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RESEARCH PAPER · Angewandte Chemie International Edition · 2008

Soluble Direct‐Band‐Gap Semiconductors LiAsS2 and NaAsS2: Large Electronic Structure Effects from Weak As⋅⋅⋅S Interactions and Strong Nonlinear Optical Response

Tarun Kumar Bera, Jung‐Hwan Song, Arthur J Freeman, Joon Ik Jang, John B. Ketterson, Mercouri G. Kanatzidis

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Soluble Direct‐Band‐Gap Semiconductors LiAsS2 and NaAsS2: Large Electronic Structure Effects from Weak As⋅⋅⋅S Interactions and Strong Nonlinear Optical ResponseOriginalChemInform Abstract: Soluble Direct‐Band‐Gap Semiconductors LiAsS2 and NaAsS2: Large Electronic Structure Effects from Weak As×××S Interactions and Strong Nonlinear Optical Response.0Flexible Polar Nanowires of Cs5BiP4Se12 from Weak Interactions between Coordination Complexes: Strong Nonlinear Optical Second Harmonic Generation102Solution Processing of Chalcogenide Semiconductors via Dimensional Reduction239Use of Hydrazine in the Hydrothermal Synthesis of Chalcogenides: the Neutral Framework Material [Mn 2 SnS 4 (N 2 H 4 ) 2 ]52First-principles prediction of an enhanced optical second-harmonic susceptibility of low-dimensional alkali-metal chalcogenides64Synthesis and Characterization of One-Dimensional and Molecular M(tren)InAsS4 (M = Mn, Co, and Zn) Compounds with a Noncondensed AsS33− Unit46Pr4S3[AsS3]2: Praseodym(III)‐Sulfid‐Thioarsenat(III) mit Ketten und Schichten aus kondensierten [SPr4]‐Tetraedern14Syntheses and Characterization of a Series of Silver−Thioantimonates(III) and Thioarsenates(III) Containing Two Types of Silver−Sulfur Chains50KBiMS4 (M=Si, Ge): Synthesis, structure, and electronic structure26A Series of Novel Organically Templated Germanium Antimony Sulfides42Arsenic-Containing Chalcophosphate Molecular Anions17K3B6O10Cl: A New Structure Analogous to Perovskite with a Large Second Harmonic Generation Response and Deep UV Absorption Edge670Syntheses and Characterization of New Mid-Infrared Transparency Compounds: Centric Ba2BiGaS5 and Acentric Ba2BiInS595Stabilization of Noncondensed (AsIIIS3)3– Anions by Coordinating to [MnII(phen)]2+ Complex Cations: a Mixed-Valent Thioarsenate (III, V) {[Mn(phen)]3(AsVS4)(AsIIIS3)}n·nH2O Showing the Coexistence of Antiferromagnetic Order, Photoluminescence, and Nonlinear Optical Properties60Thallium Chalcogenide-Based Wide-Band-Gap Semiconductors: TlGaSe2 for Radiation Detectors97Rb4Sn5P4Se20: A Semimetallic Selenophosphate23Rb4Sn5P4Se20: A Semimetallic Selenophosphate1Dimensional Reduction: A Design Tool for New Radiation Detection Materials247NaSr3Be3B3O9F4: A Promising Deep‐Ultraviolet Nonlinear Optical Material Resulting from the Cooperative Alignment of the [Be3B3O12F]10− Anionic Group369NaSr3Be3B3O9F4: A Promising Deep‐Ultraviolet Nonlinear Optical Material Resulting from the Cooperative Alignment of the [Be3B3O12F]10− Anionic Group67Synthesis, crystal structures, and optical properties of NaCdPnS3 (Pn=As, Sb)49Tl2Hg3Q4 (Q = S, Se, and Te): High-Density, Wide-Band-Gap Semiconductors54Strongly Nonlinear Optical Chalcogenide Thin Films of APSe6 (A=K, Rb) from Spin‐Coating51Strongly Nonlinear Optical Chalcogenide Thin Films of APSe6 (A=K, Rb) from Spin‐Coating8Layered indium chalcogenidoantimonates [Me 2 NH 2 ] 2 In 2 Sb 2 S 7-x Se x (x = 0, 2.20, 4.20, 7) with tunable band gaps and photocatalytic properties51Symmetry preservation in a new noncentrosymmetric lattice comprised of acentric POM clusters residing in bowls of Cs + -based half SOD β-cage9Synthesis, structure, and electronic structure of CsAgGa2Se49Structural Diversity, Optical and Magnetic Properties of a Series of Manganese Thioarsenates with 1,10-Phenanthroline or 2,2′-Bipyridine Ligands: Using Monodentate Methylamine as an Alkalinity Regulator47BaGa2MQ6 (M = Si, Ge; Q = S, Se): a new series of promising IR nonlinear optical materials199Large Crystal Growth and New Crystal Exploration of Mid-Infrared Second-Order Nonlinear Optical Materials56pH-induced solvothermal synthesis and characterization of two novel thioarsenate compounds: Three-dimensional (1,2-pdaH2)0.5As5S8 containing ψ-As(iii)S4 and two-dimensional (NH4)2As8S1312Growth and characterization of BaGa4Se7 crystal136First-principles studies on linear and nonlinear optical effects in Ln4GaSbS9 (Ln=Ce–Nd, Sm, Gd–Tm, Lu)9Na2EuAs2S5, NaEuAsS4, and Na4Eu(AsS4)2: Controlling the Valency of Arsenic in Polysulfide Fluxes22Disconnection Enhances the Second Harmonic Generation Response: Synthesis and Characterization of Ba23Ga8Sb2S38247Synthesis, Structure, and Properties of Li2In2MQ6 (M = Si, Ge; Q = S, Se): A New Series of IR Nonlinear Optical Materials125CsSnI 3 : Semiconductor or Metal? High Electrical Conductivity and Strong Near-Infrared Photoluminescence from a Single Material. High Hole Mobility and Phase-Transitions1203Na2Ge2Se5: A highly nonlinear optical material62Synthesis, structural characterization and optical properties of new compounds: Centrosymmetric Ba2GaMQ5 (M=Sb,Bi; Q=Se,Te), Ba2InSbTe5 and noncentrosymmetric Ba2InSbSe533Synthesis, structure and characterization of two new copper(І)-thioarsenates (ІІІ) constructed by the [AsS3]3− and CuS units25A first-principles investigation of the electronic, elastic, piezoelectric and acoustic properties of K3B6O10Cl11Second order non-linear optical activity of arsenic and antimony dithiolene complexes2The syntheses, structures and properties of three new lanthanoid thioarsenates: the only example of thioarsenate acting as a ligand to a lanthanide complex20Growing Crystalline Chalcogenidoarsenates in Surfactants: From Zero-Dimensional Cluster to Three-Dimensional Framework285Cs2B4SiO9: A Deep‐Ultraviolet Nonlinear Optical Crystal278Cs2B4SiO9: A Deep‐Ultraviolet Nonlinear Optical Crystal224Ab initio study of elasticity, piezoelectricity, and nonlinear optical performance in monoclinic NaAsSe226Heterometallic Clusters [CuSn3S9]5− and [Cu6Sn6S20]10−: Solvothermal Synthesis and Characterization of 4f–3d Thiostannates26Noncentrosymmetric mixed-cation borate: Crystal growth, structure and optical properties of Cs2Ca[B4O5(OH)4]2·8H2O14Metal Chalcogenides: A Rich Source of Nonlinear Optical Materials680Crystalline and Glassy Phases in the Cs/Bi/As/S System8(enH 2 ) 4.5 [In(As V S 4 ) 3 ][As 2 III (μ-S 2 )S 3 ]Cl and (enH 2 )MnAs III As V S 6 : two thioarsenates( iii , v ) with mixed-valent optical properties16[Ni(dap) 3 ] 4 [As 10 Cu 2 S 18 ]: a new thioarsenate containing the rare [As 3 CuS 6 ] cluster with mixed-valence As 2+ /As 3+ ions27Copper substitutions in synthetic miargyrite α-AgSbS2 mineral: Synthesis, characterization and dielectrical properties6Computational design of inorganic nonlinear optical crystals based on a genetic algorithm93Exploring the influence of cationic skeletons on the arrangement of isolated BO 3 groups based on RbMgBO 3 , CsZn 4 (BO 3 ) 3 and Cs 4 Mg 4 (BO 3 ) 422Influence of the cation size on the second harmonic generation response of chiral A(VO 2 ) 2 (PO 4 )·3H 2 O (A = K + , NH 4 + and Rb + )3Noncentrosymmetric chalcohalide NaBa 4 Ge 3 S 10 Cl with large band gap and IR NLO response104Novel thioarsenates {[Mn(2,2′-bipy) 2 (SCN)][Mn(2,2′-bipy)](As V S 4 )} 2 and {[Mn(2,2′-bipy) 2 (SCN)] 2 [As III 2 (S 2 ) 2 S 2 ]}: introducing an anionic second ligand to modify Mn II complex cations of 2,2′-bipyridine20Ag 3 Ga 3 SiSe 8 : a new infrared nonlinear optical material with a chalcopyrite structure34Syntheses, structures, optical properties, and electronic structures of KBaMSe 3 (M = As, Sb)22The interaction between cations and anionic groups inducing SHG enhancement in a series of apatite-like crystals: A first-principles study23Highly efficient infrared optical nonlinearity of a wide-bandgap chalcogenide Li_2CdGeS_422Realgar as a Building Block for Lanthanide Clusters: Encapsulation of a Copper Cluster by a Lanthanide Cluster28Syntheses, structures, and optical properties of Ba 4 Ga 4 SnSe 12 and Ba 6 Ga 2 SnSe 1119A series of new lanthanoid thioarsenates: insights into the influence of lanthanide contraction on the formation of new lanthanoid thioarsenates25A series of new manganese thioarsenates( v ) based on different unsaturated [Mn(amine) x ] 2+ complexes14BaGa 2 SnSe 6 : a new phase-matchable IR nonlinear optical material with strong second harmonic generation response58Synthesis and characterization of a new mid-infrared transparent compound: acentric Ba 5 In 4 Te 4 S 713Tailored Synthesis of a Nonlinear Optical Phosphate with a Short Absorption Edge241Tailored Synthesis of a Nonlinear Optical Phosphate with a Short Absorption Edge60Phase-Change Behavior and Nonlinear Optical Second and Third Harmonic Generation of the One-Dimensional K(1–x)CsxPSe6 and Metastable β-CsPSe662Soft Chemistry Routes8Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS2 and Centric Ba8Hg4S5Se752Syntheses, crystal structures, and NLO properties of the quaternary sulfides RE3Sb0.33SiS7 (RE=La, Pr)24Hybrid Germanium Iodide Perovskite Semiconductors: Active Lone Pairs, Structural Distortions, Direct and Indirect Energy Gaps, and Strong Nonlinear Optical Properties945Pb2Ba3(BO3)3Cl: A Material with Large SHG Enhancement Activated by Pb-Chelated BO3 Groups279The first examples of 1-D organic hybrid lanthanoid thioarsenates based on two [As V S 4 ] 3− linkage modes8Metal Thiophosphates with Good Mid-infrared Nonlinear Optical Performances: A First-Principles Prediction and Analysis441Syntheses, crystal structures and physical properties of three new chalcogenides: NaGaGe 3 Se 8 , K 3 Ga 3 Ge 7 S 20 , and K 3 Ga 3 Ge 7 Se 2018A 3-D net based on weak metallophilic (Cu⋯Cu) interactions4Experimental and theoretical studies on the linear and nonlinear optical properties of lead phosphate crystals LiPbPO 474New fluoroborate Cd 8 B 5 O 15 F with two different isolated borate anions prepared by an open high-temperature solution method7Unsaturated Mn complex decorated hybrid thioarsenates: Syntheses, crystal structures and physical properties11Thioarsenate anions acting as ligands: Solvothermal syntheses, crystal structures and characterizations of transition metal complexes of thioarsenate and polyethyleneamine ligands7Synthesis of heterometallic chalcogenides containing lanthanide and group 13–15 metal elements94The structure and band gap design of high Si doping level Ag1−xGa1−xSixSe2 (x=1/2)15Na 2 BaMQ 4 (M=Ge, Sn; Q=S, Se): Infrared Nonlinear Optical Materials with Excellent Performances and that Undergo Structural Transformations202Na2BaMQ4 (M=Ge, Sn; Q=S, Se): Infrared Nonlinear Optical Materials with Excellent Performances and that Undergo Structural Transformations44Electronic structure of layered quaternary chalcogenide materials for band-gap engineering: The example of Cs2MIIM3IVQ814Facile Hydrazine‐Hydrothermal Syntheses and Characterizations of Two Quaternary Thioarsenates(III): Two‐Dimensional SrAg4As2S6⋅2 H2O and One‐Dimensional BaAgAsS320Na 2 ZnGe 2 S 6 : A New Infrared Nonlinear Optical Material with Good Balance between Large Second-Harmonic Generation Response and High Laser Damage Threshold302Effect of alkali cations on two-dimensional networks of two new quaternary thioarsenates (III) prepared by a facile surfactant-thermal method13Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation382Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation129Recent studies of nonlinear chalcogenide crystals for the mid-IR148Solvothermal syntheses and characterization of three new silver(I)/copper(I)-thioarsenates based on As2+/As3+ ions9Analysis and prediction of mid-IR nonlinear optical metal sulfides with diamond-like structures336Recent achievements on middle and far-infrared second-order nonlinear optical materials433Intrinsic defects and their effects on the optical properties in the nonlinear optical crystal CdSiP 2 : a first-principles study21Na 2 CdGe 2 Q 6 (Q = S, Se): two metal-mixed chalcogenides with phase-matching abilities and large second-harmonic generation responses78Screening novel candidates for mid-IR nonlinear optical materials from I 3 –V–VI 4 compounds51Syntheses, structures and properties of a series of new lanthanide chalcoarsenates(III) containing crown-shaped [As3Q6]3− (Q = S, Se) clusters11Superpolyhedron-Built Second Harmonic Generation Materials Exhibit Large Mid-Infrared Conversion Efficiencies and High Laser-Induced Damage Thresholds101Second harmonic generation response of the cubic chalcogenides Ba(6−x)Srx[Ag(4−y)Sn(y/4)](SnS4)49Mid-Infrared Nonlinear Optical Materials Based on Metal Chalcogenides: Structure–Property Relationship338Na2ZnSn2S6: A mixed-metal thiostannate with large second-harmonic generation response activated by penta-tetrahedral [ZnSn4S14]10− clusters10Noncentrosymmetric quaternary selenide Ba23Ga8Sb2Se38: Synthesis, structure, and optical properties15The Power of Heterometalation through Lithium for Helix Chain-Based Noncentrosymmetric Metal–Organic Frameworks with Tunable Second-Harmonic Generation Effects19LiGaGe2S6: A Chalcogenide with Good Infrared Nonlinear Optical Performance and Low Melting Point56Design and synthesis of a nonlinear optical material BaAl 4 S 7 with a wide band gap inspired from SrB 4 O 764First principle study of nonlinear optical crystals15Synthesis, Structure, and Optical Properties of Antiperovskite-Derived Ba2MQ3X (M = As, Sb; Q = S, Se; X = Cl, Br, I) Chalcohalides27Effect of Element Substitution on Structural Transformation and Optical Performances in I2BaMIVQ4 (I = Li, Na, Cu, and Ag; MIV = Si, Ge, and Sn; Q = S and Se)63Exploring the Surfactant–Thermal Synthesis of Crystalline Functional Thioarsenates48BaM2As2S6 (M = Cd, Hg): Synthesis, crystal structure, optical and electronic properties16MgSiAs: An Unexplored System with Promising Nonlinear Optical Properties53Nonbonding Electrons Driven Strong SHG Effect in Hg2GeSe4: Experimental and Theoretical Investigations61A review on structure-performance relationship toward the optimal design of infrared nonlinear optical materials with balanced performances253Recent advances and future perspectives on infrared nonlinear optical metal halides223A review on the development of infrared nonlinear optical materials with triangular anionic groups38From CuFeS 2 to Ba 6 Cu 2 FeGe 4 S 16 : rational band gap engineering achieves large second-harmonic-generation together with high laser damage threshold22Candidate Inorganic Photovoltaic Materials from Electronic Structure-Based Optical Absorption and Charge Transport Proxies77Sr 6 Cd 2 Sb 6 O 7 S 10 : Strong SHG Response Activated by Highly Polarizable Sb/O/S Groups124Sr6Cd2Sb6O7S10: Strong SHG Response Activated by Highly Polarizable Sb/O/S Groups22First-principles study of dopant stability and related optical properties in CdSiP2 crystal3Chemical Flexibility of Mg in Pnictide Materials: Structure and Properties Diversity27Ba 6 In 6 Zn 4 Se 19 : a high performance infrared nonlinear optical crystal with [InSe 3 ] 3− trigonal planar functional motifs22Two new members in the quaternary Cs–Ag–As–S family with different arrangements of Ag–S and As–S asymmetric building units: syntheses, structures, and theoretical studies14Synthesizing Crystalline Chalcogenidoarsenates in Thiol–Amine Solvent Mixtures26Na4CdGe2S7: A Sodium-Rich Quaternary Wide-Band-Gap Chalcogenide with Two-Dimensional [Ge2CdS7]∞ Layers6AMnAs3S6 (A = Cs, Rb): Phase-Matchable Infrared Nonlinear Optical Functional Motif [As3S6]3– Obtained via Surfactant–Thermal Method32From AgGaS 2 to AgHgPS 4 : vacancy defects and highly distorted HgS 4 tetrahedra double-induced remarkable second-harmonic generation response68Investigation of the second-order nonlinear optical property of Sr6Sb6S173Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials95Ba 2 BS 3 Cl and Ba 5 B 2 S 8 Cl 2 : first alkaline-earth metal thioborate halides with [BS 3 ] units21M 2 As 2 Q 5 (M = Ba, Pb; Q = S, Se): a source of infrared nonlinear optical materials with excellent overall performance activated by multiple discrete arsenate anions70Role of lone-pair electrons in determining the thermal transport behavior of LiAsS 2 : first-principles investigation5Structural diversities in centrosymmetric La 8 S 4 Cl 8 La 12 S 8 Cl 4 [SbS 3 ] 8 and non-centrosymmetric Ln 12 S 8 Cl 8 [SbS 3 ] 4 (Ln = La and Ce): syntheses, crystal and electronic structures, and optical properties10Direct synthesis of nanostructured silver antimony sulfide powders from metal xanthate precursors24Structural Modulation from Cu 3 PS 4 to Cu 5 Zn 0.5 P 2 S 8 : Single-Site Aliovalent-Substitution-Driven Second-Harmonic-Generation Enhancement28A Copper(I)-Thioarsenate(III) Inorganic Framework Directed by [Ni(en)3]2+13AZn4Ga5Se12 (A = K, Rb, or Cs): Infrared Nonlinear Optical Materials with Simultaneous Large Second Harmonic Generation Responses and High Laser-Induced Damage Thresholds34Structure Tuning, Strong Second Harmonic Generation Response, and High Optical Stability of the Polar Semiconductors Na1–xKxAsQ234Dimensionality reduction made high-performance mid-infrared nonlinear halide crystal74Investigation into Structural Variation from 3D to 1D and Strong Second Harmonic Generation of the AHgPS4 (A+ = Na+, K+, Rb+, Cs+) Family26Two Organic Hybrid Manganese Selenoarsenates: The Discovery of One-Dimensional Low-Valent Selenoarsenate(II)10Structural modification from centrosymmetric Rb 4 Hg 2 Ge 2 S 8 to noncentrosymmetric (Na 3 Rb)Hg 2 Ge 2 S 8 : mixed alkali metals strategy for infrared nonlinear optical material design28Recent Development of Non-π-Conjugated Deep Ultraviolet Nonlinear Optical Materials106Ba 3 Zr 2 Cu 4 S 9 : the first quaternary phase of the Ba–Zr–Cu–S system5

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  1. ChemInform Abstract: Soluble Direct‐Band‐Gap Semiconductors LiAsS2 and NaAsS2: Large Electronic Structure Effects from Weak As×××S Interactions and Strong Nonlinear Optical Response.

    ChemInform · 2008-12-04

    Tarun K. Bera, Jung‐Hwan Song, Arthur J Freeman, Joon Ik Jang, John B. Ketterson, Mercouri G. Kanatzidis

    Read original paper ↗ ·

  2. Flexible Polar Nanowires of Cs5BiP4Se12 from Weak Interactions between Coordination Complexes: Strong Nonlinear Optical Second Harmonic Generation

    Journal of the American Chemical Society · 2009-01-30

    In Jae Chung, Jung-Hwan Song, Joon Ik Jang, Arthur J Freeman, John B. Ketterson, Mercouri G. Kanatzidis

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  3. Solution Processing of Chalcogenide Semiconductors via Dimensional Reduction

    Advanced Materials · 2009-04-21

    David B. Mitzi

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  4. Use of Hydrazine in the Hydrothermal Synthesis of Chalcogenides: the Neutral Framework Material [Mn 2 SnS 4 (N 2 H 4 ) 2 ]

    Inorganic Chemistry · 2009-04-23

    Manolis J. Manos, Mercouri G. Kanatzidis

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  5. First-principles prediction of an enhanced optical second-harmonic susceptibility of low-dimensional alkali-metal chalcogenides

    Physical Review B · 2009-06-09

    Jung Hwan Song, Arthur J Freeman, Tarun K. Bera, In Jae Chung, Mercouri G. Kanatzidis

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  6. Synthesis and Characterization of One-Dimensional and Molecular M(tren)InAsS4 (M = Mn, Co, and Zn) Compounds with a Noncondensed AsS33− Unit

    Inorganic Chemistry · 2009-07-31

    Zhenqing Wang, Hongjie Zhang, Cheng Wang

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  7. Pr4S3[AsS3]2: Praseodym(III)‐Sulfid‐Thioarsenat(III) mit Ketten und Schichten aus kondensierten [SPr4]‐Tetraedern

    Zeitschrift für anorganische und allgemeine Chemie · 2009-08-31

    Dong‐Hee Kang, Thomas Schleid

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  8. Syntheses and Characterization of a Series of Silver−Thioantimonates(III) and Thioarsenates(III) Containing Two Types of Silver−Sulfur Chains

    Inorganic Chemistry · 2009-12-28

    Hua–Gang Yao, Peng Zhou, Shou‐Hua Ji, Ren‐Chun Zhang, Min Ji, Yong‐Lin An, Guiling Ning

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  9. KBiMS4 (M=Si, Ge): Synthesis, structure, and electronic structure

    Journal of Solid State Chemistry · 2010-05-07

    Dajiang Mei, Zheshuai Lin, Lei Bai, Jiyong Yao, Peizhen Fu, Yicheng Wu

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  10. A Series of Novel Organically Templated Germanium Antimony Sulfides

    Chemistry - An Asian Journal · 2010-06-10

    Mei‐Ling Feng, Wei‐Wei Xiong, Dong Ye, Jian‐Rong Li, Xiao‐Ying Huang

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  11. Arsenic-Containing Chalcophosphate Molecular Anions

    Inorganic Chemistry · 2010-09-08

    Collin D. Morris, Mercouri G. Kanatzidis

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  12. K3B6O10Cl: A New Structure Analogous to Perovskite with a Large Second Harmonic Generation Response and Deep UV Absorption Edge

    Journal of the American Chemical Society · 2011-05-02

    Hongping Wu, Shilie Pan, Kenneth Reinhard Poeppelmeier, Hongyi Li, Dianzeng Jia, Zhaohui Chen, Xiaoyun Fan, Yun Mo Yang, James M. Rondinelli, Haosu Luo

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  13. Syntheses and Characterization of New Mid-Infrared Transparency Compounds: Centric Ba2BiGaS5 and Acentric Ba2BiInS5

    Inorganic Chemistry · 2011-05-19

    Lei Geng, Wen‐Dan Cheng, Chensheng Lin, Weilong Zhang, Hao Zhang, Zhangzhen He

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  14. Stabilization of Noncondensed (AsIIIS3)3– Anions by Coordinating to [MnII(phen)]2+ Complex Cations: a Mixed-Valent Thioarsenate (III, V) {[Mn(phen)]3(AsVS4)(AsIIIS3)}n·nH2O Showing the Coexistence of Antiferromagnetic Order, Photoluminescence, and Nonlinear Optical Properties

    Inorganic Chemistry · 2011-05-20

    Guang‐Ning Liu, Xiao‐Ming Jiang, Mei‐Feng Wu, Guan‐E Wang, Guo‐Cong Guo, Jin‐Shun Huang

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  15. Thallium Chalcogenide-Based Wide-Band-Gap Semiconductors: TlGaSe2 for Radiation Detectors

    Chemistry of Materials · 2011-05-31

    Simon Johnsen, Zhifu Liu, John A. Peters, Jung-Hwan Song, Sebastian Chirambatte Peter, Christos D. Malliakas, Nam Ki Cho, Hosub Jin, Arthur J Freeman, Bruce W. Wessels, Mercouri G. Kanatzidis

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  16. Rb4Sn5P4Se20: A Semimetallic Selenophosphate

    Angewandte Chemie International Edition · 2011-08-02

    In Jae Chung, Kanishka Biswas, Jung‐Hwan Song, John Androulakis, Konstantinos Chondroudis, Konstantinos Paraskevopoulos, Arthur J Freeman, Mercouri G. Kanatzidis

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  17. Rb4Sn5P4Se20: A Semimetallic Selenophosphate

    Angewandte Chemie · 2011-08-02

    In Jae Chung, Kanishka Biswas, Jung‐Hwan Song, John Androulakis, Konstantinos Chondroudis, Konstantinos Paraskevopoulos, Arthur J Freeman, Mercouri G. Kanatzidis

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  18. Dimensional Reduction: A Design Tool for New Radiation Detection Materials

    Advanced Materials · 2011-08-09

    John Androulakis, Sebastian Chirambatte Peter, Hao Li, Christos D. Malliakas, John A. Peters, Zhifu Liu, Bruce W. Wessels, Jung‐Hwan Song, Hosub Jin, Arthur J Freeman, Mercouri G. Kanatzidis

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  19. NaSr3Be3B3O9F4: A Promising Deep‐Ultraviolet Nonlinear Optical Material Resulting from the Cooperative Alignment of the [Be3B3O12F]10− Anionic Group

    Angewandte Chemie International Edition · 2011-08-24

    Hongwei Huang, Jiyong Yao, Zheshuai Lin, Xiaoyang Wang, Ran He, Wenjiao Yao, Naixia Zhai, Chuangtian Chen

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  20. NaSr3Be3B3O9F4: A Promising Deep‐Ultraviolet Nonlinear Optical Material Resulting from the Cooperative Alignment of the [Be3B3O12F]10− Anionic Group

    Angewandte Chemie · 2011-08-24

    Hongwei Huang, Jiyong Yao, Zheshuai Lin, Xiaoyang Wang, Ran He, Wenjiao Yao, Naixia Zhai, Chuangtian Chen

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  21. Synthesis, crystal structures, and optical properties of NaCdPnS3 (Pn=As, Sb)

    Journal of Alloys and Compounds · 2011-09-11

    Yuandong Wu, Wolfgang Bensch

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  22. Tl2Hg3Q4 (Q = S, Se, and Te): High-Density, Wide-Band-Gap Semiconductors

    Chemistry of Materials · 2011-09-16

    Simon Johnsen, Sebastian Chirambatte Peter, Sandy L. Nguyen, Jung-Hwan Song, Hosub Jin, Arthur J Freeman, Mercouri G. Kanatzidis

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  23. Strongly Nonlinear Optical Chalcogenide Thin Films of APSe6 (A=K, Rb) from Spin‐Coating

    Angewandte Chemie International Edition · 2011-09-20

    In Jae Chung, Myung‐Gil Kim, Joon Ik Jang, Jiaqing He, John B. Ketterson, Mercouri G. Kanatzidis

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  24. Strongly Nonlinear Optical Chalcogenide Thin Films of APSe6 (A=K, Rb) from Spin‐Coating

    Angewandte Chemie · 2011-09-20

    In Jae Chung, Myung‐Gil Kim, Joon Ik Jang, Jiaqing He, John B. Ketterson, Mercouri G. Kanatzidis

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  25. Layered indium chalcogenidoantimonates [Me 2 NH 2 ] 2 In 2 Sb 2 S 7-x Se x (x = 0, 2.20, 4.20, 7) with tunable band gaps and photocatalytic properties

    CrystEngComm · 2011-11-09

    Kai‐Yao Wang, Mei‐Ling Feng, De‐Nian Kong, Shijing Liang, Ling Wu, Xiao‐Ying Huang

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  26. Symmetry preservation in a new noncentrosymmetric lattice comprised of acentric POM clusters residing in bowls of Cs + -based half SOD β-cage

    Chemical Communications · 2011-11-16

    Wendy Lee Queen, J. Palmer West, Shiou‐Jyh Hwu, T. Thao Tran, P. Shiv Halasyamani, Don G. VanDerveer

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  27. Synthesis, structure, and electronic structure of CsAgGa2Se4

    Journal of Solid State Chemistry · 2011-11-17

    Dajiang Mei, Wenlong Yin, Kai Feng, Lei Bai, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  28. Structural Diversity, Optical and Magnetic Properties of a Series of Manganese Thioarsenates with 1,10-Phenanthroline or 2,2′-Bipyridine Ligands: Using Monodentate Methylamine as an Alkalinity Regulator

    Inorganic Chemistry · 2011-12-08

    Guang‐Ning Liu, Guo‐Cong Guo, Feng Chen, Shuai‐Hua Wang, Jing Zhi Sun, Jin‐Shun Huang

    Read original paper ↗ ·

  29. BaGa2MQ6 (M = Si, Ge; Q = S, Se): a new series of promising IR nonlinear optical materials

    Dalton Transactions · 2012-01-01

    Wenlong Yin, Kai Feng, Ran He, Dajiang Mei, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  30. Large Crystal Growth and New Crystal Exploration of Mid-Infrared Second-Order Nonlinear Optical Materials

    Structure and bonding · 2012-01-01

    Xiao‐Ming Jiang, Sheng‐Ping Guo, Hui‐Yi Zeng, Ming‐Jian Zhang, Guo‐Cong Guo

    Read original paper ↗ ·

  31. pH-induced solvothermal synthesis and characterization of two novel thioarsenate compounds: Three-dimensional (1,2-pdaH2)0.5As5S8 containing ψ-As(iii)S4 and two-dimensional (NH4)2As8S13

    CrystEngComm · 2012-01-01

    Ke‐Zhao Du, Mei‐Ling Feng, Jian‐Rong Li, Xiao‐Ying Huang

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  32. Growth and characterization of BaGa4Se7 crystal

    Journal of Crystal Growth · 2012-03-02

    Jiyong Yao, Wenlong Yin, Kai Feng, Xiaomao Li, Dajiang Mei, Qinming Lu, Youbao Ni, Zhengwei Zhang, Zhanggui Hu, Yicheng Wu

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  33. First-principles studies on linear and nonlinear optical effects in Ln4GaSbS9 (Ln=Ce–Nd, Sm, Gd–Tm, Lu)

    Journal of Solid State Chemistry · 2012-03-05

    Liujiang Zhou, Ling Chen, Junqian Li, Li‐Ming Wu

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  34. Na2EuAs2S5, NaEuAsS4, and Na4Eu(AsS4)2: Controlling the Valency of Arsenic in Polysulfide Fluxes

    Inorganic Chemistry · 2012-03-13

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  35. Disconnection Enhances the Second Harmonic Generation Response: Synthesis and Characterization of Ba23Ga8Sb2S38

    Journal of the American Chemical Society · 2012-03-28

    Mei‐Chun Chen, Li‐Ming Wu, Hua Lin, Liujiang Zhou, Ling Chen

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  36. Synthesis, Structure, and Properties of Li2In2MQ6 (M = Si, Ge; Q = S, Se): A New Series of IR Nonlinear Optical Materials

    Inorganic Chemistry · 2012-05-04

    Wenlong Yin, Kai Feng, Wenyu Hao, Jiyong Yao, Yicheng Wu

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  37. CsSnI 3 : Semiconductor or Metal? High Electrical Conductivity and Strong Near-Infrared Photoluminescence from a Single Material. High Hole Mobility and Phase-Transitions

    Journal of the American Chemical Society · 2012-05-11

    In Jae Chung, Jung-Hwan Song, Jino Im, John Androulakis, Christos D. Malliakas, Hao Li, Arthur J Freeman, John T. Kenney, Mercouri G. Kanatzidis

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  38. Na2Ge2Se5: A highly nonlinear optical material

    Journal of Solid State Chemistry · 2012-06-05

    In Jae Chung, Jung Hwan Song, Joon Ik Jang, Arthur J Freeman, Mercouri G. Kanatzidis

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  39. Synthesis, structural characterization and optical properties of new compounds: Centrosymmetric Ba2GaMQ5 (M=Sb,Bi; Q=Se,Te), Ba2InSbTe5 and noncentrosymmetric Ba2InSbSe5

    Journal of Solid State Chemistry · 2012-10-01

    Wenyu Hao, Dajiang Mei, Wenlong Yin, Kai Feng, Jiyong Yao, Yicheng Wu

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  40. Synthesis, structure and characterization of two new copper(І)-thioarsenates (ІІІ) constructed by the [AsS3]3− and CuS units

    Journal of Solid State Chemistry · 2012-10-24

    Hua–Gang Yao, Min Ji, Shou‐Hua Ji, Yong‐Lin An

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  41. A first-principles investigation of the electronic, elastic, piezoelectric and acoustic properties of K3B6O10Cl

    Computational Materials Science · 2012-12-23

    Han Han, Gen Yin, Darshana Wickramaratne

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  42. Second order non-linear optical activity of arsenic and antimony dithiolene complexes

    Dalton Transactions · 2013-01-01

    Joyee Mitra, Kuntal Pal, Sabyasachi Sarkar

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  43. The syntheses, structures and properties of three new lanthanoid thioarsenates: the only example of thioarsenate acting as a ligand to a lanthanide complex

    Dalton Transactions · 2013-01-01

    Jian Zhou, Xing Liu, Rong Li, Litao An, Fei-Long Hu, Rong Chen, Yuanchun Wei

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  44. Growing Crystalline Chalcogenidoarsenates in Surfactants: From Zero-Dimensional Cluster to Three-Dimensional Framework

    Journal of the American Chemical Society · 2013-01-11

    Wei‐Wei Xiong, Eashwer Athresh, Yu Ting Ng, Junfeng Ding, Tom Wu, Qichun Zhang

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  45. Cs2B4SiO9: A Deep‐Ultraviolet Nonlinear Optical Crystal

    Angewandte Chemie International Edition · 2013-02-13

    Hongping Wu, Hao Yu, Shilie Pan, Zhenjun Huang, Zhihua Yang, Xin Su, Kenneth Reinhard Poeppelmeier

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  46. Cs2B4SiO9: A Deep‐Ultraviolet Nonlinear Optical Crystal

    Angewandte Chemie · 2013-02-13

    Hongping Wu, Hongwei Yu, Shilie Pan, Zhenjun Huang, Zhihua Yang, Xin Su, Kenneth Reinhard Poeppelmeier

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  47. Ab initio study of elasticity, piezoelectricity, and nonlinear optical performance in monoclinic NaAsSe2

    Journal of Alloys and Compounds · 2013-03-25

    Zuju Ma, Kechen Wu, Rongjian Sa, Qiaohong Li, Yongfan Zhang

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  48. Heterometallic Clusters [CuSn3S9]5− and [Cu6Sn6S20]10−: Solvothermal Synthesis and Characterization of 4f–3d Thiostannates

    Chemistry - A European Journal · 2013-04-24

    Ruihong Chen, Fang Wang, Chunying Tang, Yong Zhang, Dingxian Jia

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  49. Noncentrosymmetric mixed-cation borate: Crystal growth, structure and optical properties of Cs2Ca[B4O5(OH)4]2·8H2O

    Journal of Crystal Growth · 2013-06-21

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  50. Metal Chalcogenides: A Rich Source of Nonlinear Optical Materials

    Chemistry of Materials · 2013-08-09

    In Jae Chung, Mercouri G. Kanatzidis

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