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RESEARCH PAPER · Chemistry of Materials · 2009

New Polar Oxides: Synthesis, Characterization, Calculations, and Structure−Property Relationships in RbSe2V3O12 and TlSe2V3O12

Hong Chang, Sang‐Hwan Kim, Kang Min Ok, P. Shiv Halasyamani

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New Polar Oxides: Synthesis, Characterization, Calculations, and Structure−Property Relationships in RbSe2V3O12 and TlSe2V3O12OriginalChemInform Abstract: New Polar Oxides: Synthesis, Characterization, Calculations, and Structure—Property Relationships in RbSe3V3O12 and TlSe3V3O12.2New Noncentrosymmetric Material - [N(CH3)4]ZnCl3: Polar Chains of Aligned ZnCl4 Tetrahedra63New thallium iodates—Synthesis, characterization, and calculations of Tl(IO3)3 and Tl4(IO3)6, [Tl+3Tl3+(IO3)6]25Noncentrosymmetric Polar Oxide Material, Pb3SeO5: Synthesis, Characterization, Electronic Structure Calculations, and Structure−Property Relationships147Lone electron-pair enhancement of SHG responses in eulytite-type compounds: A II 3 M III (PO 4 ) 3 (A = Pb, M = Bi; A = Ba, M = Bi, La)34Larger Spontaneous Polarization Ferroelectric Inorganic−Organic Hybrids: [PbI3]∞ Chains Directed Organic Cations Aggregation to Kagomé-Shaped Tubular Architecture110New compounds and structures in the solid state1Syntheses, crystal structures, and properties of three new lanthanum( iii ) vanadium iodates56Polar Hexagonal Tungsten Oxide (HTO) Materials: (1) Synthesis, Characterization, Functional Properties, and Structure−Property Relationships in A2(MoO3)3(SeO3) (A = Rb+ and Tl+) and (2) Classification, Structural Distortions, and Second-Harmonic Generating Properties of Known Polar HTOs104Alkaline Beryllium Borate NaBeB3O6 and ABe2B3O7 (A = K, Rb) as UV Nonlinear Optical Crystals359A3V5O14 (A = K+, Rb+, or Tl+), New Polar Oxides with a Tetragonal Tungsten Bronze Related Structural Topology: Synthesis, Structure, and Functional Properties76Top-Seeded Solution Crystal Growth and Functional Properties of a Polar Material—Na2TeW2O956Polar or Non-Polar? Syntheses, Crystal Structures, and Optical Properties of Three New Palladium(II) Iodates45Syntheses and Crystal Structures of a Series of Alkaline Earth Vanadium Selenites and Tellurites41A series of new phases in the alkali metal–NbV/TaV–SeIV/TeIV–O systems19Inorganic–organic hybrid compounds based on face-sharing octahedral [PbI3]∞ chains: self-assemblies, crystal structures, and ferroelectric, photoluminescence properties41Synthesis and structure of A4V6[Te24+Te6+]O24 (A = K, Rb)—two new quaternary mixed-valent tellurium oxides9Toward design of multiple-property inorganic–organic hybrid compounds based on face-sharing octahedral iodoplumbate chains50New Second-Order NLO Materials Based on Polymeric Borate Clusters and GeO4 Tetrahedra: A Combined Experimental and Theoretical Study69Explorations of New Second-Order Nonlinear Optical Materials in the Potassium Vanadyl Iodate System268[R-C7H16N2][V2Te2O10] and [S-C7H16N2][V2Te2O10]; new polar templated vanadium tellurite enantiomers34Syntheses, Crystal Structures, Magnetic and Luminescent Properties of two Classes of Molybdenum(VI) Rich Quaternary Lanthanide Selenites34Synthesis, Characterization, and Structure–Property Relationships in Two New Polar Oxides: Zn2(MoO4)(SeO3) and Zn2(MoO4)(TeO3)80Anisotropic Thermal Properties of the Nonlinear Optical and Polar Oxide Material Na2TeW2O931Na2CsBe6B5O15: An Alkaline Beryllium Borate as a Deep-UV Nonlinear Optical Crystal318BiO(IO3): A New Polar Iodate that Exhibits an Aurivillius-Type (Bi2O2)2+ Layer and a Large SHG Response503Polymorphism of BaTeMo 2 O 9 : A New Polar Polymorph and the Phase Transformation186New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)50New mixed metal selenites and tellurites containing Pd 2+ ions in a square planar geometry14Cadmium-rare earth oxyborates Cd4ReO(BO3)3 (Re = Y, Gd, Lu): congruently melting compounds with large SHG responses65Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites60Structural Designs and Property Characterizations for Second-Harmonic Generation Materials1Structure Design and Crystal Growth of UV Nonlinear Borate Materials14Syntheses, crystal structures and properties of new lead(ii) or bismuth(iii) selenites and tellurite41Syntheses, crystal structures and SHG properties of a series of polar alkali-metal molybdenum(vi) selenites based on strandberg-type [Mo5O15(SeO3)2]4− polyanion28Structure, growth and properties of a novel polar material, KSr4B3O921Top‐seeded growth, optical properties and theoretical studies of noncentrosymmetric Te2V2O914Two New Noncentrosymmetric (NCS) Polar Oxides: Syntheses, Characterization, and Structure–Property Relationships in BaMTe2O7 (M = Mg2+ or Zn2+)50Syntheses, crystal structures and characterizations of new vanadium arsenites and arsenates4Synthesis, Crystal Structure, and Properties of a Cadmium(II) Complex with the Flexible Ligand (1′H‐[2, 2′]Biimidazoly‐1‐yl)‐acetic Acid10An acentric lanthanide-formate complex: synthesis, structure, ferroelectric and magnetic properties6Synthesis, Structure, and Characterization of New Li+ – d0 –Lone-Pair – Oxides: Noncentrosymmetric Polar Li6(Mo2O5)3(SeO3)6 and Centrosymmetric Li2(MO3)(TeO3) (M = Mo6+ or W6+)47Chemistry of Polar Transition-Metal Oxides1Pb2TiOF(SeO3)2Cl and Pb2NbO2(SeO3)2Cl: small changes in structure induced a very large SHG enhancement117Synthesis, structure, and characterization of a new promising nonlinear optical crystal: Cd5(BO3)3F42ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units53Synthesis, Structure, and Characterization of Two New Polar Sodium Tungsten Selenites: Na2(WO3)3(SeO3)·2H2O and Na6(W6O19)(SeO3)247Large scale synthesis, second-harmonic generation, and piezoelectric properties of a noncentrosymmetric vanadium phosphate, Li2VPO69Zn2(VO4)(IO3): A Novel Polar Zinc(II) Vanadium(V) Iodate with a Large SHG Response94Chiral and Noncentrosymmetric Metal–Organic Frameworks Featuring a 2D → 3D Parallel/Parallel Inclined Subpolycatenation27α-ScVSe2O8, β-ScVSe2O8, and ScVTe2O8: New Quaternary Mixed Metal Oxides Composed of Only Second-Order Jahn–Teller Distortive Cations34Synthesis, crystal structure and optical properties of Ba5V3O12F18From an Open Framework to a Layered and a Hexagonal Tungsten Oxide Structure: Controlled Transformation Reactions of an Extended Solid-State Material, Cs3Ga7(SeO3)12 to Ga(OH)(SeO3) and KGa3(SeO4)2(OH)613Sodium–rare earth carbonates with shorite structure and large second harmonic generation response44Noncentrosymmetric YVSe2O8 and Centrosymmetric YVTe2O8: Macroscopic Centricities Influenced by the Size of Lone Pair Cation Linkers63Helical ∞1[Pb2O] Chains in Polymorphs of Pb2O(C6H5COO)211Na4La2(CO3)5 and CsNa5Ca5(CO3)8: Two New Carbonates as UV Nonlinear Optical Materials65Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons67Synthesis, Structure and Physical Properties of A Novel 2D Cd(II) Coordination Polymer Involving 4-Thiopyridine Based on in situ Formation from 4,4'-Dithiodipyridine1A series of novel mercury( i ) selenites and tellurites containing SOJT Mo 6+ cations18Synthesis and Crystal Structure of Mn3(Sb2O2)(VO4)2–x(SbO3)xCl2 (0.08 < x < 0.13), a Vanadium Oxochloride with a VV – SbIII Split Position1Synthesis, crystal structure and magnetic property of a new cobalt(II) vanadate9Enhanced Photocatalytic Activity of N-doped Li2VPO6 Under Visible Light Irradiation5Theoretical exploration to the cation effect on the second-order nonlinear optical properties of Strandberg-type polyoxometalates3Cs(TaO 2 ) 3 (SeO 3 ) 2 and Cs(TiOF) 3 (SeO 3 ) 2 : Structural and Second Harmonic Generation Changes Induced by the Different d 0 -TM Coordination Octahedra67Synthesis, crystal structure and non-linear optical properties of inorganic–organic hybrid compound based on face-sharing octahedral [PbBr3]∞ chains9Synthesis, crystal structures and properties of lead phosphite compounds27Structure-Directing Effect of Alkali Metal Cations in New Molybdenum Selenites, Na2Mo2O5(SeO3)2, K2Mo2O5(SeO3)2, and Rb2Mo3O7(SeO3)315Symmetrically Related Construction and Optical Properties of Two Noncentrosymmetric 3D Iodides of d10 Cation (Cu+, Ag+) Based on the N-Benzylpyridinium and Its Supramolecular Interactions73Explorations of New SHG Materials in the Alkali-Metal–Nb5+–Selenite System33A series of new silver selenites with d 0 -TM cations19Three iodocuprate hybrids symmetrically modulated by positional isomers and the chiral conformation of N-benzyl-methylpyridinium36Three new phosphates with isolated P 2 O 7 units: noncentrosymmetric Cs 2 Ba 3 (P 2 O 7 ) 2 and centrosymmetric Cs 2 BaP 2 O 7 and LiCsBaP 2 O 768LnBSb2O8 (Ln = Sm, Eu, Gd, Tb): A Series of Lanthanide Boroantimonates with Unusual 3D Anionic Structures15Synthesis, Structure, and Antibacterial Activity of a Thallium(III)-Containing Polyoxometalate, [Tl2{B-β-SiW8O30(OH)}2]12–11Syntheses, Crystal Structures, and Properties of Two Quaternary Selenite/Tellurite‐Nitrates with Formula of Bi(SeO 3 )(NO 3 ) and Bi 3 (μ 3 ‐OH)(TeO 3 ) 3 (NO 3 ) 216New vanadium tellurites: Syntheses, structures, optical properties of noncentrosymmetric VTeO 4 (OH), centrosymmetric Ba 2 V 4 O 8 (Te 3 O 10 )12Two Zeolitic Open-Framework Aluminoborates Directed by Similar Zn-Complexes23ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap140ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap36Crystal Structure, Dielectric Characteristics and Conduction Mechanism of a New Hybrid Material, Tetra(Phenylpiperazinium) Decachlorotriplumbate(II)7New quaternary alkali metal cadmium selenites, A 2 Cd(SeO 3 ) 2 (A = K, Rb, and Cs) and Li 2 Cd 3 (SeO 3 ) 43Pb 10 V 6 O 25 : A new lead vanadate with apatite structure3Theoretical study on Pb2VO2F5: large birefringence derived from optical anisotropies of VO2F4 groups15A(VO 2 F)(SeO 3 ) (A = Sr, Ba) and Ba(MOF 2 )(TeO 4 ) (M = Mo, W): first examples of alkali-earth selenites/tellurites with a fluorinated d 0 -TM octahedron33Ion-induced structural and optical performance evolution in LBO-like crystals: experimental and theoretical investigation13Pb 3 (SeO 3 )Br 4 : a new nonlinear optical material with enhanced SHG response designed via an ion-substitution strategy36RbSe 3 B 2 O 9 (OH) and CsSe 3 B 2 O 9 (OH): one dimensional boroselenite-based anionic frameworks with second harmonic generation properties15LiNa4B15O25: Featuring Unprecedented B15O30 Fundamental Building Block and Deep-UV Cutoff Edge20A Series of Mixed-Metal Germanium Iodates as Second-Order Nonlinear Optical Materials71Synergetic Influence of Alkali-Metal and Lone-Pair Cations on Frameworks of Tellurites15Non-centrosymmetric BaNaP3O9 with a short deep-ultraviolet cutoff edge14NaCa4V5O17 with isolated V2O7 dimer and V3O10 trimer exhibiting a large birefringence18Excellent Infrared Nonlinear Optical Crystals BaMO(IO3)5 (M = V, Ta) Predicted by First Principle Calculations9The Rubidium Barium Borate Resulting from B7O15 Fundamental Building Block Exhibits DUV Cutoff Edge17Hybrid organic-inorganic bismuth(III)-based material [4-NH2C5H4NH]7[BiCl6]2Cl. Crystal structure, dielectric properties and molecular motions of 4-aminopyridinium cations9Syntheses, structures, anomalous phase transition and optical properties of two new polymorphic α- and β-LiMoPO 611HBa2.5(IO3)6(I2O5) and HBa(IO3)(I4O11): Explorations of Second-Order Nonlinear Optical Materials in the Alkali-Earth Polyiodate System49Anisotropic proton conduction realized by a layered vanadium selenite single crystal18Hexagonal tungsten oxides with large bandgaps synthesized by a chemical substitution method31Enhancement of Second-Order Optical Nonlinearity in a Lutetium Selenite by Monodentate Anion Partial Substitution58AGa 3 F 6 (SeO 3 ) 2 (A = Rb, Cs): A New Type of Phase-Matchable Hexagonal Tungsten Oxide Material with Strong Second-Harmonic Generation Responses63Octahedral Lattice Distortion-Driven Ferroelectricity and Canted Antiferromagnetism in Oxalate and Phenanthrolin Ligand-Based Chain Molecular Magnets [{Fe(Δ)Fe(Λ)}1–x{Cr(Δ)Cr(Λ)}x(ox)2(phen)2]n (x = 0, 0.1, and 0.5)3Stuffed Tridymite Structures: Synthesis, Structure, Second Harmonic Generation, Optical, and Multiferroic Properties14In situ hydrothermal synthesis of polar second-order nonlinear optical selenate Na 5 (SeO 4 )(HSeO 4 ) 3 (H 2 O) 219Synthesis, Structure, Characterization, and Calculation of a Noncentrosymmetric Fluorine-Containing Indium Iodate, Ba[InF3(IO3)2]10Wide bandgaps and strong SHG responses of hetero-oxyfluorides by dual-fluorination-directed bandgap engineering28Flux synthesis, crystal structure, and characterization of a gamma-vanadate selenite polymorph1Designing new polar materials1One-Side Capping in Two-Dimensional WO 3 -Type Materials Leading to Strong Second-Harmonic Response29Designing a deep-UV nonlinear optical monofluorophosphate22Synthesis, crystal structure, vibrational studies, optical properties and DFT calculation of a new Bi(III) halide complex: (C9H14N3)4[Bi2Cl11][BiCl6].4H2O3[M(OH) 2 ] 3 (IO 3 )(SeO 4 )·H 2 O (M = Ga and In): metal iodate–selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology20Synthesis, structures and properties of two new selenite optical materials: K 2 Zn 3 Se 4 O 12 and K 4 Zn 3 V 4 Se 2 O 192Syntheses, Crystal Structure, and Second Harmonic Generation Response of Noncentrosymmetric Layered Selenites and Tellurites of Antimony(V), ASb 3 X 2 O 12 (A = K, Rb, Cs, Tl; X = Se, Te)17Advances in aliovalent substitution strategy for the design and synthesis of nonlinear optical materials: d0 transition metal/gallium iodates and selenites71Investigation of Hybrid Organic-Inorganic Dihydrogen Phosphate by Hirshfeld Surface Analysis and Quantum Chemical Analysis0Syntheses and characterization of quaternary selenites and tellurite of antimony, NaSbSe2O7, AgSbSe2O7 and Na2Sb4Te2O140High-Performance InSe Photodetector Induced by Synergetic Surface Plasmon Resonance and Surface Engineering31Unveiling the recently synthesis noncentrosymmetric layered ASb3X2O12 (A = K, Rb, Cs, Tl; X = Se, Te) via first principles calculations1A HTO‐Type Nonlinear Optical Fluorophosphate with Ultrawide Bandgap16In Situ Generation of Poly(3,4‐ethylenedioxythiophene)/Ag2SeO3 Nanohybrids at Hexane/Water Interface for Photodegradation of Organic Dyes6Recent achievements of d0 transition-metal-based oxyfluorides: Crystal chemistry and application in second-order NLO materials10Thermodynamic and electronic properties of the solid Na 2 O − MoO 3 − UO 3 system: A combined experimental and first-principles study1Cd/V Ratio-Driven Centrosymmetric Transition of Crystal Structures in Cesium Cadmium Vanadate Oxychlorides Cs 3 CdV 4 O 12 Cl and CsCdV 2 O 6 Cl0

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  1. ChemInform Abstract: New Polar Oxides: Synthesis, Characterization, Calculations, and Structure—Property Relationships in RbSe3V3O12 and TlSe3V3O12.

    ChemInform · 2009-07-09

    Hong Chang, Sang‐Hwan Kim, Kang Min Ok, P. Shiv Halasyamani

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  2. New Noncentrosymmetric Material - [N(CH3)4]ZnCl3: Polar Chains of Aligned ZnCl4 Tetrahedra

    Inorganic Chemistry · 2009-08-05

    Myung‐Ho Choi, Sang‐Hwan Kim, Hong‐Young Chang, P. Shiv Halasyamani, Kang Min Ok

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  3. New thallium iodates—Synthesis, characterization, and calculations of Tl(IO3)3 and Tl4(IO3)6, [Tl+3Tl3+(IO3)6]

    Journal of Solid State Chemistry · 2009-09-24

    Jeongho Yeon, Sang‐Hwan Kim, P. Shiv Halasyamani

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  4. Noncentrosymmetric Polar Oxide Material, Pb3SeO5: Synthesis, Characterization, Electronic Structure Calculations, and Structure−Property Relationships

    Chemistry of Materials · 2009-10-12

    Sang‐Hwan Kim, Jeongho Yeon, P. Shiv Halasyamani

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  5. Lone electron-pair enhancement of SHG responses in eulytite-type compounds: A II 3 M III (PO 4 ) 3 (A = Pb, M = Bi; A = Ba, M = Bi, La)

    Dalton Transactions · 2009-12-15

    Weilong Zhang, Xinsong Lin, Hao Zhang, Jin-Yun Wang, Chen- Sheng Lin, Zhangzhen He, Wen‐Dan Cheng

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  6. Larger Spontaneous Polarization Ferroelectric Inorganic−Organic Hybrids: [PbI3]∞ Chains Directed Organic Cations Aggregation to Kagomé-Shaped Tubular Architecture

    Journal of the American Chemical Society · 2009-12-16

    Hai-Rong Zhao, Dong-Ping Li, Xiao‐Ming Ren, You Song, Wanqin Jin

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  7. New compounds and structures in the solid state

    Annual Reports Section A (Inorganic Chemistry) · 2010-01-01

    Edmund J. Cussen

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  8. Syntheses, crystal structures, and properties of three new lanthanum( iii ) vanadium iodates

    Dalton Transactions · 2010-01-01

    Chuan‐Fu Sun, Ting Hu, Xiang Xu, Jiang‐Gao Mao

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  9. Polar Hexagonal Tungsten Oxide (HTO) Materials: (1) Synthesis, Characterization, Functional Properties, and Structure−Property Relationships in A2(MoO3)3(SeO3) (A = Rb+ and Tl+) and (2) Classification, Structural Distortions, and Second-Harmonic Generating Properties of Known Polar HTOs

    Chemistry of Materials · 2010-04-27

    Hong Chang, Sun Woo Kim, P. Shiv Halasyamani

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  10. Alkaline Beryllium Borate NaBeB3O6 and ABe2B3O7 (A = K, Rb) as UV Nonlinear Optical Crystals

    Journal of the American Chemical Society · 2010-06-02

    Shichao Wang, Ning Ye, Wei Li, Dan Zhao

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  11. A3V5O14 (A = K+, Rb+, or Tl+), New Polar Oxides with a Tetragonal Tungsten Bronze Related Structural Topology: Synthesis, Structure, and Functional Properties

    Inorganic Chemistry · 2010-07-07

    Jeongho Yeon, Sang‐Hwan Kim, P. Shiv Halasyamani

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  12. Top-Seeded Solution Crystal Growth and Functional Properties of a Polar Material—Na2TeW2O9

    Crystal Growth & Design · 2010-07-21

    Weiguo Zhang, Feng Li, Sang‐Hwan Kim, P. Shiv Halasyamani

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  13. Polar or Non-Polar? Syntheses, Crystal Structures, and Optical Properties of Three New Palladium(II) Iodates

    Inorganic Chemistry · 2010-09-20

    Chuan‐Fu Sun, Chun‐Li Hu, Xiang Xu, Jiang‐Gao Mao

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  14. Syntheses and Crystal Structures of a Series of Alkaline Earth Vanadium Selenites and Tellurites

    Inorganic Chemistry · 2010-11-23

    Suyun Zhang, Chun‐Li Hu, Chuan‐Fu Sun, Jiang‐Gao Mao

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  15. A series of new phases in the alkali metal–NbV/TaV–SeIV/TeIV–O systems

    Dalton Transactions · 2011-01-01

    Qian-Hua Gu, Chun‐Li Hu, Jian‐Han Zhang, Jiang‐Gao Mao

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  16. Inorganic–organic hybrid compounds based on face-sharing octahedral [PbI3]∞ chains: self-assemblies, crystal structures, and ferroelectric, photoluminescence properties

    Dalton Transactions · 2011-01-01

    Hai‐Bao Duan, Hai-Rong Zhao, Xiao‐Ming Ren, Hong Zhou, Zhengfang Tian, Wanqin Jin

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  17. Synthesis and structure of A4V6[Te24+Te6+]O24 (A = K, Rb)—two new quaternary mixed-valent tellurium oxides

    Dalton Transactions · 2011-01-01

    Tianxiang Zhu, Jingui Qin, P. Shiv Halasyamani

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  18. Toward design of multiple-property inorganic–organic hybrid compounds based on face-sharing octahedral iodoplumbate chains

    Dalton Transactions · 2011-01-01

    Shun‐Ping Zhao, Xiao‐Ming Ren

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  19. New Second-Order NLO Materials Based on Polymeric Borate Clusters and GeO4 Tetrahedra: A Combined Experimental and Theoretical Study

    Inorganic Chemistry · 2011-01-13

    Jian‐Han Zhang, Chun‐Li Hu, Xiang Xu, Fang Kong, Jiang‐Gao Mao

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  20. Explorations of New Second-Order Nonlinear Optical Materials in the Potassium Vanadyl Iodate System

    Journal of the American Chemical Society · 2011-03-23

    Chuan‐Fu Sun, Chun‐Li Hu, Xiang Xu, Bing‐Ping Yang, Jiang‐Gao Mao

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  21. [R-C7H16N2][V2Te2O10] and [S-C7H16N2][V2Te2O10]; new polar templated vanadium tellurite enantiomers

    Journal of Solid State Chemistry · 2011-04-20

    Ethan C. Glor, Samuel M. Blau, Jeongho Yeon, Mat­thias Zeller, P. Shiv Halasyamani, Joshua Schrier, Alexander J. Norquist

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  22. Syntheses, Crystal Structures, Magnetic and Luminescent Properties of two Classes of Molybdenum(VI) Rich Quaternary Lanthanide Selenites

    Inorganic Chemistry · 2011-04-28

    Suyun Zhang, Jiang‐Gao Mao

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  23. Synthesis, Characterization, and Structure–Property Relationships in Two New Polar Oxides: Zn2(MoO4)(SeO3) and Zn2(MoO4)(TeO3)

    Inorganic Chemistry · 2011-05-10

    Sau Doan Nguyen, Sang‐Hwan Kim, P. Shiv Halasyamani

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  24. Anisotropic Thermal Properties of the Nonlinear Optical and Polar Oxide Material Na2TeW2O9

    Crystal Growth & Design · 2011-06-13

    Weiguo Zhang, P. Shiv Halasyamani, Zeliang Gao, Shanpeng Wang, Jian Wang, Xutang Tao

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  25. Na2CsBe6B5O15: An Alkaline Beryllium Borate as a Deep-UV Nonlinear Optical Crystal

    Journal of the American Chemical Society · 2011-07-08

    Shichao Wang, Ning Ye

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  26. BiO(IO3): A New Polar Iodate that Exhibits an Aurivillius-Type (Bi2O2)2+ Layer and a Large SHG Response

    Journal of the American Chemical Society · 2011-07-21

    Sau Doan Nguyen, Jeongho Yeon, Sang‐Hwan Kim, P. Shiv Halasyamani

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  27. Polymorphism of BaTeMo 2 O 9 : A New Polar Polymorph and the Phase Transformation

    Chemistry of Materials · 2011-07-25

    Junjie Zhang, Zhonghan Zhang, Weiguo Zhang, Qingxin Zheng, Youxuan Sun, Chengqian Zhang, Xutang Tao

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  28. New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)

    Inorganic Chemistry · 2011-12-06

    Jeongho Yeon, Sang‐Hwan Kim, Sau Doan Nguyen, Hana Lee, P. Shiv Halasyamani

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  29. New mixed metal selenites and tellurites containing Pd 2+ ions in a square planar geometry

    Dalton Transactions · 2011-12-16

    Suyun Zhang, Chun‐Li Hu, Jiang‐Gao Mao

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  30. Cadmium-rare earth oxyborates Cd4ReO(BO3)3 (Re = Y, Gd, Lu): congruently melting compounds with large SHG responses

    Journal of Materials Chemistry · 2012-01-01

    Guohong Zou, Zuju Ma, Kechen Wu, Ning Ye

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  31. Second-Order Nonlinear Optical Materials Based on Metal Iodates, Selenites, and Tellurites

    Structure and bonding · 2012-01-01

    Fang Kong, Chuan‐Fu Sun, Bing‐Ping Yang, Jiang‐Gao Mao

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  32. Structural Designs and Property Characterizations for Second-Harmonic Generation Materials

    Structure and bonding · 2012-01-01

    Wen‐Dan Cheng, Chensheng Lin, Weilong Zhang, Hao Zhang

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  33. Structure Design and Crystal Growth of UV Nonlinear Borate Materials

    Structure and bonding · 2012-01-01

    Ning Ye

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  34. Syntheses, crystal structures and properties of new lead(ii) or bismuth(iii) selenites and tellurite

    Dalton Transactions · 2012-01-01

    Suyun Zhang, Chun‐Li Hu, Pei-Xin Li, Hai‐Long Jiang, Jiang‐Gao Mao

    Read original paper ↗ ·

  35. Syntheses, crystal structures and SHG properties of a series of polar alkali-metal molybdenum(vi) selenites based on strandberg-type [Mo5O15(SeO3)2]4− polyanion

    Dalton Transactions · 2012-01-01

    Fang Kong, Chun‐Li Hu, Xiang Xu, Tianhua Zhou, Jiang‐Gao Mao

    Read original paper ↗ ·

  36. Structure, growth and properties of a novel polar material, KSr4B3O9

    Journal of Solid State Chemistry · 2012-01-20

    Wenwu Zhao, Shilie Pan, Yongjiang Wang, Zhihua Yang, Xian Wang, Jian Wei Han

    Read original paper ↗ ·

  37. Top‐seeded growth, optical properties and theoretical studies of noncentrosymmetric Te2V2O9

    Crystal Research and Technology · 2012-01-31

    Wenlin Zhang, Xiaoqing Wang, Guangqiu Shen, Dezhong Shen

    Read original paper ↗ ·

  38. Two New Noncentrosymmetric (NCS) Polar Oxides: Syntheses, Characterization, and Structure–Property Relationships in BaMTe2O7 (M = Mg2+ or Zn2+)

    Inorganic Chemistry · 2012-02-01

    Jeongho Yeon, Sang‐Hwan Kim, Sau Doan Nguyen, Hana Lee, P. Shiv Halasyamani

    Read original paper ↗ ·

  39. Syntheses, crystal structures and characterizations of new vanadium arsenites and arsenates

    Journal of Solid State Chemistry · 2012-04-21

    Junhui Liu, Zhangzhen He, Fang Kong, Xiang Xu, Chuan‐Fu Sun, Jiang‐Gao Mao

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  40. Synthesis, Crystal Structure, and Properties of a Cadmium(II) Complex with the Flexible Ligand (1′H‐[2, 2′]Biimidazoly‐1‐yl)‐acetic Acid

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  41. An acentric lanthanide-formate complex: synthesis, structure, ferroelectric and magnetic properties

    Journal of Rare Earths · 2012-08-01

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  42. Synthesis, Structure, and Characterization of New Li+ – d0 –Lone-Pair – Oxides: Noncentrosymmetric Polar Li6(Mo2O5)3(SeO3)6 and Centrosymmetric Li2(MO3)(TeO3) (M = Mo6+ or W6+)

    Inorganic Chemistry · 2012-08-23

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  43. Chemistry of Polar Transition-Metal Oxides

    Elsevier eBooks · 2013-01-01

    P. Shiv Halasyamani

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  44. Pb2TiOF(SeO3)2Cl and Pb2NbO2(SeO3)2Cl: small changes in structure induced a very large SHG enhancement

    Chemical Communications · 2013-01-01

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  45. Synthesis, structure, and characterization of a new promising nonlinear optical crystal: Cd5(BO3)3F

    CrystEngComm · 2013-01-01

    Guohong Zou, Liyuan Zhang, Ning Ye

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  46. ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units

    RSC Advances · 2013-01-01

    Sangen Zhao, Junhua Luo, Pan Zhou, Shuquan Zhang, Zhihua Sun, Maochun Hong

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  47. Synthesis, Structure, and Characterization of Two New Polar Sodium Tungsten Selenites: Na2(WO3)3(SeO3)·2H2O and Na6(W6O19)(SeO3)2

    Inorganic Chemistry · 2013-02-20

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  48. Large scale synthesis, second-harmonic generation, and piezoelectric properties of a noncentrosymmetric vanadium phosphate, Li2VPO6

    Journal of Solid State Chemistry · 2013-03-19

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  49. Zn2(VO4)(IO3): A Novel Polar Zinc(II) Vanadium(V) Iodate with a Large SHG Response

    Inorganic Chemistry · 2013-04-05

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  50. Chiral and Noncentrosymmetric Metal–Organic Frameworks Featuring a 2D → 3D Parallel/Parallel Inclined Subpolycatenation

    Crystal Growth & Design · 2013-07-10

    Xiao-Qiang Yao, Jin‐Song Hu, Mingdao Zhang, Ling Qin, Yi‐Zhi Li, Zijian Guo, He‐Gen Zheng

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