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RESEARCH PAPER · Science China Chemistry · 2011

Structures and properties of functional metal iodates

Chuan‐Fu Sun, Bing‐Ping Yang, Jiang‐Gao Mao

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Structures and properties of functional metal iodatesOriginalBiosynthesis and biological activity of enniatins49PbPt(IO3)6(H2O): a new polar material with two types of stereoactive lone-pairs and a very large SHG response80Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites60Noncentrosymmetric salt inclusion oxides: Role of salt lattices and counter ions in bulk polarity52A New Mixed Halide, Cs2HgI2Cl2: Molecular Engineering for a New Nonlinear Optical Material in the Infrared Region145Synthesis and Structure of Bismuth(III)-Containing Noncentrosymmetric Phosphates, Cs3KBi2M4(PO4)6Cl (M = Mn, Fe). Monoclinic (Cc) and Tetragonal (P43) Polymorphs Templated by Chlorine-Centered Cl(Bi2Cs) Acentric Units5Highlights on inorganic solid state chemistry and energy materials2Syntheses, crystal structures and magnetic properties of three new silver manganese(ii) or manganese(iii) mixed metal iodates10Tl(VO)2O2(IO3)3: a new polar material with a strong SHG response26Zn2(VO4)(IO3): A Novel Polar Zinc(II) Vanadium(V) Iodate with a Large SHG Response94Explorations of a Series of Second Order Nonlinear Optical Materials Based on Monovalent Metal Gold(III) Iodates33Explorations of New Second-Order Nonlinear Optical Materials in the Ternary Rubidium Iodate System: Noncentrosymmetric β-RbIO3(HIO3)2 and Centrosymmetric Rb3(IO3)3(I2O5)(HIO3)4(H2O)59α-AgI3O8 and β-AgI3O8 with Large SHG Responses: Polymerization of IO3 Groups into the I3O8 Polyiodate Anion113In[IO3](OH)2 – New member of hydrous and anhydrous iodate family with indium6Recent advances on second-order NLO materials based on metal iodates328Pb 2 Bi 2 GaB 3 O 11 , a new congruent-melting galloborate containing two types of asymmetric cations with a moderate birefringence5K2Au(IO3)5 and β‐KAu(IO3)4: Polar Materials with Strong SHG Responses Originating from Synergistic Effect of AuO4 and IO3 Units18New Series of Polar and Nonpolar Platinum Iodates A2Pt(IO3)6 (A = H3O, Na, K, Rb, Cs)33Iodide-Iodates M3[IO3]12·Ag4I, M = Bi, Tb, with a Framework Structure and High Second-Harmonic Generation Optical Response19Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect238Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect71Photoconversion Mechanisms and the Origin of Second-Harmonic Generation in Metal Iodates with Wide Transparency, NaLn(IO3)4 (Ln = La, Ce, Sm, and Eu) and NaLa(IO3)4:Ln3+ (Ln = Sm and Eu)32Design and Synthesis of a Series of Novel Mixed Borate and Carbonate Halides21Acentric La3(IO3)8(OH) and La(IO3)2(NO3): Partial Substitution of Iodate Anions in La(IO3)3 by Hydroxide or Nitrate Anion55Synthesis, Crystal Structure, and Topology–Symmetry Analysis of a New Modification of NaIn[IO3]44A Series of Mixed-Metal Germanium Iodates as Second-Order Nonlinear Optical Materials71Synthesis and Crystal Structure of New Indium Iodate (K0.6Na0.4Ba)In[IO3]64LiMg(IO 3 ) 3 : an excellent SHG material designed by single-site aliovalent substitution68Synthesis, structure and characterization of M(IO 3 ) 2 (HIO 3 ) (M = Ca, Sr) as new anhydrous alkaline earth metal bis-iodate hydrogeniodate compounds16TB-mBJ calculation of structural, electronic and optical properties of two monovalent iodates AIO3 (A=Tl, α-Rb)9HBa2.5(IO3)6(I2O5) and HBa(IO3)(I4O11): Explorations of Second-Order Nonlinear Optical Materials in the Alkali-Earth Polyiodate System49Synthesis and Crystal Structure of a New Iodate (Pb0.6Ba0.4)(Pb0.4Ba0.6)[IO3]4 Analogous to Sr[IO3]22A study of composition effects on the bandgaps in a series of new alkali metal aluminum/gallium iodates7Optimal arrangement of π-conjugated anionic groups in hydro-isocyanurates leads to large optical anisotropy and second-harmonic generation effect42CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework132CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework22Synthesis and Crystal Structure of New Iodate Na3Fe[IO3]6 of the A3M[IO3]6 Structural Family (A = Na, K, Rb, Cs, Tl; M = Ti, Fe, Ge, In, Pt)5Ba2[MoO3(OH)(IO3)2]IO3: A Promising SHG Material Featuring a Λ-Shaped Functional Motif Achieved by Universal Mono-Site Substitution50From Ag2Zr(IO3)6 to LaZr(IO3)5F2: A Case of Constructing Wide‐band‐gap Birefringent Materials through Chemical Cosubstitution11Titanium Iodates with a Second-Harmonic-Generation Response8Stabilizing lanthanide periodate compounds by slowing periodate reduction at elevated temperatures with NaBiO3, a sacrificial oxidant0High-Performance Second-Harmonic-Generation (SHG) Materials: New Developments and New Strategies324[ o ‐C 5 H 4 NHOH] 2 [I 7 O 18 (OH)]⋅3 H 2 O: An Organic–Inorganic Hybrid SHG Material Featuring an [I 7 O 18 (OH)] Branched Polyiodate Chain86[o‐C5H4NHOH]2[I7O18(OH)]⋅3 H2O: An Organic–Inorganic Hybrid SHG Material Featuring an [I7O18(OH)] Branched Polyiodate Chain21From borophosphate to fluoroborophosphate: a rational design of fluorine-induced birefringence enhancement33Structure-Properties Relations in Two Iodate Families Studied by Topology-Symmetry Analysis of OD Theory9AMoO3(IO3) (A = Na and K): Two promising optical materials via properly assembling the Λ-shaped basic building units19M4O(IO3)3(I3O7F3)BF4 (M = Pb, Sr): Promising Nonlinear Optical Materials Featuring the Unprecedented Windmill-Shaped [I3O7F3]2– Polyfluoroiodate Anion12K 3 V 2 O 3 F 4 (IO 3 ) 3 : a high-performance SHG crystal containing both five and six-coordinated V 5+ cations33Phase Matchability Transformation in the Infrared Nonlinear Optical Materials with Diamond‐Like Frameworks63Ba 4 Ag 5 (IO 3 ) 6 (I 3 O 8 ) 3 (I 4 O 11 ) 2 : a nonlinear optical crystal containing two types of polyiodate anions16Piezoelectricity and related properties in orthorhombic cadmium diiodate4Structure, optical and luminescence properties of anhydrous samarium iodate Sm 3 (IO 3 ) 9 (HIO 3 ) 46Pressure-induced phase transition and increase of oxygen-iodine coordination in magnesium iodate16Two New Rb3Sc(IO3)6 Polytypes in Proposed Nonlinear Optical Family A3M(IO3)6 (A = K, Rb; M = Sc, In): Topology–Symmetry Analysis, Order–Disorder and Structure–Properties Relation9Chalcohalides: A Rising Type of Second‐Order Nonlinear Optical Materials28Symmetry Analysis of the Complex Polytypism of Layered Rare-Earth Tellurites and Related Selenites: The Case of Introducing Transition Metals6Synthesis and Crystal Structure of Fluoride K2(Ta0.9I0.1)F7 with the Micro-Isomorphic Substitution in the Ta Cationic Position0New Modification of Polar Nonlinear Optical Iodate Fluoride PbF(IO3), the Family MX(IO3), M = Bi, Ba, Pb, X = O, F, (OH) Related to Aurivillius Phases and Similar Iodates3Enhancement of birefringence and refractive index dispersion optimization from iodates to fluorooxoiodates1New layered nonlinear optical iodate Cs 3 Ta(IO 3 ) 8 : topology-symmetry analysis and structure prediction6Growth and Optical Properties of Large-Sized NaVO2(IO3)2(H2O) Crystals for Second-Harmonic Generation Applications12Synthesis and Structure of a New Iodate Cs5[Sc2(IO3)9](IO3)2 with a Complex Framework Based on the Condensation of [Sc(IO3)6] Building Blocks4Novel cesium cerium( iv ) iodate Cs 2 Ce(IO 3 ) 6 : hydrothermal synthesis, crystal structures and thermal stability2Diversity of [M(IO3)6] Building Blocks in Iodate Families and the New Trigonal Polymorph of Cs2HIn(IO3)64Diversity of fundamental building blocks [M(IO3)6] in iodate families and new trigonal polymorph of Cs2HIn(IO3)60From Ba2Bi2Zn(PO4)4 to Ba2Bi2Cu(PO4)4: Rational design of an ultraviolet phosphate with enhanced birefringence2Assisting the Effective Design of an SBBO-Like Vanadium-Iodate Crystal with Mixed Metal Cations2Symmetry Breaking via Anion-Molecule Synergy: Fluorine and Crystalline Water Directed Construction of Noncentrosymmetric Sr(IO2F2)2·2H2O0Rb2HSc(IO3)6 – a new member of the iodate family with a structural unit [M(IO3)6]0Hydrothermal preparation, structures and properties of SrVO(IO3)5: a new alkaline-earth metal oxidovanadium iodate0Negative linear compressibility and phonon softening in Mg ( IO 3 ) 2 under pressure1

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  1. Biosynthesis and biological activity of enniatins

    Die Pharmazie · 2007-08-01

    S Firáková, Bohumil Proksa, M. Šturdíková

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  2. PbPt(IO3)6(H2O): a new polar material with two types of stereoactive lone-pairs and a very large SHG response

    Chemical Communications · 2012-01-01

    Chuan‐Fu Sun, Chun‐Li Hu, Jiang‐Gao Mao

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  3. Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites

    Structure and bonding · 2012-01-01

    Fang Kong, Chuan‐Fu Sun, Bing‐Ping Yang, Jiang‐Gao Mao

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  4. Noncentrosymmetric salt inclusion oxides: Role of salt lattices and counter ions in bulk polarity

    Journal of Solid State Chemistry · 2012-06-20

    J. Palmer West, Shiou‐Jyh Hwu

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  5. A New Mixed Halide, Cs2HgI2Cl2: Molecular Engineering for a New Nonlinear Optical Material in the Infrared Region

    Journal of the American Chemical Society · 2012-08-15

    Gang Zhang, Yanjun Li, Kui Jiang, Hui‐Yi Zeng, Tao Liu, Xingguo Chen, Jingui Qin, Zheshuai Lin, Peizhen Fu, Yicheng Wu, Chuangtian Chen

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  6. Synthesis and Structure of Bismuth(III)-Containing Noncentrosymmetric Phosphates, Cs3KBi2M4(PO4)6Cl (M = Mn, Fe). Monoclinic (Cc) and Tetragonal (P43) Polymorphs Templated by Chlorine-Centered Cl(Bi2Cs) Acentric Units

    Inorganic Chemistry · 2012-08-27

    J. Palmer West, Dino Sulejmanovic, Shiou‐Jyh Hwu, Jian Ping He, Don G. VanDerveer, Boyd Johnson

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  7. Highlights on inorganic solid state chemistry and energy materials

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  8. Syntheses, crystal structures and magnetic properties of three new silver manganese(ii) or manganese(iii) mixed metal iodates

    CrystEngComm · 2013-01-01

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  9. Tl(VO)2O2(IO3)3: a new polar material with a strong SHG response

    Dalton Transactions · 2013-01-01

    Chao Huang, Chun‐Li Hu, Xiang Xu, Bing‐Ping Yang, Jiang‐Gao Mao

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  10. Zn2(VO4)(IO3): A Novel Polar Zinc(II) Vanadium(V) Iodate with a Large SHG Response

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    Bing‐Ping Yang, Chun‐Li Hu, Xiang Xu, Chao Huang, Jiang‐Gao Mao

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  11. Explorations of a Series of Second Order Nonlinear Optical Materials Based on Monovalent Metal Gold(III) Iodates

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  12. Explorations of New Second-Order Nonlinear Optical Materials in the Ternary Rubidium Iodate System: Noncentrosymmetric β-RbIO3(HIO3)2 and Centrosymmetric Rb3(IO3)3(I2O5)(HIO3)4(H2O)

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    Xiang Xu, Bing‐Ping Yang, Chao Huang, Jiang‐Gao Mao

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  13. α-AgI3O8 and β-AgI3O8 with Large SHG Responses: Polymerization of IO3 Groups into the I3O8 Polyiodate Anion

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    Xiang Xu, Chun‐Li Hu, Bingxuan Li, Bing‐Ping Yang, Jiang‐Gao Mao

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  14. In[IO3](OH)2 – New member of hydrous and anhydrous iodate family with indium

    Solid State Sciences · 2014-06-12

    Elena L. Belokoneva, Olga V. Dimitrova, Anatoly S. Volkov

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  15. Recent advances on second-order NLO materials based on metal iodates

    Coordination Chemistry Reviews · 2015-01-25

    Chun‐Li Hu, Jiang‐Gao Mao

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  16. Pb 2 Bi 2 GaB 3 O 11 , a new congruent-melting galloborate containing two types of asymmetric cations with a moderate birefringence

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    Lili Liu, Yun Mo Yang, Linping Li, Zhihua Yang, Shilie Pan

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  17. K2Au(IO3)5 and β‐KAu(IO3)4: Polar Materials with Strong SHG Responses Originating from Synergistic Effect of AuO4 and IO3 Units

    Chemistry - A European Journal · 2016-01-07

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  18. New Series of Polar and Nonpolar Platinum Iodates A2Pt(IO3)6 (A = H3O, Na, K, Rb, Cs)

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  19. Iodide-Iodates M3[IO3]12·Ag4I, M = Bi, Tb, with a Framework Structure and High Second-Harmonic Generation Optical Response

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  20. Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect

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  21. Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect

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  22. Photoconversion Mechanisms and the Origin of Second-Harmonic Generation in Metal Iodates with Wide Transparency, NaLn(IO3)4 (Ln = La, Ce, Sm, and Eu) and NaLa(IO3)4:Ln3+ (Ln = Sm and Eu)

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    Seung‐Jin Oh, Hyung-Gu Kim, Hongil Jo, Tae Gil Lim, Jae Soo Yoo, Kang Min Ok

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  23. Design and Synthesis of a Series of Novel Mixed Borate and Carbonate Halides

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  24. Acentric La3(IO3)8(OH) and La(IO3)2(NO3): Partial Substitution of Iodate Anions in La(IO3)3 by Hydroxide or Nitrate Anion

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  25. Synthesis, Crystal Structure, and Topology–Symmetry Analysis of a New Modification of NaIn[IO3]4

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  26. A Series of Mixed-Metal Germanium Iodates as Second-Order Nonlinear Optical Materials

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  27. Synthesis and Crystal Structure of New Indium Iodate (K0.6Na0.4Ba)In[IO3]6

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  28. LiMg(IO 3 ) 3 : an excellent SHG material designed by single-site aliovalent substitution

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  29. Synthesis, structure and characterization of M(IO 3 ) 2 (HIO 3 ) (M = Ca, Sr) as new anhydrous alkaline earth metal bis-iodate hydrogeniodate compounds

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  30. TB-mBJ calculation of structural, electronic and optical properties of two monovalent iodates AIO3 (A=Tl, α-Rb)

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  31. HBa2.5(IO3)6(I2O5) and HBa(IO3)(I4O11): Explorations of Second-Order Nonlinear Optical Materials in the Alkali-Earth Polyiodate System

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  32. Synthesis and Crystal Structure of a New Iodate (Pb0.6Ba0.4)(Pb0.4Ba0.6)[IO3]4 Analogous to Sr[IO3]2

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    Elena L. Belokoneva, Olga Reutova, Olga V. Dimitrova, Anatoly S. Volkov

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  33. A study of composition effects on the bandgaps in a series of new alkali metal aluminum/gallium iodates

    Dalton Transactions · 2020-01-01

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  34. Optimal arrangement of π-conjugated anionic groups in hydro-isocyanurates leads to large optical anisotropy and second-harmonic generation effect

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  35. CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework

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  36. CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework

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  37. Synthesis and Crystal Structure of New Iodate Na3Fe[IO3]6 of the A3M[IO3]6 Structural Family (A = Na, K, Rb, Cs, Tl; M = Ti, Fe, Ge, In, Pt)

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  38. Ba2[MoO3(OH)(IO3)2]IO3: A Promising SHG Material Featuring a Λ-Shaped Functional Motif Achieved by Universal Mono-Site Substitution

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  39. From Ag2Zr(IO3)6 to LaZr(IO3)5F2: A Case of Constructing Wide‐band‐gap Birefringent Materials through Chemical Cosubstitution

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  41. Stabilizing lanthanide periodate compounds by slowing periodate reduction at elevated temperatures with NaBiO3, a sacrificial oxidant

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  42. High-Performance Second-Harmonic-Generation (SHG) Materials: New Developments and New Strategies

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  43. [ o ‐C 5 H 4 NHOH] 2 [I 7 O 18 (OH)]⋅3 H 2 O: An Organic–Inorganic Hybrid SHG Material Featuring an [I 7 O 18 (OH)] Branched Polyiodate Chain

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  45. From borophosphate to fluoroborophosphate: a rational design of fluorine-induced birefringence enhancement

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  46. Structure-Properties Relations in Two Iodate Families Studied by Topology-Symmetry Analysis of OD Theory

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  47. AMoO3(IO3) (A = Na and K): Two promising optical materials via properly assembling the Λ-shaped basic building units

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  48. M4O(IO3)3(I3O7F3)BF4 (M = Pb, Sr): Promising Nonlinear Optical Materials Featuring the Unprecedented Windmill-Shaped [I3O7F3]2– Polyfluoroiodate Anion

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  50. Phase Matchability Transformation in the Infrared Nonlinear Optical Materials with Diamond‐Like Frameworks

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