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RESEARCH PAPER · Dalton Transactions · 2012

ZnIO3(OH): a new layered noncentrosymmetric polar iodate – hydrothermal synthesis, crystal structure, and second-harmonic generating (SHG) properties

Dong Woo Lee, Saet Byeol Kim, Kang Min Ok

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ZnIO3(OH): a new layered noncentrosymmetric polar iodate – hydrothermal synthesis, crystal structure, and second-harmonic generating (SHG) propertiesOriginalK4TM4(V2O7)2(IO3)4(H2O) (TM = Zn, Ni, Co): a series of quinary mixed metal–vanadium(v)–iodates18Tl(VO)2O2(IO3)3: a new polar material with a strong SHG response26ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units53Zn2(VO4)(IO3): A Novel Polar Zinc(II) Vanadium(V) Iodate with a Large SHG Response94Synthesis, growth, structural, thermal, optical properties of new metal-organic crystals: Methyltriphenylphosphonium iodide thiourea and methyltriphenylphosphonium iodide chloroform hemisolvate15Explorations of a Series of Second Order Nonlinear Optical Materials Based on Monovalent Metal Gold(III) Iodates33Sr 4 B 10 O 18 (OH) 2 ·2H 2 O: a new UV nonlinear optical material with a [B 10 O 23 ] 16− building block53Second harmonic generation by micropowders: a revision of the Kurtz–Perry method and its practical application40Explorations of New Second-Order Nonlinear Optical Materials in the Ternary Rubidium Iodate System: Noncentrosymmetric β-RbIO3(HIO3)2 and Centrosymmetric Rb3(IO3)3(I2O5)(HIO3)4(H2O)59A New UV Nonlinear Optical Material CsZn2B3O7: ZnO4 Tetrahedra Double the Efficiency of Second-Harmonic Generation121Variable Framework Structures and Centricities in Alkali Metal Yttrium Selenites, AY(SeO3)2 (A = Na, K, Rb, and Cs)51α-AgI3O8 and β-AgI3O8 with Large SHG Responses: Polymerization of IO3 Groups into the I3O8 Polyiodate Anion113In[IO3](OH)2 – New member of hydrous and anhydrous iodate family with indium6Synthesis, crystal structure and optical properties of two new layered cadmium iodates: Cd(IO3)X (X=Cl, OH)13Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework36Macroscopic polarity control with alkali metal cation size and coordination environment in a series of tin iodates82Recent advances on second-order NLO materials based on metal iodates328Two New Crystals in LimCsnBm+nO2(m+n) (m + n = 5, 7; m > n) Series: Noncentrosymmetric Li5Cs2B7O14 and Centrosymmetric Li4CsB5O1016KSbI6O18: An antimony iodate semiconductor material with cyclic chiral S6-symmetric hexaiodate7A Polar Titanium–Organic Chain with a Very Large Second-Harmonic-Generation Response5Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures601Noncentrosymmetric (NCS) solid solutions: elucidating the structure–nonlinear optical (NLO) property relationship and beyond21Photoconversion Mechanisms and the Origin of Second-Harmonic Generation in Metal Iodates with Wide Transparency, NaLn(IO3)4 (Ln = La, Ce, Sm, and Eu) and NaLa(IO3)4:Ln3+ (Ln = Sm and Eu)32Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals258Cadmium Iodate Syntheses and Characterization3Second-order nonlinear optical crystals with mixed anions250Synthesis, Characterization, and Crystal Structure Determination of a New Lithium Zinc Iodate Polymorph LiZn(IO3)320ZnIO3F: Zinc Iodate Fluoride with Large Birefringence and Wide Band Gap57Crystal growth, characterization and theoretical studies of the noncentrosymmetric compound Al3(IO3)9·(HIO3)6·18H2O4M4O(IO3)3(I3O7F3)BF4 (M = Pb, Sr): Promising Nonlinear Optical Materials Featuring the Unprecedented Windmill-Shaped [I3O7F3]2– Polyfluoroiodate Anion12New Modification of Polar Nonlinear Optical Iodate Fluoride PbF(IO3), the Family MX(IO3), M = Bi, Ba, Pb, X = O, F, (OH) Related to Aurivillius Phases and Similar Iodates3A Rare‐Earth Selenite with Unexpectedly Well‐Balanced Ultraviolet Nonlinear Optical Functionality, Sc(HSeO 3 ) 331First-Principles Study of the Electronic and Optical Properties of Sn-BeO Heterostructure1Recent progress in structural design strategies of high-birefringence optical crystals55Engineering oxygen vacancy-enriched S-scheme ZnIO3(OH)/BiOIO3 heterojunction architectures for enhanced charge separation and photocatalytic efficiency15In-situ fabrication of hierarchical ternary S-scheme ZnCO3/ZnIO3(OH)/ZnO heterojunctions with oxygen vacancy-engineered interfaces for optimized charge dynamics and visible-light-driven catalysis1

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  1. K4TM4(V2O7)2(IO3)4(H2O) (TM = Zn, Ni, Co): a series of quinary mixed metal–vanadium(v)–iodates

    CrystEngComm · 2013-01-01

    Bing‐Ping Yang, Xiang Xu, Chao Huang, Jiang‐Gao Mao

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  2. Tl(VO)2O2(IO3)3: a new polar material with a strong SHG response

    Dalton Transactions · 2013-01-01

    Chao Huang, Chun‐Li Hu, Xiang Xu, Bing‐Ping Yang, Jiang‐Gao Mao

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  3. ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units

    RSC Advances · 2013-01-01

    Sangen Zhao, Junhua Luo, Pan Zhou, Shuquan Zhang, Zhihua Sun, Maochun Hong

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  4. Zn2(VO4)(IO3): A Novel Polar Zinc(II) Vanadium(V) Iodate with a Large SHG Response

    Inorganic Chemistry · 2013-04-05

    Bing‐Ping Yang, Chun‐Li Hu, Xiang Xu, Chao Huang, Jiang‐Gao Mao

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  5. Synthesis, growth, structural, thermal, optical properties of new metal-organic crystals: Methyltriphenylphosphonium iodide thiourea and methyltriphenylphosphonium iodide chloroform hemisolvate

    Journal of Crystal Growth · 2013-04-29

    Boris Lubomirov Shivachev, K. Kosev, L. Dimowa, Georgi Petkov Yankov, Todor S. Petrov, Rositsa P. Nikolova, Nadia Petrova

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  6. Explorations of a Series of Second Order Nonlinear Optical Materials Based on Monovalent Metal Gold(III) Iodates

    Inorganic Chemistry · 2013-09-16

    Chao Huang, Chun‐Li Hu, Xiang Xu, Bing‐Ping Yang, Jiang‐Gao Mao

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  7. Sr 4 B 10 O 18 (OH) 2 ·2H 2 O: a new UV nonlinear optical material with a [B 10 O 23 ] 16− building block

    Journal of Materials Chemistry C · 2013-10-23

    Fangyuan Zhang, Fangyuan Zhang, Qun Jing, Fangfang Zhang, Fangfang Zhang, Shilie Pan, Zhihua Yang, Jian Wei Han, Min Zhang, Shujuan Han

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  8. Second harmonic generation by micropowders: a revision of the Kurtz–Perry method and its practical application

    Applied Physics B · 2013-12-05

    Ibon Aramburu, Josu Ortega, César Luis Folcia, J. Etxebarría

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  9. Explorations of New Second-Order Nonlinear Optical Materials in the Ternary Rubidium Iodate System: Noncentrosymmetric β-RbIO3(HIO3)2 and Centrosymmetric Rb3(IO3)3(I2O5)(HIO3)4(H2O)

    Inorganic Chemistry · 2014-01-15

    Xiang Xu, Bing‐Ping Yang, Chao Huang, Jiang‐Gao Mao

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  10. A New UV Nonlinear Optical Material CsZn2B3O7: ZnO4 Tetrahedra Double the Efficiency of Second-Harmonic Generation

    Inorganic Chemistry · 2014-02-10

    Sangen Zhao, Jia Zhang, Shuquan Zhang, Zhihua Sun, Zheshuai Lin, Yicheng Wu, Maochun Hong, Junhua Luo

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  11. Variable Framework Structures and Centricities in Alkali Metal Yttrium Selenites, AY(SeO3)2 (A = Na, K, Rb, and Cs)

    Inorganic Chemistry · 2014-04-22

    Seong‐eun Bang, Dong Woo Lee, Kang Min Ok

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  12. α-AgI3O8 and β-AgI3O8 with Large SHG Responses: Polymerization of IO3 Groups into the I3O8 Polyiodate Anion

    Chemistry of Materials · 2014-04-25

    Xiang Xu, Chun‐Li Hu, Bingxuan Li, Bing‐Ping Yang, Jiang‐Gao Mao

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  13. In[IO3](OH)2 – New member of hydrous and anhydrous iodate family with indium

    Solid State Sciences · 2014-06-12

    Elena L. Belokoneva, Olga V. Dimitrova, Anatoly S. Volkov

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  14. Synthesis, crystal structure and optical properties of two new layered cadmium iodates: Cd(IO3)X (X=Cl, OH)

    Journal of Solid State Chemistry · 2014-07-31

    Bing‐Ping Yang, Jiang‐Gao Mao

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  15. Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework

    Inorganic Chemistry · 2014-09-26

    Chunyan Bai, Hongwei Yu, Shujuan Han, Shilie Pan, Bingbing Zhang, Ying Wang, Hongping Wu, Zhihua Yang

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  16. Macroscopic polarity control with alkali metal cation size and coordination environment in a series of tin iodates

    Inorganic Chemistry Frontiers · 2015-01-01

    Yeong Hun Kim, T. Thao Tran, P. Shiv Halasyamani, Kang Min Ok

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  17. Recent advances on second-order NLO materials based on metal iodates

    Coordination Chemistry Reviews · 2015-01-25

    Chun‐Li Hu, Jiang‐Gao Mao

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  18. Two New Crystals in LimCsnBm+nO2(m+n) (m + n = 5, 7; m > n) Series: Noncentrosymmetric Li5Cs2B7O14 and Centrosymmetric Li4CsB5O10

    Inorganic Chemistry · 2015-07-21

    Lin Li, Shujuan Han, Bing‐Hua Lei, Xiaoyu Dong, Hongping Wu, Zhongxiang Zhou, Zhihua Yang, Shilie Pan

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  19. KSbI6O18: An antimony iodate semiconductor material with cyclic chiral S6-symmetric hexaiodate

    Inorganic Chemistry Communications · 2016-01-11

    Guo-Xiang He, Yi-gang Chen, Nan Qing Yang, Meiling Xing, Xian‐Ming Zhang

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  20. A Polar Titanium–Organic Chain with a Very Large Second-Harmonic-Generation Response

    Inorganic Chemistry · 2016-11-10

    Bongsu Kim, Seung‐Jin Oh, Hongil Jo, Kang Min Ok

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  21. Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures

    Accounts of Chemical Research · 2016-11-14

    Kang Min Ok

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  22. Noncentrosymmetric (NCS) solid solutions: elucidating the structure–nonlinear optical (NLO) property relationship and beyond

    Dalton Transactions · 2017-01-01

    Hongil Jo, Seung‐Jin Oh, Kang Min Ok

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  23. Photoconversion Mechanisms and the Origin of Second-Harmonic Generation in Metal Iodates with Wide Transparency, NaLn(IO3)4 (Ln = La, Ce, Sm, and Eu) and NaLa(IO3)4:Ln3+ (Ln = Sm and Eu)

    Inorganic Chemistry · 2017-06-01

    Seung‐Jin Oh, Hyung-Gu Kim, Hongil Jo, Tae Gil Lim, Jae Soo Yoo, Kang Min Ok

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  24. Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals

    Coordination Chemistry Reviews · 2018-03-15

    Chao Wu, Gang Yang, Mark Graeme Humphrey, Chi Zhang

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  25. Cadmium Iodate Syntheses and Characterization

    InTech eBooks · 2018-06-27

    Zoulikha Hebboul

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  26. Second-order nonlinear optical crystals with mixed anions

    Coordination Chemistry Reviews · 2018-08-06

    Yu Pan, Sheng‐Ping Guo, Bin‐Wen Liu, Huaiguo Xue, Guo‐Cong Guo

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  27. Synthesis, Characterization, and Crystal Structure Determination of a New Lithium Zinc Iodate Polymorph LiZn(IO3)3

    Crystals · 2019-09-04

    Zoulikha Hebboul, Christine Galez, Djamal Benbertal, Sandrine Beauquis, Yannick Mugnier, Abdelnour Benmakhlouf, M. Bouchenafa, Daniel Errandonea

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  28. ZnIO3F: Zinc Iodate Fluoride with Large Birefringence and Wide Band Gap

    Inorganic Chemistry · 2020-03-19

    Minqiang Gai, Ying Wang, Tinghao Tong, Zhihua Yang, Shilie Pan

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  29. Crystal growth, characterization and theoretical studies of the noncentrosymmetric compound Al3(IO3)9·(HIO3)6·18H2O

    Journal of Alloys and Compounds · 2020-12-08

    Yang Li, Junben Huang, Huimin Chen

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  30. M4O(IO3)3(I3O7F3)BF4 (M = Pb, Sr): Promising Nonlinear Optical Materials Featuring the Unprecedented Windmill-Shaped [I3O7F3]2– Polyfluoroiodate Anion

    Crystal Growth & Design · 2021-11-18

    Yiyi Xu, Yuqiao Zhou, Chensheng Lin, Bingxuan Li, Xia Hao, Ning Ye, Min Luo

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  31. New Modification of Polar Nonlinear Optical Iodate Fluoride PbF(IO3), the Family MX(IO3), M = Bi, Ba, Pb, X = O, F, (OH) Related to Aurivillius Phases and Similar Iodates

    Symmetry · 2022-12-30

    Elena L. Belokoneva, Olga Reutova, Anatoly S. Volkov, Olga V. Dimitrova, Sergey Yu. Stefanovich

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  32. A Rare‐Earth Selenite with Unexpectedly Well‐Balanced Ultraviolet Nonlinear Optical Functionality, Sc(HSeO 3 ) 3

    Small · 2023-02-09

    Zhiyong Bai, Jihyun Lee, Heewon Kim, Yunseung Kuk, Myung‐Ho Choi, Chun‐Li Hu, Kang Min Ok

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  33. First-Principles Study of the Electronic and Optical Properties of Sn-BeO Heterostructure

    Journal of Electronic Materials · 2024-04-14

    Bipradip Chakraborty, Madhurjya Modhur Borgohain, Eeshankur Saikia, Gaurav Trivedi, Nirab Chandra Adhikary

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  34. Recent progress in structural design strategies of high-birefringence optical crystals

    Coordination Chemistry Reviews · 2025-05-08

    A-Lan Xu, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  35. Engineering oxygen vacancy-enriched S-scheme ZnIO3(OH)/BiOIO3 heterojunction architectures for enhanced charge separation and photocatalytic efficiency

    Journal of Colloid and Interface Science · 2025-06-02

    Weina Mu, Chun Yen Chang, Lijuan Wang, Jingsan Xu

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  36. In-situ fabrication of hierarchical ternary S-scheme ZnCO3/ZnIO3(OH)/ZnO heterojunctions with oxygen vacancy-engineered interfaces for optimized charge dynamics and visible-light-driven catalysis

    Journal of Alloys and Compounds · 2025-09-24

    Weina Mu, Chun Yen Chang, Lijuan Wang

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