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RESEARCH ARTICLE · Inorganic Chemistry · 2010

New Noncentrosymmetric Tellurite Phosphate Material: Synthesis, Characterization, and Calculations of Te2O(PO4)2

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New Noncentrosymmetric Tellurite Phosphate Material: Synthesis, Characterization, and Calculations of Te2O(PO4)2OriginalChemInform Abstract: New Noncentrosymmetric Tellurite Phosphate Material: Synthesis, Characterization, and Calculations of Te2O(PO4)2.1Syntheses and Crystal Structures of a Series of Alkaline Earth Vanadium Selenites and Tellurites41A series of new phases in the alkali metal–NbV/TaV–SeIV/TeIV–O systems19Bulk crystal growth and characterization of a new polar polymorph of BaTeMo2O9: α-BaTeMo2O998Oxygen, sulfur, selenium, tellurium and polonium9New Quaternary Tellurite and Selenite: Synthesis, Structure, and Characterization of Centrosymmetric InVTe2O8 and Noncentrosymmetric InVSe2O887Syntheses, Crystal Structures, Magnetic and Luminescent Properties of two Classes of Molybdenum(VI) Rich Quaternary Lanthanide Selenites34Synthesis, Characterization, and Structure–Property Relationships in Two New Polar Oxides: Zn2(MoO4)(SeO3) and Zn2(MoO4)(TeO3)80Syntheses and Characterization of New Mid-Infrared Transparency Compounds: Centric Ba2BiGaS5 and Acentric Ba2BiInS595Synthesis, crystal structure and magnetic properties of the open framework compound Co3Te2O2(PO4)2(OH)49PbMSeO6 (M = Mo and W): New quaternary mixed metal selenites with asymmetric cationic coordination environments37Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites60Syntheses, crystal structures and properties of new lead(ii) or bismuth(iii) selenites and tellurite41Noncentrosymmetric Inorganic Open-Framework Chalcohalides with Strong Middle IR SHG and Red Emission: Ba3AGa5Se10Cl2 (A = Cs, Rb, K)257Chemistry of Polar Transition-Metal Oxides1Pb2TiOF(SeO3)2Cl and Pb2NbO2(SeO3)2Cl: small changes in structure induced a very large SHG enhancement117Large scale synthesis, second-harmonic generation, and piezoelectric properties of a noncentrosymmetric vanadium phosphate, Li2VPO69Na1.4InTe3.6O9.4: New Variant of a Hexagonal Tungsten Oxide (HTO)-Like Layered Framework Containing Both a Main-Group Cation, In3+, and a Lone-Pair Cation, Te4+14Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)2F2Cl and Noncentrosymmetric NaBa4(AlB4O9)2Br350Metal Chalcogenides: A Rich Source of Nonlinear Optical Materials680α-ScVSe2O8, β-ScVSe2O8, and ScVTe2O8: New Quaternary Mixed Metal Oxides Composed of Only Second-Order Jahn–Teller Distortive Cations34Two Modifications of (TeO)(HAsO4) and its Dehydration Product (Te3O3)(AsO4)2 – Three more Examples of Tellurium(IV) with a Fivefold Oxygen Coordination5Growth and properties of a noncentrosymmetric polyphosphate CsLa(PO 3 ) 4 crystal with deep-ultraviolet transparency100Noncentrosymmetric YVSe2O8 and Centrosymmetric YVTe2O8: Macroscopic Centricities Influenced by the Size of Lone Pair Cation Linkers63Strong Second Harmonic Generation (SHG) Originating from Combined Second-Order Jahn–Teller (SOJT) Distortive Cations in a New Noncentrosymmetric Tellurite, InNb(TeO4)252Effect of polarizable lone pair cations on the second-harmonic generation (SHG) properties of noncentrosymmetric (NCS) Bi 2−x Y x TeO 5 (x = 0–0.2)24Dimensional and Coordination Number Reductions in a Large Family of Lanthanide Tellurite Sulfates21Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons67New Polymorphs of Ternary Sodium Tellurium Oxides: Hydrothermal Synthesis, Structure Determination, and Characterization of β-Na2Te4O9 and Na2Te2O6·1.5H2O21Cooperative Effects of Cation Size and Variable Coordination Modes of Te4+ on the Frameworks of New Alkali Metal Indium Tellurites, NaIn(TeO3)2, KIn(TeO3)2, RbInTe3O8, and CsInTe3O833Rich Structural Chemistry in New Alkali Metal Yttrium Tellurites: Three-Dimensional Frameworks of NaYTe4O10, KY(TeO3)2, RbY(TeO3)2, and a Novel Variant of Hexagonal Tungsten Bronze, CsYTe3O823Stacking faults in a layered cobalt tellurium phosphate oxochloride3Effects of Te(IV) Oxo-Anion Incorporation into Thorium Molybdates and Tungstates14Structure–Property Correlations in the Heterobimetallic 4f/3d Materials Ln2M(TeO3)2(SO4) (Ln = Y, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or Lu; M = Co or Zn)25Investigation of reactivity and structure formation in a K–Te–U oxo-system under high-temperature/high-pressure conditions7IR Spectra of Minerals and Related Compounds, and Reference Samples’ Data21Rb 2 SeOCl 4 ·H 2 O: a polar material among the alkali metal selenite halides with a strong SHG response18Structural variety in zinc telluro-phosphates: syntheses, crystal structures and characterizations of Sr 2 Zn 3 Te 2 P 2 O 14 , Pb 2 Zn 3 Te 2 P 2 O 14 and Ba 2 Zn 2 TeP 2 O 1119Rich Non-centrosymmetry in a Na–U–Te Oxo-System Achieved under Extreme Conditions13A review of the structural architecture of tellurium oxycompounds170A New Deep-Ultraviolet Transparent Orthophosphate LiCs 2 PO 4 with Large Second Harmonic Generation Response384Strong Nonlinear-Optical Response in the Pyrophosphate CsLiCdP2O7 with a Short Cutoff Edge69Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures601A new β-CdTeO 3 polymorph with a structure related to α-CdTeO 39Thorium Chemistry in Oxo-Tellurium System under Extreme Conditions10New vanadium tellurites: Syntheses, structures, optical properties of noncentrosymmetric VTeO 4 (OH), centrosymmetric Ba 2 V 4 O 8 (Te 3 O 10 )12125Te NMR Probes of Tellurium Oxide Crystals: Shielding-Structure Correlations18K 2 TeP 2 O 8 : a new telluro-phosphate with a pentagonal Te–P–O layer structure26Na 3 Ca 4 (TeO 3 )(PO 4 ) 3 : a new noncentrosymmetric tellurite phosphate with fascinating multimember-ring architectures and intriguing nonlinear optical performance30Three new d10 transition metal selenites containing PO4 tetrahedron: Cd7(HPO4)2(PO4)2(SeO3)2, Cd6(PO4)1.34(SeO3)4.66 and Zn3(HPO4)(SeO3)2(H2O)16Synergetic Influence of Alkali-Metal and Lone-Pair Cations on Frameworks of Tellurites15Czochralski Growth and Characterization of a Novel Nonlinear Optical Crystal Te2P2O923A Langbeinite-Type Yttrium Phosphate LiCs2Y2(PO4)336Preparation of tellurium doped graphitic carbon nitride and its visible-light photocatalytic performance on nitrogen fixation47An alkali metal phosphate RbPbBi 2 (PO 4 ) 3 with three kinds of disorder: the effect of isolated soft cation units on the crystal structure7Lone pair effects on ternary infrared nonlinear optical materials19[Ge2S5(S2)]4−, A NLO‐Active Unit Leading to an Asymmetric Structure Discovered in Li2Cs4Ge2S5(S2)Cl2: An Experimental and Theoretical study18Structure of tin phosphate glasses by neutron and X-ray diffraction11Syntheses, crystal structures, and characterizations of three new pyrophosphates CsNaZnP2O7, RbNaZnP2O7, and RbLiMgP2O710IR Spectra of Minerals and Related Compounds, and Reference Samples Data3BaLiTe2O5X (X = Cl, Br): mixed alkali/alkaline-earth metal tellurite halides with [Te2O5]∞ chains11Recent progress in selenite and tellurite based SHG materials32Te 3 O 3 (PO 4 ) 2 : a phosphate crystal with large birefringence activated by the highly distorted [TeO 5 ] group and antiparallel [PO 4 ] pseudo-layer33Three diphosphates, α-Li 2 Na 2 P 2 O 7 , Li 8 Pb 3 Ba(P 2 O 7 ) 4 and Li 7 Rb(P 2 O 7 ) 2 : influences of co-substitution on the crystal structure9Influence of Cation on the Anion Frameworks and Properties of Four Lead Phosphates, A2PbBi2(PO4)2(P2O7) (A = Rb, Cs) and A2PbP2O7 (A = K, Rb)15Two Pyrophosphates with Large Birefringences and Second‐Harmonic Responses as Ultraviolet Nonlinear Optical Materials137Two Pyrophosphates with Large Birefringences and Second‐Harmonic Responses as Ultraviolet Nonlinear Optical Materials29Unique synthesis, structure determination, and optical properties of seven new layered rare earth tellurite nitrates, RE(TeO3)(NO3) (RE = La, Nd, Eu, Gd, Dy, Er, and Y)15Influence of various transition metals incorporated into tellurium used as antimicrobial agent and textile dye degrader7NaTePO5, SrTeP2O8 and Ba2TeP2O9: Three tellurite-phosphates with large birefringence22Na3AMg7(PO4)6 (A = K, Rb and Cs): Structures, properties and theoretical studies of alkali metal magnesium orthophosphates14K8Cd21Pb7(P2O7)16 and KCd2P3O10: Two new phosphates featuring special structure configurations2Ba3Sb2(PO4)4 and Cd3Sb2(PO4)4(H2O)2: Two New Antimonous Phosphates with Distinct [Sb(PO4)2] Structure Types and Enhanced Birefringence37Two Tellurium(IV)-Based Sulfates Exhibiting Strong Second Harmonic Generation and Moderate Birefringence as Promising Ultraviolet Nonlinear Optical Materials28KIn0.33IIITe0.67VITe2IVO7: Zirconolite-like Mixed-Valent Metal Oxide with a 3D Framework2Cd3(PO4)(TePO6): A Novel Cadmium Tellurite‐Phosphate featuring a {[TePO6]3−}∞ Chain15Effects of M Cations on Crystal Structure and Optical Properties of Mte3o8 Tellurites2Two new tellurite halides with cationic layers: syntheses, structures, and characterizations of CdPb 2 Te 3 O 8 Cl 2 and Cd 13 Pb 8 Te 14 O 42 Cl 1418Potential optical functional crystals with large birefringence: Recent advances and future prospects322Structure of binary antimony phosphate glasses by diffraction methods4Charge compensation and solid-state lighting application for dysprosium-activated Ba2TeP2O9 phosphor25Synthesis, Crystal Structure, and Characterizations of Two Tantalum Phosphates A3TaP2O9 (A=K, Na)4Synthesis and crystal structure of the first ternary tellurium borate TeB4O83Tunable luminescence and improved thermostability via Tm―Dy energy transfer in a tellurooxyphosphate phosphor29Luminescent Improvement Via the Partial Substitution of Gd3+ in Microwave-Assisted Synthesized Dy3+-Activated Na3ca4(Teo3)(Po4)3 Phosphor0Understanding of the structural chemistry in the uranium oxo-tellurium system under HT/HP conditions5Highly thermally stable and tunable luminescence in microwave-assisted synthesized Na3Ca4(TeO3)(PO4)3:Dy3+,Eu3+ for ultra-high color rendering white light-emitting diodes16AKTeO2(CO3) (A = Li, Na): The First Carbonatotellurites Featuring a Zero-Dimensional [Te2C2O10]4– Cluster and a Wide Band Gap5Design of a highly efficient heterostructure of transition metal tellurides with outstanding photocatalytic and antimicrobial potential12Guangyuanite, Pb3Cl3(Se4+O3)(OH), a new lead chloride selenite mineral from the El Dragón mine, Potosí, Bolivia5Molybdomenite-P21/c, Polymorphous with Molybdomenite and the Natural Analogue of Synthetic α-PbSe4+O3, from the El Dragón Mine, Potosí, Bolivia1Wangkuirenite—a new lead chloride-selenite mineral0Ag(Te2O3)(PO4): The first Ag-containing phosphate-tellurite nonlinear optical crystal featuring novel zigzag layered structure0Rare 3 × 3 Layering in High‐Pressure Pseudo‐Perovskite Sr 4 Te 4 O 150Shenganfuite, PbTe4+3O5(OH)Cl3(H2O), a New Lead-Tellurite Mineral from the Moctezuma Mine, Sonora, Mexico1

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  12. Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites

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  19. Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)2F2Cl and Noncentrosymmetric NaBa4(AlB4O9)2Br3

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