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RESEARCH PAPER · Journal of the American Chemical Society · 2009

BaNbO(IO3)5: A New Polar Material with a Very Large SHG Response

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BaNbO(IO3)5: A New Polar Material with a Very Large SHG ResponseOriginalBiosynthesis and biological activity of enniatins49ChemInform Abstract: BaNbO(IO3)5: A New Polar Material with a Very Large SHG Response.0Noncentrosymmetric Polar Oxide Material, Pb3SeO5: Synthesis, Characterization, Electronic Structure Calculations, and Structure−Property Relationships147Syntheses, Crystal Structures, and Properties of Five New Transition Metal Molybdenum(VI) Selenites and Tellurites54Syntheses and crystal structures of four new silver(i) iodates with d 0 -transition metal cations45Syntheses, crystal structures, and properties of three new lanthanum( iii ) vanadium iodates56NaVO2(IO3)2(H2O): A Unique Layered Material Produces A Very Strong SHG Response143Electron and vibrational spectroscopies using DFT, plane waves and pseudopotentials: CASTEP implementation351Growth of Bi2ZnOB2O6 crystal by the Czochralski method17First-principles study of electronic structures and nonlinear optical properties of AMoO3(IO3) (A = Li, Rb and Cs) crystals13Explorations of New Second-Order Nonlinear Optical Materials in the KI-MII -IV-O Systems43Size and Shape Dependent Second Order Nonlinear Optical Properties of Nanomaterials and Their Application in Biological and Chemical Sensing773Alkaline Beryllium Borate NaBeB3O6 and ABe2B3O7 (A = K, Rb) as UV Nonlinear Optical Crystals359Interrelationship of Micro- and Macrostructure with Nonlinear Optical Properties of Simple and Binary Acentric Niobate Crystals7A3V5O14 (A = K+, Rb+, or Tl+), New Polar Oxides with a Tetragonal Tungsten Bronze Related Structural Topology: Synthesis, Structure, and Functional Properties76Novel Noncentrosymmetric Zinc Coordination Polymer Containing an Unusual Zinc Carboxylate−Sulfonate Substructure with a (10,3)-d Topology and Its Second-Harmonic-Generation Properties51Polar or Non-Polar? Syntheses, Crystal Structures, and Optical Properties of Three New Palladium(II) Iodates45A series of new alkali metal indium iodates with isolated or extended anions22Bulk crystal growth and characterization of a new polar polymorph of BaTeMo2O9: α-BaTeMo2O998Inorganic–organic hybrid compounds based on face-sharing octahedral [PbI3]∞ chains: self-assemblies, crystal structures, and ferroelectric, photoluminescence properties41Toward design of multiple-property inorganic–organic hybrid compounds based on face-sharing octahedral iodoplumbate chains50Research progress on mid-IR nonlinear optical crystals with high laser damage threshold in China10New Second-Order NLO Materials Based on Polymeric Borate Clusters and GeO4 Tetrahedra: A Combined Experimental and Theoretical Study69Inorganic Supramolecular Compounds with 3-D Chiral Frameworks Show Potential as Both Mid-IR Second-Order Nonlinear Optical and Piezoelectric Materials132Explorations of New Second-Order Nonlinear Optical Materials in the Potassium Vanadyl Iodate System268Top-Seeded Solution Growth, Morphology, and Properties of a Polar Crystal Cs2TeMo3O1277Synthesis, Characterization, and Structure–Property Relationships in Two New Polar Oxides: Zn2(MoO4)(SeO3) and Zn2(MoO4)(TeO3)80[Ni(en)3][InSbS4]: A One‐Dimensional Polymeric Indium Thioantimonate with a Polar Structure25Structures and properties of functional metal iodates72Anisotropic Thermal Properties of the Nonlinear Optical and Polar Oxide Material Na2TeW2O931Na2CsBe6B5O15: An Alkaline Beryllium Borate as a Deep-UV Nonlinear Optical Crystal318A Highly Thermally Stable Ferroelectric Metal–Organic Framework and Its Thin Film with Substrate Surface Nature Dependent Morphology84BiO(IO3): A New Polar Iodate that Exhibits an Aurivillius-Type (Bi2O2)2+ Layer and a Large SHG Response503Polymorphism of BaTeMo 2 O 9 : A New Polar Polymorph and the Phase Transformation186Alkaline-Alkaline Earth Fluoride Carbonate Crystals ABCO3F (A = K, Rb, Cs; B = Ca, Sr, Ba) as Nonlinear Optical Materials525Rational Synthesis of Noncentrosymmetric Metal–Organic Frameworks for Second-Order Nonlinear Optics1005Bi2(IO4)(IO3)3: A New Potential Infrared Nonlinear Optical Material Containing [IO4]3– Anion111New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)50Synthesis, structure characterization and optical properties of a new lead cadmium borate27Anisotropic thermal properties of the polar crystal Cs2TeMo3O1224A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O1222Cadmium-rare earth oxyborates Cd4ReO(BO3)3 (Re = Y, Gd, Lu): congruently melting compounds with large SHG responses65Cation Effect in Doped BBO and Halogen Anion Effect in Pb2B5O9X (X− = I−, Br−, Cl−)1Crystal growth and optical properties of a noncentrosymmetric molybdenum tellurite, Na2Te3Mo3O1641Luminescent lanthanide metal–organic frameworks with a large SHG response76MgTeMoO6: A neutral layered material showing strong second-harmonic generation110PbPt(IO3)6(H2O): a new polar material with two types of stereoactive lone-pairs and a very large SHG response80Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites60Structure Design and Crystal Growth of UV Nonlinear Borate Materials14Noncentrosymmetric Inorganic Open-Framework Chalcohalides with Strong Middle IR SHG and Red Emission: Ba3AGa5Se10Cl2 (A = Cs, Rb, K)257Probing the linear and nonlinear optical properties of nitrogen-substituted carbon nanotube18Structure, growth and properties of a novel polar material, KSr4B3O921Top‐seeded growth, optical properties and theoretical studies of noncentrosymmetric Te2V2O914Two New Noncentrosymmetric (NCS) Polar Oxides: Syntheses, Characterization, and Structure–Property Relationships in BaMTe2O7 (M = Mg2+ or Zn2+)50Small non-polar complexes exhibiting significant piezoelectric properties: Solvothermal synthesis and crystal structures of MO5V(tren)·H2O (M=Mo and W; tren=tris(2-aminoethyl)amine)7Syntheses, crystal structures and characterizations of new vanadium arsenites and arsenates4Exploratory Investigation of New SHG Materials Based on Galloborates46Investigation of the dielectric, elastic, and piezoelectric properties of Cs2TeMo3O12 crystals22Syntheses, crystal structures and characterizations of two new bismuth(III) arsenites2Noncentrosymmetric Organic Solid and Its Zinc Coordination Polymer with Diamonded Network Prepared from an Ionothermal Reaction: Syntheses, Crystal Structures, and Second-Order Nonlinear Optics Properties58Synthesis, Structure, and Characterization of New Li+ – d0 –Lone-Pair – Oxides: Noncentrosymmetric Polar Li6(Mo2O5)3(SeO3)6 and Centrosymmetric Li2(MO3)(TeO3) (M = Mo6+ or W6+)47Titanyl Iodate – A Promising Material for Infrared Nonlinear Optics Showing Structural Similarities with KTP32Highlights on inorganic solid state chemistry and energy materials2Chemistry of Polar Transition-Metal Oxides1K4TM4(V2O7)2(IO3)4(H2O) (TM = Zn, Ni, Co): a series of quinary mixed metal–vanadium(v)–iodates18Na2Cd7B8O20: a new noncentrosymmetric compound with special [B3O7] units20Pb2TiOF(SeO3)2Cl and Pb2NbO2(SeO3)2Cl: small changes in structure induced a very large SHG enhancement117Syntheses, crystal structures and magnetic properties of three new silver manganese(ii) or manganese(iii) mixed metal iodates10Synthesis, crystal growth and characterization of a new noncentrosymmetric borophosphate: RbPbBP2O836Synthesis, crystal growth, and characterization of the orthorhombic BaTeW2O9: a new polymorph of BaTeW2O925Synthesis, structure, and characterization of a new promising nonlinear optical crystal: Cd5(BO3)3F42Tl(VO)2O2(IO3)3: a new polar material with a strong SHG response26ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units53New Molybdenum(VI) Phosphates: Synthesis, Characterization, and Calculations of Centrosymmetric RbMoO2PO4and Noncentrosymmetric Rb4Mo5P2O2239New Fluoride Carbonates: Centrosymmetric KPb2(CO3)2F and Noncentrosymmetric K2.70Pb5.15(CO3)5F367Synthesis, Structure, and Characterization of Two New Polar Sodium Tungsten Selenites: Na2(WO3)3(SeO3)·2H2O and Na6(W6O19)(SeO3)247Computational Study on Redox-Switchable Second-Order Nonlinear Optical Properties of Totally Inorganic Keggin-Type Polyoxometalate Complexes25Zn2(VO4)(IO3): A Novel Polar Zinc(II) Vanadium(V) Iodate with a Large SHG Response94First Evidence of a Phase Transition in a High‐Pressure Metal Iodate: Structural and Thermal Studies of AgIO3 Polymorphs12Chiral and Noncentrosymmetric Metal–Organic Frameworks Featuring a 2D → 3D Parallel/Parallel Inclined Subpolycatenation27Metal Chalcogenides: A Rich Source of Nonlinear Optical Materials680Explorations of a Series of Second Order Nonlinear Optical Materials Based on Monovalent Metal Gold(III) Iodates33Noncentrosymmetric Cubic CsCdBO3 with Bichromophore23Ab initio calculation of structural, electronic and optical properties of Hg(IO3)27Lanthanide Metal–Organic Frameworks Showing Luminescence in the Visible and Near‐Infrared Regions with Potential for Acetone Sensing137A 2 BiI 5 O 15 (A = K + or Rb + ): two new promising nonlinear optical materials containing [I 3 O 9 ] 3− bridging anionic groups62Dimensionality variations in new zirconium iodates: hydrothermal syntheses, structural determination, and characterization of BaZr(IO 3 ) 6 and K 2 Zr(IO 3 ) 619Optical properties of Nd 3+ and Yb 3+ -doped AgM(IO 3 ) 4 metal iodates: transparent host matrices for mid-IR lasers and nonlinear materials40Synthesis and characterization of Cd 4 YbO(BO 3 ) 3 – a congruent melting cadmium–ytterbium oxyborate with large nonlinear optical properties11Explorations of New Second-Order Nonlinear Optical Materials in the Ternary Rubidium Iodate System: Noncentrosymmetric β-RbIO3(HIO3)2 and Centrosymmetric Rb3(IO3)3(I2O5)(HIO3)4(H2O)59A New UV Nonlinear Optical Material CsZn2B3O7: ZnO4 Tetrahedra Double the Efficiency of Second-Harmonic Generation121Investigation of the second-order nonlinear optical properties of Cs2TeMo3O12 single crystal31α-AgI3O8 and β-AgI3O8 with Large SHG Responses: Polymerization of IO3 Groups into the I3O8 Polyiodate Anion113Li2CdGeS4, A Diamond-Like Semiconductor with Strong Second-Order Optical Nonlinearity in the Infrared and Exceptional Laser Damage Threshold193Series of Lead Oxide Hydroxide Nitrates Obtained by Adjusting the pH Values of the Reaction Systems32Linear and Nonlinear Optical Properties of K3B6O10Br Single Crystal: Experiment and Calculation81Synthesis, Crystal Structure and Thermal Decomposition of the New Cadmium Selenite Chloride, Cd4(SeO3)2OCl210Synthesis, crystal structure and optical properties of two new layered cadmium iodates: Cd(IO3)X (X=Cl, OH)13A series of novel mercury( i ) selenites and tellurites containing SOJT Mo 6+ cations18Lanthanum Lead Oxide Hydroxide Nitrates with a Nonlinear Optical Effect30An non-centrosymmetric mononuclear Zr complex exhibiting UV second-harmonic-generation0Bi 2 Te(IO 3 )O 5 Cl: a novel polar iodate oxychloride exhibiting a second-order nonlinear optical response29ACdCO 3 F (A = K and Rb): new noncentrosymmetric materials with remarkably strong second-harmonic generation (SHG) responses enhanced via π-interaction61Assembly of noncentrosymmetric coordination polymers by the integration of acentric Ba( ii )/Sr( ii ) and Li( i ) coordination polyhedra8Ba 4 AgGa 5 Pn 8 (Pn = P, As): new pnictide-based compounds with nonlinear optical potential30BaBi(SeO 3 ) 2 Cl: a new polar material showing high second-harmonic generation efficiency enhanced by constructive alignment of chloride ions36Effect of cation substitution on structural transition: synthesis, characterization and theoretical studies of NaCa 4 B 3 O 9 , NaCaBO 3 , NaSrBO 3 and Li 4 CaB 2 O 618Macroscopic polarity control with alkali metal cation size and coordination environment in a series of tin iodates82PbGa 4 S 7 : a wide-gap nonlinear optical material91Second-harmonic generation (SHG) and photoluminescence properties of noncentrosymmetric (NCS) layered perovskite solid solutions, CsBi 1−x Eu x Nb 2 O 7 (x = 0, 0.1, and 0.2)30Sr 2 (OH) 3 NO 3 : the first nitrate as a deep UV nonlinear optical material with large SHG responses166Recent advances on second-order NLO materials based on metal iodates328Na2RE2TeO4(BO3)2 (RE = Y, Dy–Lu): Luminescent and Structural Studies on a Series of Mixed Metal Borotellurates51Structures, Thermal Behaviors, and Luminescent Properties of Anhydrous Lanthanum Iodate Polymorphs26Linear electrooptic microscopy : applications to micro and nano-structured materials0RbMgCO3F: A New Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material341Structure-Directing Effect of Alkali Metal Cations in New Molybdenum Selenites, Na2Mo2O5(SeO3)2, K2Mo2O5(SeO3)2, and Rb2Mo3O7(SeO3)315Metal Thiophosphates with Good Mid-infrared Nonlinear Optical Performances: A First-Principles Prediction and Analysis441Crystal growth and anisotropic thermal properties of the nonlinear and polar oxide Cs2TeW3O1213Explorations of New SHG Materials in the Alkali-Metal–Nb5+–Selenite System33Bidenticity-Enhanced Second Harmonic Generation from Pb Chelation in Pb3Mg3TeP2O14169Pb4(OH)4(BrO3)3(NO3): An Example of SHG Crystal in Metal Bromates Containing π-Conjugated Planar Triangle59Versatile Coordination Mode of LiNaB8O13 and α- and β-LiKB8O13 via the Flexible Assembly of Four-Connected B5O10 and B3O7 Groups19Synthesis and characterization of CsSrCO 3 F – a beryllium-free new deep-ultraviolet nonlinear optical material34New fluoroborate Cd 8 B 5 O 15 F with two different isolated borate anions prepared by an open high-temperature solution method7Structural variety in zinc telluro-phosphates: syntheses, crystal structures and characterizations of Sr 2 Zn 3 Te 2 P 2 O 14 , Pb 2 Zn 3 Te 2 P 2 O 14 and Ba 2 Zn 2 TeP 2 O 1119K2Au(IO3)5 and β‐KAu(IO3)4: Polar Materials with Strong SHG Responses Originating from Synergistic Effect of AuO4 and IO3 Units18KSbI6O18: An antimony iodate semiconductor material with cyclic chiral S6-symmetric hexaiodate7Second order nonlinear optical properties of Cs_2TeW_3O_12 single crystal21RbIO3 and RbIO2F2: Two Promising Nonlinear Optical Materials in Mid-IR Region and Influence of Partially Replacing Oxygen with Fluorine for Improving Laser Damage Threshold124New Series of Polar and Nonpolar Platinum Iodates A2Pt(IO3)6 (A = H3O, Na, K, Rb, Cs)33Nonlinear optical (NLO) properties and temperature-dependent photoluminescence in activator-doped noncentrosymmetric (NCS) bismuth tellurite solid solutions, Bi2−Ln TeO5 (Ln = Ce and Eu)8Electronic, Crystal Chemistry, and Nonlinear Optical Property Relationships in the Dugganite A3B3CD2O14 Family148Rb2Na(NO3)3: A Congruently Melting UV-NLO Crystal with a Very Strong Second-Harmonic Generation Response71Crystal growth and optical characteristics of beryllium-free polyphosphate, KLa(PO3)4, a possible deep-ultraviolet nonlinear optical crystal101Synthesis, crystal structure and optical properties of a new nocentrosymmetric borate: Ba7(BO3)3F55BiFSeO 3 : An Excellent SHG Material Designed by Aliovalent Substitution207Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation382Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation129Growth, Properties, and Theoretical Analysis of KBa2(PO3)5 Single Crystal51A High Laser Damage Threshold and a Good Second-Harmonic Generation Response in a New Infrared NLO Material: LiSm3SiS725“All-Three-in-One”: A New Bismuth–Tellurium–Borate Bi3TeBO9 Exhibiting Strong Second Harmonic Generation Response223Mixed-Metal Carbonate Fluorides as Deep-Ultraviolet Nonlinear Optical Materials259Ag 3 I[(MoO 3 ) 2 (IO 3 ) 2 ]: a new polar material synthesized from the structural modulation of molybdenyl iodate architectures by polarizable cation (Ag + ) and anion (I − )6Characterization and optimization of the growth conditions of a novel Cs 2 TeW 3 O 12 piezoelectric crystal5K 8 Ce 2 I 18 O 53 : a novel potassium cerium( iv ) iodate with enhanced visible light driven photocatalytic activity resulting from polar zero dimensional [Ce(IO 3 ) 8 ] 4− units14Li 2 CdGeSe 4 and Li 2 CdSnSe 4 : biaxial nonlinear optical materials with strong infrared second-order responses and laser-induced damage thresholds influenced by photoluminescence54Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect238Bi(IO3)F2: The First Metal Iodate Fluoride with a Very Strong Second Harmonic Generation Effect71Li2HgMS4 (M = Si, Ge, Sn): New Quaternary Diamond-Like Semiconductors for Infrared Laser Frequency Conversion64

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  2. ChemInform Abstract: BaNbO(IO3)5: A New Polar Material with a Very Large SHG Response.

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  5. Syntheses and crystal structures of four new silver(i) iodates with d 0 -transition metal cations

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  6. Syntheses, crystal structures, and properties of three new lanthanum( iii ) vanadium iodates

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  7. NaVO2(IO3)2(H2O): A Unique Layered Material Produces A Very Strong SHG Response

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  13. Alkaline Beryllium Borate NaBeB3O6 and ABe2B3O7 (A = K, Rb) as UV Nonlinear Optical Crystals

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  14. Interrelationship of Micro- and Macrostructure with Nonlinear Optical Properties of Simple and Binary Acentric Niobate Crystals

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  18. A series of new alkali metal indium iodates with isolated or extended anions

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  34. Polymorphism of BaTeMo 2 O 9 : A New Polar Polymorph and the Phase Transformation

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  36. Rational Synthesis of Noncentrosymmetric Metal–Organic Frameworks for Second-Order Nonlinear Optics

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  37. Bi2(IO4)(IO3)3: A New Potential Infrared Nonlinear Optical Material Containing [IO4]3– Anion

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  38. New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)

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