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RESEARCH PAPER · Inorganic Chemistry · 2010

Synthesis, Crystal Structure, and Magnetic Properties of the Copper Selenite Chloride Cu5(SeO3)4Cl2

Dong Zhang, Helmuth Berger, Reinhard Karl Kremer, Dirk Wulferding, P. Lemmens, Mats Johnsson

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Synthesis, Crystal Structure, and Magnetic Properties of the Copper Selenite Chloride Cu5(SeO3)4Cl2OriginalChemInform Abstract: Synthesis, Crystal Structure, and Magnetic Properties of the Copper Selenite Chloride Cu5(SeO3)4Cl2.0Lanthanide Antimony Oxohalides: From Discrete Nanoclusters to Inorganic–Organic Hybrid Chains and Layers25Lanthanide Antimony Oxohalides: From Discrete Nanoclusters to Inorganic–Organic Hybrid Chains and Layers4Crystal Structure and Magnetic Properties of Two New Antiferromagnetic Spin Dimer Compounds; FeTe3O7X (X = Cl, Br)22New mixed metal selenites and tellurites containing Pd 2+ ions in a square planar geometry14Syntheses, crystal structures and properties of new lead(ii) or bismuth(iii) selenites and tellurite41The crystal structure of ilinskite, NaCu5O2(SeO3)2Cl3, and review of mixed-ligand CuOmCln coordination geometries in minerals and inorganic compounds31Crystal structures and variable magnetism of PbCu2(XO3)2Cl2 with X = Se, Te40Prewittite, KPb1.5Cu6Zn(SeO3)2O2Cl10, a new mineral from Tolbachik fumaroles, Kamchatka peninsula, Russia: Description and crystal structure33Self-assembly of a pentanuclear {Cu5} complex resulting from the trapping of a Cu2+ ion by two {Cu2} building units12Solid-state synthesis, structure and properties of a novel open-framework cadmium selenite bromide: [Cd10(SeO3)8Br4]·HBr·H2O6Nicksobolevite, Cu7(SeO3)2O2Cl6, a new complex copper oxoselenite chloride from Tolbachik fumaroles, Kamchatka peninsula, Russia25Rich Structural Chemistry in Scandium Selenium/Tellurium Oxides: Mixed-Valent Selenite–Selenates, Sc2(SeO3)2(SeO4) and Sc2(TeO3)(SeO3)(SeO4), and Ternary Tellurite, Sc2(TeO3)341Crystal Structure and Magnetic Properties of the S = 1/2 Quantum Spin System Cu7(TeO3)6F2 with Mixed Dimensionality16Structural and magnetic studies on three new mixed metal copper( ii ) selenites and tellurites16Emulating exhalative chemistry: synthesis and structural characterization of ilinskite, Na[Cu5O2](SeO3)2Cl3, and its K-analogue34Dimers of oxocentred [OCu4]6+ tetrahedra in two novel copper selenite chlorides, K[Cu3O](SeO3)2Cl and Na2[Cu7O2] (SeO3)4Cl4, and related minerals and inorganic compounds20Chemical vapor transport and solid-state exchange synthesis of new copper selenite bromides6Li13Mn(SeO3)8: Lithium-Rich Transition Metal Selenite Containing Jahn–Teller Distortive Cations5New quaternary alkali metal cadmium selenites, A 2 Cd(SeO 3 ) 2 (A = K, Rb, and Cs) and Li 2 Cd 3 (SeO 3 ) 43Strategic synthesis of [Cu 2 ], [Cu 4 ] and [Cu 5 ] complexes: inhibition and triggering of ligand arm hydrolysis and self-aggregation by chosen ancillary bridges6Synthesis and Physical Properties of the Oxofluoride Cu2(SeO3)F213Transition Metal Selenite Halides: A Fascinating Family of Magnetic Compounds38Se–Cl Interactions in Selenite Chlorides: A Theoretical Study10Dicobalt (II) hydroxo-selenite: Hydrothermal synthesis, crystal structure and magnetic properties of Co2SeO3(OH)26Cycloidal Magnetic Order Promoted by Labile Mixed Anionic Paths in M2(SeO3)F2 (M = Mn2+, Ni2+)4Cu9O2(SeO3)4Cl6 revisited: Crystal structure, Raman scattering and first-principles calculations4Observation of a 1/3 magnetization plateau in Pb 2 Cu 10 O 4 (SeO 3 ) 4 Cl 7 arising from (Cu 2+ ) 7 clusters of corner-sharing (Cu 2+ ) 4 tetrahedra10Fabrication of novel oxochalcogens halides of manganese and tin nanocomposites as highly efficient photocatalysts for dye degradation and excellent antimicrobial activity7Three new copper-lead selenite bromides obtained by chemical vapor transport: Pb5Cu+4(SeO3)4Br6, Pb8Cu2+(SeO3)4Br10, and the synthetic analogue of the mineral sarrabusite, Pb5Cu2+(SeO3)4(Br,Cl)46Precursor recommendation for inorganic synthesis by machine learning materials similarity from scientific literature65Guangyuanite, Pb3Cl3(Se4+O3)(OH), a new lead chloride selenite mineral from the El Dragón mine, Potosí, Bolivia5Ferromagnetic Mn3+ Sawtooth Chains in A2(Mn2O)(SeO3)3 (A = K, Rb) Quaternary Selenites0Exploring new members of magnetoelectric materials in CuO–CuCl2–SeO2 system4Polar Layered Magnet Ba 2 Cu 3 (SeO 3 ) 4 F 2 Composed of Bitriangular Chains: Observation of 1/3-Magnetization Plateau5Wangkuirenite—a new lead chloride-selenite mineral0Syntheses, Structures, and Magnetic Properties of ACu4(SeO3)4F2 (A = Cd, Hg) with a Distorted Honeycomb Lattice0The crystal chemistry and topology of modular structures. I. Selenites of rare-earth elements5Magnetic Copper Selenite-Sulfate Cu 3 O 2 (HSeO 3 )(HSO 4 )(H 2 O) with T26-Type Non-Archimedean Lattice Featuring a Robust 1/3-Magnetization Plateau2Single Crystal Growth and Easy-Plane Anisotropic Magnetism of Distorted T26-Type Non-Archimedean Antiferromagnet Cu 3 O 2 (HSeO 3 )(HSO 4 )(H 2 O) with 1/3-Magnetization Plateau2High-selectivity fluoride capture by purely inorganic copper tellurite of Cu7F2(TeO3)6: Adsorption performance and mechanistic insights0

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  1. ChemInform Abstract: Synthesis, Crystal Structure, and Magnetic Properties of the Copper Selenite Chloride Cu5(SeO3)4Cl2.

    ChemInform · 2010-11-26

    Dong Zhang, Helmuth Berger, Reinhard Karl Kremer, Dirk Wulferding, P. Lemmens, Mats Johnsson

    Read original paper ↗ ·

  2. Lanthanide Antimony Oxohalides: From Discrete Nanoclusters to Inorganic–Organic Hybrid Chains and Layers

    Angewandte Chemie International Edition · 2011-07-14

    Bing Hu, Mei‐Ling Feng, Jian‐Rong Li, Qipu Lin, Xiao‐Ying Huang

    Read original paper ↗ ·

  3. Lanthanide Antimony Oxohalides: From Discrete Nanoclusters to Inorganic–Organic Hybrid Chains and Layers

    Angewandte Chemie · 2011-07-14

    Bing Hu, Mei‐Ling Feng, Jian‐Rong Li, Qipu Lin, Xiao‐Ying Huang

    Read original paper ↗ ·

  4. Crystal Structure and Magnetic Properties of Two New Antiferromagnetic Spin Dimer Compounds; FeTe3O7X (X = Cl, Br)

    Inorganic Chemistry · 2011-11-11

    Dong Zhang, Reinhard Karl Kremer, P. Lemmens, Kwang‐Yong Choi, Jia Liu, Myung‐Hwan Whangbo, Helmuth Berger, Y. Skourski, Mats Johnsson

    Read original paper ↗ ·

  5. New mixed metal selenites and tellurites containing Pd 2+ ions in a square planar geometry

    Dalton Transactions · 2011-12-16

    Suyun Zhang, Chun‐Li Hu, Jiang‐Gao Mao

    Read original paper ↗ ·

  6. Syntheses, crystal structures and properties of new lead(ii) or bismuth(iii) selenites and tellurite

    Dalton Transactions · 2012-01-01

    Suyun Zhang, Chun‐Li Hu, Pei-Xin Li, Hai‐Long Jiang, Jiang‐Gao Mao

    Read original paper ↗ ·

  7. The crystal structure of ilinskite, NaCu5O2(SeO3)2Cl3, and review of mixed-ligand CuOmCln coordination geometries in minerals and inorganic compounds

    Mineralogy and Petrology · 2012-11-15

    Sergey V. Krivovichev, С. К. Филатов, L. P. Vergasova

    Read original paper ↗ ·

  8. Crystal structures and variable magnetism of PbCu2(XO3)2Cl2 with X = Se, Te

    Dalton Transactions · 2013-01-01

    Peter S. Berdonosov, Oleg Janson, Andrei V. Olenev, Sergey V. Krivovichev, Helge Rosner, В. А. Долгих, Alexander A. Tsirlin

    Read original paper ↗ ·

  9. Prewittite, KPb1.5Cu6Zn(SeO3)2O2Cl10, a new mineral from Tolbachik fumaroles, Kamchatka peninsula, Russia: Description and crystal structure

    American Mineralogist · 2013-02-01

    Robert R. Shuvalov, L. P. Vergasova, T. F. Semenova, С. К. Филатов, Sergey V. Krivovichev, Oleg I. Siidra, Nikolay S. Rudashevsky

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  10. Self-assembly of a pentanuclear {Cu5} complex resulting from the trapping of a Cu2+ ion by two {Cu2} building units

    Polyhedron · 2013-03-05

    Aloke Kumar Ghosh, Rodolphe Clérac, Corine Mathonière, Debashis Ray

    Read original paper ↗ ·

  11. Solid-state synthesis, structure and properties of a novel open-framework cadmium selenite bromide: [Cd10(SeO3)8Br4]·HBr·H2O

    Journal of Solid State Chemistry · 2013-06-03

    Wen‐Tong Chen, Ming‐Sheng Wang, Guan‐E Wang, Hui-Fen Chen, Guo‐Cong Guo

    Read original paper ↗ ·

  12. Nicksobolevite, Cu7(SeO3)2O2Cl6, a new complex copper oxoselenite chloride from Tolbachik fumaroles, Kamchatka peninsula, Russia

    European Journal of Mineralogy · 2014-03-26

    L. P. Vergasova, T. F. Semenova, Sergey V. Krivovichev, С. К. Филатов, Andrey A. Zolotarev, Vladimir V. Ananiev

    Read original paper ↗ ·

  13. Rich Structural Chemistry in Scandium Selenium/Tellurium Oxides: Mixed-Valent Selenite–Selenates, Sc2(SeO3)2(SeO4) and Sc2(TeO3)(SeO3)(SeO4), and Ternary Tellurite, Sc2(TeO3)3

    Inorganic Chemistry · 2014-06-11

    Seung Yoon Song, Dong Woo Lee, Kang Min Ok

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  14. Crystal Structure and Magnetic Properties of the S = 1/2 Quantum Spin System Cu7(TeO3)6F2 with Mixed Dimensionality

    Inorganic Chemistry · 2014-06-23

    Shichao Hu, Amber Mace, Mats Johnsson, V. P. Gnezdilov, P. Lemmens, Joshua H. Tapp, Angela Möller

    Read original paper ↗ ·

  15. Structural and magnetic studies on three new mixed metal copper( ii ) selenites and tellurites

    Dalton Transactions · 2015-01-01

    Xue‐Li Cao, Fang Kong, Zhangzhen He, Jiang‐Gao Mao

    Read original paper ↗ ·

  16. Emulating exhalative chemistry: synthesis and structural characterization of ilinskite, Na[Cu5O2](SeO3)2Cl3, and its K-analogue

    Mineralogy and Petrology · 2015-02-18

    Vadim M. Kovrugin, Oleg I. Siidra, Marie Colmont, Olivier Mentré, Sergey V. Krivovichev

    Read original paper ↗ ·

  17. Dimers of oxocentred [OCu4]6+ tetrahedra in two novel copper selenite chlorides, K[Cu3O](SeO3)2Cl and Na2[Cu7O2] (SeO3)4Cl4, and related minerals and inorganic compounds

    Mineralogical Magazine · 2016-04-01

    Vadim M. Kovrugin, Marie Colmont, Olivier Mentré, Oleg I. Siidra, Sergey V. Krivovichev

    Read original paper ↗ ·

  18. Chemical vapor transport and solid-state exchange synthesis of new copper selenite bromides

    Solid State Sciences · 2016-12-29

    Dmitri O. Charkin, Roman A. Kayukov, Karim A. Zagidullin, Oleg I. Siidra

    Read original paper ↗ ·

  19. Li13Mn(SeO3)8: Lithium-Rich Transition Metal Selenite Containing Jahn–Teller Distortive Cations

    Inorganic Chemistry · 2017-07-25

    Hongil Jo, Seung Yoon Song, Eunjeong Cho, Jongho So, Suheon Lee, Kwang‐Yong Choi, Kang Min Ok

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  20. New quaternary alkali metal cadmium selenites, A 2 Cd(SeO 3 ) 2 (A = K, Rb, and Cs) and Li 2 Cd 3 (SeO 3 ) 4

    Journal of Solid State Chemistry · 2017-09-14

    Minfeng Lü, Hongil Jo, Seung‐Jin Oh, Kang Min Ok

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  21. Strategic synthesis of [Cu 2 ], [Cu 4 ] and [Cu 5 ] complexes: inhibition and triggering of ligand arm hydrolysis and self-aggregation by chosen ancillary bridges

    Dalton Transactions · 2018-01-01

    Manisha Das, Angelos B. Canaj, Valerio Bertolasi, Mark Murrie, Debashis Ray

    Read original paper ↗ ·

  22. Synthesis and Physical Properties of the Oxofluoride Cu2(SeO3)F2

    Inorganic Chemistry · 2018-04-03

    Eleni Mitoudi Vagourdi, Wassilios Papawassiliou, Silvia Müllner, Aleksander Jaworski, Andrew J. Pell, P. Lemmens, Reinhard Karl Kremer, Mats Johnsson

    Read original paper ↗ ·

  23. Transition Metal Selenite Halides: A Fascinating Family of Magnetic Compounds

    Crystals · 2018-04-04

    Peter S. Berdonosov, Е. С. Кузнецова, В. А. Долгих

    Read original paper ↗ ·

  24. Se–Cl Interactions in Selenite Chlorides: A Theoretical Study

    Crystals · 2018-04-29

    Sergey V. Krivovichev, Liudmila A. Gorelova

    Read original paper ↗ ·

  25. Dicobalt (II) hydroxo-selenite: Hydrothermal synthesis, crystal structure and magnetic properties of Co2SeO3(OH)2

    Journal of Solid State Chemistry · 2020-02-07

    Ruidan Zhong, Shu Hai Guo, Danrui Ni, R. J. Cava

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  26. Cycloidal Magnetic Order Promoted by Labile Mixed Anionic Paths in M2(SeO3)F2 (M = Mn2+, Ni2+)

    Inorganic Chemistry · 2021-07-26

    Tianyu Zhu, Olivier Mentré, Haoming Yang, Yong Jin, Xinan Zhang, Ángel M. Arévalo‐López, C. Ritter, Kwang‐Yong Choi, Minfeng Lü

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  27. Cu9O2(SeO3)4Cl6 revisited: Crystal structure, Raman scattering and first-principles calculations

    Journal of Alloys and Compounds · 2021-10-13

    Ksenia Denisova, P. Lemmens, Dirk Wulferding, Peter S. Berdonosov, В. А. Долгих, Alisher F. Murtazoev, Ekaterina S. Kozlyakova, Olga V. Maximova, Alexander N. Vasiliev, Igor V. Shchetinin, Fedor M. Dolgushin, Asif Iqbal, Badiur Rahaman, Tanusri Saha‐Dasgupta

    Read original paper ↗ ·

  28. Observation of a 1/3 magnetization plateau in Pb 2 Cu 10 O 4 (SeO 3 ) 4 Cl 7 arising from (Cu 2+ ) 7 clusters of corner-sharing (Cu 2+ ) 4 tetrahedra

    Dalton Transactions · 2022-01-01

    Alexander N. Vasiliev, Peter S. Berdonosov, Ekaterina S. Kozlyakova, Olga V. Maximova, Alisher F. Murtazoev, В. А. Долгих, Konstantin Alexandrovich Lyssenko, Z. V. Pchelkina, Denis Ivanovich Gorbunov, S. H. Chung, Hyun‐Joo Koo, Myung‐Hwan Whangbo

    Read original paper ↗ ·

  29. Fabrication of novel oxochalcogens halides of manganese and tin nanocomposites as highly efficient photocatalysts for dye degradation and excellent antimicrobial activity

    Frontiers in Materials · 2023-02-27

    Misbah Umar, Sana Mansoor, Mohsin Javed, Nadia Hussain, Majed A. Bajaber, Shahid Iqbal, Ahmad Alhujaily, Ayesha Mohyuddin, Humayun Ajaz, Abdul Rauf, Ali Bahadur, Foziah F. Al-Fawzan, Eslam B. Elkaeed

    Read original paper ↗ ·

  30. Three new copper-lead selenite bromides obtained by chemical vapor transport: Pb5Cu+4(SeO3)4Br6, Pb8Cu2+(SeO3)4Br10, and the synthetic analogue of the mineral sarrabusite, Pb5Cu2+(SeO3)4(Br,Cl)4

    Mineralogy and Petrology · 2023-05-15

    Oleg I. Siidra, Vasili Yu Grishaev, Еvgeny V. Nazarchuk, Roman A. Kayukov

    Read original paper ↗ ·

  31. Precursor recommendation for inorganic synthesis by machine learning materials similarity from scientific literature

    Science Advances · 2023-06-09

    Tanjin He, Haoyan Huo, Christopher J. Bartel, Zheren Wang, Kevin Cruse, Gerbrand Ceder

    Read original paper ↗ ·

  32. Guangyuanite, Pb3Cl3(Se4+O3)(OH), a new lead chloride selenite mineral from the El Dragón mine, Potosí, Bolivia

    Mineralogical Magazine · 2023-12-07

    Hexiong Yang, Xiangping Gu, James A. McGlasson, Ronald B. Gibbs, Robert T. Downs

    Read original paper ↗ ·

  33. Ferromagnetic Mn3+ Sawtooth Chains in A2(Mn2O)(SeO3)3 (A = K, Rb) Quaternary Selenites

    Inorganic Chemistry · 2024-05-24

    Yaping Li, Feifan Li, Olivier Mentré, Claire Minaud, Ángel M. Arévalo‐López, Qingqing Huang, Xiedong Cheng, Rui Cui, Minfeng Lü

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  34. Exploring new members of magnetoelectric materials in CuO–CuCl2–SeO2 system

    Materials Today Physics · 2024-08-01

    D. Chandrasekhar Kakarla, Yuan-Han Ku, Hung‐Cheng Wu, C. C. Chen, M.Y. Hsu, T.R. Hu, J.-Y. Lin, Nidhi Puri, M.-J. Hsieh, Chin‐Wei Wang, W.-H. Li, C. Dhanasekhar, Ajay Tiwari, C.H. Lu, K.J. You, T. W. Kuo, Kaiyuan Fan, Yao-Chung Chang, H. D. Yang

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  35. Polar Layered Magnet Ba 2 Cu 3 (SeO 3 ) 4 F 2 Composed of Bitriangular Chains: Observation of 1/3-Magnetization Plateau

    Chemistry of Materials · 2024-08-12

    Alimujiang Yalikun, Yanhong Wang, Nian Shi, Yiwen Chen, Hao Huang, Hyun‐Joo Koo, Zhongwen Ouyang, Zhengcai Xia, Reinhard Karl Kremer, Myung‐Hwan Whangbo, Hongcheng Lu

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  36. Wangkuirenite—a new lead chloride-selenite mineral

    Acta Mineralogica Sinica · 2024-09-30

    Hexiong YANG, Xiangping GU, Xiande Xie, Jie PENG, B. Gibbs R., T. Downs R.

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  37. Syntheses, Structures, and Magnetic Properties of ACu4(SeO3)4F2 (A = Cd, Hg) with a Distorted Honeycomb Lattice

    Crystal Growth & Design · 2025-01-21

    Tianyu Zhu, Zhiying Zhao, Meiyan Cui, Wenhao Zhang, Zhangzhen He

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  38. The crystal chemistry and topology of modular structures. I. Selenites of rare-earth elements

    Structural Chemistry · 2025-09-08

    Sergey M. Aksenov

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  39. Magnetic Copper Selenite-Sulfate Cu 3 O 2 (HSeO 3 )(HSO 4 )(H 2 O) with T26-Type Non-Archimedean Lattice Featuring a Robust 1/3-Magnetization Plateau

    Inorganic Chemistry · 2026-04-14

    Nian Shi, Yue Wang, Hui Li, Yun Lv, Hiroshi Takatsu, Hyun‐Joo Koo, Chao Dong, Reinhard Karl Kremer, J. F. Wang, Myung‐Hwan Whangbo, Hiroshi Kageyama, Hongcheng Lu

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  40. Single Crystal Growth and Easy-Plane Anisotropic Magnetism of Distorted T26-Type Non-Archimedean Antiferromagnet Cu 3 O 2 (HSeO 3 )(HSO 4 )(H 2 O) with 1/3-Magnetization Plateau

    Crystal Growth & Design · 2026-05-16

    Nian Shi, Yue Wang, Hui Li, Yun Lv, SeungGyum Jung, Hyun‐Joo Koo, Hiroshi Takatsu, Hiroshi Kageyama, Reinhard Karl Kremer, Zhaosheng Wang, Myung‐Hwan Whangbo, Hongcheng Lu

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  41. High-selectivity fluoride capture by purely inorganic copper tellurite of Cu7F2(TeO3)6: Adsorption performance and mechanistic insights

    Journal of Solid State Chemistry · 2026-06-29

    Yao Huang, Xianjin Huang, Xiaozhou Jiang, Feie Fu, Dandan Ge, Zhehui Weng

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