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RESEARCH PAPER · Journal of the American Chemical Society · 2011

Explorations of New Second-Order Nonlinear Optical Materials in the Potassium Vanadyl Iodate System

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Explorations of New Second-Order Nonlinear Optical Materials in the Potassium Vanadyl Iodate SystemOriginalBiosynthesis and biological activity of enniatins49Bulk crystal growth and characterization of a new polar polymorph of BaTeMo2O9: α-BaTeMo2O998BiO(IO3): A New Polar Iodate that Exhibits an Aurivillius-Type (Bi2O2)2+ Layer and a Large SHG Response503Polymorphism of BaTeMo 2 O 9 : A New Polar Polymorph and the Phase Transformation186“A” Cation Polarity Control in ACuTe2O7 (A = Sr2+, Ba2+, or Pb2+)52Novel Trumpet-Shaped Conjugation Bridge (Carbon Nanocone) for Nonlinear Optical Materials31Bi2(IO4)(IO3)3: A New Potential Infrared Nonlinear Optical Material Containing [IO4]3– Anion111New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)50Anisotropic thermal properties of the polar crystal Cs2TeMo3O1224BaGa2MQ6 (M = Si, Ge; Q = S, Se): a new series of promising IR nonlinear optical materials199Crystal growth and optical properties of a noncentrosymmetric molybdenum tellurite, Na2Te3Mo3O1641Luminescent lanthanide metal–organic frameworks with a large SHG response76PbPt(IO3)6(H2O): a new polar material with two types of stereoactive lone-pairs and a very large SHG response80Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites60Synthesis and crystal structure of two synthetic oxofluoride framework compounds – Co2TeO3F2 and Co2SeO3F221UV Nonlinear Optical Crystal Ba2[B6O9(OH)4] Featuring Unique Chiral Layers with a New B18O42 Circle Based on BO3 and BO4 Units97Controlled Synthesis of Bulk Polymer Nanocomposites with Tunable Second Order Nonlinear Optical Properties30New nonlinear optical potassium iodate K[IO3] and borates K3[B6O10]Br, KTa[B4O6(OH)4](OH)2·1.33H2O—Synthesis, structures and relation to the properties35Two New Noncentrosymmetric (NCS) Polar Oxides: Syntheses, Characterization, and Structure–Property Relationships in BaMTe2O7 (M = Mg2+ or Zn2+)50Syntheses, crystal structures and characterizations of new vanadium arsenites and arsenates4Synthesis, crystal structure and nonlinear optical property of a Zinc(II) complex base on the reduced Schiff-base ligand27Syntheses, crystal structures and characterizations of two new bismuth(III) arsenites2Synthesis, Structure, and Characterization of New Li+ – d0 –Lone-Pair – Oxides: Noncentrosymmetric Polar Li6(Mo2O5)3(SeO3)6 and Centrosymmetric Li2(MO3)(TeO3) (M = Mo6+ or W6+)47Titanyl Iodate – A Promising Material for Infrared Nonlinear Optics Showing Structural Similarities with KTP32Synthesis, crystal structure and nonlinear optical property of CsV2O58A combination of multiple chromophores enhances second-harmonic generation in a nonpolar noncentrosymmetric oxide: CdTeMoO681Crystal structure and magnetic properties of Cr3Te5O13Cl39From achiral tetrazolate-based tectons to chiral coordination networks: effects of substituents on the structures and NLO properties18Growth, optical and electrical properties of a nonlinear optical crystal NaBa4Al2B8O18Cl315K4TM4(V2O7)2(IO3)4(H2O) (TM = Zn, Ni, Co): a series of quinary mixed metal–vanadium(v)–iodates18Organic microbelt array based on hydrogen-bond architecture showing polarized fluorescence and two-photon emission47Pb2TiOF(SeO3)2Cl and Pb2NbO2(SeO3)2Cl: small changes in structure induced a very large SHG enhancement117Synthesis and crystal structure of Fe6Ca2(SeO3)9Cl4 – a porous oxohalide11Tl(VO)2O2(IO3)3: a new polar material with a strong SHG response26ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units53New Fluoride Carbonates: Centrosymmetric KPb2(CO3)2F and Noncentrosymmetric K2.70Pb5.15(CO3)5F367Cs2B4SiO9: A Deep‐Ultraviolet Nonlinear Optical Crystal278Cs2B4SiO9: A Deep‐Ultraviolet Nonlinear Optical Crystal224Designing a Deep-Ultraviolet Nonlinear Optical Material with a Large Second Harmonic Generation Response597Syntheses, crystal structures, and characterization of four homochiral coordination polymers based on two chiral reduced Schiff base ligands4Large scale synthesis, second-harmonic generation, and piezoelectric properties of a noncentrosymmetric vanadium phosphate, Li2VPO69Zn2(VO4)(IO3): A Novel Polar Zinc(II) Vanadium(V) Iodate with a Large SHG Response94A new strontium antimonateIII Sr5Sb22O38: Synthesis, crystal structure and characterizations9The first transition metal iodato peroxido complex: the synthesis, vibrational spectra and crystal structure from powder diffraction data of K3[V2O2(O2)4(IO3)]·H2O1Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)2F2Cl and Noncentrosymmetric NaBa4(AlB4O9)2Br350Pb2B3O5.5(OH)2 and [Pb3(B3O7)](NO3): Facile Syntheses of New Lead(II) Borates by Simply Changing the pH Values of the Reaction Systems55Metal Chalcogenides: A Rich Source of Nonlinear Optical Materials680Explorations of a Series of Second Order Nonlinear Optical Materials Based on Monovalent Metal Gold(III) Iodates33Noncentrosymmetric Cubic CsCdBO3 with Bichromophore23Characterization and strong piezoelectric response of an organometallic nonlinear optical crystal: CdHg(SCN) 4 (C 2 H 6 SO) 212Ab initio calculation of structural, electronic and optical properties of Hg(IO3)27Lanthanide Metal–Organic Frameworks Showing Luminescence in the Visible and Near‐Infrared Regions with Potential for Acetone Sensing137CsPbCO3F: A Strong Second-Harmonic Generation Material Derived from Enhancement via p−π Interaction272Probe the accumulation modes of the Au–C22H14dimer on the structure and NLO properties4A 2 BiI 5 O 15 (A = K + or Rb + ): two new promising nonlinear optical materials containing [I 3 O 9 ] 3− bridging anionic groups62Ba 2 B 10 O 17 : a new centrosymmetric alkaline-earth metal borate with a deep-UV cut-off edge50Coligand-directed synthesis of five Co( ii )/Ni( ii ) coordination polymers with a neutral tetradentate ligand: syntheses, crystal structures, and properties22Dimensionality variations in new zirconium iodates: hydrothermal syntheses, structural determination, and characterization of BaZr(IO 3 ) 6 and K 2 Zr(IO 3 ) 619Growth and properties of a noncentrosymmetric polyphosphate CsLa(PO 3 ) 4 crystal with deep-ultraviolet transparency100Sodium–rare earth carbonates with shorite structure and large second harmonic generation response44Th(VO 3 ) 2 (SeO 3 ) and Ln(VO 3 ) 2 (IO 3 ) (Ln = Ce, Pr, Nd, Sm, and Eu): unusual cases of aliovalent substitution45Cs 3 Zn 6 B 9 O 21 : A Chemically Benign Member of the KBBF Family Exhibiting the Largest Second Harmonic Generation Response361Explorations of New Second-Order Nonlinear Optical Materials in the Ternary Rubidium Iodate System: Noncentrosymmetric β-RbIO3(HIO3)2 and Centrosymmetric Rb3(IO3)3(I2O5)(HIO3)4(H2O)59A Nitrate Nonlinear Optical Crystal Pb16(OH)16(NO3)16 with a Large Second-Harmonic Generation Response57KSbB2O6 and BaSb2B4O12: Novel Boroantimonates with 3D Anionic Architectures Composed of 1D Chains of SbO6 Octahedra and B2O5 Groups36Synthesis, crystal structures and characterizations of two homochiral coordination polymers based on a chiral reduced Schiff base ligand6Crystal Structure and Magnetic Properties of FeSeO3F—Alternating Antiferromagnetic S = 5/2 chains42α-AgI3O8 and β-AgI3O8 with Large SHG Responses: Polymerization of IO3 Groups into the I3O8 Polyiodate Anion113Acentric Pseudo-Kagome Structures: The Solid Solution (Co 1– x Ni x ) 3 Sb 4 O 6 F 625Rich Structural Chemistry in Scandium Selenium/Tellurium Oxides: Mixed-Valent Selenite–Selenates, Sc2(SeO3)2(SeO4) and Sc2(TeO3)(SeO3)(SeO4), and Ternary Tellurite, Sc2(TeO3)341Na4La2(CO3)5 and CsNa5Ca5(CO3)8: Two New Carbonates as UV Nonlinear Optical Materials65Synthesis, crystal structure and optical properties of two new layered cadmium iodates: Cd(IO3)X (X=Cl, OH)13A Synthetic Route toward Layered Materials: Introducing Stereochemically Active Lone-Pairs into Transition Metal Oxohalides25A series of novel mercury( i ) selenites and tellurites containing SOJT Mo 6+ cations18A facile strategy to adjust the density of planar triangle units in lead borate–nitrates16BaBi(SeO 3 ) 2 Cl: a new polar material showing high second-harmonic generation efficiency enhanced by constructive alignment of chloride ions36Evidence of “new hot spots” from determining the nonlinear optical behavior of materials: mechanistic studies of the vanadium borate crystal, Na 3 VO 2 B 6 O 1116Second-harmonic generation (SHG) and photoluminescence properties of noncentrosymmetric (NCS) layered perovskite solid solutions, CsBi 1−x Eu x Nb 2 O 7 (x = 0, 0.1, and 0.2)30Recent advances on second-order NLO materials based on metal iodates328Structures, Thermal Behaviors, and Luminescent Properties of Anhydrous Lanthanum Iodate Polymorphs26Pb7O(OH)3(CO3)3(BO3): First Mixed Borate and Carbonate Nonlinear Optical Material Exhibiting Large Second-Harmonic Generation Response74β-Alanine Zn(II) and Cd(II) coordination complexes with diamondoid frameworks possessing second-order nonlinear optics properties19Ba2B6O11, a Member of the BaO‐B2O3 Family, Featuring a Layer Framework19Synthesis, crystal structures and properties of lead phosphite compounds27Structure-Directing Effect of Alkali Metal Cations in New Molybdenum Selenites, Na2Mo2O5(SeO3)2, K2Mo2O5(SeO3)2, and Rb2Mo3O7(SeO3)315K2Pb3(CO3)3F2 and KCdCO3F: Novel Fluoride Carbonates with Layered and 3D Framework Structures42Explorations of New SHG Materials in the Alkali-Metal–Nb5+–Selenite System33Preparation, nonlinear optical properties, and theoretical analysis of the non-centrosymmetric bismuth oxyfluoride, Bi 7 F 11 O 525Bidenticity-Enhanced Second Harmonic Generation from Pb Chelation in Pb3Mg3TeP2O14169Experimental and theoretical studies on the linear and nonlinear optical properties of lead phosphate crystals LiPbPO 474Influence of an oxygen vacancy on the electronic structure of the asymmetric mixed borate–carbonate Pb 7 O(OH) 3 (CO 3 ) 3 (BO 3 )3Nonlinear optical response mechanism of noncentrosymmetric lead borate Pb 6 [B 4 O 7 (OH) 2 ] 3 with three crystallographically independent [B 4 O 7 (OH) 2 ] 4− chains8Spontaneous chiral resolution and hierarchical directing effects of two-winged propeller-like SDAs on the construction of noncentrosymmetric iodoargentates/iodocuprates15Synthesis, crystal structure and second-order nonlinear optical property of a novel pentanary selenide (K 3 I)[InB 12 (InSe 4 ) 3 ]48Three iodocuprate hybrids symmetrically modulated by positional isomers and the chiral conformation of N-benzyl-methylpyridinium36Top-seeded solution growth and characterization of Raman crystal LiVMoO 63K2Au(IO3)5 and β‐KAu(IO3)4: Polar Materials with Strong SHG Responses Originating from Synergistic Effect of AuO4 and IO3 Units18KSbI6O18: An antimony iodate semiconductor material with cyclic chiral S6-symmetric hexaiodate7RbIO3 and RbIO2F2: Two Promising Nonlinear Optical Materials in Mid-IR Region and Influence of Partially Replacing Oxygen with Fluorine for Improving Laser Damage Threshold124New Series of Polar and Nonpolar Platinum Iodates A2Pt(IO3)6 (A = H3O, Na, K, Rb, Cs)33Nonlinear optical (NLO) properties and temperature-dependent photoluminescence in activator-doped noncentrosymmetric (NCS) bismuth tellurite solid solutions, Bi2−Ln TeO5 (Ln = Ce and Eu)8Lead nitrate hydroxide: A strong second-order optical nonlinearity acentric crystal with high laser damage thresholds13Electronic, Crystal Chemistry, and Nonlinear Optical Property Relationships in the Dugganite A3B3CD2O14 Family148Rb2Na(NO3)3: A Congruently Melting UV-NLO Crystal with a Very Strong Second-Harmonic Generation Response71Synthesis, structure and properties of nonlinear optical crystal Li(H 2 O) 4 B(OH) 4 ·2H 2 O5Na 2 ZnGe 2 S 6 : A New Infrared Nonlinear Optical Material with Good Balance between Large Second-Harmonic Generation Response and High Laser Damage Threshold302BiFSeO 3 : An Excellent SHG Material Designed by Aliovalent Substitution207K3B3O4(OH)4·2H2O: A UV Nonlinear Optical Crystal with Isolated [B3O4(OH)4]3– Anion Groups21Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation382Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation129Exploring the electronic structure of Pb2+ ions containing material Pb16(OH)16(NO3)162Bi 2 O(XO 4 )(IO 3 ) 2 (X = S, Se, Cr): Three-dimensional frameworks containing [Bi 4 O 2 ] 8+ clusters19Ag 3 I[(MoO 3 ) 2 (IO 3 ) 2 ]: a new polar material synthesized from the structural modulation of molybdenyl iodate architectures by polarizable cation (Ag + ) and anion (I − )6Collaborative enhancement from Pb 2+ and F − in Pb 2 (NO 3 ) 2 (H 2 O)F 2 generates the largest second harmonic generation effect among nitrates91Efficient Raman scattering response and large piezoelectricity in noncentrosymmetric MnHg(SCN) 4 crystals9Enhancing optical anisotropy of crystals by optimizing bonding electron distribution in anionic groups237Li 2 CdGeSe 4 and Li 2 CdSnSe 4 : biaxial nonlinear optical materials with strong infrared second-order responses and laser-induced damage thresholds influenced by photoluminescence54Li 3 Ge 3 Se 6 : the first ternary lithium germanium selenide with interesting ∞ [Ge 6 Se 12 ] n chains constructed by ethane-like [Ge 2 Se 6 ] 6− clusters8Na 2 CdGe 2 Q 6 (Q = S, Se): two metal-mixed chalcogenides with phase-matching abilities and large second-harmonic generation responses78Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect238Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect71Fluorooxoborates: Beryllium‐Free Deep‐Ultraviolet Nonlinear Optical Materials without Layered Growth893Fluorooxoborates: Beryllium‐Free Deep‐Ultraviolet Nonlinear Optical Materials without Layered Growth99Li3VO4: A Promising Mid-Infrared Nonlinear Optical Material with Large Laser Damage Threshold51Two Barium Gold Iodates: Syntheses, Structures, and Properties of Polar BaAu(IO3)5 and Nonpolar HBa4Au(IO3)12 Materials5ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap140ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap36M(IO3)(HPO4)(H2O) (M = Sc, Fe, Ga, In): Introduction of Phosphate Anions into Metal Iodates16Novel ternary semiconductor CdLa2X4 (X=S or Se) single crystal with efficient second harmonic generation in the visible spectral range11Pb 10 V 6 O 25 : A new lead vanadate with apatite structure3LiGaGe2S6: A Chalcogenide with Good Infrared Nonlinear Optical Performance and Low Melting Point56Acentric La3(IO3)8(OH) and La(IO3)2(NO3): Partial Substitution of Iodate Anions in La(IO3)3 by Hydroxide or Nitrate Anion55Theoretical study on Pb2VO2F5: large birefringence derived from optical anisotropies of VO2F4 groups15Investigation on synthesis, growth, structure and physical properties of AgGa0.5In0.5S2 single crystals for Mid-IR application6Design and synthesis of a nonlinear optical material BaAl 4 S 7 with a wide band gap inspired from SrB 4 O 764Influence of A-site cations on germanium iodates as mid-IR nonlinear optical materials: A 2 Ge(IO 3 ) 6 (A = Li, K, Rb and Cs) and BaGe(IO 3 ) 6 ·H 2 O43Oxyhalides: prospecting ore for optical functional materials with large laser damage thresholds76Tailored fabrication of a prospective acousto–optic crystal TiTe 3 O 8 endowed with high performance26Synthesis, second-harmonic generation (SHG), and photoluminescence (PL) properties of noncentrosymmetric bismuth selenite solid solutions, Bi 2-x Ln x SeO 5 (Ln = La and Eu; x = 0–0.3)2From AgGaS2 to Li2ZnSiS4: Realizing Impressive High Laser Damage Threshold Together with Large Second-Harmonic Generation Response134A Large Family of Centrosymmetric and Chiral f-Element-Bearing Iodate Selenates Exhibiting Coordination Number and Dimensional Reductions26Functional Materials Design via Structural Regulation Originated from Ions Introduction: A Study Case in Cesium Iodate System90Effect of Element Substitution on Structural Transformation and Optical Performances in I2BaMIVQ4 (I = Li, Na, Cu, and Ag; MIV = Si, Ge, and Sn; Q = S and Se)63A Series of Mixed-Metal Germanium Iodates as Second-Order Nonlinear Optical Materials71Assisting the Effective Design of Polar Iodates with Early Transition-Metal Oxide Fluoride Anions206Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)2(IO3)4O, Ba3[(MoO2)2(IO3)4O(OH)4]·2H2O, and Sr[(MoO2)6(IO4)2O4]·H2O24Second-order nonlinear optical crystals with mixed anions250Rational Design of a LiNbO3-like Nonlinear Optical Crystal, Li2ZrTeO6, with High Laser-Damage Threshold and Wide Mid-IR Transparency Window152Excellent Infrared Nonlinear Optical Crystals BaMO(IO3)5 (M = V, Ta) Predicted by First Principle Calculations9Recent advances and future perspectives on infrared nonlinear optical metal halides223

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  2. Bulk crystal growth and characterization of a new polar polymorph of BaTeMo2O9: α-BaTeMo2O9

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  3. BiO(IO3): A New Polar Iodate that Exhibits an Aurivillius-Type (Bi2O2)2+ Layer and a Large SHG Response

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  4. Polymorphism of BaTeMo 2 O 9 : A New Polar Polymorph and the Phase Transformation

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  5. “A” Cation Polarity Control in ACuTe2O7 (A = Sr2+, Ba2+, or Pb2+)

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  33. Synthesis and crystal structure of Fe6Ca2(SeO3)9Cl4 – a porous oxohalide

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