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RESEARCH PAPER · Inorganic Chemistry · 2010

Cerium(IV), Neptunium(IV), and Plutonium(IV) 1,2-Phenylenediphosphonates: Correlations and Differences between Early Transuranium Elements and Their Proposed Surrogates

Juan Diwu, Shuao Wang, Zuolei Liao, Peter Carman Burns, Thomas E. Albrecht‐Schmitt

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Cerium(IV), Neptunium(IV), and Plutonium(IV) 1,2-Phenylenediphosphonates: Correlations and Differences between Early Transuranium Elements and Their Proposed SurrogatesOriginalRole of Anions and Reaction Conditions in the Preparation of Uranium(VI), Neptunium(VI), and Plutonium(VI) Borates56Self‐Assembly of Hexanuclear Clusters of 4f and 5f Elements with Cation Specificity30Deviation Between the Chemistry of Ce(IV) and Pu(IV) and Routes to Ordered and Disordered Heterobimetallic 4f/5f and 5f/5f Phosphonates50Pillared and open-framework uranyl diphosphonates32Facile Routes to ThIV, UIV, and NpIV Phosphites and Phosphates23The oxidative degradation of dibenzoazepine derivatives by cerium( iv ) complexes in acidic sulfate media17Mixed-Valent Uranium(IV,VI) Diphosphonate: Synthesis, Structure, and Spectroscopy26Systematic Evolution from Uranyl(VI) Phosphites to Uranium(IV) Phosphates43Periodic Trends in Lanthanide and Actinide Phosphonates: Discontinuity between Plutonium and Americium49Cerium(IV) Tellurite Halides [Ce2Te7O17]X2 (X = Cl– or Br–): The First Cerium-Containing Cationic Frameworks30Unusual Coordination for Plutonium(IV), Cerium(IV), and Zirconium(IV) in the Cationic Layered Materials [M2Te4O11]X2 (M = Pu, Ce, Zr; X = Cl, Br)29From Order to Disorder and Back Again: In Situ Hydrothermal Redox Reactions of Uranium Phosphites and Phosphates28From Yellow to Black: Dramatic Changes between Cerium(IV) and Plutonium(IV) Molybdates37Comparisons of Plutonium, Thorium, and Cerium Tellurite Sulfates41Crystal Growth and First Crystallographic Characterization of Mixed Uranium(IV)–Plutonium(III) Oxalates51Dissolution of uranyl and plutonyl borates: Influences of crystalline structures and aqueous ligands4Actinide oxalates, solid state structures and applications160Mixed-Valent Neptunium(IV/V) Compound with Cation–Cation-Bound Six-Membered Neptunyl Rings24Thermochromism, the Alexandrite Effect, and Dynamic Jahn–Teller Distortions in Ho2Cu(TeO3)2(SO4)221Supramolecular Interactions in PuO2Cl42– and PuCl62– Complexes with Protonated Pyridines: Synthesis, Crystal Structures, and Raman Spectroscopy33Challenges in the Search for Magnetic Coupling in 3d/4f Materials: Syntheses, Structures, and Magnetic Properties of the Lanthanide Copper Heterobimetallic Compounds, RE2Cu(TeO3)2(SO4)229The influence of pressure on the structure of a 2D uranium(VI) carboxyphosphonoate compound11Expansion of the Rich Structures and Magnetic Properties of Neptunium Selenites: Soft Ferromagnetism in Np(SeO3)213Hydroxypyridinonate Complex Stability of Group (IV) Metals and Tetravalent f-Block Elements: The Key to the Next Generation of Chelating Agents for Radiopharmaceuticals58Probing the Influence of Phosphonate Bonding Modes to Uranium(VI) on Structural Topology and Stability: A Complementary Experimental and Computational Investigation51Structural and spectroscopic characterization of two new layered uranyl(VI) p-xylenediphosphonate compounds synthesized via ionothermal method13Monomers, Dimers, and Helices: Complexities of Cerium and Plutonium Phenanthrolinecarboxylates22Covalency-Driven Dimerization of Plutonium(IV) in a Hydroxamate Complex16A Mixed‐Valent Uranium Phosphonate Framework Containing UIV, UV, and UVI39Cerium(IV) phenylphosphonates and para-substituted phenylphosphonates: preparation and characterization4Systematic Investigation of the in Situ Reduction Process from U(VI) to U(IV) in a Phosphonate System under Mild Solvothermal Conditions23Précipitation des molybdates mixtes zirconium-cérium/plutonium en milieu aqueux HNO30Solid‐State Structure of Tris‐Cyclopentadienide Uranium(III) and Plutonium(III)22Towards the development of chitosan nanoparticles for plutonium pulmonary decorporation10Speciation of Actinide Complexes, Clusters, and Nanostructures in Solution2Unexpected Behavior of Np in Oxo-selenate/Oxo-selenite Systems9Crystallographic and Spectroscopic Characterization of Americium Complexes Containing the Bis[(phosphino)methyl]pyridine-1-oxide (NOPOPO) Ligand Platform26[Ag 2 M(Te 2 O 5 ) 2 ]SO 4 (M = Ce IV or Th IV ): A New Purely Inorganic d/f-Heterometallic Cationic Material12Unexpected Crystallographic Phase Transformation in Nonstoichiometric SrUO4–x: Reversible Oxygen Defect Ordering and Symmetry Lowering with Increasing Temperature18Mechanochemical synthesis of cerium(IV)-phosphonates8The anodic behavior of cerium in AlCl3-1-ethyl-3-methyl-imidazolium chloride ionic liquid3pH Driven Hydrothermal Syntheses of Neodymium Sulfites and Mixed Sulfate-Sulfites7New Uranyl Open Framework and Sheet Compounds Formed via In-Situ Protonation of Piperazine by Phosphorous Acid1Establishing Cost-Effective Computational Models for the Prediction of Lanthanoid Binding in [Ln(NO3)]2+ (with Ln = La to Lu)9How Do Actinyls Interact with Hyperphosphorylated Yolk Protein Phosvitin?6The presence of mixed-valent silver in the uranyl phenylenediphosphonate framework5Exploring the Oxidation States of Neptunium with Schiff Base Coordination Complexes19The crystal and coordination chemistry of neptunium in all its oxidation states: An expanded structural hierarchy of neptunium compounds41Preliminary Study of Using Colloidal SiO2@ZrO2 Particles in Recovering Actinides from Water and Immobilizing them in a Glass-Ceramic0A Tetravalent Plutonium Organic Framework Containing [ Pu2O16 ] Dimers as Secondary Building Units: Synthesis, Structure, and Radiation Stability9Influence of Di-n-butyl Phosphoric Acid on Cerium Redox and Speciation in Tri-n-butyl Phosphate3The Corrosion Behavior of Refractory Body-Centered Cubic High-Entropy Alloys in Molten Cerium1Syntheses and characterization of non-molecular phenyl- and methyl-phosphonates and ethylenediphosphonates of thorium and cerium1Narrowband green emission in CaF2: U6+ phosphors via dynamic F–O coordination and defect synergy0

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  1. Role of Anions and Reaction Conditions in the Preparation of Uranium(VI), Neptunium(VI), and Plutonium(VI) Borates

    Inorganic Chemistry · 2011-02-03

    Shuao Wang, Eric M. Villa, Juan Diwu, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  2. Self‐Assembly of Hexanuclear Clusters of 4f and 5f Elements with Cation Specificity

    European Journal of Inorganic Chemistry · 2011-02-10

    Juan Diwu, Justin J. Good, V.H. DiStefano, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  3. Deviation Between the Chemistry of Ce(IV) and Pu(IV) and Routes to Ordered and Disordered Heterobimetallic 4f/5f and 5f/5f Phosphonates

    Inorganic Chemistry · 2011-04-25

    Juan Diwu, Shuao Wang, Justin J. Good, V.H. DiStefano, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  4. Pillared and open-framework uranyl diphosphonates

    Journal of Solid State Chemistry · 2011-07-06

    Pius O. Adelani, Thomas E. Albrecht‐Schmitt

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  5. Facile Routes to ThIV, UIV, and NpIV Phosphites and Phosphates

    European Journal of Inorganic Chemistry · 2011-08-05

    Eric M. Villa, Shuao Wang, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  6. The oxidative degradation of dibenzoazepine derivatives by cerium( iv ) complexes in acidic sulfate media

    Dalton Transactions · 2011-11-30

    Joanna Wı́sniewska, Grzegorz Wrzeszcz, Marzanna Kurzawa, Rudi van Eldik

    Read original paper ↗ ·

  7. Mixed-Valent Uranium(IV,VI) Diphosphonate: Synthesis, Structure, and Spectroscopy

    Inorganic Chemistry · 2012-03-29

    Juan Diwu, Thomas E. Albrecht‐Schmitt

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  8. Systematic Evolution from Uranyl(VI) Phosphites to Uranium(IV) Phosphates

    Inorganic Chemistry · 2012-05-30

    Eric M. Villa, Connor J. Marr, Laurent J. Jouffret, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  9. Periodic Trends in Lanthanide and Actinide Phosphonates: Discontinuity between Plutonium and Americium

    Inorganic Chemistry · 2012-06-05

    Juan Diwu, Daniel J. Grant, Shuao Wang, Laura Gagliardi, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  10. Cerium(IV) Tellurite Halides [Ce2Te7O17]X2 (X = Cl– or Br–): The First Cerium-Containing Cationic Frameworks

    Inorganic Chemistry · 2012-09-19

    Jian Hung Lin, Juan Diwu, Justin N. Cross, Eric M. Villa, Thomas E. Albrecht‐Schmitt

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  11. Unusual Coordination for Plutonium(IV), Cerium(IV), and Zirconium(IV) in the Cationic Layered Materials [M2Te4O11]X2 (M = Pu, Ce, Zr; X = Cl, Br)

    Inorganic Chemistry · 2012-10-17

    Jian Hung Lin, Justin N. Cross, Juan Diwu, Matthew J. Polinski, Eric M. Villa, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  12. From Order to Disorder and Back Again: In Situ Hydrothermal Redox Reactions of Uranium Phosphites and Phosphates

    Inorganic Chemistry · 2013-01-09

    Eric M. Villa, Connor J. Marr, Juan Diwu, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  13. From Yellow to Black: Dramatic Changes between Cerium(IV) and Plutonium(IV) Molybdates

    Journal of the American Chemical Society · 2013-01-29

    Justin N. Cross, Patrick M. Duncan, Eric M. Villa, Matthew J. Polinski, Jean‐Marie Babo, Evgeny V. Alekseev, Corwin H. Booth, Thomas E. Albrecht‐Schmitt

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  14. Comparisons of Plutonium, Thorium, and Cerium Tellurite Sulfates

    Inorganic Chemistry · 2013-03-25

    Jian Hung Lin, Justin N. Cross, Juan Diwu, Nathan A. Meredith, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  15. Crystal Growth and First Crystallographic Characterization of Mixed Uranium(IV)–Plutonium(III) Oxalates

    Inorganic Chemistry · 2013-04-11

    Christelle Tamain, Bénédicte Arab-Chapelet, Murielle Rivenet, F. Abraham, R. Caraballo, S. Grandjean

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  16. Dissolution of uranyl and plutonyl borates: Influences of crystalline structures and aqueous ligands

    Chemical Geology · 2013-08-28

    Yu Yang, Shuao Wang, Matthew J. Polinski, Yi Liu, Mark O. Barnett, Thomas E. Albrecht‐Schmitt

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  17. Actinide oxalates, solid state structures and applications

    Coordination Chemistry Reviews · 2013-09-06

    F. Abraham, Bénédicte Arab-Chapelet, Murielle Rivenet, Christelle Tamain, S. Grandjean

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  18. Mixed-Valent Neptunium(IV/V) Compound with Cation–Cation-Bound Six-Membered Neptunyl Rings

    Inorganic Chemistry · 2013-10-24

    Geng Bang Jin

    Read original paper ↗ ·

  19. Thermochromism, the Alexandrite Effect, and Dynamic Jahn–Teller Distortions in Ho2Cu(TeO3)2(SO4)2

    Inorganic Chemistry · 2013-11-01

    Jian Hung Lin, Kariem Diefenbach, Justin N. Cross, Jean‐Marie Babo, Thomas E. Albrecht‐Schmitt

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  20. Supramolecular Interactions in PuO2Cl42– and PuCl62– Complexes with Protonated Pyridines: Synthesis, Crystal Structures, and Raman Spectroscopy

    Inorganic Chemistry · 2013-12-13

    Richard E. Wilson, David D. Schnaars, Michael B. Andrews, Christopher L. Cahill

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  21. Challenges in the Search for Magnetic Coupling in 3d/4f Materials: Syntheses, Structures, and Magnetic Properties of the Lanthanide Copper Heterobimetallic Compounds, RE2Cu(TeO3)2(SO4)2

    Chemistry of Materials · 2014-03-01

    Jian Hung Lin, Ping Chai, Kariem Diefenbach, Michael Shatruk, Thomas E. Albrecht‐Schmitt

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  22. The influence of pressure on the structure of a 2D uranium(VI) carboxyphosphonoate compound

    Journal of Solid State Chemistry · 2014-06-09

    E.C. Spencer, Nancy L. Ross, Robert G. Surbella, Christopher L. Cahill

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  23. Expansion of the Rich Structures and Magnetic Properties of Neptunium Selenites: Soft Ferromagnetism in Np(SeO3)2

    Inorganic Chemistry · 2014-06-25

    Kariem Diefenbach, Jian Hung Lin, Justin N. Cross, Naresh S. Dalal, Michael Shatruk, Thomas E. Albrecht‐Schmitt

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  24. Hydroxypyridinonate Complex Stability of Group (IV) Metals and Tetravalent f-Block Elements: The Key to the Next Generation of Chelating Agents for Radiopharmaceuticals

    Inorganic Chemistry · 2015-03-23

    Manuel Sturzbecher‐Hoehne, Taylor A. Choi, Rebecca J. Abergel

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  25. Probing the Influence of Phosphonate Bonding Modes to Uranium(VI) on Structural Topology and Stability: A Complementary Experimental and Computational Investigation

    Inorganic Chemistry · 2015-03-27

    Tao Zheng, Qun‐Yan Wu, Yang Gao, Daxiang Gui, Shiwen Qiu, Lanhua Chen, Daopeng Sheng, Juan Diwu, Wei‐Qun Shi, Zhifang Chai, Thomas E. Albrecht‐Schmitt, Shuao Wang

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  26. Structural and spectroscopic characterization of two new layered uranyl(VI) p-xylenediphosphonate compounds synthesized via ionothermal method

    Inorganica Chimica Acta · 2015-07-04

    Tao Zheng, Yang Gao, Lanhua Chen, Juan Diwu, Zhifang Chai, Thomas E. Albrecht‐Schmitt, Shuao Wang

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  27. Monomers, Dimers, and Helices: Complexities of Cerium and Plutonium Phenanthrolinecarboxylates

    Inorganic Chemistry · 2016-04-12

    Samantha K. Cary, Maryline G. Ferrier, Ryan Baumbach, Mark A. Silver, Juan S. Lezama-Pacheco, Stosh A. Kozimor, Henry S. La Pierre, Benjamin William Stein, Alexandra A. Arico, Danielle L. Gray, Thomas E. Albrecht‐Schmitt

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  28. Covalency-Driven Dimerization of Plutonium(IV) in a Hydroxamate Complex

    Inorganic Chemistry · 2016-05-26

    Mark A. Silver, Samantha K. Cary, Jared T. Stritzinger, T. Gannon Parker, Laurent Maron, Thomas E. Albrecht‐Schmitt

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  29. A Mixed‐Valent Uranium Phosphonate Framework Containing UIV, UV, and UVI

    Chemistry - A European Journal · 2016-06-29

    Lanhua Chen, Tao Zheng, Song‐Song Bao, Linjuan Zhang, Hsin‐Kuan Liu, Li‐Min Zheng, Jian‐Qiang Wang, Yaxing Wang, Juan Diwu, Zhifang Chai, Thomas E. Albrecht‐Schmitt, Shuao Wang

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  30. Cerium(IV) phenylphosphonates and para-substituted phenylphosphonates: preparation and characterization

    Journal of Inclusion Phenomena and Macrocyclic Chemistry · 2017-02-25

    Klára Melánová, Ludvı́k Beneš, Jan Svoboda, Vı́tězslav Zima, Miroslava Trchová, Milan Vlček, Numan Almonasy

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  31. Systematic Investigation of the in Situ Reduction Process from U(VI) to U(IV) in a Phosphonate System under Mild Solvothermal Conditions

    Inorganic Chemistry · 2017-05-26

    Lanhua Chen, Juan Diwu, Daxiang Gui, Yaxing Wang, Zhehui Weng, Zhifang Chai, Thomas E. Albrecht‐Schmitt, Shuao Wang

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  32. Précipitation des molybdates mixtes zirconium-cérium/plutonium en milieu aqueux HNO3

    Unknown journal · 2017-11-24

    Margot Nadolny

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  33. Solid‐State Structure of Tris‐Cyclopentadienide Uranium(III) and Plutonium(III)

    Chemistry - A European Journal · 2017-11-29

    Christos Apostolidis, Michał S. Dutkiewicz, Attila Kovács, Olaf Walter

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  34. Towards the development of chitosan nanoparticles for plutonium pulmonary decorporation

    Dalton Transactions · 2018-01-01

    Laurane Léost, Jérôme Roques, Anne Van der Meeren, Luc Vincent, Nicolas Sbirrazzuoli, Christoph Hennig, A. Roßberg, Jean Aupiais, Sophie Pagnotta, Christophe Den Auwer, Christophe Di Giorgio

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  35. Speciation of Actinide Complexes, Clusters, and Nanostructures in Solution

    Unknown journal · 2018-01-12

    Rami J. Batrice, Jennifer N. Wacker, Karah E. Knope

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  36. Unexpected Behavior of Np in Oxo-selenate/Oxo-selenite Systems

    Inorganic Chemistry · 2018-01-22

    Eike M. Langer, Olaf Walter, Jean‐Yves Colle, Dirk Bosbach, Evgeny V. Alekseev

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  37. Crystallographic and Spectroscopic Characterization of Americium Complexes Containing the Bis[(phosphino)methyl]pyridine-1-oxide (NOPOPO) Ligand Platform

    Inorganic Chemistry · 2018-02-06

    Jordan F. Corbey, Brian M. Rapko, Zhe-Ming Wang, Bruce K. McNamara, Robert G. Surbella, Kristi L. Pellegrini, Jon M. Schwantes

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  38. [Ag 2 M(Te 2 O 5 ) 2 ]SO 4 (M = Ce IV or Th IV ): A New Purely Inorganic d/f-Heterometallic Cationic Material

    Inorganic Chemistry · 2018-04-16

    Todd N. Poe, Frankie D. White, Vanessa Proust, Eric M. Villa, Matthew J. Polinski

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  39. Unexpected Crystallographic Phase Transformation in Nonstoichiometric SrUO4–x: Reversible Oxygen Defect Ordering and Symmetry Lowering with Increasing Temperature

    Inorganic Chemistry · 2018-05-01

    Gabriel L. Murphy, Chun‐Hai Wang, George Beridze, Zhaoming Zhang, Justin A. Kimpton, Maxim Avdeev, Piotr M. Kowalski, Brendan J. Kennedy

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  40. Mechanochemical synthesis of cerium(IV)-phosphonates

    Journal of Materials Science · 2018-06-04

    Manuel Wilke, Irina Akhmetova, Klaus Rademann, Franziska Emmerling

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  41. The anodic behavior of cerium in AlCl3-1-ethyl-3-methyl-imidazolium chloride ionic liquid

    Journal of Rare Earths · 2018-06-09

    Yidong Jiang, Lizhu Luo, Jun Mei, Xiaolin Wang

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  42. pH Driven Hydrothermal Syntheses of Neodymium Sulfites and Mixed Sulfate-Sulfites

    Crystal Growth & Design · 2018-08-03

    Jakob T. Dovgan, Matthew J. Polinski, Brandon Q. Mercado, Eric M. Villa

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  43. New Uranyl Open Framework and Sheet Compounds Formed via In-Situ Protonation of Piperazine by Phosphorous Acid

    Minerals · 2018-11-01

    Eric M. Villa, Justin N. Cross, Thomas E. Albrecht‐Schmitt

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  44. Establishing Cost-Effective Computational Models for the Prediction of Lanthanoid Binding in [Ln(NO3)]2+ (with Ln = La to Lu)

    ACS Omega · 2019-01-16

    Charles C. Peterson, Deborah A. Penchoff, John D. Auxier, Howard L. Hall

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  45. How Do Actinyls Interact with Hyperphosphorylated Yolk Protein Phosvitin?

    Chemistry - A European Journal · 2019-06-17

    Sumit Kumar, Gaëlle Creff, Christoph Hennig, A. Roßberg, Robin Steudtner, Johannes Raff, Claude Vidaud, François R. Oberhaensli, Marie‐Yasmine Dechraoui Bottein, Christophe Den Auwer

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  46. The presence of mixed-valent silver in the uranyl phenylenediphosphonate framework

    New Journal of Chemistry · 2020-01-01

    Ru Bai, Lanhua Chen, Yugang Zhang, Long Chen, Juan Diwu, Xiao‐Feng Wang

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  47. Exploring the Oxidation States of Neptunium with Schiff Base Coordination Complexes

    Inorganic Chemistry · 2020-11-25

    Bonnie E. Klamm, Cory J. Windorff, Cristian Celis‐Barros, María Joaquina Beltrán-Leiva, Joseph M. Sperling, Thomas E. Albrecht-Schönzart

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  48. The crystal and coordination chemistry of neptunium in all its oxidation states: An expanded structural hierarchy of neptunium compounds

    Coordination Chemistry Reviews · 2021-06-05

    Sara E. Gilson, Peter Carman Burns

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  49. Preliminary Study of Using Colloidal SiO2@ZrO2 Particles in Recovering Actinides from Water and Immobilizing them in a Glass-Ceramic

    ChemRxiv · 2021-12-29

    Pablo Arnal, Ariana Salvia

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  50. A Tetravalent Plutonium Organic Framework Containing [ Pu2O16 ] Dimers as Secondary Building Units: Synthesis, Structure, and Radiation Stability

    Chinese Journal of Chemistry · 2023-03-02

    Yugang Zhang, Yingzhe Du, Lili Li, Ye Tao, Kai Li, Hailong Zhang, Yanlong Wang, Lanhua Chen, Yaxing Wang, Zhifang Chai, Shuao Wang

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