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RESEARCH PAPER · Inorganic Chemistry · 2005

New Metal Iodates: Syntheses, Structures, and Characterizations of Noncentrosymmetric La(IO3)3 and NaYI4O12 and Centrosymmetric β-Cs2I4O11 and Rb2I6O15(OH)2·H2O

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New Metal Iodates: Syntheses, Structures, and Characterizations of Noncentrosymmetric La(IO3)3 and NaYI4O12 and Centrosymmetric β-Cs2I4O11 and Rb2I6O15(OH)2·H2OOriginalHalogens and noble gases2New Metal Iodates: Syntheses, Structures, and Characterizations of Noncentrosymmetric La(IO3)3 and NaYI4O12 and Centrosymmetric β‐Cs2I4O11 and Rb2I6O15 (OH)2×H2O.0Structural Polarity Induced by Cooperative Hydrogen Bonding and Lone-Pair Alignment in the Molecular Uranyl Iodate Na2[UO2(IO3)4(H2O)]18Square‐Planar Noble Metal Iodate [M(IO3)4]n– (M = PdII, AuIII; n = 2, 1) Anions and Their Ability to Form Polar and Centrosymmetric Architectures17Synthesis, Structure, Characterization, and Calculations of Two New Sn2+−W6+−oxides, Sn2WO5 and Sn3WO620Hydrothermal Synthesis, Structural Characterisations, and Photoluminescence Properties of Four Inorganic‐Organic Hybrid Compounds in the Indium/Gallium Iodate Family11Prediction of the structures in the family of La(IO3)3 iodates based on topology and symmetry analysis within the OD theory7Isotope Effect on SHG Response and Ferroelectric Properties of a Homochiral Zinc Coordination Compound Containing Tetrazole Ligand98New Polar Oxides: Synthesis, Characterization, Calculations, and Structure−Property Relationships in RbSe2V3O12 and TlSe2V3O12125Polar or Nonpolar? A+ Cation Polarity Control in A2Ti(IO3)6(A = Li, Na, K, Rb, Cs, Tl)306BaNbO(IO3)5: A New Polar Material with a Very Large SHG Response331Two-dimensional dysprosium(III) triiodate(V) dihydrate, Dy(IO3)3(H2O)·H2O1New Noncentrosymmetric Material - [N(CH3)4]ZnCl3: Polar Chains of Aligned ZnCl4 Tetrahedra63New thallium iodates—Synthesis, characterization, and calculations of Tl(IO3)3 and Tl4(IO3)6, [Tl+3Tl3+(IO3)6]25Syntheses and crystal structures of four new silver(i) iodates with d 0 -transition metal cations45Anionic templating in a new layered bismuth tellurium oxychloride, Bi3Te4O10Cl529Syntheses, crystal structures, and properties of three new lanthanum( iii ) vanadium iodates56Lone Pairs as Chemical Scissors in New Antimony Oxychlorides, Sb2ZnO3Cl2 and Sb16Cd8O25Cl1445Reinterpretation of Three Crystal Structures of Alkali Oxoiodate(V) – Description of the [I3O8]–Anion and the Infinite 2D [I3O8–]∞Anion43Explorations of New Second-Order Nonlinear Optical Materials in the KI-MII -IV-O Systems43New Noncentrosymmetric Tellurite Phosphate Material: Synthesis, Characterization, and Calculations of Te2O(PO4)295A new layered indium selenium oxychloride material: Synthesis, structure, and characterization of InSeO3Cl20Polar or Non-Polar? Syntheses, Crystal Structures, and Optical Properties of Three New Palladium(II) Iodates45A series of new alkali metal indium iodates with isolated or extended anions22Structures and properties of functional metal iodates72Polymorphism of BaTeMo 2 O 9 : A New Polar Polymorph and the Phase Transformation186Bi2(IO4)(IO3)3: A New Potential Infrared Nonlinear Optical Material Containing [IO4]3– Anion111Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites60ZnIO3(OH): a new layered noncentrosymmetric polar iodate – hydrothermal synthesis, crystal structure, and second-harmonic generating (SHG) properties36Titanyl Iodate – A Promising Material for Infrared Nonlinear Optics Showing Structural Similarities with KTP32K4TM4(V2O7)2(IO3)4(H2O) (TM = Zn, Ni, Co): a series of quinary mixed metal–vanadium(v)–iodates18Synthesis, crystal growth, and characterization of the orthorhombic BaTeW2O9: a new polymorph of BaTeW2O925Tl(VO)2O2(IO3)3: a new polar material with a strong SHG response26Zn2(VO4)(IO3): A Novel Polar Zinc(II) Vanadium(V) Iodate with a Large SHG Response94First Evidence of a Phase Transition in a High‐Pressure Metal Iodate: Structural and Thermal Studies of AgIO3 Polymorphs12Hydrothermal synthesis, growth, and properties of a new chloride iodate13Explorations of a Series of Second Order Nonlinear Optical Materials Based on Monovalent Metal Gold(III) Iodates33The Synthesis, Structure, and Tunable Emission Spectra of A New Phosphor Sm(IO3)3·2H2O6A 2 BiI 5 O 15 (A = K + or Rb + ): two new promising nonlinear optical materials containing [I 3 O 9 ] 3− bridging anionic groups62A new polymorph of Cd 3 B 2 O 6 : synthesis, crystal structure and phase transformation18Dimensionality variations in new zirconium iodates: hydrothermal syntheses, structural determination, and characterization of BaZr(IO 3 ) 6 and K 2 Zr(IO 3 ) 619Optical properties of Nd 3+ and Yb 3+ -doped AgM(IO 3 ) 4 metal iodates: transparent host matrices for mid-IR lasers and nonlinear materials40Explorations of New Second-Order Nonlinear Optical Materials in the Ternary Rubidium Iodate System: Noncentrosymmetric β-RbIO3(HIO3)2 and Centrosymmetric Rb3(IO3)3(I2O5)(HIO3)4(H2O)59Synthesis, Structure, and Properties of a New ErIII Iodate2α-AgI3O8 and β-AgI3O8 with Large SHG Responses: Polymerization of IO3 Groups into the I3O8 Polyiodate Anion113Linear and Nonlinear Optical Properties of K3B6O10Br Single Crystal: Experiment and Calculation81Synthesis, crystal structure and optical properties of two new layered cadmium iodates: Cd(IO3)X (X=Cl, OH)13Raman scattering structural studies of nonlinear optical M ( IO 3)3( M = Fe , Ga , α- In ) and linear optical β- In ( IO 3)323Hydrothermal synthesis of C3N4/BiOIO3 heterostructures with enhanced photocatalytic properties74An unusual density evolution between SrCdB 2 O 5 polymorphs6Recent advances on second-order NLO materials based on metal iodates328Structures, Thermal Behaviors, and Luminescent Properties of Anhydrous Lanthanum Iodate Polymorphs26K2Au(IO3)5 and β‐KAu(IO3)4: Polar Materials with Strong SHG Responses Originating from Synergistic Effect of AuO4 and IO3 Units18RbIO3 and RbIO2F2: Two Promising Nonlinear Optical Materials in Mid-IR Region and Influence of Partially Replacing Oxygen with Fluorine for Improving Laser Damage Threshold124Differences and Similarities between Lanthanum and Rare-Earth Iodate Anhydrous Polymorphs: Structures, Thermal Behaviors, and Luminescent Properties12Tuning of nonlinear optical and ferroelectric properties via the cationic composition of Ca9.5–1.5Bi Cd(VO4)7 solid solutions27A new cerium iodate infrared nonlinear optical material with a large second-harmonic generation response30Iodide-Iodates M3[IO3]12·Ag4I, M = Bi, Tb, with a Framework Structure and High Second-Harmonic Generation Optical Response19Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect238Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect71Bi3OF3(IO3)4: Metal Oxyiodate Fluoride Featuring a Carbon-Nanotube-like Topological Structure with Large Second Harmonic Generation Response121Photoconversion Mechanisms and the Origin of Second-Harmonic Generation in Metal Iodates with Wide Transparency, NaLn(IO3)4 (Ln = La, Ce, Sm, and Eu) and NaLa(IO3)4:Ln3+ (Ln = Sm and Eu)32M(IO3)(HPO4)(H2O) (M = Sc, Fe, Ga, In): Introduction of Phosphate Anions into Metal Iodates16Acentric La3(IO3)8(OH) and La(IO3)2(NO3): Partial Substitution of Iodate Anions in La(IO3)3 by Hydroxide or Nitrate Anion55Enhanced nonlinear optical activity and Ca2+-conductivity in Са10.5-Pb (VO4)7 ferroelectrics23Oxyhalides: prospecting ore for optical functional materials with large laser damage thresholds76A Large Family of Centrosymmetric and Chiral f-Element-Bearing Iodate Selenates Exhibiting Coordination Number and Dimensional Reductions26Functional Materials Design via Structural Regulation Originated from Ions Introduction: A Study Case in Cesium Iodate System90Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)2(IO3)4O, Ba3[(MoO2)2(IO3)4O(OH)4]·2H2O, and Sr[(MoO2)6(IO4)2O4]·H2O24Ce(IO3)2F2⋅H2O: The First Rare‐Earth‐Metal Iodate Fluoride with Large Second Harmonic Generation Response66From centrosymmetric to noncentrosymmetric: cation-directed structural evolution in X 3 ZnB 5 O 10 (X = Na, K, Rb) and Cs 12 Zn 4 (B 5 O 10 ) 4 crystals26KBi(IO 3 ) 3 (OH) and NaBi(IO 3 ) 4 : from the centrosymmetric chain to a noncentrosymmetric double layer18Synthesis, structure and characterization of M(IO 3 ) 2 (HIO 3 ) (M = Ca, Sr) as new anhydrous alkaline earth metal bis-iodate hydrogeniodate compounds16Microwave Synthesis and Up-Conversion Properties of SHG-Active α-(La, Er)(IO3)3 Nanocrystals14TB-mBJ calculation of structural, electronic and optical properties of two monovalent iodates AIO3 (A=Tl, α-Rb)9HBa2.5(IO3)6(I2O5) and HBa(IO3)(I4O11): Explorations of Second-Order Nonlinear Optical Materials in the Alkali-Earth Polyiodate System49Two Polar Molybdenum(VI) Iodates(V) with Large Second-Harmonic Generation Responses67Barium-induced effects on structure and properties of β-Ca3(PO4)2-type Ca9Bi(VO4)712REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion125REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion62Five New Silver Rare‐Earth Iodates, AgLn(IO3)4 (Ln=Pr, Sm, Dy, Er and Tm): Synthesis, Structures and Properties6SrI3O9H: A new alkaline earth metal iodate with two different anionic units using mild aqua-solution method8Dual light-emitting Yb3+,Er3+-doped La(IO3)3 iodate nanocrystals: up-conversion and second harmonic generation6Evidence of reaction intermediates in microwave-assisted synthesis of SHG active α-La(IO 3 ) 3 nanocrystals4From centrosymmetric to noncentrosymmetric: intriguing structure evolution in d 10 -transition metal iodate fluorides36Incorporating rare-earth cations with moderate electropositivity into iodates for the optimized second-order nonlinear optical performance17KNiB4O6F3: A Layered Fluorooxoborate with Charge‐Oriented Ordering18K2Na(IO3)2(I3O8) with Strong Second Harmonic Generation Response Activated by Two Types of Isolated Iodate Anions46A review on phase transition and structure-performance relationship of second-order nonlinear optical polymorphs107Bond-length distributions for ions bonded to oxygen: results for the transition metals and quantification of the factors underlying bond-length variation in inorganic solids128Second-Harmonic Generation and Photoluminescence Properties of Sn(II)- and Bi(III)-Based Lone Pair Cation–Pyridine Dicarboxylate Coordination Compounds17Effect of iodic acid concentration in preparation of zinc iodate: Experimental characterization of Zn(IO3)2, and its physical properties from density functional theory18Simple New Method for the Preparation of La(IO3)3 Nanoparticles6The first actinide polyiodate: a complex multifunctional compound with promising X-ray luminescence properties and proton conductivity17Na3Bi(IO3)6: An Alkali-Metal Bismuth Iodate with Intriguing One-Dimensional [BiI6O18] Chains and Pressure-Induced Structural Transition11Cd3(IO3)(IO4)F2·0.1CdO: A Nonlinear-Optical Crystal with the Introduction of Fluoride into Iodate Containing Both [IO3]− and [IO4]3– Groups18[ o ‐C 5 H 4 NHOH] 2 [I 7 O 18 (OH)]⋅3 H 2 O: An Organic–Inorganic Hybrid SHG Material Featuring an [I 7 O 18 (OH)] Branched Polyiodate Chain86[o‐C5H4NHOH]2[I7O18(OH)]⋅3 H2O: An Organic–Inorganic Hybrid SHG Material Featuring an [I7O18(OH)] Branched Polyiodate Chain21Hydrothermal Synthesis of New Iodates Ln2(IO3)3(IO4) (Ln = La, Nd, Pr) Containing the Tetraoxoiodate(V) Anion: Creation of Luminescence Properties by Doping with Eu, Dy, and Tb5Pressure-Driven Symmetry-Preserving Phase Transitions in Co(IO3)223Synthesis and Characterization of Novel Nanoparticles of Lithium Aluminum Iodate LiAl(IO3)4, and DFT Calculations of the Crystal Structure and Physical Properties6Ba 4 Ag 5 (IO 3 ) 6 (I 3 O 8 ) 3 (I 4 O 11 ) 2 : a nonlinear optical crystal containing two types of polyiodate anions16BaI 3 O 9 H: a new alkaline-earth metal hydroxy iodate with two groups2Mg(H 2 O) 6 [(IO 2 (OH)) 2 (IO 3 )] 2 : a new iodate with a very large band gap and optical anisotropy14Polar lanthanide copper iodates LnCu(IO3)5 (Ln = La, Ce, Pr, and Nd): Synthesis, crystal structure and characterization6Synthesis, crystal structure and optical properties of the first bromine-containing iodate: Pb2IO3Br30C(NH2)3Rb(I3O8)(IO3)(I2O6H2): An unprecedented organic–inorganic hybrid polyiodate with two different polyiodate groups13[M(OH) 2 ] 3 (IO 3 )(SeO 4 )·H 2 O (M = Ga and In): metal iodate–selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology20Noncentrosymmetric γ-Cs2I4O11 Obtained from IO4 Polyhedral Rearrangements in the Centrosymmetric β-Phase16A review on the advancements in the characterization of the high-pressure properties of iodates44ε-La(IO3)3: A Polar Iodate with High Thermal Stability and a Large Second-Harmonic-Generation Response Obtained by a Supercritical Hydrothermal Method8Designing a Strong Second-Harmonic Generation Polar Iodate by the Structure-Directing Properties of the “Tumbler-like” [Zn(IO3)(I2O5(OH))] Polyanions20Ce(IO3)3F and Ce(IO3)2(NO3): Two Mixed-Anion Cerium Iodates with Good Nonlinear Optical and Birefringent Properties14Novel experimental methodology and optical analysis of (Ni, Co, Fe, and Cr) iodate nanocrystals3NaLn(IO3)4 Iodates (Ln = Pr, Tb): New Representatives of Nonlinear Optical Crystals with the NaY(IO3)4 Structure3NaLn(IO3)4 Iodates (Ln = Pr, Tb): New Representatives of Nonlinear Optical Crystals with the NaY(IO3)4 Structure0Rb‐Doped Perovskite Oxides: Surface Enrichment and Structural Reconstruction During the Oxygen Evolution Reaction13Lanthanide Contraction Eliminates Disorder while Holding Robust Second Harmonic Generation in a Series of Polyiodates13Rational Design of Novel Polar Nonlinear Optical Materials in Alkali Metal Rare Earth Iodates5Microwave-hydrothermal synthesis, near ultraviolet/infrared-excited green fluorescence and ratiometric thermometry of Er3+-activated iodate phosphors17Reactive transport modeling to quantify the transformation of iron oxyhydroxides on the enrichment of iodine in groundwater of central Datong Basin4Narrow Optical Linewidths in Stoichiometric Layered Rare-Earth Crystals4Ce-centered polyhedral arrangement pattern and optical performance in Ce-based nonlinear optical materials3Negative linear compressibility and phonon softening in Mg ( IO 3 ) 2 under pressure1Synthesis and Optical Quantum Memory Characterization of α-Eu(IO 3 ) 3 , β-Eu(IO 3 ) 3 , and NaEu(IO 3 ) 41

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  2. New Metal Iodates: Syntheses, Structures, and Characterizations of Noncentrosymmetric La(IO3)3 and NaYI4O12 and Centrosymmetric β‐Cs2I4O11 and Rb2I6O15 (OH)2×H2O.

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  3. Structural Polarity Induced by Cooperative Hydrogen Bonding and Lone-Pair Alignment in the Molecular Uranyl Iodate Na2[UO2(IO3)4(H2O)]

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  7. Prediction of the structures in the family of La(IO3)3 iodates based on topology and symmetry analysis within the OD theory

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  8. Isotope Effect on SHG Response and Ferroelectric Properties of a Homochiral Zinc Coordination Compound Containing Tetrazole Ligand

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  9. New Polar Oxides: Synthesis, Characterization, Calculations, and Structure−Property Relationships in RbSe2V3O12 and TlSe2V3O12

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  10. Polar or Nonpolar? A+ Cation Polarity Control in A2Ti(IO3)6(A = Li, Na, K, Rb, Cs, Tl)

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  11. BaNbO(IO3)5: A New Polar Material with a Very Large SHG Response

    Journal of the American Chemical Society · 2009-06-22

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  13. New Noncentrosymmetric Material - [N(CH3)4]ZnCl3: Polar Chains of Aligned ZnCl4 Tetrahedra

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  16. Anionic templating in a new layered bismuth tellurium oxychloride, Bi3Te4O10Cl5

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  17. Syntheses, crystal structures, and properties of three new lanthanum( iii ) vanadium iodates

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