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RESEARCH PAPER · Inorganic Chemistry · 2012

Sulfonate Complexes of Actinide Ions: Structural Diversity in Uranyl Complexes with 2-Sulfobenzoate

P. Thuéry

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Sulfonate Complexes of Actinide Ions: Structural Diversity in Uranyl Complexes with 2-SulfobenzoateOriginalOne- to three-dimensional uranyl–organic assemblies with 3-sulfophthalic and 5-sulfoisophthalic acids29Syntheses and Structures of a Series of Uranyl Phosphonates and Sulfonates: An Insight into Their Correlations and Discrepancies752,2′‐Bipyridine and 1,10‐Phenanthroline as Coligands or Structure‐Directing Agents in Uranyl–Organic Assemblies with Polycarboxylic Acids56The crystal chemistry of uranium carboxylates394Uranyl Coordination Polymers Incorporating η5-Cyclopentadienyliron-Functionalized η6-Phthalate Metalloligands: Syntheses, Structures and Photophysical Properties29Synthesis, Structures, and Properties of Uranyl Hybrids Constructed by a Variety of Mono- and Polycarboxylic Acids70Molecular and Polymeric Uranyl and Thorium Complexes with Sulfonate‐Containing Ligands33Diverse silver( i ) sulfobenzoate coordination polymers and their recycling property as homogeneous catalyst in oxygenation of sulfide10Isolation of a series of uranium organophosphinates11MOFs of Uranium and the Actinides95Crystal Chemistry of Uranyl Carboxylate Coordination Networks Obtained in the Presence of Organic Amine Molecules60Structural Variation within Heterometallic Uranyl Hybrids Based on Flexible Alkyldiphosphonate Ligands40Postsynthetic Rearrangement/Metalation as a Route to Bimetallic Uranyl Coordination Polymers: Syntheses, Structures, and Luminescence70In situ syntheses of two viologen(4,4′-bipyridinium)-based cadmium compounds: structures, fluorescence and theoretical investigations5Synthesis, crystal structure and spectroscopic studies of some organic/inorganic hybrid materials containing isostructural monomeric uranyl complexes bridged by bipyridyl typed ligands16Incorporation of Cu2+ Ions into Nanotubular Uranyl Diphosphonates28A new organically templated open-framework uranyl ethylenediphosphonate6CuPYDC Metalloligands and Postsynthetic Rearrangement/Metalation as Routes to Bimetallic Uranyl Containing Hybrid Materials: Syntheses, Structures, and Fluorescence37Copper(I) and Copper(II) Uranyl Heterometallic Hybrid Materials49Two new two-dimensional layered uranyl-bearing polycarboxylates from semi-rigid tetracarboxylic acids15Coordination polymers from 1-D to 3-D assembled from disulfonate ligands: Structures and luminescent properties2The First Family of Actinide Carboxyphosphinates: Two‐ and Three‐Dimensional Uranyl Coordination Polymers27Use of 2,2-Bipyrimidine for the Preparation of UO22+-3d Diphosphonates18Incorporating Guest Molecules into Honeycomb Structures Constructed from Uranium(VI)-Polycarboxylates: Structural Diversities and Photocatalytic Activities for the Degradation of Organic Dye91Combining coordination and supramolecular chemistry to explore uranyl assembly in the solid state51New Zn(II) Coordination Polymers Constructed from Amino-Alcohols and Aromatic Dicarboxylic Acids: Synthesis, Structure, Photocatalytic Properties, and Solid-State Conversion to ZnO22Hybrid Materials of the f-Elements Part I5Hybrid Materials of the f-Elements Part II5Assembly, Disassembly, and Reassembly: Conversion of Homometallic Coordination Networks into Mixed Metal–Organic Frameworks37Comparison of uranium(VI) and thorium(IV) coordination polymers with p-toluenesulfonic acid16Heterometallic zinc uranium oxyfluorides incorporating imidazole ligands3Multidimensional (0D to 3D) Alkaline-Earth Metal Diphosphonates: Synthesis, Structural Diversity, and Luminescence Properties17Hydrothermal synthesis, crystal structures and properties of Tiron-bridged di- and trinuclear strontium complexes containing nitrogen-donor ligands3Role of N-Donor Sterics on the Coordination Environment and Dimensionality of Uranyl Thiophenedicarboxylate Coordination Polymers53Two Uranyl Complexes with Pyromellitic Acid. A Heterometallic Complex with U=O–CuII Interaction7Uranyl Carboxyphosphonates Derived from Hydrothermal in Situ Ligand Reaction: Syntheses, Structures, and Computational Investigations25Silver Ion-Mediated Heterometallic Three-Fold Interpenetrating Uranyl–Organic Framework52Probing the Influence of N‐Donor Capping Ligands on Supramolecular Assembly in Molecular Uranyl Materials45Anchoring flexible uranyl dicarboxylate chains through stacking interactions of ancillary ligands on chiral U( vi ) centres37Directing dimensionality in uranyl malate and copper uranyl malate compounds15Structural Variations of the First Family of Heterometallic Uranyl Carboxyphosphinate Assemblies by Synergy between Carboxyphosphinate and Imidazole Ligands21Entangled Uranyl Organic Frameworks with (10,3)-b Topology and Polythreading Network: Structure, Luminescence, and Computational Investigation43Exploring Crystal Engineering for Porous Uranyl–Organic Frameworks: Insight into Hydrolysis and In Situ Reaction, Structural Variation‐Dependent Physical Properties6Novel Uranyl Coordination Polymers Based on Quinoline-Containing Dicarboxylate by Altering Auxiliary Ligands: From 1D Chain to 3D Framework31Complexation of Uranyl Ion with Sulfonates: One‐ to Three‐Dimensional Assemblies with 1,5‐ and 2,7‐Naphthalenedisulfonates15Uranyl Complexes as Scaffolding or Spacers for Cucurbit[6]uril Molecules in Homo‐ and Heterometallic Species, Including a Uranyl–Lanthanide Complex13Syntheses, Structures, and Comparisons of Heterometallic Uranyl Iodobenzoates with Monovalent Cations27Complexes of Uranyl Ions with Aromatic Di‐ and Tetracarboxylates Involving [Ni(bipy)n]2+ (n = 2, 3) Counterions12Interpenetrated Uranyl–Organic Frameworks with bor and pts Topology: Structure, Spectroscopy, and Computation40Reversible Single-Crystal-to-Single-Crystal Structural Transformation in a Mixed-Ligand 2D Layered Metal-Organic Framework: Structural Characterization and Sorption Study10Structural Design and Properties of Coordination Polymers4In Situ Reduction from Uranyl Ion into a Tetravalent Uranium Trimer and Hexamer Featuring Ion-Exchange Properties and the Alexandrite Effect16Conformational 2-Fold Interpenetrated Uranyl Supramolecular Isomers Based on (6,3) Sheet Topology: Structure, Luminescence, and Ion Exchange37The sulfonate group as a ligand: a fine balance between hydrogen bonding and metal ion coordination in uranyl ion complexes29Uranyl Compounds Involving a Weakly Bonded Pseudorotaxane Linker: Combined Effect of pH and Competing Ligands on Uranyl Coordination and Speciation33Bipyridine-Directed Syntheses of Uranyl Compounds Containing Semirigid Dicarboxylate Linkers: Diversity and Consistency in Uranyl Speciation28Two uranyl-copper(II) bimetallic coordination polymers containing trans-3,3(pyridyl)acrylic acid: Structural variance through synthetic subtleties9Water de/adsorption associated with single‐crystal‐to‐single‐crystal structural transformation of a series of two‐dimensional metal–organic frameworks, [M(bipy)(C4O4)(H2O)2]·3H2O (M = Mn (1), Fe (2), and Zn (3), and bipy=4,4′‐bipyridine)5A unique uranyl framework containing uranyl pentamers as secondary building units: synthesis, structure, and spectroscopic properties25Zero-, mono- and diperiodic uranyl ion complexes with the diphenate dianion: influences of transition metal ion coordination and differential U VI chelation11Variability of structural motifs in the crystal structure of U( vi ) complexes with p -methoxybenzoic acid3Rare Three-Dimensional Uranyl–Biphenyl-3,3′-disulfonyl-4,4′-dicarboxylate Frameworks: Crystal Structures, Proton Conductivity, and Luminescence28Expanding uranyl dicyanoaurate coordination polymers into the second and third dimensions4CRYSTAL STRUCTURE OF NORFLOXACINIUM AND 2,2′-BIPYRIDYL-1′-IUM 2-THIOBARBITURATES2Introducing Bluish-Green Light-Emitting Diodes (OLEDs) and Tuning Their Color Intensity by Uranium Complexes: Synthesis, Characterization, and Photoluminescence Studies of 8‑Hydroxyquinoline Complexes of Uranium8Varied role of organic carboxylate dizwitterions and anionic donors in mixed-ligand uranyl ion coordination polymers14Syntheses, Crystal Structures, and Properties of Two Dysprosium Coordination Compounds Based on Na2H2L Ligands3Weak, Broken, but Working—Intramolecular Hydrogen Bond in 2,2′-bipyridine4Utilizing Ionic Liquids as Bifunctional Reagents for the Ionothermal Synthesis of Uranyl Compounds13Uranyl-Tc( vii )/Tc( v ) hybrid clusters5Macroscopic Thermosalient Effect in a Thermoresponsive Bimetallic Coordination Polymer with Multicomponent Orderly Organization3

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  1. One- to three-dimensional uranyl–organic assemblies with 3-sulfophthalic and 5-sulfoisophthalic acids

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  2. Syntheses and Structures of a Series of Uranyl Phosphonates and Sulfonates: An Insight into Their Correlations and Discrepancies

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  3. 2,2′‐Bipyridine and 1,10‐Phenanthroline as Coligands or Structure‐Directing Agents in Uranyl–Organic Assemblies with Polycarboxylic Acids

    European Journal of Inorganic Chemistry · 2013-07-05

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  4. The crystal chemistry of uranium carboxylates

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    Thierry Loiseau, Ionut Mihalcea, Natacha Henry, Christophe Volkringer

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  5. Uranyl Coordination Polymers Incorporating η5-Cyclopentadienyliron-Functionalized η6-Phthalate Metalloligands: Syntheses, Structures and Photophysical Properties

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  6. Synthesis, Structures, and Properties of Uranyl Hybrids Constructed by a Variety of Mono- and Polycarboxylic Acids

    Inorganic Chemistry · 2013-10-16

    Weiting Yang, Song Dang, Hao Wang, Tao Tian, Qing‐Jiang Pan, Zhong‐Ming Sun

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  7. Molecular and Polymeric Uranyl and Thorium Complexes with Sulfonate‐Containing Ligands

    European Journal of Inorganic Chemistry · 2013-11-25

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  8. Diverse silver( i ) sulfobenzoate coordination polymers and their recycling property as homogeneous catalyst in oxygenation of sulfide

    RSC Advances · 2014-01-01

    Ai-Qing Ma, Long‐Guan Zhu

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  9. Isolation of a series of uranium organophosphinates

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  10. MOFs of Uranium and the Actinides

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  11. Crystal Chemistry of Uranyl Carboxylate Coordination Networks Obtained in the Presence of Organic Amine Molecules

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  12. Structural Variation within Heterometallic Uranyl Hybrids Based on Flexible Alkyldiphosphonate Ligands

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  13. Postsynthetic Rearrangement/Metalation as a Route to Bimetallic Uranyl Coordination Polymers: Syntheses, Structures, and Luminescence

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  14. In situ syntheses of two viologen(4,4′-bipyridinium)-based cadmium compounds: structures, fluorescence and theoretical investigations

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    Wen‐Tong Chen, Rong‐Hua Hu, Yinfeng Wang, Xian Zhang, Juan Liu

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  15. Synthesis, crystal structure and spectroscopic studies of some organic/inorganic hybrid materials containing isostructural monomeric uranyl complexes bridged by bipyridyl typed ligands

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  16. Incorporation of Cu2+ Ions into Nanotubular Uranyl Diphosphonates

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  17. A new organically templated open-framework uranyl ethylenediphosphonate

    Inorganic Chemistry Communications · 2014-05-24

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  18. CuPYDC Metalloligands and Postsynthetic Rearrangement/Metalation as Routes to Bimetallic Uranyl Containing Hybrid Materials: Syntheses, Structures, and Fluorescence

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  19. Copper(I) and Copper(II) Uranyl Heterometallic Hybrid Materials

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  20. Two new two-dimensional layered uranyl-bearing polycarboxylates from semi-rigid tetracarboxylic acids

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  21. Coordination polymers from 1-D to 3-D assembled from disulfonate ligands: Structures and luminescent properties

    Inorganic Chemistry Communications · 2014-08-28

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  22. The First Family of Actinide Carboxyphosphinates: Two‐ and Three‐Dimensional Uranyl Coordination Polymers

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  23. Use of 2,2-Bipyrimidine for the Preparation of UO22+-3d Diphosphonates

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  24. Incorporating Guest Molecules into Honeycomb Structures Constructed from Uranium(VI)-Polycarboxylates: Structural Diversities and Photocatalytic Activities for the Degradation of Organic Dye

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  25. Combining coordination and supramolecular chemistry to explore uranyl assembly in the solid state

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  26. New Zn(II) Coordination Polymers Constructed from Amino-Alcohols and Aromatic Dicarboxylic Acids: Synthesis, Structure, Photocatalytic Properties, and Solid-State Conversion to ZnO

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  30. Comparison of uranium(VI) and thorium(IV) coordination polymers with p-toluenesulfonic acid

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  31. Heterometallic zinc uranium oxyfluorides incorporating imidazole ligands

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  34. Role of N-Donor Sterics on the Coordination Environment and Dimensionality of Uranyl Thiophenedicarboxylate Coordination Polymers

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  35. Two Uranyl Complexes with Pyromellitic Acid. A Heterometallic Complex with U=O–CuII Interaction

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  36. Uranyl Carboxyphosphonates Derived from Hydrothermal in Situ Ligand Reaction: Syntheses, Structures, and Computational Investigations

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  37. Silver Ion-Mediated Heterometallic Three-Fold Interpenetrating Uranyl–Organic Framework

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  38. Probing the Influence of N‐Donor Capping Ligands on Supramolecular Assembly in Molecular Uranyl Materials

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  39. Anchoring flexible uranyl dicarboxylate chains through stacking interactions of ancillary ligands on chiral U( vi ) centres

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  40. Directing dimensionality in uranyl malate and copper uranyl malate compounds

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  41. Structural Variations of the First Family of Heterometallic Uranyl Carboxyphosphinate Assemblies by Synergy between Carboxyphosphinate and Imidazole Ligands

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  42. Entangled Uranyl Organic Frameworks with (10,3)-b Topology and Polythreading Network: Structure, Luminescence, and Computational Investigation

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  43. Exploring Crystal Engineering for Porous Uranyl–Organic Frameworks: Insight into Hydrolysis and In Situ Reaction, Structural Variation‐Dependent Physical Properties

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  44. Novel Uranyl Coordination Polymers Based on Quinoline-Containing Dicarboxylate by Altering Auxiliary Ligands: From 1D Chain to 3D Framework

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  45. Complexation of Uranyl Ion with Sulfonates: One‐ to Three‐Dimensional Assemblies with 1,5‐ and 2,7‐Naphthalenedisulfonates

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  46. Uranyl Complexes as Scaffolding or Spacers for Cucurbit[6]uril Molecules in Homo‐ and Heterometallic Species, Including a Uranyl–Lanthanide Complex

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  47. Syntheses, Structures, and Comparisons of Heterometallic Uranyl Iodobenzoates with Monovalent Cations

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  48. Complexes of Uranyl Ions with Aromatic Di‐ and Tetracarboxylates Involving [Ni(bipy)n]2+ (n = 2, 3) Counterions

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  49. Interpenetrated Uranyl–Organic Frameworks with bor and pts Topology: Structure, Spectroscopy, and Computation

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  50. Reversible Single-Crystal-to-Single-Crystal Structural Transformation in a Mixed-Ligand 2D Layered Metal-Organic Framework: Structural Characterization and Sorption Study

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