and the Infinite 2D [I3O8–]∞Anion

    Zeitschrift für anorganische und allgemeine Chemie · 2010-03-31

    Isabelle Gautier‐Luneau, Yan Suffren, Hélène Jamet, Julien Pilmé

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  31. Explorations of New Second-Order Nonlinear Optical Materials in the KI-MII -IV-O Systems

    Inorganic Chemistry · 2010-04-16

    Pei-Xin Li, Chun‐Li Hu, Xiang Xu, Rui‐Yao Wang, Chuan‐Fu Sun, Jiang‐Gao Mao

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  32. First‐Principles Studies on Novel Polar Oxide ZnSnO3; Pressure‐Induced Phase Transition and Electric Properties

    Advanced Materials · 2010-05-05

    Masanobu Nakayama, Masayuki Nogami, Masashi Yoshida, Tetsuhiro Katsumata, Yoshiyuki Inaguma

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  33. Noncentrosymmetric Inorganic Oxide Materials: Synthetic Strategies and Characterisation Techniques

    Unknown journal · 2010-06-11

    P. Shiv Halasyamani

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  34. New Noncentrosymmetric Tellurite Phosphate Material: Synthesis, Characterization, and Calculations of Te2O(PO4)2

    Inorganic Chemistry · 2010-06-29

    Min Kyung Kim, Sang‐Hwan Kim, Hong‐Young Chang, P. Shiv Halasyamani, Kang Min Ok

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  35. A3V5O14 (A = K+, Rb+, or Tl+), New Polar Oxides with a Tetragonal Tungsten Bronze Related Structural Topology: Synthesis, Structure, and Functional Properties

    Inorganic Chemistry · 2010-07-07

    Jeongho Yeon, Sang‐Hwan Kim, P. Shiv Halasyamani

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  36. Polar or Non-Polar? Syntheses, Crystal Structures, and Optical Properties of Three New Palladium(II) Iodates

    Inorganic Chemistry · 2010-09-20

    Chuan‐Fu Sun, Chun‐Li Hu, Xiang Xu, Jiang‐Gao Mao

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  37. Synthesis, Crystal Structure, and Magnetic Properties of the Copper Selenite Chloride Cu5(SeO3)4Cl2

    Inorganic Chemistry · 2010-09-21

    Dong Zhang, Helmuth Berger, Reinhard Karl Kremer, Dirk Wulferding, P. Lemmens, Mats Johnsson

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  38. A series of new alkali metal indium iodates with isolated or extended anions

    Dalton Transactions · 2010-12-14

    Bing‐Ping Yang, Chuan‐Fu Sun, Chun‐Li Hu, Jiang‐Gao Mao

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  39. Explorations of New Second-Order Nonlinear Optical Materials in the Potassium Vanadyl Iodate System

    Journal of the American Chemical Society · 2011-03-23

    Chuan‐Fu Sun, Chun‐Li Hu, Xiang Xu, Bing‐Ping Yang, Jiang‐Gao Mao

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  40. New Quaternary Tellurite and Selenite: Synthesis, Structure, and Characterization of Centrosymmetric InVTe2O8 and Noncentrosymmetric InVSe2O8

    Inorganic Chemistry · 2011-04-12

    Dong Woo Lee, Seung‐Jin Oh, P. Shiv Halasyamani, Kang Min Ok

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  41. Synthesis, Characterization, and Structure–Property Relationships in Two New Polar Oxides: Zn2(MoO4)(SeO3) and Zn2(MoO4)(TeO3)

    Inorganic Chemistry · 2011-05-10

    Sau Doan Nguyen, Sang‐Hwan Kim, P. Shiv Halasyamani

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  42. Syntheses and Characterization of New Mid-Infrared Transparency Compounds: Centric Ba2BiGaS5 and Acentric Ba2BiInS5

    Inorganic Chemistry · 2011-05-19

    Lei Geng, Wen‐Dan Cheng, Chensheng Lin, Weilong Zhang, Hao Zhang, Zhangzhen He

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  43. Structures and properties of functional metal iodates

    Science China Chemistry · 2011-05-30

    Chuan‐Fu Sun, Bing‐Ping Yang, Jiang‐Gao Mao

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  44. BiO(IO3): A New Polar Iodate that Exhibits an Aurivillius-Type (Bi2O2)2+ Layer and a Large SHG Response

    Journal of the American Chemical Society · 2011-07-21

    Sau Doan Nguyen, Jeongho Yeon, Sang‐Hwan Kim, P. Shiv Halasyamani

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  45. Polymorphism of BaTeMo 2 O 9 : A New Polar Polymorph and the Phase Transformation

    Chemistry of Materials · 2011-07-25

    Junjie Zhang, Zhonghan Zhang, Weiguo Zhang, Qingxin Zheng, Youxuan Sun, Chengqian Zhang, Xutang Tao

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  46. Coordination Polymers with Tetrafluoroterephthalate as Bridging Ligand

    Crystal Growth & Design · 2011-10-05

    Christiane Seidel, Ruth Ahlers, Uwe Ruschewitz

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  47. Crystal Structure and Magnetic Properties of Two New Antiferromagnetic Spin Dimer Compounds; FeTe3O7X (X = Cl, Br)

    Inorganic Chemistry · 2011-11-11

    Dong Zhang, Reinhard Karl Kremer, P. Lemmens, Kwang‐Yong Choi, Jia Liu, Myung‐Hwan Whangbo, Helmuth Berger, Y. Skourski, Mats Johnsson

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  48. PbPt(IO3)6(H2O): a new polar material with two types of stereoactive lone-pairs and a very large SHG response

    Chemical Communications · 2012-01-01

    Chuan‐Fu Sun, Chun‐Li Hu, Jiang‐Gao Mao

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  49. Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites

    Structure and bonding · 2012-01-01

    Fang Kong, Chuan‐Fu Sun, Bing‐Ping Yang, Jiang‐Gao Mao

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  50. ZnIO3(OH): a new layered noncentrosymmetric polar iodate – hydrothermal synthesis, crystal structure, and second-harmonic generating (SHG) properties

    Dalton Transactions · 2012-01-01

    Dong Woo Lee, Saet Byeol Kim, Kang Min Ok

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