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RESEARCH PAPER · Inorganic Chemistry · 2009

Homometallic Uranium(VI) Phosphonoacetates Containing Interlayer Dipyridines

Karah E. Knope, Christopher L. Cahill

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Homometallic Uranium(VI) Phosphonoacetates Containing Interlayer DipyridinesOriginalPhosphonoacetate as a Ligand for Constructing Layered and Framework Alkali Metal Uranyl Compounds45Uranyl Ion Complexation by Cucurbiturils in the Presence of Perrhenic, Phosphoric, or Polycarboxylic Acids. Novel Mixed-Ligand Uranyl−Organic Frameworks79Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: new methods for constructing porous materials113Homometallic UO22+ diphosphonates assembled under ambient and hydrothermal conditions29Uranyl–organic assemblies with the macrocyclic ligand 1,4,8,11-tetraazacyclotetradecane-1,4,8,11-tetraacetate (TETA)34Synthesis and Characterization of 1‐, 2‐, and 3‐Dimensional Bimetallic UO22+/Zn2+ Phosphonoacetates66Rhomboidal Heterometallic Alkynyl Based Pt2Cd2 Clusters: Structural, Photophysical, and Theoretical Studies22Comparison of Thorium(IV) and Uranium(VI) Carboxyphosphonates80Room temperature assembly of a uranyl carboxyphosphonate: Synthesis, characterization and UO22+ hydrolysis34Synthesis, structure and fluorescence properties of a uranyl-2,5-pyridinedicarboxylic acid coordination polymer: The missing member of the UO22+-2,n-pyridinedicarboxylic series34Synthesis, Structure, and Solid-State Transformation Studies of Phosphonoacetate Based Hybrid Compounds of Uranium and Thorium48Uranyl−Organic Assemblies with Acetate-Bearing Phenyl- and Cyclohexyl-Based Ligands45In situ oxalate formation during hydrothermal synthesis of uranyl hybrid materials50Uranyl carboxyphosphonates that incorporate Cd(II)20Layered and Three-Dimensional Framework Cesium and Barium Uranyl Carboxyphenylphosphonates69Heterobimetallic Copper(II) Uranyl Carboxyphenylphosphonates67Coordination Polymers and Frameworks in Uranyl Ion Complexes with Sulfonates and Cucurbit[6]uril32Metal-Controlled Assembly of Uranyl Diphosphonates toward the Design of Functional Uranyl Nanotubules77Uranyl Sensitization of Samarium(III) Luminescence in a Two-Dimensional Coordination Polymer127Syntheses, structures and luminescent properties of two one-dimensional uranium oxyfluorides12Synthesis, crystal structures, and infrared spectroscopy of a series of lanthanide phosphonoacetate coordination polymers9Tailor-Made Zinc Uranyl Diphosphonates from Layered to Framework Structures46The First Uranyl Arsonates Featuring Heterometallic Cation–Cation Interactions with UVI═O–ZnII Bonding40From 1D Chain to 3D Framework Uranyl Diphosphonates: Syntheses, Crystal Structures, and Selective Ion Exchange82Uranium diphosphonates templated by interlayer organic amines22Sulfonate Complexes of Actinide Ions: Structural Diversity in Uranyl Complexes with 2-Sulfobenzoate71One- to three-dimensional uranyl–organic assemblies with 3-sulfophthalic and 5-sulfoisophthalic acids29Syntheses and Structures of a Series of Uranyl Phosphonates and Sulfonates: An Insight into Their Correlations and Discrepancies75Syntheses, structures and luminescent properties of two organic templated uranyl phosphonates18Syntheses and Structures of Uranyl Ethylenediphosphonates: From Layers to Elliptical Nanochannels33Molecular Copper(II) Complexes Derived from Phosphonoacetic Acid: Crystal Structures and Magnetic Behavior82,2′‐Bipyridine and 1,10‐Phenanthroline as Coligands or Structure‐Directing Agents in Uranyl–Organic Assemblies with Polycarboxylic Acids56The crystal chemistry of uranium carboxylates394Uranyl Coordination Polymers Incorporating η5-Cyclopentadienyliron-Functionalized η6-Phthalate Metalloligands: Syntheses, Structures and Photophysical Properties29Synthesis, Structures, and Properties of Uranyl Hybrids Constructed by a Variety of Mono- and Polycarboxylic Acids70Molecular and Polymeric Uranyl and Thorium Complexes with Sulfonate‐Containing Ligands33Isolation of a series of uranium organophosphinates11MOFs of Uranium and the Actinides95Structural Variation within Heterometallic Uranyl Hybrids Based on Flexible Alkyldiphosphonate Ligands40Three New Silver Uranyl Diphosphonates: Structures and Properties23Synthesis and characterization of 1-D uranyl thiodigycolate coordination polymers10The influence of pressure on the structure of a 2D uranium(VI) carboxyphosphonoate compound11UO 2 2+ -amino hybrid materials: structural variation and photocatalysis properties29Design, synthesis and structure of uranyl coordination polymers from 2-D layer to 3-D network structure2A family of uranyl-aromatic dicarboxylate (pht-, ipa-, tpa-) framework hybrid materials: photoluminescence, surface photovoltage and dye adsorption31Ordered Microporous Layered Lanthanide 1,3,5‐Benzenetriphosphonates Pillared with Cationic Organic Molecules8Probing the Influence of Phosphonate Bonding Modes to Uranium(VI) on Structural Topology and Stability: A Complementary Experimental and Computational Investigation51Uranyl-Promoted Peroxide Generation: Synthesis and Characterization of Three Uranyl Peroxo [(UO 2 ) 2 (O 2 )] Complexes42Role of N-Donor Sterics on the Coordination Environment and Dimensionality of Uranyl Thiophenedicarboxylate Coordination Polymers53Structural chemistry of uranium phosphonates143Structural and spectroscopic characterization of two new layered uranyl(VI) p-xylenediphosphonate compounds synthesized via ionothermal method13A Family of Uranyl Coordination Polymers Containing O-Donor Dicarboxylates and Trispyridyltriazine Guests36Novel Uranyl Coordination Polymers Based on Quinoline-Containing Dicarboxylate by Altering Auxiliary Ligands: From 1D Chain to 3D Framework31Photochromic Terbium Phosphonates with Photomodulated Luminescence and Metal Ion Sensitive Detection72Construction of Uranyl Organic Hybrids by Phosphonate and in Situ Generated Carboxyphosphonate Ligands39Reversible solvent-induced transformation of a one-dimensional uranyl coordination polymer using 4,4′-oxybis(benzoate)1A General Model of Sensitized Luminescence in Lanthanide-Based Coordination Polymers and Metal–Organic Framework Materials98Influence of Pyrazine/Piperazine Based Guest Molecules in the Crystal Structures of Uranyl Thiophene Dicarboxylate Coordination Polymers: Structural Diversities and Photocatalytic Activities for the Degradation of Organic Dye47Bipyridine-Directed Syntheses of Uranyl Compounds Containing Semirigid Dicarboxylate Linkers: Diversity and Consistency in Uranyl Speciation28Highly conjugated systems with pedal motion in uranyl crotonate compounds with 1,2-bis(4-pyridyl)ethylene as a neutral ligand or a counter cation3The role of 1-ethyl-3-methylimidazolium diethyl phosphate ionic liquid in uranyl phosphate compounds7Actinides12Photochromism of metal–organic frameworks based on carbazole-dicarboxylic acid and bipyridine: sensing adjustment by controlling strut-to-strut energy transfer9Uranyl phosphonates: crystalline materials and nanosheets for temperature sensing18Chemical and Redox Speciation of Uranyl with Three Environmentally Relevant Bifunctional Chelates: Multi-Technique Approach Combined with Theoretical Estimations14Cation directed formation of uranyl phosphonocarboxylates frameworks comprised of cross-linked chains1Unusual redox stability of pentavalent uranium with hetero-bifunctional phosphonocarboxylate: insight into aqueous speciation9Neptunyl Pyrrophen Complexes: Exploring Schiff Base Chemistry with Multidentate Acyclic Ligands and Transuranics3Mild Hydrothermal Crystal Growth of Two Luminescing Uranyl Phosphates Exhibiting an Autunite-Type Sheet Structure3

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  1. Phosphonoacetate as a Ligand for Constructing Layered and Framework Alkali Metal Uranyl Compounds

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  2. Uranyl Ion Complexation by Cucurbiturils in the Presence of Perrhenic, Phosphoric, or Polycarboxylic Acids. Novel Mixed-Ligand Uranyl−Organic Frameworks

    Crystal Growth & Design · 2009-11-19

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  3. Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: new methods for constructing porous materials

    Chemical Communications · 2010-01-01

    A.N. Alsobrook, Brad G. Hauser, Joseph T. Hupp, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

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  4. Homometallic UO22+ diphosphonates assembled under ambient and hydrothermal conditions

    Dalton Transactions · 2010-01-01

    Karah E. Knope, Christopher L. Cahill

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  5. Uranyl–organic assemblies with the macrocyclic ligand 1,4,8,11-tetraazacyclotetradecane-1,4,8,11-tetraacetate (TETA)

    CrystEngComm · 2010-01-01

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  6. Synthesis and Characterization of 1‐, 2‐, and 3‐Dimensional Bimetallic UO22+/Zn2+ Phosphonoacetates

    European Journal of Inorganic Chemistry · 2010-01-29

    Karah E. Knope, Christopher L. Cahill

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  7. Rhomboidal Heterometallic Alkynyl Based Pt2Cd2 Clusters: Structural, Photophysical, and Theoretical Studies

    Inorganic Chemistry · 2010-04-09

    Jesús Rubén Berenguer, Julio Fernández‐Cestau, Belén Gil, Elena Lalinde, Sergio Sánchez

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  8. Comparison of Thorium(IV) and Uranium(VI) Carboxyphosphonates

    Inorganic Chemistry · 2010-05-13

    Pius O. Adelani, Thomas E. Albrecht‐Schmitt

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  9. Room temperature assembly of a uranyl carboxyphosphonate: Synthesis, characterization and UO22+ hydrolysis

    Inorganic Chemistry Communications · 2010-06-10

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  10. Synthesis, structure and fluorescence properties of a uranyl-2,5-pyridinedicarboxylic acid coordination polymer: The missing member of the UO22+-2,n-pyridinedicarboxylic series

    Inorganic Chemistry Communications · 2010-06-10

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  11. Synthesis, Structure, and Solid-State Transformation Studies of Phosphonoacetate Based Hybrid Compounds of Uranium and Thorium

    Inorganic Chemistry · 2010-07-27

    Padmini Ramaswamy, Ramanath Prabhu, Srinivasan Natarajan

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  12. Uranyl−Organic Assemblies with Acetate-Bearing Phenyl- and Cyclohexyl-Based Ligands

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  13. In situ oxalate formation during hydrothermal synthesis of uranyl hybrid materials

    CrystEngComm · 2011-01-01

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  14. Uranyl carboxyphosphonates that incorporate Cd(II)

    Journal of Solid State Chemistry · 2011-04-14

    A.N. Alsobrook, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

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  15. Layered and Three-Dimensional Framework Cesium and Barium Uranyl Carboxyphenylphosphonates

    Crystal Growth & Design · 2011-05-18

    Pius O. Adelani, Allen G. Oliver, Thomas E. Albrecht‐Schmitt

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  16. Heterobimetallic Copper(II) Uranyl Carboxyphenylphosphonates

    Crystal Growth & Design · 2011-08-30

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  17. Coordination Polymers and Frameworks in Uranyl Ion Complexes with Sulfonates and Cucurbit[6]uril

    Crystal Growth & Design · 2011-10-26

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  18. Metal-Controlled Assembly of Uranyl Diphosphonates toward the Design of Functional Uranyl Nanotubules

    Inorganic Chemistry · 2011-11-03

    Pius O. Adelani, Thomas E. Albrecht‐Schmitt

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  19. Uranyl Sensitization of Samarium(III) Luminescence in a Two-Dimensional Coordination Polymer

    Inorganic Chemistry · 2011-12-15

    Karah E. Knope, Daniel T. de Lill, Clare E. Rowland, Paula M. Cantos, Ana de Bettencourt‐Dias, Christopher L. Cahill

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  20. Syntheses, structures and luminescent properties of two one-dimensional uranium oxyfluorides

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    Hongyue Wu, Xiuyun Yang, Yunhui Li, Weiting Yang

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  21. Synthesis, crystal structures, and infrared spectroscopy of a series of lanthanide phosphonoacetate coordination polymers

    Journal of Coordination Chemistry · 2012-08-02

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  22. Tailor-Made Zinc Uranyl Diphosphonates from Layered to Framework Structures

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  23. The First Uranyl Arsonates Featuring Heterometallic Cation–Cation Interactions with UVI═O–ZnII Bonding

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  24. From 1D Chain to 3D Framework Uranyl Diphosphonates: Syntheses, Crystal Structures, and Selective Ion Exchange

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  25. Uranium diphosphonates templated by interlayer organic amines

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    Anna‐Gay D. Nelson, Evgeny V. Alekseev, Thomas E. Albrecht‐Schmitt, Rodney Charles Ewing

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  26. Sulfonate Complexes of Actinide Ions: Structural Diversity in Uranyl Complexes with 2-Sulfobenzoate

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  27. One- to three-dimensional uranyl–organic assemblies with 3-sulfophthalic and 5-sulfoisophthalic acids

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  28. Syntheses and Structures of a Series of Uranyl Phosphonates and Sulfonates: An Insight into Their Correlations and Discrepancies

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  29. Syntheses, structures and luminescent properties of two organic templated uranyl phosphonates

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  30. Syntheses and Structures of Uranyl Ethylenediphosphonates: From Layers to Elliptical Nanochannels

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  31. Molecular Copper(II) Complexes Derived from Phosphonoacetic Acid: Crystal Structures and Magnetic Behavior

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  32. 2,2′‐Bipyridine and 1,10‐Phenanthroline as Coligands or Structure‐Directing Agents in Uranyl–Organic Assemblies with Polycarboxylic Acids

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  33. The crystal chemistry of uranium carboxylates

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  34. Uranyl Coordination Polymers Incorporating η5-Cyclopentadienyliron-Functionalized η6-Phthalate Metalloligands: Syntheses, Structures and Photophysical Properties

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  35. Synthesis, Structures, and Properties of Uranyl Hybrids Constructed by a Variety of Mono- and Polycarboxylic Acids

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  36. Molecular and Polymeric Uranyl and Thorium Complexes with Sulfonate‐Containing Ligands

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  37. Isolation of a series of uranium organophosphinates

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  38. MOFs of Uranium and the Actinides

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  39. Structural Variation within Heterometallic Uranyl Hybrids Based on Flexible Alkyldiphosphonate Ligands

    Crystal Growth & Design · 2014-02-07

    Weiting Yang, Fei‐Yan Yi, Tao Tian, Wan‐Guo Tian, Zhong‐Ming Sun

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  40. Three New Silver Uranyl Diphosphonates: Structures and Properties

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  41. Synthesis and characterization of 1-D uranyl thiodigycolate coordination polymers

    Polyhedron · 2014-02-20

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  42. The influence of pressure on the structure of a 2D uranium(VI) carboxyphosphonoate compound

    Journal of Solid State Chemistry · 2014-06-09

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  43. UO 2 2+ -amino hybrid materials: structural variation and photocatalysis properties

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  44. Design, synthesis and structure of uranyl coordination polymers from 2-D layer to 3-D network structure

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  45. A family of uranyl-aromatic dicarboxylate (pht-, ipa-, tpa-) framework hybrid materials: photoluminescence, surface photovoltage and dye adsorption

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  46. Ordered Microporous Layered Lanthanide 1,3,5‐Benzenetriphosphonates Pillared with Cationic Organic Molecules

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  47. Probing the Influence of Phosphonate Bonding Modes to Uranium(VI) on Structural Topology and Stability: A Complementary Experimental and Computational Investigation

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  48. Uranyl-Promoted Peroxide Generation: Synthesis and Characterization of Three Uranyl Peroxo [(UO 2 ) 2 (O 2 )] Complexes

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  49. Role of N-Donor Sterics on the Coordination Environment and Dimensionality of Uranyl Thiophenedicarboxylate Coordination Polymers

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  50. Structural chemistry of uranium phosphonates

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