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RESEARCH PAPER · Inorganic Chemistry · 2011

New Quaternary Tellurite and Selenite: Synthesis, Structure, and Characterization of Centrosymmetric InVTe2O8 and Noncentrosymmetric InVSe2O8

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New Quaternary Tellurite and Selenite: Synthesis, Structure, and Characterization of Centrosymmetric InVTe2O8 and Noncentrosymmetric InVSe2O8OriginalChemInform Abstract: New Quaternary Tellurite and Selenite: Synthesis, Structure, and Characterization of Centrosymmetric InVTe2O8 and Noncentrosymmetric InVSe2O80Centrosymmetric [N(CH3)4]2TiF6 vs. noncentrosymmetric polar [C(NH2)3]2TiF6: A hydrogen-bonding effect on the out-of-center distortion of TiF6 octahedra31New mixed metal selenites and tellurites containing Pd 2+ ions in a square planar geometry14Oxygen, sulfur, selenium, tellurium and polonium0PbMSeO6 (M = Mo and W): New quaternary mixed metal selenites with asymmetric cationic coordination environments37Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites60Syntheses, crystal structures and properties of new lead(ii) or bismuth(iii) selenites and tellurite41Explorations of new selenites of the group IIIA and IVA metals13Effect of the Framework Flexibility on the Centricities in Centrosymmetric In2Zn(SeO3)4 and Noncentrosymmetric Ga2Zn(TeO3)450Cation Size Effect on the Framework Structures in a Series of New Alkali-Metal Indium Selenites, AIn(SeO3)2 (A = Na, K, Rb, and Cs)28Syntheses, crystal structures and characterizations of two new bismuth(III) arsenites2Oxygen, sulfur, selenium, tellurium and polonium3New Bismuth Selenium Oxides: Syntheses, Structures, and Characterizations of Centrosymmetric Bi2(SeO3)2(SeO4) and Bi2(TeO3)2(SeO4) and Noncentrosymmetric Bi(SeO3)(HSeO3)53Large scale synthesis, second-harmonic generation, and piezoelectric properties of a noncentrosymmetric vanadium phosphate, Li2VPO69New Alkali-Metal Gallium Selenites, AGa(SeO3)2 (A = Li, Na, K, and Cs): Effect of Cation Size on the Framework Structures and Macroscopic Centricities76A new strontium antimonateIII Sr5Sb22O38: Synthesis, crystal structure and characterizations9Formation Principles for Templated Vanadium Selenite Oxalates22New Selenites: Hydrothermal Syntheses, Crystal Structures, and Characterization of Rb3HGa2(OH)2(SeO3)4, Rb3Ga5(SeO3)8(HSeO3)2·0.5H2O, and RbGa(SeO3)2·H2O16α-ScVSe2O8, β-ScVSe2O8, and ScVTe2O8: New Quaternary Mixed Metal Oxides Composed of Only Second-Order Jahn–Teller Distortive Cations34Y2MoSe3O12 and Y2MoTe3O12: Solid-state synthesis, structure determination, and characterization of two new quaternary mixed metal oxides containing asymmetric coordination environment22From an Open Framework to a Layered and a Hexagonal Tungsten Oxide Structure: Controlled Transformation Reactions of an Extended Solid-State Material, Cs3Ga7(SeO3)12 to Ga(OH)(SeO3) and KGa3(SeO4)2(OH)613Sr 4 B 10 O 18 (OH) 2 ·2H 2 O: a new UV nonlinear optical material with a [B 10 O 23 ] 16− building block53VSb(SeO3)4, First Selenite Containing V3+ Cation: Synthesis, Structure, Characterization, Magnetic Properties, and Calculations15Dimensionality variations in new zirconium iodates: hydrothermal syntheses, structural determination, and characterization of BaZr(IO 3 ) 6 and K 2 Zr(IO 3 ) 619Noncentrosymmetric YVSe2O8 and Centrosymmetric YVTe2O8: Macroscopic Centricities Influenced by the Size of Lone Pair Cation Linkers63Variable Framework Structures and Centricities in Alkali Metal Yttrium Selenites, AY(SeO3)2 (A = Na, K, Rb, and Cs)51Strong Second Harmonic Generation (SHG) Originating from Combined Second-Order Jahn–Teller (SOJT) Distortive Cations in a New Noncentrosymmetric Tellurite, InNb(TeO4)252Effect of polarizable lone pair cations on the second-harmonic generation (SHG) properties of noncentrosymmetric (NCS) Bi 2−x Y x TeO 5 (x = 0–0.2)24Rich Structural Chemistry in Scandium Selenium/Tellurium Oxides: Mixed-Valent Selenite–Selenates, Sc2(SeO3)2(SeO4) and Sc2(TeO3)(SeO3)(SeO4), and Ternary Tellurite, Sc2(TeO3)341Dimensional and Coordination Number Reductions in a Large Family of Lanthanide Tellurite Sulfates21Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons67New Polymorphs of Ternary Sodium Tellurium Oxides: Hydrothermal Synthesis, Structure Determination, and Characterization of β-Na2Te4O9 and Na2Te2O6·1.5H2O21Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework36Sr3Bi2(SeO3)6·H2O: A novel anionic layer consisting of second-order Jahn–Teller (SOJT) distortive cations9Cooperative Effects of Cation Size and Variable Coordination Modes of Te4+ on the Frameworks of New Alkali Metal Indium Tellurites, NaIn(TeO3)2, KIn(TeO3)2, RbInTe3O8, and CsInTe3O833Rich Structural Chemistry in New Alkali Metal Yttrium Tellurites: Three-Dimensional Frameworks of NaYTe4O10, KY(TeO3)2, RbY(TeO3)2, and a Novel Variant of Hexagonal Tungsten Bronze, CsYTe3O823Macroscopic polarity control with alkali metal cation size and coordination environment in a series of tin iodates82SnGa 2 GeS 6 : synthesis, structure, linear and nonlinear optical properties46New quaternary oxides with both families of second-order Jahn–Teller (SOJT) distortive cations: Solid-state synthesis, structure determination, and characterization of YNbTe2O8 and YNbSe2O813Cs(TaO 2 ) 3 (SeO 3 ) 2 and Cs(TiOF) 3 (SeO 3 ) 2 : Structural and Second Harmonic Generation Changes Induced by the Different d 0 -TM Coordination Octahedra67Modulation of Framework and Centricity: Cation Size Effect in New Quaternary Selenites, ASc(SeO3)2 (A = Na, K, Rb, and Cs)41Structure-Directing Effect of Alkali Metal Cations in New Molybdenum Selenites, Na2Mo2O5(SeO3)2, K2Mo2O5(SeO3)2, and Rb2Mo3O7(SeO3)315Explorations of New SHG Materials in the Alkali-Metal–Nb5+–Selenite System33New niobium selenites, ANbO(SeO3)2 (A = Na, K, Rb, and Cs): Effect of alkali metal cation size on the dimensionality and intraoctahedral distortion10A series of new silver selenites with d 0 -TM cations19IR Spectra of Minerals and Related Compounds, and Reference Samples’ Data21Metal–organic frameworks as competitive materials for non-linear optics312Synthesis and Characterization of Three New Layered Vanadium Tellurites, MVTe2O8 (M = Al, Ga, and Mn): Three-Dimensional (3-D) Antiferromagnetic Behavior of MnVTe2O8 with a Zigzag S = 2 Spin Chain19Nonlinear optical (NLO) properties and temperature-dependent photoluminescence in activator-doped noncentrosymmetric (NCS) bismuth tellurite solid solutions, Bi2−Ln TeO5 (Ln = Ce and Eu)8A review of the structural architecture of tellurium oxycompounds170A new one-dimensional strontium vanadium tellurite, Sr7V4Te12O415Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures601Noncentrosymmetric (NCS) solid solutions: elucidating the structure–nonlinear optical (NLO) property relationship and beyond21Organically templated inorganic–organic hybrid metal (Zn and Cd) Sulfite–oxalates with layered and three-dimensional structures7New vanadium tellurites: Syntheses, structures, optical properties of noncentrosymmetric VTeO 4 (OH), centrosymmetric Ba 2 V 4 O 8 (Te 3 O 10 )12Synthesis, second-harmonic generations (SHG), and photoluminescence (PL) properties of Ca 4 Bi 6-x Ln x O 13 (Ln=La and Eu) solid solutions3Li13Mn(SeO3)8: Lithium-Rich Transition Metal Selenite Containing Jahn–Teller Distortive Cations5Antiskyrmions stabilized at interfaces by anisotropic Dzyaloshinskii-Moriya interactions253Electronic, optical and thermoelectric properties of SnGa2GeX6 (X = S, Se) compounds10Cation-tuned synthesis of the A 2 SO 4 ·SbF 3 (A = Na + , NH 4 + , K + , Rb + ) family with nonlinear optical properties78Centrosymmetric (NH4)2SbCl(SO4)2 and Non-centrosymmetric (NH4)SbCl2(SO4): Synergistic Effect of Hydrogen-Bonding Interactions and Lone-Pair Cations on the Framework Structures and Macroscopic Centricities89Three Cadmium Tartratoborates with Good Second Harmonic Generation (SHG) or Luminescence Performances10Exploration of New Birefringent Crystals in Bismuth d0 Transition Metal Selenites35Elastic and optoelectronic properties of CaTa2O6 compounds: Cubic and orthorhombic phases50Crystal structure and second harmonic generation in Bi2TeO5: An X-N study from synchrotron and neutron diffraction data8Crystal Structures and Optical Properties of Group 14 Chalcogenides0IR Spectra of Minerals and Related Compounds, and Reference Samples Data3BaLiTe2O5X (X = Cl, Br): mixed alkali/alkaline-earth metal tellurite halides with [Te2O5]∞ chains11Recent progress in selenite and tellurite based SHG materials32Enhancement of Second-Order Optical Nonlinearity in a Lutetium Selenite by Monodentate Anion Partial Substitution58Dimensionality–Band Gap–Third-Harmonic Generation Property Relationship in Novel Main-Group Metal Iodates37Optoelectronic properties of Nd3+ doped CaTa2O6: Insights from the GGA + U calculations6Influence of various transition metals incorporated into tellurium used as antimicrobial agent and textile dye degrader7Mixed-valent titanium tellurium oxides, Ti1-xTexTe3O8+x (x = 0, 0.1, and 0.12): Hydrothermal synthesis, structure, and characterization3Structure, Photoluminescence Emissions, and Photocatalytic Activity of Ag2SeO3: A Joint Experimental and Theoretical Investigation23KIn0.33IIITe0.67VITe2IVO7: Zirconolite-like Mixed-Valent Metal Oxide with a 3D Framework2Towards a relationship between photoluminescence emissions and photocatalytic activity of Ag 2 SeO 4 : combining experimental data and theoretical insights10Two new tellurite halides with cationic layers: syntheses, structures, and characterizations of CdPb 2 Te 3 O 8 Cl 2 and Cd 13 Pb 8 Te 14 O 42 Cl 1418Flux synthesis, crystal structure, and characterization of a gamma-vanadate selenite polymorph1Nonlinear optical and detonation properties of semiorganic nitrate crystal C6H14N2(NO3)3·H3O8LiVTeO 5 : a mid-infrared nonlinear optical vanadium tellurate crystal exhibiting enhanced second harmonic generation activities and notable birefringence21Noncentrosymmetric γ-Cs2I4O11 Obtained from IO4 Polyhedral Rearrangements in the Centrosymmetric β-Phase16Design of a highly efficient heterostructure of transition metal tellurides with outstanding photocatalytic and antimicrobial potential12MgHg(SeO3)2(H2O)2: A magnesium mercury selenite with large birefringence7Syntheses and crystal structures of four new d0 transition metal tellurites1中红外非线性光学晶体AVO2SeO3(A=Rb+, Cs+)的结构和光学性能研究(特邀)0High-selectivity fluoride capture by purely inorganic copper tellurite of Cu7F2(TeO3)6: Adsorption performance and mechanistic insights0

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  1. ChemInform Abstract: New Quaternary Tellurite and Selenite: Synthesis, Structure, and Characterization of Centrosymmetric InVTe2O8 and Noncentrosymmetric InVSe2O8

    ChemInform · 2011-06-30

    Dong Woo Lee, Seung‐Jin Oh, P. Shiv Halasyamani, Kang Min Ok

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  2. Centrosymmetric [N(CH3)4]2TiF6 vs. noncentrosymmetric polar [C(NH2)3]2TiF6: A hydrogen-bonding effect on the out-of-center distortion of TiF6 octahedra

    Journal of Solid State Chemistry · 2011-12-02

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  3. New mixed metal selenites and tellurites containing Pd 2+ ions in a square planar geometry

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  4. Oxygen, sulfur, selenium, tellurium and polonium

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  5. PbMSeO6 (M = Mo and W): New quaternary mixed metal selenites with asymmetric cationic coordination environments

    Dalton Transactions · 2012-01-01

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  6. Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites

    Structure and bonding · 2012-01-01

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  7. Syntheses, crystal structures and properties of new lead(ii) or bismuth(iii) selenites and tellurite

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  8. Explorations of new selenites of the group IIIA and IVA metals

    Journal of Solid State Chemistry · 2012-02-15

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  9. Effect of the Framework Flexibility on the Centricities in Centrosymmetric In2Zn(SeO3)4 and Noncentrosymmetric Ga2Zn(TeO3)4

    Inorganic Chemistry · 2012-07-02

    Dong Woo Lee, Dan‐bee Bak, Saet Byeol Kim, Jiwon Kim, Kang Min Ok

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  10. Cation Size Effect on the Framework Structures in a Series of New Alkali-Metal Indium Selenites, AIn(SeO3)2 (A = Na, K, Rb, and Cs)

    Inorganic Chemistry · 2012-07-16

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  11. Syntheses, crystal structures and characterizations of two new bismuth(III) arsenites

    Journal of Solid State Chemistry · 2012-08-14

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  12. Oxygen, sulfur, selenium, tellurium and polonium

    Annual Reports Section A (Inorganic Chemistry) · 2013-01-01

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  13. New Bismuth Selenium Oxides: Syntheses, Structures, and Characterizations of Centrosymmetric Bi2(SeO3)2(SeO4) and Bi2(TeO3)2(SeO4) and Noncentrosymmetric Bi(SeO3)(HSeO3)

    Inorganic Chemistry · 2013-03-18

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  14. Large scale synthesis, second-harmonic generation, and piezoelectric properties of a noncentrosymmetric vanadium phosphate, Li2VPO6

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  15. New Alkali-Metal Gallium Selenites, AGa(SeO3)2 (A = Li, Na, K, and Cs): Effect of Cation Size on the Framework Structures and Macroscopic Centricities

    Inorganic Chemistry · 2013-04-16

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  16. A new strontium antimonateIII Sr5Sb22O38: Synthesis, crystal structure and characterizations

    Journal of Solid State Chemistry · 2013-04-22

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  17. Formation Principles for Templated Vanadium Selenite Oxalates

    Crystal Growth & Design · 2013-08-08

    Jacob H. Koffer, Jacob H. Olshansky, Matthew D. Smith, Kristen J. Hernandez, Mat­thias Zeller, Gregory M. Ferrence, Joshua Schrier, Alexander J. Norquist

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  18. New Selenites: Hydrothermal Syntheses, Crystal Structures, and Characterization of Rb3HGa2(OH)2(SeO3)4, Rb3Ga5(SeO3)8(HSeO3)2·0.5H2O, and RbGa(SeO3)2·H2O

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  19. α-ScVSe2O8, β-ScVSe2O8, and ScVTe2O8: New Quaternary Mixed Metal Oxides Composed of Only Second-Order Jahn–Teller Distortive Cations

    Inorganic Chemistry · 2013-09-11

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  20. Y2MoSe3O12 and Y2MoTe3O12: Solid-state synthesis, structure determination, and characterization of two new quaternary mixed metal oxides containing asymmetric coordination environment

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  21. From an Open Framework to a Layered and a Hexagonal Tungsten Oxide Structure: Controlled Transformation Reactions of an Extended Solid-State Material, Cs3Ga7(SeO3)12 to Ga(OH)(SeO3) and KGa3(SeO4)2(OH)6

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  22. Sr 4 B 10 O 18 (OH) 2 ·2H 2 O: a new UV nonlinear optical material with a [B 10 O 23 ] 16− building block

    Journal of Materials Chemistry C · 2013-10-23

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  23. VSb(SeO3)4, First Selenite Containing V3+ Cation: Synthesis, Structure, Characterization, Magnetic Properties, and Calculations

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  24. Dimensionality variations in new zirconium iodates: hydrothermal syntheses, structural determination, and characterization of BaZr(IO 3 ) 6 and K 2 Zr(IO 3 ) 6

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    Hyun Sun Ahn, Dong Woo Lee, Kang Min Ok

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  25. Noncentrosymmetric YVSe2O8 and Centrosymmetric YVTe2O8: Macroscopic Centricities Influenced by the Size of Lone Pair Cation Linkers

    Inorganic Chemistry · 2014-01-02

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  26. Variable Framework Structures and Centricities in Alkali Metal Yttrium Selenites, AY(SeO3)2 (A = Na, K, Rb, and Cs)

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  27. Strong Second Harmonic Generation (SHG) Originating from Combined Second-Order Jahn–Teller (SOJT) Distortive Cations in a New Noncentrosymmetric Tellurite, InNb(TeO4)2

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  28. Effect of polarizable lone pair cations on the second-harmonic generation (SHG) properties of noncentrosymmetric (NCS) Bi 2−x Y x TeO 5 (x = 0–0.2)

    Dalton Transactions · 2014-05-09

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  29. Rich Structural Chemistry in Scandium Selenium/Tellurium Oxides: Mixed-Valent Selenite–Selenates, Sc2(SeO3)2(SeO4) and Sc2(TeO3)(SeO3)(SeO4), and Ternary Tellurite, Sc2(TeO3)3

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  30. Dimensional and Coordination Number Reductions in a Large Family of Lanthanide Tellurite Sulfates

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  31. Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons

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  32. New Polymorphs of Ternary Sodium Tellurium Oxides: Hydrothermal Synthesis, Structure Determination, and Characterization of β-Na2Te4O9 and Na2Te2O6·1.5H2O

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  33. Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework

    Inorganic Chemistry · 2014-09-26

    Chunyan Bai, Hongwei Yu, Shujuan Han, Shilie Pan, Bingbing Zhang, Ying Wang, Hongping Wu, Zhihua Yang

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  34. Sr3Bi2(SeO3)6·H2O: A novel anionic layer consisting of second-order Jahn–Teller (SOJT) distortive cations

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  35. Cooperative Effects of Cation Size and Variable Coordination Modes of Te4+ on the Frameworks of New Alkali Metal Indium Tellurites, NaIn(TeO3)2, KIn(TeO3)2, RbInTe3O8, and CsInTe3O8

    Inorganic Chemistry · 2014-10-08

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  36. Rich Structural Chemistry in New Alkali Metal Yttrium Tellurites: Three-Dimensional Frameworks of NaYTe4O10, KY(TeO3)2, RbY(TeO3)2, and a Novel Variant of Hexagonal Tungsten Bronze, CsYTe3O8

    Inorganic Chemistry · 2014-12-17

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  37. Macroscopic polarity control with alkali metal cation size and coordination environment in a series of tin iodates

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  38. SnGa 2 GeS 6 : synthesis, structure, linear and nonlinear optical properties

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  39. New quaternary oxides with both families of second-order Jahn–Teller (SOJT) distortive cations: Solid-state synthesis, structure determination, and characterization of YNbTe2O8 and YNbSe2O8

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  40. Cs(TaO 2 ) 3 (SeO 3 ) 2 and Cs(TiOF) 3 (SeO 3 ) 2 : Structural and Second Harmonic Generation Changes Induced by the Different d 0 -TM Coordination Octahedra

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  41. Modulation of Framework and Centricity: Cation Size Effect in New Quaternary Selenites, ASc(SeO3)2 (A = Na, K, Rb, and Cs)

    Inorganic Chemistry · 2015-04-27

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  42. Structure-Directing Effect of Alkali Metal Cations in New Molybdenum Selenites, Na2Mo2O5(SeO3)2, K2Mo2O5(SeO3)2, and Rb2Mo3O7(SeO3)3

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    Seong‐eun Bang, Kang Min Ok

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  43. Explorations of New SHG Materials in the Alkali-Metal–Nb5+–Selenite System

    Inorganic Chemistry · 2015-10-29

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  44. New niobium selenites, ANbO(SeO3)2 (A = Na, K, Rb, and Cs): Effect of alkali metal cation size on the dimensionality and intraoctahedral distortion

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    Youngkwon Kim, Bongsu Kim, Kang Min Ok

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  45. A series of new silver selenites with d 0 -TM cations

    RSC Advances · 2016-01-01

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  46. IR Spectra of Minerals and Related Compounds, and Reference Samples’ Data

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  47. Metal–organic frameworks as competitive materials for non-linear optics

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  48. Synthesis and Characterization of Three New Layered Vanadium Tellurites, MVTe2O8 (M = Al, Ga, and Mn): Three-Dimensional (3-D) Antiferromagnetic Behavior of MnVTe2O8 with a Zigzag S = 2 Spin Chain

    Inorganic Chemistry · 2016-01-14

    Su‐whan Bae, Jisun Yoo, Suheon Lee, Kwang‐Yong Choi, Kang Min Ok

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  49. Nonlinear optical (NLO) properties and temperature-dependent photoluminescence in activator-doped noncentrosymmetric (NCS) bismuth tellurite solid solutions, Bi2−Ln TeO5 (Ln = Ce and Eu)

    Journal of Alloys and Compounds · 2016-02-24

    Hongil Jo, Jae Soo Yoo, Kang Min Ok

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  50. A review of the structural architecture of tellurium oxycompounds

    Mineralogical Magazine · 2016-05-01

    Andrew G. Christy, Stuart J. Mills, Anthony R. Kampf

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