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RESEARCH PAPER · Journal of the American Chemical Society · 2011

BiO(IO3): A New Polar Iodate that Exhibits an Aurivillius-Type (Bi2O2)2+ Layer and a Large SHG Response

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BiO(IO3): A New Polar Iodate that Exhibits an Aurivillius-Type (Bi2O2)2+ Layer and a Large SHG ResponseOriginalAlkaline-Alkaline Earth Fluoride Carbonate Crystals ABCO3F (A = K, Rb, Cs; B = Ca, Sr, Ba) as Nonlinear Optical Materials525Bi2(IO4)(IO3)3: A New Potential Infrared Nonlinear Optical Material Containing [IO4]3– Anion111BaGa2MQ6 (M = Si, Ge; Q = S, Se): a new series of promising IR nonlinear optical materials199Cadmium-rare earth oxyborates Cd4ReO(BO3)3 (Re = Y, Gd, Lu): congruently melting compounds with large SHG responses65PbPt(IO3)6(H2O): a new polar material with two types of stereoactive lone-pairs and a very large SHG response80Iodine Release and Recovery, Influence of Polyiodide Anions on Electrical Conductivity and Nonlinear Optical Activity in an Interdigitated and Interpenetrated Bipillared-Bilayer Metal–Organic Framework456A New Mixed Halide, Cs2HgI2Cl2: Molecular Engineering for a New Nonlinear Optical Material in the Infrared Region145A combination of multiple chromophores enhances second-harmonic generation in a nonpolar noncentrosymmetric oxide: CdTeMoO681Iodine-templated assembly of unprecedented 3d–4f metal–organic frameworks as photocatalysts for hydrogen generation105Pb2TiOF(SeO3)2Cl and Pb2NbO2(SeO3)2Cl: small changes in structure induced a very large SHG enhancement117ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units53New Bismuth Selenium Oxides: Syntheses, Structures, and Characterizations of Centrosymmetric Bi2(SeO3)2(SeO4) and Bi2(TeO3)2(SeO4) and Noncentrosymmetric Bi(SeO3)(HSeO3)53Zn2(VO4)(IO3): A Novel Polar Zinc(II) Vanadium(V) Iodate with a Large SHG Response94Anion-Centered Tetrahedra in Inorganic Compounds242Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)2F2Cl and Noncentrosymmetric NaBa4(AlB4O9)2Br350Na8Lu2(CO3)6F2 and Na3Lu(CO3)2F2: Rare Earth Fluoride Carbonates as Deep-UV Nonlinear Optical Materials139Metal Chalcogenides: A Rich Source of Nonlinear Optical Materials680Efficient Separation of Photogenerated Electron‐Hole Pairs by the Combination of a Heterolayered Structure and Internal Polar Field in Pyroelectric BiOIO 3 Nanoplates177A one-step hydrothermal preparation strategy for layered BiIO4/Bi2WO6 heterojunctions with enhanced visible light photocatalytic activities109A 2 BiI 5 O 15 (A = K + or Rb + ): two new promising nonlinear optical materials containing [I 3 O 9 ] 3− bridging anionic groups62Computational design of inorganic nonlinear optical crystals based on a genetic algorithm93Layered photocatalyst Bi 2 O 2 [BO 2 (OH)] nanosheets with internal polar field enhanced photocatalytic activity70Noncentrosymmetric YVSe2O8 and Centrosymmetric YVTe2O8: Macroscopic Centricities Influenced by the Size of Lone Pair Cation Linkers63Novel Bi-based iodate photocatalysts with high photocatalytic activity92Explorations of New Second-Order Nonlinear Optical Materials in the Ternary Rubidium Iodate System: Noncentrosymmetric β-RbIO3(HIO3)2 and Centrosymmetric Rb3(IO3)3(I2O5)(HIO3)4(H2O)59Syntheses, characterization and nonlinear optical properties of a bismuth subcarbonate Bi2O2CO363A New UV Nonlinear Optical Material CsZn2B3O7: ZnO4 Tetrahedra Double the Efficiency of Second-Harmonic Generation121SHG Materials SnGa4Q7 (Q = S, Se) Appearing with Large Conversion Efficiencies, High Damage Thresholds, and Wide Transparencies in the Mid-Infrared Region141α-AgI3O8 and β-AgI3O8 with Large SHG Responses: Polymerization of IO3 Groups into the I3O8 Polyiodate Anion113Role of Acentric Displacements on the Crystal Structure and Second-Harmonic Generating Properties of RbPbCO3F and CsPbCO3F90Beryllium-free Li4Sr(BO3)2 for deep-ultraviolet nonlinear optical applications462Novel g-C 3 N 4 /BiIO 4 heterojunction photocatalysts: synthesis, characterization and enhanced visible-light-responsive photocatalytic activity70Hydrothermal synthesis of C3N4/BiOIO3 heterostructures with enhanced photocatalytic properties74Bi 2 O 2 (OH)(NO 3 ) as a desirable [Bi 2 O 2 ] 2+ layered photocatalyst: strong intrinsic polarity, rational band structure and {001} active facets co-beneficial for robust photooxidation capability384Controlling interfacial contact and exposed facets for enhancing photocatalysis via 2D–2D heterostructures160PbGa2MSe6 (M = Si, Ge): Two Exceptional Infrared Nonlinear Optical Crystals131Recent advances on second-order NLO materials based on metal iodates328New insights into how RGO influences the photocatalytic performance of BiOIO3/RGO nanocomposites under visible and UV irradiation81RbMgCO3F: A New Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material341Monolayered Bi2WO6 nanosheets mimicking heterojunction interface with open surfaces for photocatalysis746Metal Thiophosphates with Good Mid-infrared Nonlinear Optical Performances: A First-Principles Prediction and Analysis441Fabrication of BiOIO3 nanosheets with remarkable photocatalytic oxidation removal for gaseous elemental mercury107In Situ Composition-Transforming Fabrication of BiOI/BiOIO3 Heterostructure: Semiconductor p–n Junction and Dominantly Exposed Reactive Facets98Oxychalcogenide BaGeOSe2: Highly Distorted Mixed-Anion Building Units Leading to a Large Second-Harmonic Generation Response96Synchronously Achieving Plasmonic Bi Metal Deposition and I– Doping by Utilizing BiOIO3 as the Self-Sacrificing Template for High-Performance Multifunctional Applications126Ternary Ag/AgCl/BiOIO3 composites for enhanced visible-light-driven photocatalysis64Bidenticity-Enhanced Second Harmonic Generation from Pb Chelation in Pb3Mg3TeP2O14169Experimental and theoretical studies on the linear and nonlinear optical properties of lead phosphate crystals LiPbPO 474Interlayer-I-doped BiOIO 3 nanoplates with an optimized electronic structure for efficient visible light photocatalysis81Nanosheets-built flowerlike micro/nanostructured Bi2O2.33 and its highly efficient iodine removal performances106RbIO3 and RbIO2F2: Two Promising Nonlinear Optical Materials in Mid-IR Region and Influence of Partially Replacing Oxygen with Fluorine for Improving Laser Damage Threshold124Molecular Engineering as an Approach To Design a New Beryllium-Free Fluoride Carbonate as a Deep-Ultraviolet Nonlinear Optical Material101Electronic, Crystal Chemistry, and Nonlinear Optical Property Relationships in the Dugganite A3B3CD2O14 Family148Rb2Na(NO3)3: A Congruently Melting UV-NLO Crystal with a Very Strong Second-Harmonic Generation Response71Na 2 ZnGe 2 S 6 : A New Infrared Nonlinear Optical Material with Good Balance between Large Second-Harmonic Generation Response and High Laser Damage Threshold302Internal polar field enhanced H2 evolution of BiOIO3 nanoplates69Deep‐Ultraviolet Nonlinear Optics in a Borate Framework with 21‐Ring Channels109Hydrothermal synthesis of carbon spheres – BiOI/BiOIO3 heterojunctions for photocatalytic removal of gaseous Hg0 under visible light126BiFSeO 3 : An Excellent SHG Material Designed by Aliovalent Substitution207Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation382Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation129Cd3(MoO4)(TeO3)2: A Polar 3D Compound Containing d10–d0 SCALP-Effect Cations85Mixed-Metal Carbonate Fluorides as Deep-Ultraviolet Nonlinear Optical Materials259Li 2 CdGeSe 4 and Li 2 CdSnSe 4 : biaxial nonlinear optical materials with strong infrared second-order responses and laser-induced damage thresholds influenced by photoluminescence54Na 2 CdGe 2 Q 6 (Q = S, Se): two metal-mixed chalcogenides with phase-matching abilities and large second-harmonic generation responses77Structural Modulation of Nitrate Group with Cations to Affect SHG Responses in RE(OH)2NO3 (RE = La, Y, and Gd): New Polar Materials with Large NLO Effect after Adjusting pH Values of Reaction Systems151Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect238Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect71Bi3OF3(IO3)4: Metal Oxyiodate Fluoride Featuring a Carbon-Nanotube-like Topological Structure with Large Second Harmonic Generation Response121Enhancing Charge Separation in Photocatalysts with Internal Polar Electric Fields100BiOBr0.75I0.25/BiOIO3 as a Novel Heterojunctional Photocatalyst with Superior Visible-Light-Driven Photocatalytic Activity in Removing Diverse Industrial Pollutants109Fabrication of BiOIO3 with induced oxygen vacancies for efficient separation of the electron-hole pairs205ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap140Macroscopic Polarization Enhancement Promoting Photo‐ and Piezoelectric‐Induced Charge Separation and Molecular Oxygen Activation1041Macroscopic Polarization Enhancement Promoting Photo‐ and Piezoelectric‐Induced Charge Separation and Molecular Oxygen Activation82Achieving Enhanced UV and Visible Light Photocatalytic Activity for Ternary Ag/AgBr/BiOIO 3 : Decomposition for Diverse Industrial Contaminants with Distinct Mechanisms and Complete Mineralization Ability102Acentric La3(IO3)8(OH) and La(IO3)2(NO3): Partial Substitution of Iodate Anions in La(IO3)3 by Hydroxide or Nitrate Anion55Functional Materials Design via Structural Regulation Originated from Ions Introduction: A Study Case in Cesium Iodate System90A Series of Mixed-Metal Germanium Iodates as Second-Order Nonlinear Optical Materials71Controlling dominantly reactive (010) facets and impurity level by in-situ reduction of BiOIO3 for enhancing photocatalytic activity131Rational Design of the First Lead/Tin Fluorooxoborates MB2O3F2 (M = Pb, Sn), Containing Flexible Two-Dimensional [B6O12F6]∞ Single Layers with Widely Divergent Second Harmonic Generation Effects211Assisting the Effective Design of Polar Iodates with Early Transition-Metal Oxide Fluoride Anions206Enhanced photocatalytic performance of a two-dimensional BiOIO3/g-C3N4 heterostructured composite with a Z-scheme configuration124Second-order nonlinear optical crystals with mixed anions250Recent advances and future perspectives on infrared nonlinear optical metal halides223Ce(IO3)2F2⋅H2O: The First Rare‐Earth‐Metal Iodate Fluoride with Large Second Harmonic Generation Response66Ferroelectric polarization promoted bulk charge separation for highly efficient CO2 photoreduction of SrBi4Ti4O15204[(( R )-C8H12N)4][Bi2Br10] and [(( S )-C8H12N)4][Bi2Br10]: Chiral Hybrid Bismuth Bromides Templated by Chiral Organic Cations74A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions137LiMg(IO 3 ) 3 : an excellent SHG material designed by single-site aliovalent substitution68The Role of Polarization in Photocatalysis930The Role of Polarization in Photocatalysis60Two Polar Molybdenum(VI) Iodates(V) with Large Second-Harmonic Generation Responses67The utility of the template effect in metal-organic frameworks116Iodine self-doping and oxygen vacancies doubly surface-modified BiOIO3: Facile in situ synthesis, band gap modulation, and excellent visible-light photocatalytic activity94REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion125REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion62LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO399Influence of BiOIO3 morphology on the photocatalytic efficiency of Z-scheme BiOIO3/g-C3N4 heterojunctioned composite for Hg0 removal123Freeing the Polarons to Facilitate Charge Transport in BiVO 4 from Oxygen Vacancies with an Oxidative 2D Precursor90Sensing of Fe3+ and Cr2O72– in Water and White Light: Synthesis, Characterization, and Fluorescence Properties of a Crystalline Bismuth-1,3,5-benzenetricarboxylic Acid Framework67Spontaneous Polarization Effect and Photocatalytic Activity of Layered Compound of BiOIO373Internal electric field engineering for steering photogenerated charge separation and enhancing photoactivity260K5(W3O9F4)(IO3): An Efficient Mid-Infrared Nonlinear Optical Compound with High Laser Damage Threshold114(NH4)Bi2(IO3)2F5: An Unusual Ammonium‐Containing Metal Iodate Fluoride Showing Strong Second Harmonic Generation Response and Thermochromic Behavior92Novel ultraviolet (UV) nonlinear optical (NLO) materials discovered by chemical substitution-oriented design302Two-stage evolution from phosphate to sulfate of new KTP-type family members as UV nonlinear optical materials through chemical cosubstitution-oriented design51CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework132Rational Design of the Nonlinear Optical Response in a Tin Iodate Fluoride Sn(IO3)2F290Alignment of Polar Moieties Leading to Strong Second Harmonic Response in KCsMoP2O951In situ self-growing 3D hierarchical BiOBr/BiOIO3 Z-scheme heterojunction with rich oxygen vacancies and iodine ions as carriers transfer dual-channels for enhanced photocatalytic activity274Z-scheme photocatalytic NO removal on a 2D/2D iodine doped BiOIO3/g-C3N4 under visible-light irradiation55[ABa2Cl][Ga4S8] (A = Rb, Cs): Wide-Spectrum Nonlinear Optical Materials Obtained by Polycation-Substitution-Induced Nonlinear Optical (NLO)-Functional Motif Ordering270CeO2/BiOIO3 heterojunction with oxygen vacancies and Ce4+/Ce3+ redox centers synergistically enhanced photocatalytic removal heavy metal161Tribo-catalytic degradation of organic pollutants through bismuth oxyiodate triboelectrically harvesting mechanical energy153Piezocatalysis and Piezo‐Photocatalysis: Catalysts Classification and Modification Strategy, Reaction Mechanism, and Practical Application986Pressure-Regulated Dynamic Stereochemical Role of Lone-Pair Electrons in Layered Bi2O2S64Chemistry of Quantum Spin Liquids185Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials95A review on the recently developed promising infrared nonlinear optical materials103Centrosymmetric RbSnF 2 NO 3 vs. noncentrosymmetric Rb 2 SbF 3 (NO 3 ) 254Conduction Band Control of Oxyhalides with a Triple-Fluorite Layer for Visible Light Photocatalysis109Fabrication of 3D Bi5O7I/BiOIO3 heterojunction material with enhanced photocatalytic activity towards tetracycline antibiotics69Synergistic catalysis of BiOIO3 catalyst for elimination of organic pollutants under simultaneous photo-irradiation and ultrasound-vibration treatment70High-Performance Second-Harmonic-Generation (SHG) Materials: New Developments and New Strategies323[ o ‐C 5 H 4 NHOH] 2 [I 7 O 18 (OH)]⋅3 H 2 O: An Organic–Inorganic Hybrid SHG Material Featuring an [I 7 O 18 (OH)] Branched Polyiodate Chain86Bismuth-based photocatalyst for photocatalytic oxidation of flue gas mercury removal: A review146Role of the Polar Electric Field in Bismuth Oxyhalides for Photocatalytic Water Splitting67Giant Second-Harmonic Generation Response and Large Band Gap in the Partially Fluorinated Mid-Infrared Oxide RbTeMo 2 O 8 F149Thickness-dependent layered BiOIO3 modified with carbon quantum dots for photodegradation of bisphenol A: Mechanism, pathways and DFT calculation167Efficient removal and immobilization of radioactive iodide and iodate from aqueous solutions by bismuth-based composite beads72An Effective Strategy for Designing Nonlinear Optical Crystals by Combining the Structure‐Directing Property of Oxyfluorides with Chemical Substitution73A Lanthanum Ammonium Sulfate Double Salt with a Strong SHG Response and Wide Deep‐UV Transparency96Metal oxyhalides: an emerging family of nonlinear optical materials124Layered bismuth-based photocatalysts298RbBiP2S6: A Promising IR Nonlinear Optical Material with a Giant Second-Harmonic Generation Response Designed by Aliovalent Substitution802D Z-scheme heterojunction and oxygen deficiency synergistically boosting the photocatalytic activity of a layered BaTiO3/BiOIO3 composite64PbBi(SeO 3 ) 2 F and Pb 2 Bi(SeO 3 ) 2 Cl 3 : Coexistence of Three Kinds of Stereochemically Active Lone-Pair Cations Exhibiting Excellent Nonlinear Optical Properties57Recent advances in two-dimensional ultrathin Bi-based photocatalysts1162D/2D BiOIO3/g-C3N4 S-scheme hybrid heterojunction with face-to-face interfacial contact for effective photocatalytic H2 production and norfloxacin degradation62Bifunctional S-scheme hybrid heterojunction comprising CdS nanorods and BiOIO3 nanosheets for efficient solar-induced antibiotic degradation and highly-selective CO2 reduction63Advances in aliovalent substitution strategy for the design and synthesis of nonlinear optical materials: d0 transition metal/gallium iodates and selenites71Highly Efficient FeIII‐initiated Self‐cycled Fenton System in Piezo‐catalytic Process for Organic Pollutants Degradation85Optimization of the IO3 polar group of BiOIO3 by bulk phase doping amplifies pyroelectric polarization to enhance carrier separation and improve the pyro-photo-electric catalytic performance97Recent advancements in the use of novel piezoelectric materials for piezocatalytic and piezo-photocatalytic applications3092D/2D layered BiOIO3/g-C3N4 S-scheme heterojunction for photocatalytic NO oxidation107Tandem Fields Facilitating Directional Carrier Migration in Van der Waals Heterojunction for Efficient Overall Piezo‐Synthesis of H2O264Recent advances in metal titanate-based piezocatalysts: Enhancing catalytic performance through improved piezoelectric properties and regulated carrier transport72Piezoelectric effect coupled advanced oxidation processes for environmental catalysis application71Rational design and interfacial engineering of hierarchical S-scheme heterojunction and their photocatalytic applications67

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