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RESEARCH PAPER · Inorganic Chemistry · 2009

Periodic Trends in Actinide Phosphonates: Divergence and Convergence between Thorium, Uranium, Neptunium, and Plutonium Systems

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Periodic Trends in Actinide Phosphonates: Divergence and Convergence between Thorium, Uranium, Neptunium, and Plutonium SystemsOriginalFurther insights into intermediate- and mixed-valency in neptunium oxoanion compounds: structure and absorption spectroscopy of K2[(NpO2)3B10O16(OH)2(NO3)2]52Hydrothermal Synthesis and Crystal Structures of Actinide Compounds2Synthesis and Characterization of 1‐, 2‐, and 3‐Dimensional Bimetallic UO22+/Zn2+ Phosphonoacetates66USING PHOSPHONATES TO PROBE STRUCTURAL DIFFERENCES BETWEEN TRANSURANIUM ELEMENTS AND THEIR PROPOSED SURROGATES24Crystal chemistry of thorium nitrates and chromates23Cerium(IV), Neptunium(IV), and Plutonium(IV) 1,2-Phenylenediphosphonates: Correlations and Differences between Early Transuranium Elements and Their Proposed Surrogates54From Layered Structures to Cubic Frameworks: Expanding the Structural Diversity of Uranyl Carboxyphosphonates via the Incorporation of Cobalt55Deviation Between the Chemistry of Ce(IV) and Pu(IV) and Routes to Ordered and Disordered Heterobimetallic 4f/5f and 5f/5f Phosphonates50Three-Dimensional Hybrid Framework Containing U2O13 Dimers Connected via Cation–Cation Interactions48Facile Routes to ThIV, UIV, and NpIV Phosphites and Phosphates23Diphosphates and diphosphonates in polyoxometalate chemistry173Barium uranyl diphosphonates16Systematic Evolution from Uranyl(VI) Phosphites to Uranium(IV) Phosphates43Uranium diphosphonates templated by interlayer organic amines22From Order to Disorder and Back Again: In Situ Hydrothermal Redox Reactions of Uranium Phosphites and Phosphates28Ionothermal and Hydrothermal Flux Syntheses of Five New Uranyl Phosphonates43Three New Silver Uranyl Diphosphonates: Structures and Properties23Incorporation of Cu2+ Ions into Nanotubular Uranyl Diphosphonates28Unexpected Structural Complexity in Cesium Thorium Molybdates18Use of 2,2-Bipyrimidine for the Preparation of UO22+-3d Diphosphonates18Probing the Influence of Phosphonate Bonding Modes to Uranium(VI) on Structural Topology and Stability: A Complementary Experimental and Computational Investigation51Effects of Te(IV) Oxo-Anion Incorporation into Thorium Molybdates and Tungstates14Structural chemistry of uranium phosphonates143Structural and spectroscopic characterization of two new layered uranyl(VI) p-xylenediphosphonate compounds synthesized via ionothermal method13Surprising coordination for low-valent actinides resembling uranyl( vi ) in thorium( iv ) organic hybrid layered and framework structures based on a graphene-like (6,3) sheet topology34Monomers, Dimers, and Helices: Complexities of Cerium and Plutonium Phenanthrolinecarboxylates22Flotation-assisted homogeneous liquid–liquid microextraction for determination of thorium in water samples by inductively coupled plasma–mass spectrometry and Box–Behnken design10Two novel thorium organic frameworks constructed by bi- and tritopic ligands1Systematic Investigation of the in Situ Reduction Process from U(VI) to U(IV) in a Phosphonate System under Mild Solvothermal Conditions23Towards the development of chitosan nanoparticles for plutonium pulmonary decorporation10New Uranyl Open Framework and Sheet Compounds Formed via In-Situ Protonation of Piperazine by Phosphorous Acid1Carboxylate- and Phosphonate-Modified Polyethylenimine: Toward the Design of Actinide Decorporation Agents17Actinides12Targeting complex plutonium oxides by combining crystal chemical reasoning with density-functional theory calculations: the quaternary plutonium oxide Cs 2 PuSi 6 O 159The presence of mixed-valent silver in the uranyl phenylenediphosphonate framework5Synthesis of a heterobimetallic actinide nitride and an analysis of its bonding18An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application145Selective electrochemical capture and release of uranyl from aqueous alkali, lanthanide, and actinide mixtures using redox-switchable carboranes18Synthesis and structure of metal-TCPE (metal = Th, Ce) metal-organic frameworks based on 1,2,4,5-tetrakis(4-carboxyphenyl) ethylene3f‐block MOFs: A Pathway to Heterometallic Transuranics29f‐block MOFs: A Pathway to Heterometallic Transuranics1Periodic trends in trivalent actinide halides, phosphates, and arsenates5Americium Oxalate: An Experimental and Computational Investigation of Metal–Ligand Bonding15Molten Flux Synthesis of Plutonium (IV) Silicates K2PuSi2O7 and Rb2PuSi6O151Formation of a new hydrated sodium–thorium phosphate from thorium dioxide and its subsequent phase evolution3Layered metal phosphonates: Structures and properties7Syntheses and characterization of non-molecular phenyl- and methyl-phosphonates and ethylenediphosphonates of thorium and cerium1

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  1. Further insights into intermediate- and mixed-valency in neptunium oxoanion compounds: structure and absorption spectroscopy of K2[(NpO2)3B10O16(OH)2(NO3)2]

    Chemical Communications · 2010-01-01

    Shuao Wang, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

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  2. Hydrothermal Synthesis and Crystal Structures of Actinide Compounds

    Springer eBooks · 2010-01-01

    Wolfgang Runde, Mary P. Neu

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  3. Synthesis and Characterization of 1‐, 2‐, and 3‐Dimensional Bimetallic UO22+/Zn2+ Phosphonoacetates

    European Journal of Inorganic Chemistry · 2010-01-29

    Karah E. Knope, Christopher L. Cahill

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  4. USING PHOSPHONATES TO PROBE STRUCTURAL DIFFERENCES BETWEEN TRANSURANIUM ELEMENTS AND THEIR PROPOSED SURROGATES

    Comments on Inorganic Chemistry · 2010-03-30

    Juan Diwu, Anna‐Gay D. Nelson, Thomas E. Albrecht‐Schmitt

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  5. Crystal chemistry of thorium nitrates and chromates

    Journal of Solid State Chemistry · 2010-05-06

    Ginger E. Sigmon, Peter Carman Burns

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  6. Cerium(IV), Neptunium(IV), and Plutonium(IV) 1,2-Phenylenediphosphonates: Correlations and Differences between Early Transuranium Elements and Their Proposed Surrogates

    Inorganic Chemistry · 2010-10-04

    Juan Diwu, Shuao Wang, Zuolei Liao, Peter Carman Burns, Thomas E. Albrecht‐Schmitt

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  7. From Layered Structures to Cubic Frameworks: Expanding the Structural Diversity of Uranyl Carboxyphosphonates via the Incorporation of Cobalt

    Crystal Growth & Design · 2011-02-08

    A.N. Alsobrook, Brad G. Hauser, Joseph T. Hupp, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

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  8. Deviation Between the Chemistry of Ce(IV) and Pu(IV) and Routes to Ordered and Disordered Heterobimetallic 4f/5f and 5f/5f Phosphonates

    Inorganic Chemistry · 2011-04-25

    Juan Diwu, Shuao Wang, Justin J. Good, V.H. DiStefano, Thomas E. Albrecht‐Schmitt

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  9. Three-Dimensional Hybrid Framework Containing U2O13 Dimers Connected via Cation–Cation Interactions

    Inorganic Chemistry · 2011-08-04

    Rachel C. Severance, Mark D. Smith, Hans‐Conrad zur Loye

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  10. Facile Routes to ThIV, UIV, and NpIV Phosphites and Phosphates

    European Journal of Inorganic Chemistry · 2011-08-05

    Eric M. Villa, Shuao Wang, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

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  11. Diphosphates and diphosphonates in polyoxometalate chemistry

    Chemical Society Reviews · 2012-01-01

    Abhishek Banerjee, Bassem S. Bassil, Gerd‐Volker Röschenthaler, Ulrich Kortz

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  12. Barium uranyl diphosphonates

    Journal of Solid State Chemistry · 2012-04-06

    Anna‐Gay D. Nelson, Evgeny V. Alekseev, Rodney Charles Ewing, Thomas E. Albrecht‐Schmitt

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  13. Systematic Evolution from Uranyl(VI) Phosphites to Uranium(IV) Phosphates

    Inorganic Chemistry · 2012-05-30

    Eric M. Villa, Connor J. Marr, Laurent J. Jouffret, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

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  14. Uranium diphosphonates templated by interlayer organic amines

    Journal of Solid State Chemistry · 2012-10-24

    Anna‐Gay D. Nelson, Evgeny V. Alekseev, Thomas E. Albrecht‐Schmitt, Rodney Charles Ewing

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  15. From Order to Disorder and Back Again: In Situ Hydrothermal Redox Reactions of Uranium Phosphites and Phosphates

    Inorganic Chemistry · 2013-01-09

    Eric M. Villa, Connor J. Marr, Juan Diwu, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

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  16. Ionothermal and Hydrothermal Flux Syntheses of Five New Uranyl Phosphonates

    Crystal Growth & Design · 2013-12-11

    T. Gannon Parker, Justin N. Cross, Matthew J. Polinski, Jian Hung Lin, Thomas E. Albrecht‐Schmitt

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  17. Three New Silver Uranyl Diphosphonates: Structures and Properties

    Inorganic Chemistry · 2014-02-13

    Anna‐Gay D. Nelson, Zsolt Rak, Thomas E. Albrecht‐Schmitt, Udo Becker, Rodney Charles Ewing

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  18. Incorporation of Cu2+ Ions into Nanotubular Uranyl Diphosphonates

    Inorganic Chemistry · 2014-04-04

    Pius O. Adelani, Nathaniel D. Cook, Jean‐Marie Babo, Peter Carman Burns

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  19. Unexpected Structural Complexity in Cesium Thorium Molybdates

    Crystal Growth & Design · 2014-04-16

    Bin Xiao, Jakob Dellen, Hartmut Schlenz, Dirk Bosbach, Evgeny V. Suleimanov, Evgeny V. Alekseev

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  20. Use of 2,2-Bipyrimidine for the Preparation of UO22+-3d Diphosphonates

    Crystal Growth & Design · 2014-10-12

    Pius O. Adelani, Nathaniel D. Cook, Peter Carman Burns

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  21. Probing the Influence of Phosphonate Bonding Modes to Uranium(VI) on Structural Topology and Stability: A Complementary Experimental and Computational Investigation

    Inorganic Chemistry · 2015-03-27

    Tao Zheng, Qun‐Yan Wu, Yang Gao, Daxiang Gui, Shiwen Qiu, Lanhua Chen, Daopeng Sheng, Juan Diwu, Wei‐Qun Shi, Zhifang Chai, Thomas E. Albrecht‐Schmitt, Shuao Wang

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  22. Effects of Te(IV) Oxo-Anion Incorporation into Thorium Molybdates and Tungstates

    Inorganic Chemistry · 2015-05-28

    Bin Xiao, Martina Klinkenberg, Dirk Bosbach, Evgeny V. Suleimanov, Evgeny V. Alekseev

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  23. Structural chemistry of uranium phosphonates

    Coordination Chemistry Reviews · 2015-05-30

    Weiting Yang, T. Gannon Parker, Zhong‐Ming Sun

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  24. Structural and spectroscopic characterization of two new layered uranyl(VI) p-xylenediphosphonate compounds synthesized via ionothermal method

    Inorganica Chimica Acta · 2015-07-04

    Tao Zheng, Yang Gao, Lanhua Chen, Juan Diwu, Zhifang Chai, Thomas E. Albrecht‐Schmitt, Shuao Wang

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  25. Surprising coordination for low-valent actinides resembling uranyl( vi ) in thorium( iv ) organic hybrid layered and framework structures based on a graphene-like (6,3) sheet topology

    Dalton Transactions · 2015-12-08

    Yuxiang Li, Zhehui Weng, Yanlong Wang, Lanhua Chen, Daopeng Sheng, Juan Diwu, Zhifang Chai, Thomas E. Albrecht‐Schmitt, Shuao Wang

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  26. Monomers, Dimers, and Helices: Complexities of Cerium and Plutonium Phenanthrolinecarboxylates

    Inorganic Chemistry · 2016-04-12

    Samantha K. Cary, Maryline G. Ferrier, Ryan Baumbach, Mark A. Silver, Juan S. Lezama-Pacheco, Stosh A. Kozimor, Henry S. La Pierre, Benjamin William Stein, Alexandra A. Arico, Danielle L. Gray, Thomas E. Albrecht‐Schmitt

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  27. Flotation-assisted homogeneous liquid–liquid microextraction for determination of thorium in water samples by inductively coupled plasma–mass spectrometry and Box–Behnken design

    Separation Science and Technology · 2017-01-31

    Somayeh Veyseh, Али Ниази

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  28. Two novel thorium organic frameworks constructed by bi- and tritopic ligands

    Radiochimica Acta · 2017-02-23

    Fei Chen, Cui Wang, Jian‐Hui Lan, Yanqin Ji, Zhifang Chai

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  29. Systematic Investigation of the in Situ Reduction Process from U(VI) to U(IV) in a Phosphonate System under Mild Solvothermal Conditions

    Inorganic Chemistry · 2017-05-26

    Lanhua Chen, Juan Diwu, Daxiang Gui, Yaxing Wang, Zhehui Weng, Zhifang Chai, Thomas E. Albrecht‐Schmitt, Shuao Wang

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  30. Towards the development of chitosan nanoparticles for plutonium pulmonary decorporation

    Dalton Transactions · 2018-01-01

    Laurane Léost, Jérôme Roques, Anne Van der Meeren, Luc Vincent, Nicolas Sbirrazzuoli, Christoph Hennig, A. Roßberg, Jean Aupiais, Sophie Pagnotta, Christophe Den Auwer, Christophe Di Giorgio

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  31. New Uranyl Open Framework and Sheet Compounds Formed via In-Situ Protonation of Piperazine by Phosphorous Acid

    Minerals · 2018-11-01

    Eric M. Villa, Justin N. Cross, Thomas E. Albrecht‐Schmitt

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  32. Carboxylate- and Phosphonate-Modified Polyethylenimine: Toward the Design of Actinide Decorporation Agents

    Inorganic Chemistry · 2019-10-02

    Florian Lahrouch, B. Siberchicot, Jeanne Fèvre, Laurane Léost, Jean Aupiais, Pier Lorenzo Solari, Christophe Den Auwer, Christophe Di Giorgio

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  33. Actinides

    Elsevier eBooks · 2019-12-02

    Sascha T. Löffler, Karsten Meyer

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  34. Targeting complex plutonium oxides by combining crystal chemical reasoning with density-functional theory calculations: the quaternary plutonium oxide Cs 2 PuSi 6 O 15

    Chemical Communications · 2020-01-01

    Kristen A. Pace, Vladislav V. Klepov, Matthew S. Christian, Gregory W. Morrison, Travis K. Deason, Ceren Kütahyalı Aslani, Theodore M. Besmann, David P. DiPrete, Jake Amoroso, Hans‐Conrad zur Loye

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  35. The presence of mixed-valent silver in the uranyl phenylenediphosphonate framework

    New Journal of Chemistry · 2020-01-01

    Ru Bai, Lanhua Chen, Yugang Zhang, Long Chen, Juan Diwu, Xiao‐Feng Wang

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  36. Synthesis of a heterobimetallic actinide nitride and an analysis of its bonding

    Chemical Science · 2021-01-01

    Selena L. Staun, Guang Xin Wu, Wayne W. Lukens, Trevor W. Hayton

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  37. An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application

    Coordination Chemistry Reviews · 2021-07-07

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  38. Selective electrochemical capture and release of uranyl from aqueous alkali, lanthanide, and actinide mixtures using redox-switchable carboranes

    Chemical Science · 2022-01-01

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  39. Synthesis and structure of metal-TCPE (metal = Th, Ce) metal-organic frameworks based on 1,2,4,5-tetrakis(4-carboxyphenyl) ethylene

    Royal Society Open Science · 2022-08-01

    Lin Li, Ting Yu, Zhenghua Qian, Xiaoling Wu, Hui He, Ye Guoan, Yanbo Qiao

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  40. f‐block MOFs: A Pathway to Heterometallic Transuranics

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  41. f‐block MOFs: A Pathway to Heterometallic Transuranics

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  42. Periodic trends in trivalent actinide halides, phosphates, and arsenates

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  43. Americium Oxalate: An Experimental and Computational Investigation of Metal–Ligand Bonding

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  44. Molten Flux Synthesis of Plutonium (IV) Silicates K2PuSi2O7 and Rb2PuSi6O15

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  45. Formation of a new hydrated sodium–thorium phosphate from thorium dioxide and its subsequent phase evolution

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  46. Layered metal phosphonates: Structures and properties

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  47. Syntheses and characterization of non-molecular phenyl- and methyl-phosphonates and ethylenediphosphonates of thorium and cerium

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