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RESEARCH PAPER · Inorganic Chemistry · 2010

Lone Pairs as Chemical Scissors in New Antimony Oxychlorides, Sb2ZnO3Cl2 and Sb16Cd8O25Cl14

Vinna Jo, Min Kyung Kim, Dong Woo Lee, Il‐Wun Shim, Kang Min Ok

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Lone Pairs as Chemical Scissors in New Antimony Oxychlorides, Sb2ZnO3Cl2 and Sb16Cd8O25Cl14OriginalAnionic templating in a new layered bismuth tellurium oxychloride, Bi3Te4O10Cl529ChemInform Abstract: Lone Pairs as Chemical Scissors in New Antimony Oxychlorides, Sb2ZnO3Cl2 and Sb16Cd8O25Cl14.0A new layered indium selenium oxychloride material: Synthesis, structure, and characterization of InSeO3Cl20Syntheses, crystal structures and characterizations of two new quaternary thioborates: PbMBS4 (M = Sb, Bi)13Syntheses and Characterization of New Mid-Infrared Transparency Compounds: Centric Ba2BiGaS5 and Acentric Ba2BiInS595Lanthanide Antimony Oxohalides: From Discrete Nanoclusters to Inorganic–Organic Hybrid Chains and Layers25Lanthanide Antimony Oxohalides: From Discrete Nanoclusters to Inorganic–Organic Hybrid Chains and Layers4Microporous, Homochiral Structures Containing Iron Oxo-Clusters Supported by Antimony(III) Tartrate Scaffolds18A homochiral diamond framework constructed from Fe(iii) and Mn(ii) oxo-clusters supported by Sb(iii) tartrate scaffolds17“Cage‐like” Carboxyl Bridged Octaphenyltetraantimony Compounds (SbPh2)4(μ‐O)4(μ‐OH)2(μ‐O2CR)2: Synthesis and Structural Characterization4Crystal structure and magnetic properties of Cr3Te5O13Cl39New Bismuth Selenium Oxides: Syntheses, Structures, and Characterizations of Centrosymmetric Bi2(SeO3)2(SeO4) and Bi2(TeO3)2(SeO4) and Noncentrosymmetric Bi(SeO3)(HSeO3)53A new strontium antimonateIII Sr5Sb22O38: Synthesis, crystal structure and characterizations9New Selenites: Hydrothermal Syntheses, Crystal Structures, and Characterization of Rb3HGa2(OH)2(SeO3)4, Rb3Ga5(SeO3)8(HSeO3)2·0.5H2O, and RbGa(SeO3)2·H2O16Effect of polarizable lone pair cations on the second-harmonic generation (SHG) properties of noncentrosymmetric (NCS) Bi 2−x Y x TeO 5 (x = 0–0.2)24Synthesis and Crystal Structure of the Iron(III) Oxotellurate(IV) Phosphate Oxide Chloride Fe11(TeO3)2(TeO4)3(PO4)2O4Cl35Sr3Bi2(SeO3)6·H2O: A novel anionic layer consisting of second-order Jahn–Teller (SOJT) distortive cations9Oxocentered Cu( ii ) lead selenite honeycomb lattices hosting Cu( i )Cl 2 groups obtained by chemical vapor transport reactions25[NaCl][Cu(HSeO3)2], NaCl-intercalated Cu(HSeO3)2: synthesis, crystal structure and comparison with related compounds18Synthesis, crystal structure and magnetic properties of a new copper oxo-antimony sulphate CuSb 6 O 8 (SO 4 ) 29Rb 2 SeOCl 4 ·H 2 O: a polar material among the alkali metal selenite halides with a strong SHG response18Sb-Based antiferromagnetic oxychlorides: MSb 2 O 3 (OH)Cl (M = Mn, Fe, Co) with 2D spin-dimer structures9Bi3n+1Ti7Fe3n–3O9n+11 Homologous Series: Slicing Perovskite Structure with Planar Interfaces Containing Anatase-like Chains7Polar Noncentrosymmetric ZnMoSb2O7 and Nonpolar Centrosymmetric CdMoSb4O10: d10 Transition Metal Size Effect Influencing the Stoichiometry and the Centricity38Porous layered and open-framework mixed-valence copper tellurites9Zn 3 Sb 4 O 6 F 6 : Hydrothermal synthesis, crystal structure and nonlinear optical properties26Belousovite, KZn(SO4)Cl, a new sulfate mineral from the Tolbachik volcano with apophyllite sheet-topology.15Crystal structures and characterizations of two new selenite chlorides: 1D Ba2Zn(SeO3)2Cl2 and 2D BaZn2(SeO3)2Cl26Copper–lead selenite bromides: a new large family of compounds partly having Cu2+ substructures derivable from kagome nets10Tin Chloride Sulfates A3Sn2(SO4)3–xCl1+2x (A = K, Rb, Cs; x = 0, 1) as Multifunctional Optical Materials33Second-Harmonic-Generation-Active Oxyhalides: CuSb2O3X (X = Cl, Br)17A Nonpolar Bond to Hydrogen vs. Lone Pair: Incorporation of Hpo32- and Seeo32- into a Lead Perrhenate Framework9Potassium rare-earth tellurite chlorides: A new branch from the old root7Sb5O7I: Exploration of Ternary Antimony-Based Oxyhalide as a Nonlinear-Optical Material27Centrosymmetric Rb2Sb(C2O4)2.5(H2O)3 and Noncentrosymmetric RbSb2(C2O4)F5: Two Antimony (III) Oxalates as UV Optical Materials20Chemical Scissor-mediated Structural Editing of Inorganic Materials0Exploration of antimony( iii ) oxyhalides via single-site substitution in quest of large birefringence10Structural Diversity of Iso-Maleonitrile Dithiolate d10s2 Metal Complexes of Lead and Bismuth2Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals66Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals8Designing a 2D van der Waals oxide with lone-pair electrons as chemical scissor15Synthesis and structural characterization of new layered hydroselenites (enH2)[Ni(HSeO3)2Br2] and (dmedaH2)[Ni(HSeO3)2X2], X = Cl, Br4Cs2CdV2O6Br2: A Mid-Infrared Nonlinear Optical Vanadate Containing Both d0/d10 Transition Metal Cations and Bromine Anions5Complex layered praseodymium tellurite halides: synthesis, crystal chemistry, principles of modular construction, and the character of polytypism0Hydrothermal synthesis and characterization of Pb 3 Cu 2 (SeO 3 ) 4 Cl 2 , structurally similar to the mineral sarrabusite0

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  1. Anionic templating in a new layered bismuth tellurium oxychloride, Bi3Te4O10Cl5

    Dalton Transactions · 2010-01-01

    Min Kyung Kim, Vinna Jo, Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·

  2. ChemInform Abstract: Lone Pairs as Chemical Scissors in New Antimony Oxychlorides, Sb2ZnO3Cl2 and Sb16Cd8O25Cl14.

    ChemInform · 2010-06-17

    Vinna Jo, Min Kyung Kim, Dong Woo Lee, Il‐Wun Shim, Kang Min Ok

    Read original paper ↗ ·

  3. A new layered indium selenium oxychloride material: Synthesis, structure, and characterization of InSeO3Cl

    Solid State Sciences · 2010-09-13

    Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·

  4. Syntheses, crystal structures and characterizations of two new quaternary thioborates: PbMBS4 (M = Sb, Bi)

    Dalton Transactions · 2011-01-01

    Lei Geng, Wen‐Dan Cheng, Weilong Zhang, Ye‐Yu Li, Zhong‐Zhen Luo, Hao Zhang, Chensheng Lin, Zhangzhen He

    Read original paper ↗ ·

  5. Syntheses and Characterization of New Mid-Infrared Transparency Compounds: Centric Ba2BiGaS5 and Acentric Ba2BiInS5

    Inorganic Chemistry · 2011-05-19

    Lei Geng, Wen‐Dan Cheng, Chensheng Lin, Weilong Zhang, Hao Zhang, Zhangzhen He

    Read original paper ↗ ·

  6. Lanthanide Antimony Oxohalides: From Discrete Nanoclusters to Inorganic–Organic Hybrid Chains and Layers

    Angewandte Chemie International Edition · 2011-07-14

    Bing Hu, Mei‐Ling Feng, Jian‐Rong Li, Qipu Lin, Xiao‐Ying Huang

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  7. Lanthanide Antimony Oxohalides: From Discrete Nanoclusters to Inorganic–Organic Hybrid Chains and Layers

    Angewandte Chemie · 2011-07-14

    Bing Hu, Mei‐Ling Feng, Jian‐Rong Li, Qipu Lin, Xiao‐Ying Huang

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  8. Microporous, Homochiral Structures Containing Iron Oxo-Clusters Supported by Antimony(III) Tartrate Scaffolds

    Crystal Growth & Design · 2011-08-29

    Qiang Gao, Xiqu Wang, Marlon T. Conato, Tatyana Makarenko, Allan J. Jacobson

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  9. A homochiral diamond framework constructed from Fe(iii) and Mn(ii) oxo-clusters supported by Sb(iii) tartrate scaffolds

    Chemical Communications · 2012-01-01

    Qiang Gao, Xiqu Wang, Allan J. Jacobson

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  10. “Cage‐like” Carboxyl Bridged Octaphenyltetraantimony Compounds (SbPh2)4(μ‐O)4(μ‐OH)2(μ‐O2CR)2: Synthesis and Structural Characterization

    Zeitschrift für anorganische und allgemeine Chemie · 2012-03-23

    Handong Yin, Qingkun Wu, Min Hong, Wenkuan Li

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  11. Crystal structure and magnetic properties of Cr3Te5O13Cl3

    Dalton Transactions · 2013-01-01

    Iwan Zimmermann, Reinhard Karl Kremer, P. Reuvekamp, Mats Johnsson

    Read original paper ↗ ·

  12. New Bismuth Selenium Oxides: Syntheses, Structures, and Characterizations of Centrosymmetric Bi2(SeO3)2(SeO4) and Bi2(TeO3)2(SeO4) and Noncentrosymmetric Bi(SeO3)(HSeO3)

    Inorganic Chemistry · 2013-03-18

    Eun Pyo Lee, Seung Yoon Song, Dong Woo Lee, Kang Min Ok

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  13. A new strontium antimonateIII Sr5Sb22O38: Synthesis, crystal structure and characterizations

    Journal of Solid State Chemistry · 2013-04-22

    Lei Geng, Chang‐Yu Meng, Chensheng Lin, Wen‐Dan Cheng

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  14. New Selenites: Hydrothermal Syntheses, Crystal Structures, and Characterization of Rb3HGa2(OH)2(SeO3)4, Rb3Ga5(SeO3)8(HSeO3)2·0.5H2O, and RbGa(SeO3)2·H2O

    Inorganic Chemistry · 2013-08-16

    Dong Woo Lee, Kang Min Ok

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  15. Effect of polarizable lone pair cations on the second-harmonic generation (SHG) properties of noncentrosymmetric (NCS) Bi 2−x Y x TeO 5 (x = 0–0.2)

    Dalton Transactions · 2014-05-09

    Hongil Jo, Yeong Hun Kim, Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·

  16. Synthesis and Crystal Structure of the Iron(III) Oxotellurate(IV) Phosphate Oxide Chloride Fe11(TeO3)2(TeO4)3(PO4)2O4Cl3

    Zeitschrift für anorganische und allgemeine Chemie · 2014-09-12

    Iwan Zimmermann, Mats Johnsson

    Read original paper ↗ ·

  17. Sr3Bi2(SeO3)6·H2O: A novel anionic layer consisting of second-order Jahn–Teller (SOJT) distortive cations

    Journal of Solid State Chemistry · 2014-09-30

    Hyun Sun Ahn, Eun Pyo Lee, Hong‐Young Chang, Dong Woo Lee, Kang Min Ok

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  18. Oxocentered Cu( ii ) lead selenite honeycomb lattices hosting Cu( i )Cl 2 groups obtained by chemical vapor transport reactions

    Chemical Communications · 2015-01-01

    Vadim M. Kovrugin, Marie Colmont, Oleg I. Siidra, Olivier Mentré, Alexander Al‐Shuray, Vladislav V. Gurzhiy, Sergey V. Krivovichev

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  19. [NaCl][Cu(HSeO3)2], NaCl-intercalated Cu(HSeO3)2: synthesis, crystal structure and comparison with related compounds

    Zeitschrift für Kristallographie - Crystalline Materials · 2015-08-07

    Vadim M. Kovrugin, Sergey V. Krivovichev, Olivier Mentré, Marie Colmont

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  20. Synthesis, crystal structure and magnetic properties of a new copper oxo-antimony sulphate CuSb 6 O 8 (SO 4 ) 2

    Dalton Transactions · 2015-11-18

    Iwan Zimmermann, Reinhard Karl Kremer, Shichao Hu, Mats Johnsson

    Read original paper ↗ ·

  21. Rb 2 SeOCl 4 ·H 2 O: a polar material among the alkali metal selenite halides with a strong SHG response

    Dalton Transactions · 2016-01-01

    Qi Wu, Hongming Liu, Lei Kang, Zheshuai Lin, Xiang‐Gao Meng, Xingguo Chen, Jingui Qin

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  22. Sb-Based antiferromagnetic oxychlorides: MSb 2 O 3 (OH)Cl (M = Mn, Fe, Co) with 2D spin-dimer structures

    Dalton Transactions · 2016-01-01

    Lei Geng, Qiang Li, Hong‐Yan Lu, Kai Dai, P. Shiv Halasyamani

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  23. Bi3n+1Ti7Fe3n–3O9n+11 Homologous Series: Slicing Perovskite Structure with Planar Interfaces Containing Anatase-like Chains

    Inorganic Chemistry · 2016-01-08

    Dmitry Batuk, Alexander A. Tsirlin, Dmitry S. Filimonov, Konstantin V. Zakharov, О. С. Волкова, Alexander N. Vasiliev, Joke Hadermann, Artem M. Abakumov

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  24. Polar Noncentrosymmetric ZnMoSb2O7 and Nonpolar Centrosymmetric CdMoSb4O10: d10 Transition Metal Size Effect Influencing the Stoichiometry and the Centricity

    Inorganic Chemistry · 2016-05-26

    Hongil Jo, Kang Min Ok

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  25. Porous layered and open-framework mixed-valence copper tellurites

    Journal of Solid State Chemistry · 2016-08-27

    Mishel R. Markovski, Oleg I. Siidra, Roman A. Kayukov, Еvgeny V. Nazarchuk

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  26. Zn 3 Sb 4 O 6 F 6 : Hydrothermal synthesis, crystal structure and nonlinear optical properties

    Journal of Solid State Chemistry · 2017-08-25

    S. Ali, Weiguo Zhang, P. Shiv Halasyamani, Mats Johnsson

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  27. Belousovite, KZn(SO4)Cl, a new sulfate mineral from the Tolbachik volcano with apophyllite sheet-topology.

    Mineralogical Magazine · 2018-05-15

    Oleg I. Siidra, Еvgeny V. Nazarchuk, Evgeniya A. Lukina, Anatoly N. Zaitsev, Vladimir Vladimirovich Shilovskikh

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  28. Crystal structures and characterizations of two new selenite chlorides: 1D Ba2Zn(SeO3)2Cl2 and 2D BaZn2(SeO3)2Cl2

    Journal of Solid State Chemistry · 2018-05-26

    Qiang Li, Lei Geng, Hong‐Yan Lu, Kai Dai, Wen‐Dan Cheng

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  29. Copper–lead selenite bromides: a new large family of compounds partly having Cu2+ substructures derivable from kagome nets

    Acta Crystallographica Section B Structural Science Crystal Engineering and Materials · 2018-11-30

    Oleg I. Siidra, M.S. Kozin, Wulf Depmeier, Roman A. Kayukov, Vadim M. Kovrugin

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  30. Tin Chloride Sulfates A3Sn2(SO4)3–xCl1+2x (A = K, Rb, Cs; x = 0, 1) as Multifunctional Optical Materials

    Inorganic Chemistry · 2021-05-14

    Yuwei Ge, Qiang Wang, Fei Yang, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  31. Second-Harmonic-Generation-Active Oxyhalides: CuSb2O3X (X = Cl, Br)

    Inorganic Chemistry · 2021-12-15

    Mei Yang, Zhi‐Hui Shi, Wen‐Dong Yao, Sheng‐Ping Guo

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  32. A Nonpolar Bond to Hydrogen vs. Lone Pair: Incorporation of Hpo32- and Seeo32- into a Lead Perrhenate Framework

    Journal of Solid State Chemistry · 2022-01-01

    Dmitri O. Charkin, Vasili Yu Grishaev, Artem S. Borisov, Pavel A. Chachin, Еvgeny V. Nazarchuk, Oleg I. Siidra

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  33. Potassium rare-earth tellurite chlorides: A new branch from the old root

    Solid State Sciences · 2022-04-25

    Dmitri O. Charkin, Sergey N. Volkov, В. А. Долгих, Sergey M. Aksenov

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  34. Sb5O7I: Exploration of Ternary Antimony-Based Oxyhalide as a Nonlinear-Optical Material

    Inorganic Chemistry · 2022-09-06

    Mei Yang, Wenlong Liu, Sheng‐Ping Guo

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  35. Centrosymmetric Rb2Sb(C2O4)2.5(H2O)3 and Noncentrosymmetric RbSb2(C2O4)F5: Two Antimony (III) Oxalates as UV Optical Materials

    Inorganic Chemistry · 2023-08-02

    Weiyi Wang, Xinyue Wang, Lu Xiong Xu, Die Zhang, Jiale Xue, Shuyao Wang, Xuehua Dong, Liling Cao, Ling Huang, Guohong Zou

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  36. Chemical Scissor-mediated Structural Editing of Inorganic Materials

    Journal of Inorganic Materials · 2023-12-19

    Haoming Ding, Ke Chen, Mian Li, Youbing Li, Zhifang Chai, Qing Huang

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  37. Exploration of antimony( iii ) oxyhalides via single-site substitution in quest of large birefringence

    Inorganic Chemistry Frontiers · 2024-01-01

    Chenhui Hu, Dongdong Chu, Xueling Hou, Feng Zhang, Jian Wei Han

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  38. Structural Diversity of Iso-Maleonitrile Dithiolate d10s2 Metal Complexes of Lead and Bismuth

    Crystal Growth & Design · 2024-06-03

    William W. L. Ho, Jefferson A. Pells, Daniel B. Leznoff

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  39. Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals

    Angewandte Chemie International Edition · 2024-06-26

    Yang Li, Kang Min Ok

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  40. Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals

    Angewandte Chemie · 2024-06-26

    Yang Li, Kang Min Ok

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  41. Designing a 2D van der Waals oxide with lone-pair electrons as chemical scissor

    National Science Review · 2024-10-20

    Zhipeng Du, Xu Chen, Wei Liu, Han Wang, Qian-Ting Xu, Xiaoying Shang, Yipeng Song, Xueyuan Chen, Junhua Luo, Sangen Zhao

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  42. Synthesis and structural characterization of new layered hydroselenites (enH2)[Ni(HSeO3)2Br2] and (dmedaH2)[Ni(HSeO3)2X2], X = Cl, Br

    Structural Chemistry · 2025-03-13

    Dmitri O. Charkin, Vasili Yu Grishaev, Oleg I. Siidra, A. M. Banaru, Sergey M. Aksenov

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  43. Cs2CdV2O6Br2: A Mid-Infrared Nonlinear Optical Vanadate Containing Both d0/d10 Transition Metal Cations and Bromine Anions

    Inorganic Chemistry · 2025-06-30

    Lei Geng, Baozhu Zhu, You‐Zhao Lan, Chang‐Yu Meng, Qi Wu

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  44. Complex layered praseodymium tellurite halides: synthesis, crystal chemistry, principles of modular construction, and the character of polytypism

    Russian Chemical Bulletin · 2025-12-01

    Dmitri O. Charkin, S.V. Chegodin, V. E. Kireev, Sergey M. Aksenov

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  45. Hydrothermal synthesis and characterization of Pb 3 Cu 2 (SeO 3 ) 4 Cl 2 , structurally similar to the mineral sarrabusite

    Zeitschrift für Kristallographie - Crystalline Materials · 2026-06-29

    Olga V. Yakubovich, Galina V. Kiriukhina, Larisa V. Shvanskaya, Alexander N. Vasiliev, Anatoly S. Volkov, Olga V. Dimitrova, Peter S. Berdonosov, В. А. Долгих

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