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RESEARCH PAPER · Journal of the American Chemical Society · 2003

[(Th2F5)(NC7H5O4)2(H2O)][NO3]: An Actinide−Organic Open Framework

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[(Th2F5)(NC7H5O4)2(H2O)][NO3]: An Actinide−Organic Open FrameworkOriginal18 Scandium, yttrium, the lanthanides and the actinides11Two-dimensional hydrogen-bonded networks based on bent oxadiazole bridging organic spacers20Syntheses, structures and fluorescent properties of two novel coordination polymers in the U–Cu–H 3 pdc system159(C7H20N2)[(UO2)2(SO4)3(H2O)]: an organically templated uranium sulfate with a novel layer topology18Actinides: Inorganic & Coordination ChemistryBased in part on the article Actinides: Inorganic & Coordination Chemistry by Grigorii L. Soloveichik which appeared in the Encyclopedia of Inorganic Chemistry, First Edition .1Actinides: Inorganic & Coordination ChemistryBased in part on the article Actinides: Inorganic & Coordination Chemistry by Grigorii L. Soloveichik which appeared in the Encyclopedia of Inorganic Chemistry, First Edition .0Synthesis, structure and fluorescent studies of novel uranium coordination polymers in the pyridinedicarboxylic acid system172Extended networks, porous sheets, and chiral frameworks. Thorium materials containing mixed geometry anions: Structures and properties of Th(SeO3)(SeO4), Th(IO3)2(SeO4)(H2O)3·H2O, and Th(CrO4)(IO3)244Largest Mixed Transition Metal/Actinide Cluster: A Bimetallic Mn/Th Complex with a [Mn10Th6O22(OH)2]18+Core18Synthesis and structure of the two-dimensional coordination networks [Ln(PDC)(N-HPDC)]∞ (PDC=pyridine-3,4-dicarboxylate, Ln=La, Ce, Pr)29High-Nuclearity Ce/Mn and Th/Mn Cluster Chemistry: Preparation of Complexes with [Ce4Mn10O10(OMe)6]18+ and [Th6Mn10O22(OH)2]18+ Cores70A Crown Ether as Template for Microporous and Nanostructured Uranium Compounds90A Crown Ether as Template for Microporous and Nanostructured Uranium Compounds11Hydrothermal chemistry of Th(IV) with aromatic dicarboxylates: New framework compounds and in situ ligand syntheses78Spontaneously resolved 3D homochiral In(III) coordination polymer with extended In-OH-In helical chains35Supramolecular networks assembled from binuclear complexes with pyridazine-3,6-dicarboxylate18Synthesis, structure, and characterization of a new thorium–organic framework material, Th3F5[(C10H14)(CH2CO2)2]3(NO3)53TOF-2: A Large 1D Channel Thorium Organic Framework140Highly Porous Polysilsesquioxane Networks via Hydrosilylative Polymerization of Macrocyclic Oligomeric Silsesquioxanes24Spontaneous Assembly of 63 Topological Metal−Organic Nanotubes with Distinct Asymmetric Subunits for the Construction of Hydrophilic Intertube Channels Encapsulating Rare Helical Water-Chains36Synthesis, structures, and photoluminescent properties of 3D lanthanide coordination polymers with rare (4,5)-connected topology133-D Metal−Organic Framework Based on Cationic 2-D Cuprate Layers: Cu3(OH)4[C10H6(SO3)2]27Amine templated two- and three-dimensional uranyl sulfates24Comparison of Thorium(IV) and Uranium(VI) Carboxyphosphonates80Template-assisted self-assembly: Synthesis, structures, and magnetic properties of lanthanide(III)-cobalt(II) coordination complexes constructed with deprotonated 3,5-pyridinedicarboxylic acid ligand28Synthesis, Structure, and Solid-State Transformation Studies of Phosphonoacetate Based Hybrid Compounds of Uranium and Thorium48catena-Poly[thorium(IV)-tetrakis(μ2-3-carboxyadamantane-1-carboxylato)]: a quadruple helical strand driven by a synergy of coordination and hydrogen bonding9Solid State Structure of Thorium(IV) Complexes with Common Aminopolycarboxylate Ligands423-Fold-Interpenetrated Uranium–Organic Frameworks: New Strategy for Rationally Constructing Three-Dimensional Uranyl Organic Materials76A Robust Porous Metal–Organic Framework with a New Topology That Demonstrates Pronounced Porosity and High‐Efficiency Sorption/Selectivity Properties of Small Molecules50DMF/H2O Volume-Ratio-Controlled Assembly of 2D and 3D Ln-MOFs with 5-(Pyridin-4-yl)isophthalic Acid Ligand15Nanomaterials and nanotechnologies in nuclear energy chemistry46Assemblies of several supramolecular networks containing quinoline-2,3-dicarboxylic acid9The crystal chemistry of uranium carboxylates394Isolation of thorium benzoate polytypes with discrete ThO8 square antiprismatic units involved in chain-like assemblies16Crystalline metal-organic frameworks (MOFs): synthesis, structure and function361MOFs of Uranium and the Actinides95Centrosymmetric and chiral porous thorium organic frameworks exhibiting uncommon thorium coordination environments45Supramolecular inclusion-based molecular integral rigidity: a feasible strategy for controlling the structural connectivity of uranyl polyrotaxane networks46Thorium Terephthalates Coordination Polymers Synthesized in Solvothermal DMF/H2O System143Surprising coordination for low-valent actinides resembling uranyl( vi ) in thorium( iv ) organic hybrid layered and framework structures based on a graphene-like (6,3) sheet topology34Construction of metal–organic coordination networks with various metal-linker secondary building units: structures and properties26Synthesis and Crystal Structure Characterization of Thorium Trimesate Coordination Polymers34Inorganic Synthesis of Actinides3Synthesis of Coordination Polymers of Tetravalent Actinides (Uranium and Neptunium) with a Phthalate or Mellitate Ligand in an Aqueous Medium34Two novel thorium organic frameworks constructed by bi- and tritopic ligands1Ligand-Induced Variations in Symmetry and Structural Dimensionality of Lead Oxide Carboxylates14Multifaceted Modularity: A Key for Stepwise Building of Hierarchical Complexity in Actinide Metal–Organic Frameworks127Actinide-based MOFs: a middle ground in solution and solid-state structural motifs110Employing an Unsaturated Th 4+ Site in a Porous Thorium–Organic Framework for Kr/Xe Uptake and Separation152Employing an Unsaturated Th4+ Site in a Porous Thorium–Organic Framework for Kr/Xe Uptake and Separation32Synthesis chemistry of metal-organic frameworks for CO 2 capture and conversion for sustainable energy future124Solution and Solid State Structural Chemistry of Th(IV) and U(IV) 4-Hydroxybenzoates42Hierarchical Materials as Tailored Nuclear Waste Forms: A Perspective123Autoluminescent Metal–Organic Frameworks (MOFs): Self-Photoemission of a Highly Stable Thorium MOF81Time-controlled synthesis of the 3D coordination polymer U(1,2,3-Hbtc) 2 followed by the formation of molecular poly-oxo cluster {U 14 } containing hemimellitate uranium( iv )14High Uptake of ReO 4 − and CO 2 Conversion by a Radiation‐Resistant Thorium–Nickle [Th 48 Ni 6 ] Nanocage‐Based Metal–Organic Framework148High Uptake of ReO4− and CO2 Conversion by a Radiation‐Resistant Thorium–Nickle [Th48Ni6] Nanocage‐Based Metal–Organic Framework21Stabilization of an Unprecedented Hexanuclear Secondary Building Unit in a Thorium-Based Metal–Organic Framework44Synthetic Control of Thorium Polyoxo-Clusters in Metal–Organic Frameworks toward New Thorium-Based Materials40A Thorium Metal‐Organic Framework with Outstanding Thermal and Chemical Stability50A Double-Walled Thorium-Based Metal–Organic Framework as a Promising Dual-Function Absorbent for Efficiently Capturing Iodine and Dyes54Unexpected structural complexity of thorium coordination polymers and polyoxo cluster built from simple formate ligands34From Isolated Molecular Complexes to Extended Networks: Synthesis and Characterization of Thorium Furanmono‐ and Dicarboxylates2The opportunity of metal organic frameworks and covalent organic frameworks in lithium (ion) batteries and fuel cells84Metal–Organic Frameworks Based on Group 3 and 4 Metals140Metal-organic frameworks as a versatile platform for radionuclide management162A cationic thorium–organic framework with triple single-crystal-to-single-crystal transformation peculiarities for ultrasensitive anion recognition29Emergence of a thorium–organic framework as a radiation attenuator for selective X-ray dosimetry20Synthesis of luminescent thorium-based metal–organic frameworks with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene10Successive Crystallization of Organically Templated Uranyl Sulfates: Synthesis and Crystal Structures of [pyH](H3O)[(UO2)3(SO4)4(H2O)2], [pyH]2[(UO2)6(SO4)7(H2O)], and [pyH]2[(UO2)2(SO4)3]3Structural Evolution from Noninterpenetrated to Interpenetrated Thorium–Organic Frameworks Exhibiting High Propyne Storage19An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application145Unveiling the Unique Roles of Metal Coordination and Modulator in the Polymorphism Control of Metal‐Organic Frameworks20State-of-the-art progress for the selective crystallization of actinides, synthesis of actinide compounds and their functionalization20Recent advances in the applications of thorium-based metal–organic frameworks and molecular clusters50Synthesis and structure of metal-TCPE (metal = Th, Ce) metal-organic frameworks based on 1,2,4,5-tetrakis(4-carboxyphenyl) ethylene3Extremely Stable Thorium‐MOF Assembly of Tetraphenylethylene Derivative With Tunable AIE Property and Highly Selective Detection of Nitro Aromatic Compounds28Fabrication of a Cd( ii ) metal–organic framework as a dual functional material: efficient iodine capture and selective adsorption of a cationic dye24Unveiling the Structure–Modulator Relationships in Thorium-Based Metal–Organic Framework Crystallization18Fluoride Clusterfullerenes: Tuning Metal–Metal Bonding and Magnetic Properties via Single Fluorine Atom Doping14Nanostructures and nuclear fuels1Functionalized Thorium‐Based Metal‐Organic Frameworks for the Photocatalytic Oxidation of 1, 5‐Dihydroxynaphthalene1Converging the Complementary Traits of Metal–Organic Frameworks and Covalent Organic Frameworks42A Zn-based MOF with honeycomb topology for highly efficient iodine uptake from vapor and liquid phases: synthesis, crystal structure, topology and dual-phase sorption performance4

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  4. (C7H20N2)[(UO2)2(SO4)3(H2O)]: an organically templated uranium sulfate with a novel layer topology

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  15. Spontaneously resolved 3D homochiral In(III) coordination polymer with extended In-OH-In helical chains

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  17. Synthesis, structure, and characterization of a new thorium–organic framework material, Th3F5[(C10H14)(CH2CO2)2]3(NO3)

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