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RESEARCH PAPER · Inorganic Chemistry · 2010

A3V5O14 (A = K+, Rb+, or Tl+), New Polar Oxides with a Tetragonal Tungsten Bronze Related Structural Topology: Synthesis, Structure, and Functional Properties

Jeongho Yeon, Sang‐Hwan Kim, P. Shiv Halasyamani

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A3V5O14 (A = K+, Rb+, or Tl+), New Polar Oxides with a Tetragonal Tungsten Bronze Related Structural Topology: Synthesis, Structure, and Functional PropertiesOriginalChemInform Abstract: A3V5O14 (A: K+, R+, or Tl+), New Polar Oxides with a Tetragonal Tungsten Bronze Related Structural Topology: Synthesis, and Functional Properties.0Synthesis, crystal structure and nonlinear optical property of Rb3V5O1411Bulk crystal growth and characterization of a new polar polymorph of BaTeMo2O9: α-BaTeMo2O998Computational modelling of inorganic solids1Top-Seeded Solution Growth, Morphology, and Properties of a Polar Crystal Cs2TeMo3O1277[R-C7H16N2][V2Te2O10] and [S-C7H16N2][V2Te2O10]; new polar templated vanadium tellurite enantiomers34Synthesis, Characterization, and Structure–Property Relationships in Two New Polar Oxides: Zn2(MoO4)(SeO3) and Zn2(MoO4)(TeO3)80BiO(IO3): A New Polar Iodate that Exhibits an Aurivillius-Type (Bi2O2)2+ Layer and a Large SHG Response503Polymorphism of BaTeMo 2 O 9 : A New Polar Polymorph and the Phase Transformation186Anisotropic thermal properties of the polar crystal Cs2TeMo3O1224Top-seeded solution crystal growth of noncentrosymmetric and polar K3V5O1411Two New Noncentrosymmetric (NCS) Polar Oxides: Syntheses, Characterization, and Structure–Property Relationships in BaMTe2O7 (M = Mg2+ or Zn2+)50Inducing polarity in [VO3]nn− chain compounds using asymmetric hydrogen-bonding networks17Small non-polar complexes exhibiting significant piezoelectric properties: Solvothermal synthesis and crystal structures of MO5V(tren)·H2O (M=Mo and W; tren=tris(2-aminoethyl)amine)7Synthesis, Structure, and Characterization of New Li+ – d0 –Lone-Pair – Oxides: Noncentrosymmetric Polar Li6(Mo2O5)3(SeO3)6 and Centrosymmetric Li2(MO3)(TeO3) (M = Mo6+ or W6+)47Role of Hydrogen-Bonding in the Formation of Polar Achiral and Nonpolar Chiral Vanadium Selenite Frameworks26Influence of the Devitrification Mechanism on Second Harmonic Generation Efficiency and Transparency in Ba 2 NaNb 5 O 15 Nanostructures6A combination of multiple chromophores enhances second-harmonic generation in a nonpolar noncentrosymmetric oxide: CdTeMoO681Chemistry of Polar Transition-Metal Oxides1ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units53New Molybdenum(VI) Phosphates: Synthesis, Characterization, and Calculations of Centrosymmetric RbMoO2PO4and Noncentrosymmetric Rb4Mo5P2O2239New Fluoride Carbonates: Centrosymmetric KPb2(CO3)2F and Noncentrosymmetric K2.70Pb5.15(CO3)5F367Synthesis, Structure, and Characterization of Two New Polar Sodium Tungsten Selenites: Na2(WO3)3(SeO3)·2H2O and Na6(W6O19)(SeO3)247Crystal Growth, Structure, Polarization, and Magnetic Properties of Cesium Vanadate, Cs2V3O8: A Structure–Property Study40Alignment of Acentric Units in Infinite Chains: A “Lock and Key” Model16Formation Principles for Templated Vanadium Selenite Oxalates22Metal Chalcogenides: A Rich Source of Nonlinear Optical Materials680Synthesis, crystal structure and optical properties of Ba5V3O12F18Synthesis and characterization of ASnF3 (A=Na+, K+, Rb+, Cs+)29A New UV Nonlinear Optical Material CsZn2B3O7: ZnO4 Tetrahedra Double the Efficiency of Second-Harmonic Generation121Sr8MB18O36 (M = Zn or Cd): Design and Synthesis of Two New Borates with a Special Ratio of 8:16How Lewis Acidity of the Cationic Framework Affects KNaNbOF5 Polymorphism19An non-centrosymmetric mononuclear Zr complex exhibiting UV second-harmonic-generation0Density functional theory calculations, growth, structure, and optical properties of birefringent LiNaV2O69Thermal Expansion and Second Harmonic Generation Response of the Tungsten Bronze Pb2AgNb5O1515Environmentally friendly Rb 3 V 5 O 14 fluorescent red pigment23M 3 V 2 B 10 O 23 (M = Ca, Sr): two new vanadoborates with [V 2 B 10 O 23 ] ∞ double layers11Thorium Chemistry in Oxo-Tellurium System under Extreme Conditions10Growth, Properties, and Theoretical Analysis of M2LiVO4 (M = Rb, Cs) Crystals: Two Potential Mid-Infrared Nonlinear Optical Materials36Assisting the Effective Design of Polar Iodates with Early Transition-Metal Oxide Fluoride Anions206Anisotropy optical properties of KSr2Nb5O15 lead-free ferroelectrics: First-principle calculations19Novel Polyoxovanadate K2ZnV5O14: Crystal Structure and Peculiarities of Crystal Chemistry1NaCa4V5O17 with isolated V2O7 dimer and V3O10 trimer exhibiting a large birefringence18Syntheses, structures, anomalous phase transition and optical properties of two new polymorphic α- and β-LiMoPO 611Synthesis, crystal structures, second harmonic generation response and temperature phase transitions of two noncentrosymmetric Cu(II)-hybrid halides compounds: [(R)-C7H16N2][CuX4] (X = Cl or Br)25Monolayer MgVOx/Al2O3 catalysts for propane oxidative dehydrogenation: Insights into a role of structural, redox, and acid-base properties in catalytic performance30Bond-length distributions for ions bonded to oxygen: results for the transition metals and quantification of the factors underlying bond-length variation in inorganic solids128A new nonlinear optical sulfate of layered structure: Cs2Zn2(SO4)319Sr2Nb6O13F8·4H2O and Sr3Nb2O2F12·2H2O: A Variant of Three-Dimensional Tungsten Bronze and a Polar Molecular Oxide Fluoride17A Congruent‐Melting Mid‐Infrared Nonlinear Optical Vanadate Exhibiting Strong Second‐Harmonic Generation22A Congruent‐Melting Mid‐Infrared Nonlinear Optical Vanadate Exhibiting Strong Second‐Harmonic Generation64K 3 V 2 O 3 F 4 (IO 3 ) 3 : a high-performance SHG crystal containing both five and six-coordinated V 5+ cations33Designing new polar materials1Solvothermal and hydrothermal methods for preparative solid-state chemistry5Synthesis and characterization of Cs 2 Zn 4 V 4 O 15 —a new vanadate in the Cs–Zn–V–O quaternary system5Shooting mid-infrared nonlinear optical materials with targeted balance performances in ternary d0-transition metal oxides through first-principles14Vanadate Crystals with an Enhanced Birefringence and a Broadened Transparency Spectrum through Controlled [VO3]∞ Chain Arrangements and Alkali Metal Cation Introduction4The Influence of Melting on Catalysis in Propane Oxidation2K4ZnV5O15Cl: A Congruent‐Melting Mid‐Infrared Nonlinear Optical Crystal Combined with Strong Second‐Harmonic Generation and High Laser‐Induced Damage Threshold14Three in one: a cadmium bismuth vanadate NLO crystal exhibiting a large second-harmonic generation response and enhanced birefringence12Advanced Effect of the Substitution of Zn2+ on the Solid‐State Synthesis of Red Phosphor, High Temperature Phase NaMgPO4:Eu2+20A congruent-melting rubidium zinc vanadium oxychloride exhibiting strong mid-infrared second-harmonic generation and high laser-induced damage threshold6Chiral Organic Cations and Distorted Inorganic Polyhedra Composing Metal Halide Nonlinear Optical Materials22Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances18Design and Synthesis of Vanadium-Based Infrared Nlo Crystal K4cdv5o15br Through Aliovalent Substitution with Strongly Polarized Active Units0Exploring quaternary vanadates containing alkali metals, alkaline earth metals, and [VO 4 ] in the quest for nonlinear optical materials1Enhanced Birefringence and Excellent Thermal Stability in Two Tellurium(IV) Vanadates: KTeOVO4 and Ca2TeV2O95Three Cases of Borates with Different Dimensional Frameworks Induced by Metal Cations1Two-Step Substitutions of Square Pyramidal VO5 with CdO4Br to Achieve Higher Laser-Induced Damage Threshold from Polar Oxybromides Rb4CdV5O15Br to Rb3CdV4O12Br10First-Principles High-Throughput Screening Combined with Experimental Synthesis to Find Vanadate Nonlinear Optical Material BiCa2VO64Strong Piezoelectric Response in an Oxalate-Coordinated Aluminum Crystal NaBaAl(C 2 O 4 ) 3 ·5H 2 O0Mid Infrared Nonlinear Optical Series A 4 MV 5 O 15 X (A = K, Rb; M = Zn, Cd; X = Cl, Br) with Strong Second Harmonic Generation Responses3中红外氧化物非线性光学晶体研究进展（特邀）0Effect of sintering time on microstructure, relaxor behavior and energy storage properties of lead-free Sr2NaNb5O15 (SNN) ceramics0Λ‐Shaped Dimers Enables Polar Antiperovskites Through A‐Site Displacement Mechanism0

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  1. ChemInform Abstract: A3V5O14 (A: K+, R+, or Tl+), New Polar Oxides with a Tetragonal Tungsten Bronze Related Structural Topology: Synthesis, and Functional Properties.

    ChemInform · 2010-09-02

    Jeongho Yeon, Sang‐Hwan Kim, P. Shiv Halasyamani

    Read original paper ↗ ·

  2. Synthesis, crystal structure and nonlinear optical property of Rb3V5O14

    Journal of Solid State Chemistry · 2010-09-19

    Jianguo Pan, Yuebao Li, Yuejie Cui, Lingyan Zhao, Xing Li, Lei Han

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  3. Bulk crystal growth and characterization of a new polar polymorph of BaTeMo2O9: α-BaTeMo2O9

    CrystEngComm · 2011-01-01

    Junjie Zhang, Zhonghan Zhang, Youxuan Sun, Chengqian Zhang, Xutang Tao

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  4. Computational modelling of inorganic solids

    Annual Reports Section A (Inorganic Chemistry) · 2011-01-01

    Elaine Ann Moore

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  5. Top-Seeded Solution Growth, Morphology, and Properties of a Polar Crystal Cs2TeMo3O12

    Crystal Growth & Design · 2011-03-25

    Junjie Zhang, Xutang Tao, Youxuan Sun, Zhonghan Zhang, Chengqian Zhang, Zeliang Gao, Haibing Xia, Sheng‐Qing Xia

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  6. [R-C7H16N2][V2Te2O10] and [S-C7H16N2][V2Te2O10]; new polar templated vanadium tellurite enantiomers

    Journal of Solid State Chemistry · 2011-04-20

    Ethan C. Glor, Samuel M. Blau, Jeongho Yeon, Mat­thias Zeller, P. Shiv Halasyamani, Joshua Schrier, Alexander J. Norquist

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  7. Synthesis, Characterization, and Structure–Property Relationships in Two New Polar Oxides: Zn2(MoO4)(SeO3) and Zn2(MoO4)(TeO3)

    Inorganic Chemistry · 2011-05-10

    Sau Doan Nguyen, Sang‐Hwan Kim, P. Shiv Halasyamani

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  8. BiO(IO3): A New Polar Iodate that Exhibits an Aurivillius-Type (Bi2O2)2+ Layer and a Large SHG Response

    Journal of the American Chemical Society · 2011-07-21

    Sau Doan Nguyen, Jeongho Yeon, Sang‐Hwan Kim, P. Shiv Halasyamani

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  9. Polymorphism of BaTeMo 2 O 9 : A New Polar Polymorph and the Phase Transformation

    Chemistry of Materials · 2011-07-25

    Junjie Zhang, Zhonghan Zhang, Weiguo Zhang, Qingxin Zheng, Youxuan Sun, Chengqian Zhang, Xutang Tao

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  10. Anisotropic thermal properties of the polar crystal Cs2TeMo3O12

    Journal of Solid State Chemistry · 2011-12-22

    Junjie Zhang, Zhonghan Zhang, Youxuan Sun, Chengqian Zhang, Xutang Tao

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  11. Top-seeded solution crystal growth of noncentrosymmetric and polar K3V5O14

    CrystEngComm · 2012-01-01

    Weiguo Zhang, P. Shiv Halasyamani

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  12. Two New Noncentrosymmetric (NCS) Polar Oxides: Syntheses, Characterization, and Structure–Property Relationships in BaMTe2O7 (M = Mg2+ or Zn2+)

    Inorganic Chemistry · 2012-02-01

    Jeongho Yeon, Sang‐Hwan Kim, Sau Doan Nguyen, Hana Lee, P. Shiv Halasyamani

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  13. Inducing polarity in [VO3]nn− chain compounds using asymmetric hydrogen-bonding networks

    Journal of Solid State Chemistry · 2012-02-21

    Matthew D. Smith, Samuel M. Blau, Kelvin B. Chang, T. Thao Tran, Mat­thias Zeller, P. Shiv Halasyamani, Joshua Schrier, Alexander J. Norquist

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  14. Small non-polar complexes exhibiting significant piezoelectric properties: Solvothermal synthesis and crystal structures of MO5V(tren)·H2O (M=Mo and W; tren=tris(2-aminoethyl)amine)

    Journal of Solid State Chemistry · 2012-02-24

    Maren Rasmussen, Christian Näther, Ulrich Bismayer, Wolfgang Bensch

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  15. Synthesis, Structure, and Characterization of New Li+ – d0 –Lone-Pair – Oxides: Noncentrosymmetric Polar Li6(Mo2O5)3(SeO3)6 and Centrosymmetric Li2(MO3)(TeO3) (M = Mo6+ or W6+)

    Inorganic Chemistry · 2012-08-23

    Sau Doan Nguyen, P. Shiv Halasyamani

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  16. Role of Hydrogen-Bonding in the Formation of Polar Achiral and Nonpolar Chiral Vanadium Selenite Frameworks

    Inorganic Chemistry · 2012-09-24

    Jacob H. Olshansky, T. Thao Tran, Kristen J. Hernandez, Mat­thias Zeller, P. Shiv Halasyamani, Joshua Schrier, Alexander J. Norquist

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  17. Influence of the Devitrification Mechanism on Second Harmonic Generation Efficiency and Transparency in Ba 2 NaNb 5 O 15 Nanostructures

    The Journal of Physical Chemistry C · 2012-11-30

    Esther Fanelli, Claudio Giannetti, Antonio Aronne, Stefania Pagliara, Serena Esposito, Gabriele Ferrini

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  18. A combination of multiple chromophores enhances second-harmonic generation in a nonpolar noncentrosymmetric oxide: CdTeMoO6

    Journal of Materials Chemistry C · 2013-01-01

    Sangen Zhao, Xingxing Jiang, Ran He, Shuquan Zhang, Zhihua Sun, Junhua Luo, Zheshuai Lin, Maochun Hong

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  19. Chemistry of Polar Transition-Metal Oxides

    Elsevier eBooks · 2013-01-01

    P. Shiv Halasyamani

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  20. ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units

    RSC Advances · 2013-01-01

    Sangen Zhao, Junhua Luo, Pan Zhou, Shuquan Zhang, Zhihua Sun, Maochun Hong

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  21. New Molybdenum(VI) Phosphates: Synthesis, Characterization, and Calculations of Centrosymmetric RbMoO2PO4and Noncentrosymmetric Rb4Mo5P2O22

    Inorganic Chemistry · 2013-01-15

    Ying Wang, Shilie Pan, Xin Su, Zhihua Yang, Lingyun Dong, Min Zhang

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  22. New Fluoride Carbonates: Centrosymmetric KPb2(CO3)2F and Noncentrosymmetric K2.70Pb5.15(CO3)5F3

    Inorganic Chemistry · 2013-02-08

    T. Thao Tran, P. Shiv Halasyamani

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  23. Synthesis, Structure, and Characterization of Two New Polar Sodium Tungsten Selenites: Na2(WO3)3(SeO3)·2H2O and Na6(W6O19)(SeO3)2

    Inorganic Chemistry · 2013-02-20

    Sau Doan Nguyen, P. Shiv Halasyamani

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  24. Crystal Growth, Structure, Polarization, and Magnetic Properties of Cesium Vanadate, Cs2V3O8: A Structure–Property Study

    Inorganic Chemistry · 2013-05-09

    Jeongho Yeon, Athena S. Sefat, T. Thao Tran, P. Shiv Halasyamani, Hans‐Conrad zur Loye

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  25. Alignment of Acentric Units in Infinite Chains: A “Lock and Key” Model

    Crystal Growth & Design · 2013-07-31

    Romain Gautier, Kenneth Reinhard Poeppelmeier

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  26. Formation Principles for Templated Vanadium Selenite Oxalates

    Crystal Growth & Design · 2013-08-08

    Jacob H. Koffer, Jacob H. Olshansky, Matthew D. Smith, Kristen J. Hernandez, Mat­thias Zeller, Gregory M. Ferrence, Joshua Schrier, Alexander J. Norquist

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  27. Metal Chalcogenides: A Rich Source of Nonlinear Optical Materials

    Chemistry of Materials · 2013-08-09

    In Jae Chung, Mercouri G. Kanatzidis

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  28. Synthesis, crystal structure and optical properties of Ba5V3O12F

    Journal of Molecular Structure · 2013-10-15

    Jing Kang, Yun Mo Yang, Shilie Pan, Hongwei Yu, Zhongxiang Zhou

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  29. Synthesis and characterization of ASnF3 (A=Na+, K+, Rb+, Cs+)

    Journal of Solid State Chemistry · 2013-11-25

    T. Thao Tran, P. Shiv Halasyamani

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  30. A New UV Nonlinear Optical Material CsZn2B3O7: ZnO4 Tetrahedra Double the Efficiency of Second-Harmonic Generation

    Inorganic Chemistry · 2014-02-10

    Sangen Zhao, Jia Zhang, Shuquan Zhang, Zhihua Sun, Zheshuai Lin, Yicheng Wu, Maochun Hong, Junhua Luo

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  31. Sr8MB18O36 (M = Zn or Cd): Design and Synthesis of Two New Borates with a Special Ratio of 8:1

    Chemistry Letters · 2014-05-02

    Xingwen Zhang, Hongwei Yu, Hongping Wu, Shilie Pan, Lili Liu, Anqing Jiao, Chunyan Bai

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  32. How Lewis Acidity of the Cationic Framework Affects KNaNbOF5 Polymorphism

    Inorganic Chemistry · 2014-06-12

    Kelvin B. Chang, Anastasiya I. Vinokur, Rachelle Ann F. Pinlac, Matthew R. Suchomel, Michael R. Marvel, Kenneth Reinhard Poeppelmeier

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  33. An non-centrosymmetric mononuclear Zr complex exhibiting UV second-harmonic-generation

    Functional Materials Letters · 2014-12-01

    Cai-Yun Han, Mei Qu, Qin-Qin Dang, Xian‐Ming Zhang

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  34. Density functional theory calculations, growth, structure, and optical properties of birefringent LiNaV2O6

    Journal of materials research/Pratt's guide to venture capital sources · 2016-02-12

    Qingrong Kong, Yun Mo Yang, Lili Liu, Qiang Bian, Bing‐Hua Lei, Linping Li, Zhihua Yang, Zhi Su, Shilie Pan

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  35. Thermal Expansion and Second Harmonic Generation Response of the Tungsten Bronze Pb2AgNb5O15

    Inorganic Chemistry · 2016-02-29

    Kun Lin, Pifu Gong, Jing Wei Sun, Hongqiang Ma, You Wang, Youyong Li, Jinxia Nancy Deng, Jun Chen, Zheshuai Lin, Kenichi Kato, Hui Wu, Qingzhen Huang, Xianran Xing

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  36. Environmentally friendly Rb 3 V 5 O 14 fluorescent red pigment

    Dyes and Pigments · 2016-08-23

    Sun Woog Kim, Takuya Hasegawa, Mizuki Watanabe, Kazuma Sugimoto, Y. Saito, Kazuyoshi Uematsu, Kenji Toda, Mineo Sato

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  37. M 3 V 2 B 10 O 23 (M = Ca, Sr): two new vanadoborates with [V 2 B 10 O 23 ] ∞ double layers

    New Journal of Chemistry · 2017-01-01

    Zhaohui Chen, Yaqin Liu, Yunjing Shi, Wenyao Zhang, Qun Jing, Yuan Fang, Xiaoyu Dong

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  38. Thorium Chemistry in Oxo-Tellurium System under Extreme Conditions

    Inorganic Chemistry · 2017-02-13

    Bin Xiao, Philip Kegler, Dirk Bosbach, Evgeny V. Alekseev

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  39. Growth, Properties, and Theoretical Analysis of M2LiVO4 (M = Rb, Cs) Crystals: Two Potential Mid-Infrared Nonlinear Optical Materials

    Scientific Reports · 2017-05-09

    Guopeng Han, Ying Wang, Xin Su, Zhihua Yang, Shilie Pan

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  40. Assisting the Effective Design of Polar Iodates with Early Transition-Metal Oxide Fluoride Anions

    Journal of the American Chemical Society · 2018-06-12

    Hongwei Yu, Matthew Lander Nisbet, Kenneth Reinhard Poeppelmeier

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  41. Anisotropy optical properties of KSr2Nb5O15 lead-free ferroelectrics: First-principle calculations

    Journal of Physics and Chemistry of Solids · 2018-06-18

    Qian Chen, Jie Xu, Shuyao Cao, Maosen Fu, Min Wang, Feng Gao

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  42. Novel Polyoxovanadate K2ZnV5O14: Crystal Structure and Peculiarities of Crystal Chemistry

    Crystallography Reports · 2018-09-01

    Olga V. Yakubovich, Olga V. Dimitrova

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  43. NaCa4V5O17 with isolated V2O7 dimer and V3O10 trimer exhibiting a large birefringence

    Journal of Solid State Chemistry · 2018-09-12

    Zhiqing Xie, Shichao Cheng, Shuwei Li, Hanqin Ding

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  44. Syntheses, structures, anomalous phase transition and optical properties of two new polymorphic α- and β-LiMoPO 6

    Dalton Transactions · 2019-01-01

    Haonan Liu, Hongping Wu, Hongwei Yu, Zhanggui Hu, Yicheng Wu

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  45. Synthesis, crystal structures, second harmonic generation response and temperature phase transitions of two noncentrosymmetric Cu(II)-hybrid halides compounds: [(R)-C7H16N2][CuX4] (X = Cl or Br)

    Journal of Molecular Structure · 2019-01-10

    Fadhel Hajlaoui, Ines Ben Hadj Sadok, H. Alamri Aeshah, Nathalie Audebrand, Thierry Roisnel, Nabil Zouari

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  46. Monolayer MgVOx/Al2O3 catalysts for propane oxidative dehydrogenation: Insights into a role of structural, redox, and acid-base properties in catalytic performance

    Applied Catalysis A General · 2020-04-22

    Tamara Kharlamova, Konstantin L. Timofeev, M.A. Salaev, В. А. Светличный, Olga V. Vodyankina

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  47. Bond-length distributions for ions bonded to oxygen: results for the transition metals and quantification of the factors underlying bond-length variation in inorganic solids

    IUCrJ · 2020-06-09

    Olivier Charles Gagné, Frank Christopher Hawthorne

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  48. A new nonlinear optical sulfate of layered structure: Cs2Zn2(SO4)3

    Inorganic Chemistry Communications · 2020-12-07

    Youchao Liu, Yanqiang Li, Zhou Yang, Qingran Ding, Yangxin Chen, Sangen Zhao, Junhua Luo

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  49. Sr2Nb6O13F8·4H2O and Sr3Nb2O2F12·2H2O: A Variant of Three-Dimensional Tungsten Bronze and a Polar Molecular Oxide Fluoride

    Inorganic Chemistry · 2021-05-19

    Euna Ko, Hongil Jo, Kang Min Ok

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  50. A Congruent‐Melting Mid‐Infrared Nonlinear Optical Vanadate Exhibiting Strong Second‐Harmonic Generation

    Angewandte Chemie · 2021-08-04

    Chao Wu, Xingxing Jiang, Lin Lin, Yilei Hu, Tianhui Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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